Search NASA⌕ Search

SEARCH · Search NASA

Results for “Optical Properties Polarization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

CosTuuM: Polarized Thermal Dust Emission by Magnetically Oriented Spheroidal Grains

We present the new open-source C++-based Python library CosTuuM that can be used to generate infrared absorption and emission coefficients for arbitrary mixtures of spheroidal dust grains that are (partially) aligned with a magnetic field. We outline the algorithms underlying the software, demonstrate the accuracy of our results using benchmarks from literature, and use our tool to investigate some commonly used approximative recipes. We find that the linear polarization fraction for a partially aligned dust grain mixture can be accurately represented by an appropriate linear combination of perfectly aligned grains and grains that are randomly oriented, but that the commonly used picket fence alignment breaks down for short wavelengths. We also find that for a fixed dust grain size, the absorption coefficients and linear polarization fraction for a realistic mixture of grains with various shapes cannot both be accurately represented by a single representative grain with a fixed shape, but that instead an average over an appropriate shape distribution should be used. Insufficient knowledge of an appropriate shape distribution is the main obstacle in obtaining accurate optical properties. CosTuuM is available as a standalone Python library and can be used to generate optical properties to be used in radiative transfer applications.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Spectra-Orthogonal Optical Anisotropy in Wafer-Scale Molecular Crystal Monolayers

Controlling the spectral and polarization response of two-dimensional (2D) crystals is vital for developing ultrathin platforms for compact optoelectronic devices. However, independently tuning optical anisotropy and spectral response remains challenging in conventional semiconductors due to the intertwined nature of their lattice and electronic structures. Here, we report spectra-orthogonal optical anisotropy─where polarization anisotropy is tuned independently of spectral response─in wafer-scale, one-atom-thick 2D molecular crystal (2DMC) monolayers synthesized on monolayer transition-metal dichalcogenide (TMD) crystals. Utilizing the concomitant spectral consistency and structural tunability of perylene derivatives, we demonstrate tunable optical polarization anisotropy in 2DMCs with similar spectral profiles, as confirmed by room-temperature scanning tunneling microscopy and cross-polarized reflectance microscopy. Additional angle-dependent analysis of the single-crystal and polycrystalline molecular domains reveals an epitaxial relationship between the 2DMC and TMD. In conclusion, our results establish a scalable, molecule-based 2D crystalline platform for unique and tunable functionalities unattainable in covalent 2D solids.

2D materials↗
DOE OSTI2022

Pd and octahedra do not get along: Square planar [PdS 4 ] units in non-centrosymmetric La 6 PdSi 2 S 14

Non-linear optical (NLO) materials require a balance of high second-harmonic generation (SHG) signal and laser damage threshold (LDT), as well as phase matchable behavior. Herein, we report a new member of the (RE) 6 (TM) x (Tt) 2 Q 14 family of compounds, La 6 PdSi 2 S 14 , which, unlike all other reported TM analogues crystallizing in hexagonal P6 3 space group, crystallizes in the non-centrosymmetric monoclinic P2 1 space group. The crystal structure contains chains of edge-sharing distorted square planar [PdS 4 ] units. The square-planar coordination of Pd in La 6 PdSi 2 S 14 exhibits remarkable NLO properties with high SHG (3.7 × AgGaS 2 ) and LDT (3 × AgGaS 2 ) values as well as phase matchability. This shows the promise of novel materials with distorted structural motifs for enhanced NLO properties. Further, upon formation of bimetallic chiral sulfides containing both Cu and Pd, Cu occupies the opposite faces of the octahedra forming [CuS 3 ] units while Pd can be stabilized in the center of PdS 6 octahedra in the hexagonal P6 3 crystal structure of La 6 Pd 0.5 CuSi 2 S 14 . This suggests that it is possible to form mixed metal systems which could further enhance NLO properties by incorporation of additional structural distortions.

36 MATERIALS SCIENCE↗
NASA NTRS1989

Planar Poincare chart - A planar graphic representation of the state of light polarization

The planar Poincare chart, which represents the complete planar equivalence of the Poincare sphere, is proposed. The four sets of basic lines are drawn on two separate charts for the generalization and convenience of reading the scale. The chart indicates the rotation of the principal axes of linear birefringent material. The relationships between parameters of the two charts are given as 2xi-2phi (orientation angle of the major axis-ellipticity angle) pair and 2alpha-delta (angle of amplitude ratio-phase difference angle) pair. The results are useful for designing and analyzing polarization properties of optical components with birefringent properties.

Tedjojuwono, Ken K.↗
NASA NTRS1977

Measured backscatter and attenuation properties, including polarization effects, of various dispersions at 0.9 micron

The optical properties of a wide variety of atmospheric dispersions were studied using a 0.9-micron lidar system which included a GaAs laser stack transmitter emitting a horizontally polarized beam of 4 milliradians vertical divergence and 1.5 milliradians horizontal divergence. A principal means for assessing optical properties was the polarization ratio, that is, the backscattered radiation power perpendicular to the transmitter beam divided by the backscattered radiation power parallel to the beam polarization. The ratio of the backscattered fraction to the attenuation coefficient was also determined. Data on the dispersion properties of black carbon smoke, road dust, fog, fair-weather cumulus clouds, snow and rain were obtained; the adverse effects of sunlight-induced background noise on the readings is also discussed.

Kohl, R. H.↗
DOE OSTI2024

Momentum-Space Observation of Optically Excited Nonthermal Electrons in Graphene with Persistent Pseudospin Polarization

The unique optical properties of graphene, with broadband absorption and ultrafast response, make it a critical component of optoelectronic and spintronic devices. Using time-resolved momentum microscopy with high data rate and high dynamic range, we report momentum-space measurements of electrons promoted to the graphene conduction band with visible light and their subsequent relaxation. Here, we observe a pronounced nonthermal distribution of nascent photoexcited electrons with lattice pseudospin polarization in remarkable agreement with results of simple tight-binding theory. By varying the excitation fluence, we vary the relative importance of electron-electron vs electron-phonon scattering in the relaxation of the initial distribution. Increasing the excitation fluence results in increased noncollinear electron-electron scattering and reduced pseudospin polarization, although up-scattered electrons retain a degree of polarization. These detailed momentum-resolved electron dynamics in graphene demonstrate the capabilities of high-performance time-resolved momentum microscopy in the study of 2D materials and can inform the design of graphene devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2016

Polarized Light Microscopy

Polarized light microscopy (PLM) is a technique which employs the use of polarizing filters to obtain substantial optical property information about the material which is being observed. This information can be combined with other microscopy techniques to confirm or elucidate the identity of an unknown material, determine whether a particular contaminant is present (as with asbestos analysis), or to provide important information that can be used to refine a manufacturing or chemical process. PLM was the major microscopy technique in use for identification of materials for nearly a century since its introduction in 1834 by William Fox Talbot, as other techniques such as SEM (Scanning Electron Microscopy), FTIR (Fourier Transform Infrared spectroscopy), XPD (X-ray Powder Diffraction), and TEM (Transmission Electron Microscopy) had not yet been developed. Today, it is still the only technique approved by the Environmental Protection Agency (EPA) for asbestos analysis, and is often the technique first applied for identification of unknown materials. PLM uses different configurations in order to determine different material properties. With each configuration additional clues can be gathered, leading to a conclusion of material identity. With no polarizing filter, the microscope can be used just as a stereo optical microscope, and view qualities such as morphology, size, and number of phases. With a single polarizing filter (single polars), additional properties can be established, such as pleochroism, individual refractive indices, and dispersion staining. With two polarizing filters (crossed polars), even more can be deduced: isotropy vs. anisotropy, extinction angle, birefringence/degree of birefringence, sign of elongation, and anomalous polarization colors, among others. With the use of PLM many of these properties can be determined in a matter of seconds, even for those who are not highly trained. McCrone, a leader in the field of polarized light microscopy, often advised, If you cant determine a specific optical property of a particle after two minutes, move onto another configuration. Since optical properties can be seen so very quickly and easily under polarized light, it is only necessary to spend a maximum of two minutes on a technique to determine a particular property, though often only a few seconds are required.

Engineering↗
DOE OSTI2020

Strong crystal field splitting and polarization dependence observed in the emission from Eu3+ ions doped into GaN

Eu-doped GaN is a promising material with a wide array of potential applications in optoelectronics, optogenetics, micro displays and quantum computing. While this system has been the subject of intense investigation for the last two decades, several questions still remain about certain aspects of its optical properties, such as the polarization dependence of the optical transitions, and the coupling between the 4f-electron configuration and bulk phonons, as well and the appearance of local phonon modes. Moreover, the origin of certain emission peaks remains under debate in the literature. In this proceeding, the results of a systematic series of “site-selective” photoluminescence measurements are presented, where the properties of pulsed and continuous-wave laser excitation, such as polarization and intensity, were controlled.

Copelman, S↗
NASA NTRS1994

The synchrotron continuum of the highly polarized quasar PKS 1546+027

The wavelength dependence of optical linear polarization of the highly polarized quasar (HPQ) PKS 1546+027 is investigated for the first time. Both spectropolarimetry and broad-band filter polarimetry are presented for a period when the object was undergoing a strong ourburst in flux and polarization. The rapid polarization variations observed argues that an optically thin synchrotron-emitting region, similar in polarization properties to BL Lacertae objects and optically violent variable (OVV) quasars, is the major source of polarized flux from this object. The continuum polarization increases dramatically with wavelength and is about twice as high at 8000 A than at 4000 A. Spectropolarimetry reveals that the emission-line flux from PKS 1546+027 dilutes the continuum polarization and is probably unpolarized. There is no evidence for any variation in polarization position angle with wavelength. The polarized flux spectrum is well-represented by a steep power law with a spectral index of -2.2, supporting the view that the polarized flux has a nonthermal origin. The observed polarization properties of PKS 1546+027 are consistent with a model that has been proposed to explain the optical to ultraviolet continua of several OVVs. In this model the optical to near-UV spectral flux distribution is a combination of light from a polarized synchrotron component plus an unpolarized component with spectral properties typical of low-polarization quasars.

Smith, Paul S.↗
NASA NTRS2019

Retrieval of Liquid Water Cloud Properties from POLDER-3 Measurements Using a Neural Network Ensemble Approach

This paper describes a neural network algorithm for the estimation of liquid water cloud optical properties from the Polarization and Directionality of Earth's Reflectances-3 (POLDER-3) instrument aboard the Polarization & Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar (PARASOL) satellite. The algorithm has been trained on synthetic multi-angle, multi-wavelength measurements of reflectance and polarization and has been applied to the processing of 1 year of POLDER-3 data. Comparisons of the retrieved cloud properties with Moderate Resolution Imaging Spectroradiometer (MODIS) products show that the neural network algorithm has a low bias of around 2 in cloud optical thickness (COT) and between 1 and 2µm in the cloud effective radius. Comparisons with existing POLDER-3 datasets suggest that the proposed scheme may have enhanced capabilities for cloud effective radius retrieval, at least over land. An additional feature of the presented algorithm is that it provides COT and effective radius retrievals at the native POLDER-3 Level 1B pixel level.

Di Noia, Antonio↗
NASA NTRS2008

Gold Nanoparticle Labels Amplify Ellipsometric Signals

The ellipsometric method reported in the immediately preceding article was developed in conjunction with a method of using gold nanoparticles as labels on biomolecules that one seeks to detect. The purpose of the labeling is to exploit the optical properties of the gold nanoparticles in order to amplify the measurable ellipsometric effects and thereby to enable ultrasensitive detection of the labeled biomolecules without need to develop more-complex ellipsometric instrumentation. The colorimetric, polarization, light-scattering, and other optical properties of nanoparticles depend on their sizes and shapes. In the present method, these size-and-shape-dependent properties are used to magnify the polarization of scattered light and the diattenuation and retardance of signals derived from ellipsometry. The size-and-shape-dependent optical properties of the nanoparticles make it possible to interrogate the nanoparticles by use of light of various wavelengths, as appropriate, to optimally detect particles of a specific type at high sensitivity. Hence, by incorporating gold nanoparticles bound to biomolecules as primary or secondary labels, the performance of ellipsometry as a means of detecting the biomolecules can be improved. The use of gold nanoparticles as labels in ellipsometry has been found to afford sensitivity that equals or exceeds the sensitivity achieved by use of fluorescence-based methods. Potential applications for ellipsometric detection of gold nanoparticle-labeled biomolecules include monitoring molecules of interest in biological samples, in-vitro diagnostics, process monitoring, general environmental monitoring, and detection of biohazards.

Venkatasubbarao, Srivatsa↗
DOE OSTI2021

Particle dynamics and geometric optics in Chern–Simons black holes

Highlights: • Black holes in Chern–Simons modified gravity have been studied. • The effects of the coupling constant of the Chern–Simons gravity on some physical quantities have been investigated. • The dependence of Hawking mass and Penrose process on the coupling constant is studied. • Rotation of the polarization vector is also studied for dependence on the Chern–Simons coupling constant. In this paper we study the effects of the coupling constant of the Chern–Simons modified gravity on some physical properties of black holes. The Hawking mass is one of the proposed definitions of quasilocal mass. We find that, for slowly rotating Chern–Simons black holes, the Hawking mass is independent of the coupling constant. Next, we show the dependence on the centre of mass energy, for two neutral colliding particles, of coupling constant and the rotation parameter. We also investigate energy extraction through Penrose process and find that the energy gain and efficiency of the Penrose process are independent of this coupling constant. Rotation of the polarization vector is also studied for dependence on the Chern–Simons coupling constant.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2020

Neural Network Reflectance Prediction Model for Both Open Ocean and Coastal Waters

Remote sensing of global ocean color is a valuable tool for understanding the ecology and biogeochemistry of the worlds oceans, and provides critical input to our knowledge of the global carbon cycle and the impacts of climate change. Ocean polarized reflectance contains information about the constituents of the upper ocean euphotic zone, such as colored dissolved organic matter (CDOM), sediments, phytoplankton, and pollutants. In order to retrieve the information on these constituents, remote sensing algorithms typically rely on radiative transfer models to interpret water color or remote-sensing reflectance; however, this can be resource-prohibitive for operational use due to the extensive CPU time involved in radiative transfer solutions. In this work, we report a fast model based on machine learning techniques, called Neural Network Reflectance Prediction Model (NNRPM), which can be used to predict ocean bidirectional polarized reflectance given inherent optical properties of ocean waters. This supervised model is trained using a large volume of data derived from radiative transfer simulations for coupled atmosphere and ocean systems using the successive order of scattering technique (SOS-CAOS). The performance of the model is validated against another large independent test dataset generated from SOS-CAOS. The model is able to predict both polarized and unpolarized reflectances with an absolute error (AE) less than 0.004 for 99% of test cases. We have also shown that the degree of linear polarization (DoLP) for unpolarized incident light can be predicted with an AE less than 0.002 for 99% of test cases. In general, the simulation time of SOS-CAOS depends on optical depth, and required accuracy. When comparing the average speeds of the NNRPM against the SOS-CAOS model for the same parameters, we see that the NNRPM is able to predict the Ocean BRDF 6000 times faster than SOS-CAOS. Both ultraviolet and visible wavelengths are included in the model to help differentiate between dissolved organic material and chlorophyll in the study of the open ocean and the coastal zone. The incorporation of this model into the retrieval algorithm will make the retrieval process more efficient, and thus applicable for operational use with global satellite observations.

radiative transfer↗
NASA NTRS2021

Analysis of simultaneous aerosol and ocean glint retrieval using multi-angle observations

Since early 2000, NASA's Multi-angle Imaging SpectroRadiometer (MISR) instrument has been performing remote sensing retrievals of aerosol optical properties from the polar-orbiting Terra spacecraft. A noteworthy aspect of MISR observations over the ocean is that, for much of the Earth, some of the multi-angle views have contributions from solar reflection by the ocean surface (glint, or glitter), while others do not. Aerosol retrieval algorithms often discard these glint-influenced observations because they can overwhelm the signal and are difficult to predict without knowledge of the (wind-speed-driven) ocean surface roughness. However, theoretical studies have shown that multi-angle observations of a location at geometries with and without reflected sun glint can be a rich source of information, sufficient to support simultaneous retrieval of both the aerosol state and the wind speed at the ocean surface. We are in the early stages of creating such an algorithm. In this paper, we describe our assessment of the appropriate level of parameterization for simultaneous aerosol and ocean surface property retrievals using sun glint. For this purpose, we use generalized nonlinear retrieval analysis (GENRA), an information content assessment (ICA) technique employing Bayesian inference, and simulations from the Ahmad–Fraser iterative radiative transfer code. We find that four parameters are suitable: aerosol optical depth (τ), particle size distribution (expressed as the fine mode fraction f of small particles in a bimodal size distribution), surface wind speed (w), and relative humidity (r, to define the aerosol water content and complex refractive index). None of these parameters define ocean optical properties, as we found that the aerosol state could be retrieved with the nine MISR near-infrared views alone, where the ocean body is strongly absorbing in the open ocean. We also found that retrieval capability varies with observation geometry and that as τ increases so does the ability to determine aerosol intensive optical properties (r and f, while it decreases for w). Increases in w decrease the ability to determine the true value of that parameter but have minimal impact on retrieval of aerosol properties. We explored the benefit of excluding the two most extreme MISR view angles for which radiative transfer with the plane-parallel approximation is less certain, but we found no advantage in doing so. Finally, the impact of treating wind speed as a scalar parameter, rather than as a two-parameter directional wind, was tested. While the simpler scalar model does contribute to overall aerosol uncertainty, it is not sufficiently large to justify the addition of another dimension to parameter space. An algorithm designed upon these principles is in development. It will be used to perform an atmospheric correction with MISR for coincident ocean color (OC) observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument, also on the NASA Terra spacecraft. Unlike MISR, MODIS is a single-view-angle instrument, but it has a more complete set of spectral channels ideal for determination of optical ocean properties. The atmospheric correction of MODIS OC data can therefore benefit from MISR aerosol retrievals. Furthermore, higher-spatial-resolution data from coincident MISR observations may also improve glint screening.

Kirk Knobelspiesse↗
NASA NTRS1996

Ocean observations with EOS/MODIS: Algorithm development and post launch studies

Several significant accomplishments were made during the present reporting period. We have completed our basic study of using the 1.38 micron MODIS band for removal of the effects of thin cirrus clouds and stratospheric aerosol. The results suggest that it should be possible to correct imagery for thin cirrus clouds with optical thicknesses as large as 0.5 to 1.0. We have also acquired reflectance data for oceanic whitecaps during a cruise on the RV Malcolm Baldrige in the Gulf of Mexico. The reflectance spectrum of whitecaps was found to be similar to that for breaking waves in the surf zone measured by Frouin, Schwindling and Deschamps. We installed a CIMEL sun photometer at Fort Jefferson on the Dry Tortugas off Key West in the Gulf of Mexico. The instrument has yielded a continuous stream of data since February. It shows that the aerosol optical thickness at 669 nm is often less than 0.1 in winter. This suggests that the Southern Gulf of Mexico will be an excellent winter site for vicarious calibration. In addition, we completed a study of the effect of vicarious calibration, i.e., the accuracy with which the radiance at the top of the atmosphere (TOA) can be predicted from measurement of the sky radiance at the bottom of the atmosphere (BOA). The results suggest that the neglect of polarization in the aerosol optical property inversion algorithm and in the prediction code for the TOA radiances is the largest error associated with the radiative transfer process. Overall, the study showed that the accuracy of the TOA radiance prediction is now limited by the racliometric calibration error in the sky radiometer. Finally, considerable coccolith light scattering data were obtained in the Gulf of Maine with a flow-through instrument, along with data relating to calcite concentration and the rate of calcite production.

Gordan, Howard R.↗
NASA NTRS2012

Mirror coatings with atomic layer deposition : initial results

The new technology of Atomic Layer Deposition (ALD) holds promise to enable a future strategic mission that can address both ultraviolet (UV) astrophysics and optical exoplanet science with a shared telescope. The technology path to a shared telescope requires the development of a mirror coating with high reflectance from 100 nm to 1000 nm, and low polarization effects (i.e., s-p phase shifts that can vary with angle of incidence across a primary and secondary mirror) in the optical range. Currently, UV coatings have low reflectance, and conventional optical coatings have poor polarization properties for high-contrast coronagraph applications. In this paper we attempt to take a first step toward solving both problems simultaneously by using ALD, taking advantage of the fact that ALD can potentially produce mirror coatings with denser layers than conventional coatings (hence better reflectance, durability, and water resistance). In addition, ALD can potentially produce coatings with new composite materials (hence better control of polarization). We report here the results of our initial experiments with mirror coatings using ALD.

Traub, Wesley↗
NASA NTRS2010

Polarization Imaging Apparatus

A polarization imaging apparatus has shown promise as a prototype of instruments for medical imaging with contrast greater than that achievable by use of non-polarized light. The underlying principles of design and operation are derived from observations that light interacts with tissue ultrastructures that affect reflectance, scattering, absorption, and polarization of light. The apparatus utilizes high-speed electro-optical components for generating light properties and acquiring polarization images through aligned polarizers. These components include phase retarders made of OptoCeramic (registered TradeMark) material - a ceramic that has a high electro-optical coefficient. The apparatus includes a computer running a program that implements a novel algorithm for controlling the phase retarders, capturing image data, and computing the Stokes polarization images. Potential applications include imaging of superficial cancers and other skin lesions, early detection of diseased cells, and microscopic analysis of tissues. The high imaging speed of this apparatus could be beneficial for observing live cells or tissues, and could enable rapid identification of moving targets in astronomy and national defense. The apparatus could also be used as an analysis tool in material research and industrial processing.

Zou, Yingyin K.↗