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Performance and cost of energy transport and storage systems for dish applications using reversible chemical reactions

The use of reversible chemical reactions for energy transport and storage for parabolic dish networks is considered. Performance and cost characteristics are estimated for systems using three reactions (sulfur-trioxide decomposition, steam reforming of methane, and carbon-dioxide reforming of methane). Systems are considered with and without storage, and in several energy-delivery configurations that give different profiles of energy delivered versus temperature. Cost estimates are derived assuming the use of metal components and of advanced ceramics. (The latter reduces the costs by three- to five-fold). The process that led to the selection of the three reactions is described, and the effects of varying temperatures, pressures, and heat exchanger sizes are addressed. A state-of-the-art survey was performed as part of this study. As a result of this survey, it appears that formidable technical risks exist for any attempt to implement the systems analyzed in this study, especially in the area of reactor design and performance. The behavior of all components and complete systems under thermal energy transients is very poorly understood. This study indicates that thermochemical storage systems that store reactants as liquids have efficiencies below 60%, which is in agreement with the findings of earlier investigators.

Schredder, J. M.↗

Development of Augmented Spark Impinging Igniter System for Methane Engines

The Lunar Cargo Transportation and Landing by Soft Touchdown (Lunar CATALYST) program is establishing multiple no-funds-exchanged Space Act Agreement (SAA) partnerships with U.S. private sector entities. The purpose of this program is to encourage the development of robotic lunar landers that can be integrated with U.S. commercial launch capabilities to deliver payloads to the lunar surface. As part of the efforts in Lander Technologies, NASA Marshall Space Flight Center (MSFC) is developing liquid oxygen (LOX) and liquid methane (LCH4) engine technology to share with the Lunar CATALYST partners. Liquid oxygen and liquid methane propellants are attractive owing to their relatively high specific impulse for chemical propulsion systems, modest storage requirements, and adaptability to NASA's Journey to Mars plans. Methane has also been viewed as a possible propellant choice for lunar missions, owing to the performance benefits and as a technology development stepping stone to Martian missions. However, in the development of methane propulsion, methane ignition has historically been viewed as a high risk area in the development of such an engine. A great deal of work has been conducted in the past decade devoted to risk reduction in LOX/CH4 ignition. This paper will review and summarize the history and results of LOX/CH4 ignition programs conducted at NASA. More recently, a NASA-developed Augmented Spark Impinging (ASI) igniter body, which utilizes a conventional spark exciter system, is being tested with LOX/CH4 to help support internal and commercial engine development programs, such as those in Lunar CATALYST. One challenge with spark exciter systems, especially at altitude conditions, is the ignition lead that transmits the high voltage pulse from the exciter to the spark igniter (spark plug). The ignition lead can be prone to corona discharge, reducing the energy delivered by the spark and potentially causing non-ignition events. For the current work, a commercial compact exciter system, which eliminates this high voltage cabling, was tested at altitude conditions. A modified, conventional exciter system with an improved ignition lead was also recently tested at altitude conditions. This test program demonstrated the capability of these exciter systems to operate at altitude. While more extensive testing may be required, these systems or similar ones may be used for future NASA and commercial engine programs.

methane↗

Flight Servicing of Robotic Refueling Mission 3

The Robotic Refueling Mission 3 (RRM3) payload launched aboard a SpaceX rocket en route to the International Space Station on December 5th, 2018. The Goddard Space Flight Center designed payload carried approximately 50 liters of liquid methane onboard, with a mission to demonstrate long term storage and transfer of the cryogenic fluid in microgravity. Kennedy Space Center (KSC) was tasked to design, fabricate, test, and operate a system equipped to fill an RRM3 dewar with liquid methane prior to launch. Though KSC has a rich history of fueling rockets and payloads, no such operations had previously been accomplished using liquid methane. As such, all of the hardware and processes had to be developed from scratch. The completed ground system design, along with the verification and validation testing will be outlined in this paper. Several challenges that were met and overcome during procurement of the high purity methane are described. In addition, budget restrictions prohibited fueling operations from occurring in traditional processing facilities. The unique and creative solutions which were required to maintain payload cleanliness during cryogenic servicing are also detailed.

Cryogenics↗

Flight Servicing of Robotic Refueling Mission 3

The Robotic Refueling Mission 3 (RRM3) payload launched aboard a SpaceX rocket en route to the International Space Station on December 5th, 2018. The Goddard Space Flight Center designed payload carried approximately 50 liters of liquid methane onboard, with a mission to demonstrate long term storage and transfer of the cryogenic fluid in microgravity. Kennedy Space Center (KSC) was tasked to design, fabricate, test, and operate a system equipped to fill an RRM3 dewar with liquid methane prior to launch. Though KSC has a rich history of fueling rockets and payloads, no such operations had previously been accomplished using liquid methane. As such, all of the hardware and processes had to be developed from scratch. The completed ground system design, along with the verification and validation testing will be outlined in this paper. Several challenges that were met and overcome during procurement of the high purity methane are described. In addition, budget restrictions prohibited fueling operations from occurring in traditional processing facilities. The unique and creative solutions which were required to maintain payload cleanliness during cryogenic servicing are also detailed.

Thermal Conductivity↗

Flight Servicing of Robotic Refueling Mission 3

The Robotic Refueling Mission 3 (RRM3) payload launched aboard a SpaceX rocket en route to the International Space Station on December 5th, 2018. The Goddard Space Flight Center designed payload carried approximately 50 liters of liquid methane onboard, with a mission to demonstrate long term storage and transfer of the cryogenic fluid in microgravity. Kennedy Space Center (KSC) was tasked to design, fabricate, test, and operate a system equipped to fill an RRM3 dewar with liquid methane prior to launch. Though KSC has a rich history of fueling rockets and payloads, no such operations had previously been accomplished using liquid methane. As such, all of the hardware and processes had to be developed from scratch. The completed ground system design, along with the verification and validation testing will be outlined in this paper. Several challenges that were met and overcome during procurement of the high purity methane are described. In addition, budget restrictions prohibited fueling operations from occurring in traditional processing facilities. The unique and creative solutions which were required to maintain payload cleanliness during cryogenic servicing are also detailed.

Cryogenics↗

Cryogenic Propellant Densification Study

Ground and vehicle system requirements are evaluated for the use of densified cryogenic propellants in advanced space transportation systems. Propellants studied were slush and triple point liquid hydrogen, triple point liquid oxygen, and slush and triple point liquid methane. Areas of study included propellant production, storage, transfer, vehicle loading and system requirements definition. A savings of approximately 8.2 x 100,000 Kg can be achieved in single stage to orbit gross liftoff weight for a payload of 29,484 Kg by utilizing densified cryogens in place of normal boiling point propellants.

Ewart, R. O.↗

Robotic Refueling Mission 3: Cryogenic Demonstration Subsystem Operations

The Robotic Refueling Mission 3 (RRM3) payload was installed on the International Space Station (ISS) in December 2018. Its Cryogenic Demonstation Subsystem (CDS) was loaded with 19 kilograms of liquid methane, for demonstration of on-orbit storage and transfer. We provide a short description of the design and ground testing of the CDS, and then discuss the on-orbit operations through the first half of 2019.

Cryogenic Fluid Storage↗

An Updated Zero Boil-Off Cryogenic Propellant Storage Analysis Applied to Upper Stages or Depots in a LEO Environment

Previous efforts have shown the analytical benefits of zero boil-off (ZBO) cryogenic propellant storage in launch vehicle upper stages of Mars transfer vehicles for conceptual Mars Missions. However, recent NASA mission investigations have looked at a different and broad array of missions, including a variety of orbit transfer vehicle (OTV) propulsion concepts, some requiring cryogenic storage. For many of the missions, this vehicle will remain for long periods (greater than one week) in low earth orbit (LEO), a relatively warm thermal environment. Under this environment, and with an array of tank sizes and propellants, the performance of a ZBO cryogenic storage system is predicted and compared with a traditional, passive-only storage concept. The results show mass savings over traditional, passive-only cryogenic storage when mission durations are less than one week in LEO for oxygen, two weeks for methane, and roughly 2 months for LH2. Cryogenic xenon saves mass over passive storage almost immediately.

Plachta, David↗

Cryogenic Fluid Storage Technology Development: Recent and Planned Efforts at NASA

Recent technology development work conducted at NASA in the area of Cryogenic Fluid Management (CFM) storage is highlighted, including summary results, key impacts, and ongoing efforts. Thermodynamic vent system (TVS) ground test results are shown for hydrogen, methane, and oxygen. Joule-Thomson (J-T) device tests related to clogging in hydrogen are summarized, along with the absence of clogging in oxygen and methane tests. Confirmation of analytical relations and bonding techniques for broad area cooling (BAC) concepts based on tube-to-tank tests are presented. Results of two-phase lumped-parameter computational fluid dynamic (CFD) models are highlighted, including validation of the model with hydrogen self pressurization test data. These models were used to simulate Altair representative methane and oxygen tanks subjected to 210 days of lunar surface storage. Engineering analysis tools being developed to support system level trades and vehicle propulsion system designs are also cited. Finally, prioritized technology development risks identified for Constellation cryogenic propulsion systems are presented, and future efforts to address those risks are discussed.

Moran, Matthew E.↗

Options for Martian propellant production

A quantitative evaluation methodology for utilizing in-situ resources on Mars for the production of useful substances. The emphasis is on the chemical processes. Various options considering different feedstock (mostly, carbon dioxide, water, and iron oxides) are carefully examined for the product mix and the energy needs. Oxygen, carbon monoxide, alcohols, and other chemicals are the end products. The chemical processes involve electrolysis, methanation, and variations. It is shown that maximizing the product utility is more important than the production of oxygen, methane, or alcohols. An important factor is the storage of the chemicals produced. The product utility is dependent, to some extent, upon the mission. A combination of the stability, the enthalpy of formation, and the mass fraction of the products is seen to yield a fairly good quantitative feel for the overall utility and maximum mission impact.

Dowler, Warren↗

Influence of Microstructure on the Fatigue Crack Growth of A516 in Hydrogen

Some day hydrogen may be used as a viable energy storage and transport medium within the United States. Hydrogen gas may be used to dilute and extend our present methane supply as a blend or may even be used in its pure elemental form as a primary fuel. Independent of the methods of production, storage, and distribution, the interaction of hydrogen with its containment material will play an integral role in the success of a hydrogen energy program. Presently, the selection of hydrogen containment materials can be made such that the material will remain reasonably free from environmental degradation; however, costly alloying additions are required. Unfortunately, high alloy steels are economically prohibitive when large-scale hydrogen energy storage, transmission, and conversion systems are desired. Therefore, in order to implement such hydrogen energy systems in the future, existing low-cost materials must be improved via mechanical, thermal, or thermo-mechanical processing methods or new low-cost materials which are compatible with hydrogen must be developed. Originally, low strength, low alloy steels at room temperature were thought to be immune to hydrogen gas embrittlement, since no sustained load crack growth is observed. However, results of Clark in HY8O and Nelson in SAE 1020 have shown that the fatigue crack growth rate can be greatly accelerated in the presence of hydrogen gas. In recent results reported by Louthan and Mucci, the smooth bar fatigue life of an A1068 pipeline steel was reduced up to a factor of ten when the tests were performed in a 13.8 MPa hydrogen environment. These results suggest that the selection of material for structures designed to operate in hydrogen under cyclic loads must include consideration of hydrogen/metal fatigue interaction. Although the hydrogen/metal fatigue interaction can be severe in low strength low alloy steels, the degree of degradation may be altered by the underlying ferrous microstructure. At present, no correlation between microstructure and degree of hydrogen susceptibility exists for low strength steels. However, in high strength steels, susceptibility to hydrogen embrittlement has been shown to be strongly sensitive to the metallurgical microstructure. In addition, compositional effects and grain size can 703 Some day hydrogen may be used as a viable energy storage and transport medium within the United States. Hydrogen gas may be used to dilute and extend our present methane supply as a blend or may even be used in its pure elemental form as a primary fuel. Independent of the methods of production, storage, and distribution, the interaction of hydrogen with its containment material will play an integral role in the success of a hydrogen energy program. Presently, the selection of hydrogen containment materials can be made such that the material will remain reasonably free from environmental degradation; however, costly alloying additions are required. Unfortunately, high alloy steels are economically prohibitive when large-scale hydrogen energy storage, transmission, and conversion systems are desired. Therefore, in order to implement such hydrogen energy systems in the future, existing low-cost materials must be improved via mechanical, thermal, or thermo-mechanical processing methods or new low-cost materials which are compatible with hydrogen must be developed.

Wachob, Harry F.↗

Development of an 400 L Integrated Refrigeration and Storage Cryostat for LNG/LCH4 Research

Research engineers from the Cryogenics Test Laboratory at NASA Kennedy Space Center in Florida have developed a 400 liter Integrated Refrigeration and Storage (IRAS) cryostat to explore advanced techniques for storage, conditioning, and transfer of liquefied natural gas and/or pure methane. A vertical-cylindrical configuration, the vacuum-jacketed apparatus houses a G-M cryocooler to control the state of the fluid, and sample tubes with corresponding temperature sensors fixed at various elevations to allow for sampling of the liquid. Two additional ports were also included for future instrumentation and/or mechanical feed-throughs. A primary goal of this test apparatus will be to study the effect of IRAS on the behavior of LNG during storage; most notably weathering and stratification of the bulk liquid over time. Additionally, in-situ liquefaction of natural gas can be performed, along with zero boil-off control, liquid densification, and slush production.

Swanger, Adam M.↗

Cold Helium Pressurization for Liquid Oxygen/Liquid Methane Propulsion Systems: Fully-Integrated Hot-Fire Test Results

Hot-fire test demonstrations were successfully conducted using a cold helium pressurization system fully integrated into a liquid oxygen (LOX) / liquid methane (LCH4) propulsion system (Figure 1). Cold helium pressurant storage at near liquid nitrogen (LN2) temperatures (-275 F and colder) and used as a heated tank pressurant provides a substantial density advantage compared to ambient temperature storage. The increased storage density reduces helium pressurant tank size and mass, creating payload increases of ~35% for small lunar-lander sized applications. This degree of mass reduction also enables pressure-fed propulsion systems for human-rated Mars ascent vehicle designs. Hot-fire test results from the highly-instrumented test bed will be used to demonstrate system performance and validate integrated models of the helium and propulsion systems. A pressurization performance metric will also be developed as a means to compare different active pressurization schemes.

Morehead, R. L.↗

LOX/Methane In-Space Propulsion Systems Technology Status and Gaps

Human exploration architecture studies have identified liquid oxygen (LOX)Methane (LCH4) as a strong candidate for both interplanetary and descent ascent propulsion solutions. Significant research efforts into methane propulsion have been conducted for over 50 years, ranging from fundamental combustion mixing efforts to rocket chamber and system level demonstrations. Over the past 15 years NASA and its partners have built upon these early activities that have demonstrated practical components and sub-systems needed to field future methane space transportation elements. These advanced development efforts have formed a foundation of LOXLCH4 propulsion knowledge that has significantly reduced the development risks of future methane based space transportation elements for human exploration beyond earth orbit. As a bipropellant propulsion system, LOXLCH4 has some favorable characteristics for long life and reusability, which are critical to lunar and Mars missions. Non-toxic, non-corrosive, self-venting, and simple to purge. No extensive decontamination process required as with toxic propellants. High vapor pressure provides for excellent vacuum ignition characteristics. Performance is better than current earth storable propellants for human scale spacecraft. Provides the capability for future Mars exploration missions to use propellants that are produced in-situ on Mars Liquid Methane is thermally similar to O2 as a cryogenic propellant, 90,111 K (LO2, LCH4 respectively) instead of the 23 K of LH2. Allows for common components and thus providing cost savings as compared to liquid hydrogen (LH2). Due to liquid methane having a 6x higher density than hydrogen, it can be stored in much smaller volumes. Cryogenic storage aspect of these propellants needs to be addressed. Passive techniques using shielding and orientations to deep space Refrigeration may be required to maintain both oxygen and methane in liquid forms

Propulsion systems↗

A first look at atmospheric dynamics and temperature variations on Titan.

Pollack (1973) has used a radiative equilibrium model to match radiometric data for Titan and infers the atmospheric mass, composition, opacity, and gross vertical thermal structure. These results are used to estimate the atmospheric temperature variations by means of scaling analysis, taking into account dynamics both for a baroclinic wave regime and for an axially symmetric circulation regime. Horizontal temperature variations of the atmosphere and surface are found to be very small, and the circulation is found to be weak and probably axially symmetric. The small temperature variations appear to preclude the storage of volatiles in polar caps, so that the present atmospheric methane content may be due to a balance between outgassing and photodissociation.

Leovy, C. B.↗

Atmospheric In-Situ Resource Utilization For Mars Application

NASA now looks to Mars as the next step in human space exploration. A couple of challenges of such a destination include affordability and weight/volume limitations. As a way to solve these issues NASA is looking into the practice of In-Situ Resource Utilization (ISRU). Instead of manufacturing and bringing all the supplies necessary for a Mars mission and return trip, the goal is to send a preliminary mission to produce reserves of propellant, water, and oxygen on site. Part of this effort includes the Atmospheric Processing Module (APM). The APM is part of a lander that is composed of multiple compartments, each having a unique function; regolith collection/processing, water processing, atmospheric processing, and product storage. The overall goal is to develop the capability to produce methane (CH4) and oxygen as a fuel/oxidizer combo via a Sabatier reaction using resources from the Martian environment. The APM still must undergo modifications in design, and perhaps method, to become flight-ready to produce methane at the level of purity and quantity needed for a vehicle.

isru↗

Assessment of landscape-scale fluxes of carbon dioxide and methane in subtropical coastal wetlands of South Florida

Coastal wetlands play a significant role in the storage of “blue carbon,” indicating their importance in the carbon biogeochemistry in the coastal zone and in global climate change mitigation strategies. We present airborne eddy covariance observations of CO 2 and CH 2 fluxes collected in southern Florida as part of the NASA BlueFlux mission during April 2022, October 2022, February 2023, and April 2023. The flux data generated from this mission consists of over 100 flight hours and more than 6,000 km of horizontal distance over coastal saline and freshwater wetlands. We find that the spatial and temporal heterogeneity in CO 2 and CH 2 exchange is primarily influenced by season, vegetation type, ecosystem productivity, and soil inundation. The largest CO 2 uptake fluxes of more than 20 μmol m -2 s -1 were observed over mangroves during all deployments and over swamp forests during flights in April. The greatest CH 4 effluxes of more than 250 nmol m -2 s -1 were measured at the end of the wet season in October 2022 over freshwater marshes and swamp shrublands. Although the combined Everglades National Park and Big Cypress National Preserve region was a net sink for carbon, CH 4 emissions reduced the ecosystem carbon uptake capacity (net CO 2 exchange rates) by 11%–91%. Average total net carbon exchange rates during the flight periods were −4 to −0.2 g CO 2 -eq m -2 d -1 . Our results highlight the importance of preserving mangrove forests and point to potential avenues of further research for greenhouse gas mitigation strategies.

atmosphere↗

No Need to Wait for the Clean Air Dividend

Controlling smog and soot is the classic win-win situation, so it's great that the world is finally waking up to the idea. WHAT if there was a way to simultaneously slow down climate change, save millions of lives, improve crop yields and contribute to sustainable development and energy security? It sounds too good to be true, but it is possible. It won't be free or easy, but with some effort and moderate investment, it can be done. The way to do it is to reduce emissions leading to two types of pollution: black carbon and ozone. These are the only pollutants that we know contribute to both global warming and poor air quality. Black carbon is essentially soot, emitted from incomplete combustion of fossil fuels and biomass. It warms the climate in two ways: by absorbing heat in the atmosphere - similar to the greenhouse effect - and by reducing Earth's albedo, or ability to reflect sunlight. Inhaled into the lungs, it leads to cancer and cardiovascular disease. Ozone in the atmosphere also acts as a greenhouse gas, while ground-level ozone is toxic to humans and plants, so leads to both premature death and reduced crop yields. Ozone is not emitted directly but is produced by the action of sunlight on other pollutants, which are known as ozone precursors. Since black carbon and ozone are important components of soot and smog, a great deal of effort has already been put into developing methods to reduce emissions. So effective technology is available, but needs wider implementation. The recommended control measures for black carbon include widespread and tight emission standards on diesel cars and trucks; improved solid fuel cooking stoves, brick kilns and coke ovens in the developing world; and a ban on the open burning of agricultural waste. Implementation of these measures would have a rapid impact on the climate and human health, and also have the added benefit of greatly reducing emissions of carbon monoxide, an important ozone precursor. A second key ozone precursor is methane, which is also a powerful greenhouse gas in its own right. Control measures include reducing leaks from natural gas pipelines and storage tanks, and capturing it from coal, gas and oil extraction, landfills and wastewater treatment plants. Aeration of rice paddies and manure management can also reduce methane releases. Captured methane can often be sold or turned into power. In Monterrey, Mexico, for example, electricity generated from methane collected from the city landfill powers the public transportation system. So such measures can be beneficial even when ignoring the health and climate effects, as they can contribute to energy security and often pay for themselves. According to calculations by me and my colleagues, phasing in all these measures over the next 20 years would reduce global warming by about 0.5 degC in 2050, half of the projected increase between now and then (Science, vol 335, p 183). Regional benefits would be even greater, as black carbon disrupts rainfall patterns and magnifies warming and melting of snow and ice in parts of the world including the Arctic and the Himalayas. On top of the climate benefits, cutting black carbon and ozone would prevent over 3 million premature deaths from air pollution, and increase yields of staple crops by roughly 50 million tonnes a year. Improved cooking stoves would also decrease the demand for firewood in the developing world, reducing deforestation and freeing up time for those who collect wood - primarily women and children - to pursue other activities such as education. Similarly, improved brick kilns now being used in parts of Latin America and Asia require half as much fuel as traditional ones and are less time-intensive for the operators. This means that in addition to their environmental benefits, these measures can contribute to sustainable and human development. Tackling black carbon and methane is clearly a great idea, so why hasn't it been done already? There are many barriers. The upfront costs of some measures can be prohibitive even when they eventually pay for themselves. But this can be overcome by mechanisms such as international financing of capital costs. For other measures, the costs are typically borne by a few while the benefits accrue to everybody. In such cases civil society and governments must get involved. Governments are starting to act. In February, the US, Canada, Sweden, Bangladesh, Ghana and Mexico launched the Climate and Clean Air Coalition to support implementation of measures like these. This coalition will hopefully expand and achieve rapid, widespread adoption of measures to cut black carbon and ozone. While the climate benefits will be substantial, it is important to note that these measures cannot substitute for cuts in carbon dioxide. Black carbon, ozone, carbon monoxide and methane stay in the atmosphere for a fairly short time - a few days for black carbon and about a decade for methane. They thus respond quickly to emissions changes and give us substantial leverage over near-term climate change. In contrast, carbon dioxide is very long-lived and so responds slowly to emissions changes. This means that cuts have little immediate impact, but it also means they must be made now to avoid disastrous changes later on. Controlling short-lived climate pollutants is thus an issue of fairness. Much as failure to reduce carbon dioxide emissions soon would condemn future generations to disastrous change, failure to reduce near-term climate change condemns those alive today to suffer worsening effects of the sort already seen. Some wonder if we really can do both. We can, and we must.

Shindell, Drew↗