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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1974

Determination of space vehicle contamination

The contamination and degradation of externally exposed sensitive experimental and functional surfaces of the Skylab by the self-induced atmosphere surrounding the vehicle are studied. It is shown that the major contamination sources of long-term deposits on Skylab are primarily outgassing from nonmetallic coatings and rocket engine exhaust products. Analysis showed that the characteristic decay time of the outgassing source rate may be as long as 4100 hr, and that essentially 20% of RCS deposits that stick at temperatures of 0 C will remain after sublimating at a rate whose characteristic decay time is 72 hr.

Rantanen, R. O.↗

NASA NTRSDate not supplied

Evaluation of Long-Term Storage Stability and Operational Efficiency of Rapid Cycle Amine Adsorbents

With the recent incorporation of Mars Extravehicular Activity (EVA) into the 2025 NASA roadmap, Rapid Cycle Amine (RCA) technology advancement within the Exploration Extravehicular Mobility Unit (xEMU) applies to both the upcoming Lunar Artemis missions and future human exploration of Mars. The incorporation of commercial spacesuit vendors to service NASA’s crewed-space programs since 2021 has increased the demand for regenerable, RCA-based carbon dioxide (CO2) and humidity control adsorbents. The regenerable RCA subunit is the most advanced, long-term solution for CO2 removal and humidity control, enabling both lunar and Martian EVAs. The adsorbent selected for use within the RCA unit must exhibit sufficient storage stability and operational efficiency for prolonged missions. As XploSafe worked to simultaneously develop both a recirculating sub-atmospheric test rig and adsorbents for the RCA system within the xEMU, several novel adsorbents were evaluated for long-term storage stability in support of future extended-duration missions. The chosen materials were periodically evaluated by nuclear magnetic resonance (NMR) spectroscopy, thermal desorption-coupled with gas chromatography/mass spectrometry (TD-GC/MS), and CO2 adsorption to assess long-term storage efficacy across various environmental storage conditions. NMR spectroscopy was utilized by extracting the active CO2 adsorbing chemical from the solid support with deuterated solvent and comparing the spectra over time for degradation and change. The solid adsorbents were also analyzed via TD-GC/MS to reveal any potential off-gassing chemicals over time. Additionally, XploSafe’s breakthrough test rig was utilized to dose the solid adsorbents with a 585 BTU/h metabolic rate flow-equivalent CO2 stream and monitored for 0–99% CO2 breakthrough. The performance metrics from the breakthrough analysis were compared over the storage study duration for CO2 removal and humidity control. Xplo-SA9T was evaluated for 24 months, whereas two additional adsorbent variants, MMPA-Sorbent and LPEI-Sorbent, were each evaluated for 12 months.

John R Tidwell↗

NASA NTRS1971

Long-term aging of elastomers: Chemical stress relaxation of fluorosilicone rubber and other studies

Aerospace applications of elastomers are considered, including: propellant binders, bladder materials for liquid propellant expulsion systems, and fuel tank sealants for high-speed aircraft. A comprehensive molecular theory for mechanical properties of these materials has been developed but has only been tested experimentally in cases where chemical degradation processes are excluded. Hence, a study is being conducted to ascertain the nature, extent, and rate of chemical changes that take place in some elastomers of interest. Chemical changes that may take place in the fluorosilicone elastomer, LS 420, which is regarded as a fuel and high-temperature-resistant rubber are investigated. The kinetic analysis of the chemical stress relaxation and gel permeation chromatography studies comprise the major portion of the report.

Kalfayan, S. H.↗

NASA NTRS1976

Recent advances in the development of composites based on the NCNS resins

The NCNS resins, a new class of addition polymerized polyaromatic melamines, have undergone further development in the past year. Pilot plant quantities of resin NCNS-12M have been made available for evaluation. High solids laminating varnishes were prepared in alcohol/ethyl acetate and alcohol/chlorinated solvent mixtures. The prepregs had sufficient room temperature stability after three month storage to retain good processing characteristics and good bonded mechanical properties. Laminates were fabricated by vacuum bag-autoclave processing and by 5 minute press molding cycles. These laminates had low flame spread and low smoke emitting properties and retained good elevated temperature properties upon long-term oxidative aging. Humidity aging studies were carried out for 30 days at 95% R.H., 120 F. on NCNS/graphite fiber laminates. Initial results indicate that the NCNS resins, particularly those prepared from polymethylene polyphenylamines, are resistant to environmental degradation of elevated temperature mechanical strength.

Kray, R. J.↗

NASA NTRS1975

Interim Report of the Astronomy Spacelab Payloads Study: Ultraviolet and Optical Astronomy - Volume 2

The Space Shuttle will comprise NASA's primary transportation system into near-earth orbit during the 1980s. The Shuttle will provide the astronomical community with a major new capability to send a wide variety of instrumentation into orbit, to utilize it there under manned or automatic control for periods from seven to thirty days, and to return it to the ground. To this end the European Space Research Organization (ESRO) is developing Spacelab, an array of interchangeable components -pressurized manned modules, unpressurized pallets and related support systems - to be mounted in the Shuttle payload bay. Spacelab will offer important opportunities to carry out astronomical research with instruments optimized for specific objectives. With a high flight frequency and with the ability to modify or interchange telescopes and instruments between flights, one will not need to make rigid long-term commitments to specific and compromised telescope/instrument/ detector combinations as is the case for automated satellites. Observational techniques demanding the physical return of data and equipment - in particular the use of photographic film, instruments requiring tight calibration controls, cryogens, high-risk detectors and degradeable optical coatings -will open research areas not readily addressed by automated satellites. Although Shuttle flight duration will be limited to periods from seven to thirty days, substantial data can be obtained with a single instrument on short missions, if targets are carefully selected and prioritized, and a large number of instruments can be accommodated on a single flight. Important astronomical data are regularly obtained on sounding rocket flights of five minutes duration. Spacelab will provide far longer observing periods for large and small telescopes, with resources greatly exceeding those of sounding rockets, while retaining much of the sounding rocket philosophy in terms of instrument flexibility, simplicity, reliability assurance and development costs. The Ultraviolet and Optical Astronomy Program on Spacelab is being planned to provide optical astronomers with relatively simple and regular access to the extended wavelength coverage, the superior image quality and the darkness of the night sky available above the earth's atmosphere. In a rapidly evolving science one cannot predict what problems will be timely in the 1980s. Extrapolating from the current epoch, however, one can envision a continuing interest in such areas as the structure, composition and phenomenology of planetary surfaces and atmospheres; the composition and physical nature of the interstellar medium; the composition, structure and life history of stars, especially those in advanced stages of evolution; the stellar population of other galaxies; such enigmatic phenomena as X-ray binary black holes, pulsars, active galactic nuclei and quasars; large scale interactions between galaxies and the nature of the intergalactic medium; precise calibration of the Hubble law for the expansion of the universe; the average density of the universe; and the existence of extraterrestrial life.

Source record↗

NASA NTRS1978

Long-term weathering effects on the thermal performance of the Lennox/Honeywell (liquid) solar collector

The test procedures used and the results obtained during the evaluation test program of the Lennox/Honeywell double covered liquid solar collector. The tests were performed under simulated conditions, following long-term exposure to natural weathering conditions. The Lennox/Honeywell collector is a flat-plate solar collector. The absorber plate is steel with copper tubes bonded on the upper surface, and is coated with black chrome. Visual inspection of the collector indicated slight discoloration of the absorber plate. Results indicate that performance degradation had occurred. Absorptivity and/or transmissivity decreased as a result of the weathering.

Source record↗

NASA NTRS1978

Environmental effects on composites for aircraft

The influence of the operational environment on the behavior of composite materials and aircraft components fabricated with these composite materials was considered. Structural weight savings, manufacturing cost savings, and long-term environmental durability are among the factors examined. The flight service experience to date of composite components is evaluated. In addition, the influence of a number of worldwide, ground based outdoor exposures on the physical and mechanical properties of six composite materials is discussed. In particular, the current extent of the ultraviolet surface degradation and the moisture gained by diffusion is shown.

Pride, R. A.↗

NASA NTRS1977

Development of the data base for a degradation model of a selenide RTG

The paper is concerned with the evaluation of the materials used in a selenide radioisotope thermoelectric generator (RTG). These materials are composed of n-type gadolinium selenide and n-type copper selenide. A three-fold evaluation approach is being used: (1) the study of the rate of change of the thermal conductivity of the material, (2) the investigation of the long-term stability of the material's Seebeck voltage and electrical resistivity under current and temperature gradient conditions, and (3) determination of the physical behavior and compatibility of the material with surrounding insulation at elevated temperatures. Programmatically, the third category of characteristic evaluation is being emphasized.

Stapfer, G.↗

NASA NTRS1977

Consideration of encapsulants for photovoltaic arrays in terrestrial applications

Long-term survivability of photovoltaic arrays and components in terrestrial environments will require development of adequate protective systems. Highly considered are polymeric encapsulants, a method which was successfully employed in space and aerospace applications to protect critical electrical circuitry. To be employable, however, the polymer encapsulants must themselves be chemically and mechanically resistant to failure in terrestrial service. Chemical resistance includes stability to the degrading actions of ultraviolet light, oxygen, moisture and elevated temperatures in sun rich areas. Programs are underway to identify and develop chemically stable encapsulant candidates. Chemical considerations aside, mechanical failures of the encapsulants must also be avoided in array designs. This paper discusses design considerations for avoiding mechanical failures of polymeric encapsulants, with emphasis on biaxial properties, thermal fatigue, and anisotropy and nonhomogeneity of material properties. The general principles to be presented evolved from actual failures of polymeric materials in engineering applications. Also included are brief remarks on the permeability of polymer materials to atmospheric gases.

Cuddihy, E. F.↗

NASA NTRS1978

Environmental effects on composites for aircraft

A number of ongoing, long-term environmental effects programs for composite materials are evaluated. The flight service experience was evaluated for 142 composite aircraft components after more than 5 years and 1 million successful component flight hours. Ground-based outdoor exposures of composite material coupons after 3 years of exposure at 5 sites have reached equilibrium levels of moisture pickup which are predictable. Solar ultraviolet-induced material loss is discussed for these same exposures. No significant degradation was observed in residual strength for either stressed or unstressed specimens, or for exposures to aviation fuels and fluids.

Pride, R. A.↗

NASA NTRS1978

Interim results of long-term environmental exposures of advanced composites for aircraft applications

Interim results from a number of ongoing, long-term environmental effects programs for composite materials are reported. The flight service experience is evaluated for 142 composite aircraft components after more than five years and one million successful component flight hours. Ground-based outdoor exposures of composite material coupons after 3 years of exposure at five sites have reached equilibrium levels of moisture pickup which are predictable. Solar ultraviolet-induced material loss is discussed for these same exposures. No significant degradation has been observed in residual strength for either stressed or unstressed specimens, or for exposures to aviation fuels and fluids.

Pride, R. A.↗

NASA NTRS1976

Medical experiment M-171 - Results from the second manned Skylab mission

Preflight, inflight, and postflight exercise response tests were conducted on the astronauts of the second Skylab mission as part of an evaluation of physiological adaptation to long-term weightlessness. The flight phase of this mission was 59 days in duration. An exercise protocol was designed around a bicycle ergometer which was used to apply work loads approximating 25, 50, and 75% of each crewman's measured maximum aerobic capacity. Respiratory gas exchange, heart rate, and blood pressure were measured during all tests; cardiac output was measured at selected times during preflight and postflight tests. Data obtained both at rest and during exercise in flight showed no consistent changes which would indicate a degraded physical work capacity. In fact, heart rate during exercise actually decreased for all crewmen in flight. This response indicated improved physical fitness in flight relative to preflight. The postflight period of readaptation to 1 G was characterized by a marked tachycardia, during which time stroke volume was decreased. This response returned to normal within 5-day postflight.

Rummel, J. A.↗

NASA NTRS1977

Long-term storage effects-up-date

The long-term effects of storing batteries over a period of years prior to their use in a synchronous orbit application are discussed. A previous experiment is discussed where life testing was performed on cells after having stored the battery for a period of three years with the cell shorted and at a temperature on the order of 5-10 C. The test consisted of performing a sequence of 10 simulated eclipse seasons (equivalent in cycling of five years in synchronous orbit). Results of this test indicated very little degradation and change in the physical and chemical conditions of the cell. The program was extended for an additional year (battery was stored for four years) under the same conditions and testing. The results of the four year storage (one exception) indicate that no further change occurred that is significant from the three year test.

Scott, W. R.↗

NASA NTRSDate not supplied

Numerical Investigation of Heat Transfer and Fluid Flow within Electrochemical Hydrogen Peroxide Generation Unit

Long-term manned space missions require the onboard production of disinfectants essential for maintaining crew health and supporting life systems. Currently, disinfection aboard the International Space Station (ISS) relies on disposable wetted wipes, which are regularly resupplied from Earth. This approach imposes a significant burden on resupply logistics, storage, and waste management. To address these challenges and support future missions, efforts are underway to develop an in-situ solution that electrochemically generates hydrogen peroxide disinfectant using onboard resources. In collaboration with NASA, Faraday Technology, Inc. has advanced this concept through a series of Small Business Innovation Research (SBIR) projects, resulting in the development of a Peroxide Generation Unit (PGU). The PGU can produce up to 3 wt.% hydrogen peroxide on-demand at a rate of 1 liter per day, providing a sustainable alternative to Earth-dependent supplies. The resulting aqueous hydrogen peroxide (H₂O₂) is an effective disinfectant, safe for crew use, compatible with spacecraft systems, and free from volatiles, off-gassing, or residues. This innovation offers a reliable, efficient solution for onboard disinfection, reducing dependence on Earth-based resupply while ensuring the health and safety of space crews. Generating hydrogen peroxide at the required rate needs high voltages and currents, exceeding 20V and 2A respectively, which leads to significant heat generation from Joule heating. This temperature rise poses a risk to sensitive system components, especially critical and expensive membranes that can degrade under thermal stress. To mitigate this risk, the thermal, fluid, and electrical flows within the system are modeled computationally using the commercial software COMSOL. The numerical simulations are validated against experimental data from both sub-scale and alpha-scale systems. Once verified, the model is employed to identify thermal hotspots, investigate their underlying causes, and explore solutions to prevent them.

Life Support Systems (LSS)↗

NASA NTRS1973

Study of advanced techniques for determining the long term performance of components

The application of existing and new technology to the problem of determining the long-term performance capability of liquid rocket propulsion feed systems is discussed. The long term performance of metal to metal valve seats in a liquid propellant fuel system is stressed. The approaches taken in conducting the analysis are: (1) advancing the technology of characterizing components through the development of new or more sensitive techniques and (2) improving the understanding of the physical of degradation.

Source record↗

NASA NTRS1977

The effects of cockpit environment on long-term pilot performance

A fixed-base helicopter simulator was used to examine pilot performance as influenced by noise, vibration, and fatigue. Subjects flew the simulator for periods ranging between three and eight hours while exposed to vibrations (at 17 Hz) ranging from 0.1 to 0.3 g, and noise stimuli varying between 74 (ambient) and 100 dB. Despite reports of extreme fatigue on these long flights, subject performance did not degrade. Within the limits of this study, performance tended to improve as environmental stress increased. However, subjects did suffer from lapses resulting in abnormally poor performance. These lapses are probably of short duration (seconds) and occur at unpredictable times. If such lapses occur in actual flight, they could provide an explanation for many so-called 'pilot error' accidents.

Stave, A. M.↗

NASA NTRS1979

Long-term weathering effects on the thermal performance of the Libbey-Owens-Ford (liquid) solar collector

Thermal performance tests were conducted on the Libbey-Owens-Ford liquid collector, following long term exposure to natural weathering conditions. Visual inspection of the collector, prior to the retest, indicated noticeable clouding of the inner cover glass, probably resulting from outgassing of the insulation. The absorber plate also showed some discoloration. The test results indicated that performance degradation had occurred at inlet temperatures significantly above ambient. The change in the slope of the efficiency curve, from the original data, is a direct indicator of an increase in the collector heat loss coefficient.

Source record↗

NASA NTRS2026

Mechanical Properties of Carbon Fiber Reinforced Composites Exposed to Cryogenic Conditions and Space Radiation via Simulation and Testing

As NASA missions extend beyond low Earth orbit, increasing reliance is placed on carbon fiber reinforced polymer (CFRP) composites for spacecraft structures where mass efficiency, durability, and long-term reliability are critical. In service, these materials are subjected to a combination of ultraviolet radiation, vacuum, ionizing radiation, atomic oxygen, and extreme thermal excursions under sustained mechanical loading. Flight systems such as the Boeing Starliner and SpaceX Dragon employ external composite structures that will experience these environments for extended durations. Although prior spaceflight and ground studies have reported limited changes in bulk mechanical properties, the synergistic effects of these environments on composite microstructure, particularly at the fiber matrix interphase, remain insufficiently characterized and represent a potential qualification and reliability risk. This study investigates the effects of short-term cryogenic exposure on a radiation shielding carbon epoxy composite, SC2020, as a ground-based analog for space relevant thermal extremes. The SC2020 material system has previously flown on the International Space Station under the Materials International Space Station Experiment (MISSE) program. Composite specimens were exposed to liquid nitrogen for 6 and 24 hours and evaluated using a multiscale characterization framework that combined ASTM D3039 tensile testing, Atomic Force Microscopy (AFM) based interphase analysis, and helium gas permeability measurements. Tensile testing showed no statistically significant or permanent degradation in global strength or modulus following cryogenic exposure. In contrast, AFM measurements revealed reductions in interphase modulus, weakened adhesion, and increased nanoscale heterogeneity, indicating localized degradation mechanisms not captured by conventional bulk testing. Gas permeability measurements showed a progressive increase in helium diffusion with exposure duration, consistent with micro-void formation or partial interfacial debonding. The results indicate that cryogenic exposure initiates degradation at the fiber matrix interphase while leaving global mechanical properties largely unchanged over short durations. These findings underscore the importance of multiscale diagnostics for identifying early-stage damage mechanisms that may influence long term performance and qualification margins for spaceflight composite structures. The data presented establish a cryogenic baseline for comparison with forthcoming MISSE flight exposure results and support ongoing NASA Established Program to Stimulate Competitive Research (EPSCoR) efforts aimed at improving composite qualification methodologies, risk assessment, and reliability prediction for space environments.

composite reliability↗