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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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One of the principal roles of the ocean in the global heat balance is storage of heat, which moderates seasonal extremes and leads to the contrast between ocean and continent temperatures.
The DEMO-FTES project sought to demonstrate the thermal efficiency of fracture thermal energy storage (FTES) through numerical simulations, laboratory and meso-scale field tests. A detailed dimensional and scaling analysis was performed to identify key parameters and how they can be most effectively scaled to the laboratory and decameter scale. Numerical models were developed and used for three purposes: 1. Before field experiments, numerical modelling can be used to estimate fracture properties based on previous data from the EGS Collab experiment and then predict thermal hydrological behaviors of the fracture system with hot water injection/withdrawal, therefore, help to design the experiments (e.g., to decide the duration of the cycles based on the flow rate the pump can provide, and the estimated fracture properties); 2. After the field experiment, to estimate the system properties during the experiment (as the size and shape of a fracture could change over time), and understand why system performance is different than what has been predicted, i.e., to help understand the meso-scale test; and, 3. To model the lab experiments and estimate fracture properties and storage efficiency. Ultimately, the experiment and numerical models could shed light on the processes and uncertainty happening during fracture activation and help understand the scaling between lab and field test, and finally, the design and optimization of potential fracture thermal energy storage systems.
Progress and remaining difficulties in the construction of predictive mathematical models of large bodies of water as ecosystems are reviewed. Surface temperature is at present the only variable than can be measured accurately and reliably by remote sensing techniques, but satellite infrared data are of sufficient resolution for macro-scale modeling of oceans and large lakes, and airborne radiometers are useful in meso-scale analysis (of lakes, bays, and thermal plumes). Finite-element and finite-difference techniques applied to the solution of relevant coupled time-dependent nonlinear partial differential equations are compared, and the specific problem of the Biscayne Bay and environs ecosystem is tackled in a finite-differences treatment using the rigid-lid model and a rigid-line grid system.
This report presents development of a new meso-scale geomechanics capability using an 8.84-m radius centrifuge for physically simulating underground chemical explosions and stress cage processes in scaled models.
Magnetic merging is a primary means for coupling energy from the solar wind into the magnetosphere-ionosphere system. The location and nature of the process remain as open questions. By correlating measurements form diverse locations and using large-scale MHD models to put the measurements in context, it is possible to constrain out interpretations of the global and meso-scale dynamics of magnetic merging. Recent evidence demonstrates that merging often occurs at high latitudes in the vicinity of the cusps. The location is in part controlled by the clock angle in the interplanetary magnetic field (IMF) Y-Z plane. In fact, B(sub Y) bifurcated the cusp relative to source regions. The newly opened field lines may couple to the ionosphere at MLT locations of as much as 3 hr away from local noon. On the other side of noon the cusp may be connected to merging sites in the opposite hemisphere. In face, the small convection cell is generally driven by opposite hemisphere merging. B(sub X) controls the timing of the interaction and merging sites in each hemisphere, which may respond to planar features in the IMF at different times. Correlation times are variable and are controlled by the dynamics of the tilt of the interplanetary electric field phase plane. The orientation of the phase plane may change significantly on time scales of tens of minutes. Merging is temporally variable and may be occurring at multiple sites simultaneously. Accelerated electrons from the merging process excite optical signatures at the foot of the newly opened field lines. All-sky photometer observations of 557.7 nm emissions in the cusp region provide a "television picture" of the merging process and may be used to infer the temporal and spatial variability of merging, tied to variations in the IMF.
MARMOT is a meso-scale fuel code under development by NEAMS designed to predict the microstructure evolution of fuel materials to determine updated thermal and mechanical property models. These updated models can be used by engineering scale codes such as BISON. To support its development and validation the MARMOT Validation Project (MVP) was initiated and consists of extensive microstructure and thermal characterization of U-10Zr fuel material before and at discreet levels of irradiation. This report summarizes the SEM and EDS characterization of the lowest burnup samples (1.5% FIMA) and how they compare to pre-irradiation SEM and EDS.
CEOP has contributed and will continue to provide integrated data sets from diverse platforms for better understanding of the water and energy cycles, and for validaintg models. In this talk, I will show examples of how CEOP has contributed to the formulation of a strategy for the study of the monsoon as a system. The CEOP data concept has led to the development of the CEOP Inter-Monsoon Studies (CIMS), which focuses on the identification of model bias, and improvement of model physics such as the diurnal and annual cycles. A multi-model validation project focusing on diurnal variability of the East Asian monsoon, and using CEOP reference site data, as well as CEOP integrated satellite data is now ongoing. Preliminary studies show that climate models have difficulties in simulating the diurnal signals of total rainfall, rainfall intensity and frequency of occurrence, which have different peak hours, depending on locations. Further more model diurnal cycle of rainfall in monsoon regions tend to lead the observed by about 2-3 hours. These model bias offer insight into lack of, or poor representation of, key components of the convective and stratiform rainfall. The CEOP data also stimulated studies to compare and contrasts monsoon variability in different parts of the world. It was found that seasonal wind reversal, orographic effects, monsoon depressions, meso-scale convective complexes, SST and land surface land influences are common features in all monsoon regions. Strong intraseasonal variability is present in all monsoon regions. While there is a clear demarcation of onset, breaks and withdrawal in the Asian and Australian monsoon region associated with climatological intraseasonal variabillity, it is less clear in the American and Africa monsoon regions. The examination of satellite and reference site data in monsoon has led to preliminary model experiments to study the impact of aerosol on monsoon variability. I will show examples of how the study of the dynamics of aerosol-water cycle interactions in the monsoon region, can be best achieved using the CEOP data and modeling strategy.
CEOP has contributed and will continue to provide integrated data sets from diverse platforms for better understanding of the water and energy cycles, and for validating models. In this talk, I will show examples of how CEOP has contributed to the formulation of a strategy for the study of the monsoon as a system. The CEOP data concept has led to the development of the CEOP Inter-Monsoon Studies (CIMS), which focuses on the identification of model bias, and improvement of model physics such as the diurnal and annual cycles. A multi-model validation project focusing on diurnal variability of the East Asian monsoon, and using CEOP reference site data, as well as CEOP integrated satellite data is now ongoing. Similar validation projects in other monsoon regions are being started. Preliminary studies show that climate models have difficulties in simulating the diurnal signals of total rainfall, rainfall intensity and frequency of occurrence, which have different peak hours, depending on locations. Further more model diurnal cycle of rainfall in monsoon regions tend to lead the observed by about 2-3 hours. These model bias offer insight into lack of, or poor representation of key components of the convective,and stratiform rainfall. The CEOP data also stimulated studies to compare and contrasts monsoon variability in different parts of the world. It was found that seasonal wind reversal, orographic effects, monsoon depressions, meso-scale convective complexes, SST and land surface land influences are common features in all monsoon regions. Strong intraseasonal variability is present in all monsoon regions. While there is a clear demarcation of onset, breaks and withdrawal in the Asian and Australian monsoon region associated with climatological intraseasonal variability, it is less clear in the American and Africa monsoon regions. The examination of satellite and reference site data in monsoon has led to preliminary model experiments to study the impact of aerosol on monsoon variability. I will show examples of how the study of the dynamics of aerosol-water cycle interactions in the monsoon region, can be best achieved using the CEOP data and modeling strategy.
An observing system comprised of two lidars in geosynchronous orbit would enable the synoptic and meso-scale measurement of atmospheric winds and moisture, both of which are key first-order variables of the Earth's weather equation. Simultaneous measurement of these parameters at fast revisit rates promises large advancements in our weather prediction skills. Such capabilities would be unprecedented and yield greatly improved and finer resolution initial conditions for models, make existing costly and cumbersome measurement approaches obsolete, and obviate the use of numerical techniques needed to correct data obtained using present observing systems. Additionally, simultaneous synoptic wind and moisture observations would lead to improvements in model parameterizations, and in our knowledge of small-scale weather processes. Technology and science data product assessments are ongoing. Results will be presented during the conference.
An observing system comprised of two lidars in geosychronous orbit would enable the synoptic and meso-scale measurement of atmospheric winds and moisture both of which are key first-order variables of the Earth's weather equation. Simultaneous measurement of these parameters at fast revisit rates promises large advancements in our weather prediction skills. Such capabilities would be unprecedented and a) yield greatly improved and finer resolution initial conditions for models, b) make existing costly and cumbersome measurement approaches obsolete, and c) obviate the use of numerical techniques needed to correct data obtained using present observing systems. Additionally, simultaneous synoptic wind and moisture observations would lead to improvements in model parameterizations, and in our knowledge of small-scale weather processes. Technology and science data product assessments are ongoing. Results will be presented during the conference.
Our picture of plasmaspheric erosion is dominated by a simple model of corotational and enhanced convective motion and by many decades of plasmapause boundary measurement. Observational evidence for the plasma motion that lowers the outer plasmaspheric boundary has largely been unavailable. A new analysis technique for the IMAGE Mission extreme ultraviolet imager (EUV) instrument now offers to reveal motion in the plasmaspheric boundary layer as enhanced global and meso-scale convection penetrates the quite-time plasmasphere. IMAGE EUV provides good global coverage of the striking plasmaspheric erosion that took place on July 10,2000. During this erosion event divergent flows in the vicinity of the plasmapause and centered initially near 2 hours MLT have been found. Over a period of about 1 hour the center of divergent flow drifts dawnward to almost 4 hours MLT. Plasma flows during this storm and others imaged by IMAGE EUV will be discussed along with their implication for the process of plasmaspheric erosion.
Brightness temperature maps at 18.7 and 37 GHz collected at the Fraser and North Park Meso-Scale Areas during the Cold Land Processes Experiment by the NOAA Polarimetric Scanning Radiometer (PSWA) airborne sensor are analyzed. The Fraser site is mostly covered by forest with a typical snowpack depth of 1 m while North Park has no forest cover and is characterized by patches of shallow snow. We examine histograms of the brightness temperatures at 500 m resolution for both the Fraser and North Park areas. The histograms can be modelled by a log-normal distribution in the case of the Fraser MSA and by a bi-modal distribution in the case of the North Park MSA. The histograms of the brightness temperatures at coarser resolutions are also plotted to study the effects of sensor resolution on the shape of the distribution, on the values of the average brightness temperatures and standard deviations. Finally, the values of brightness temperatures obtained by re-sampling (aggregating) the data at 25 km resolution are compared with the values of the brightness temperatures collected by the Advanced Microwave Scanning Radiometer (AMSR-E) and Special Sensor Microwave/Imager (SSMII) satellite radiometers. The results show that in both areas for sensor footprint larger than 5000 m, the brightness temperatures show a flat distribution and the memory of the initial distribution is lost. The values of the brightness temperatures measured by the satellite radiometers are in good agreement with the values obtained averaging the airborne data, even if some discrepancies occur.
Project Goal and Objective. The demand for energy and for an upgraded energy infrastructure has steadily grown, as have the needs for energy independence and alternatives to our reliance on petroleum. Hydrogen is considered the most viable fuels for wide-scale implementation in the near future as it is less-polluting, non-toxic, and has more stored energy than petroleum. It is envisioned that hydrogen can eventually become the prime energy carrier, integrating the transportation, grid, and chemical sectors in a way that improves resiliency, diversifies feedstocks, and affords new economic opportunities. A key remaining challenge is the development materials with enhanced gravimetric and volumetric hydrogen storage capacities that offer a higher performance than compressed gas. These materials would eliminate the need for large-scale compression, thereby dramatically reducing the footprint and cost of gas storage. The high gravimetric and volumetric hydrogen capacities of complex hydrides has prompted an intensive investigation of the potential of this class of materials as hydrogen storage media over the past 25 years. Among the many complex hydrides that have been explored, magnesium borohydride, Mg(BH 4 ) 2 , has been found to possess the best combination of practical thermodynamic properties. These include a gravimetric H 2 density of 14.9 wt% H 2 and thermodynamics for the dehydrogenation of Mg(BH 4 ) 2 to MgB 2 (equation 1) (ΔH° = 39 kJ/mol H 2 , ΔS = 112 J/K mol H 2 ) which lie in the narrow window required Mg(BH 4 ) 2 $\Leftrightarrow$ MgB 2 + 4 H 2 (1) for reversibility under moderate pressure and temperature. However, overcoming the extremely slow kinetics of the reversible release of hydrogen by this material in the solid state is a daunting challenge. At temperatures greater than 400 °C, the borohydride releases up to 14 wt% hydrogen giving MgB 2 . We discovered that the direct re-hydrogenation of MgB 2 to Mg(BH 4 ) 2 can be accomplished under 950 bar H 2 at 400 °C. While this demonstrated that complete reversibility can be achieved, the conditions employed are far too extreme for commercial hydrogen storage applications. More recently, we found through US DOE funded research projects (EERE HyMARC and HySCOR), that hydrogen cycling, can be accomplish at much milder conditions upon modification of the borohydride or boride. Guided by these discoveries these discoveries, the objective of this research project was to obtain key information that will enable the development of a model of reversible hydrogenation of MgB 2 to Mg(BH 4 ) 2 . The ultimate goal of our efforts is to attain a model of this transformation that can be utilized to accelerate development further advanced materials. This project directly follows on discoveries that were made over the course of a US DOE, EERE HyMARC project that was focused on improvement of the hydrogen cycling kinetics of modified MgB 2 . We found that that mechanical milling with graphene results the desired, pronounced kinetic enhancement. The dramatic lowering of the conditions required for the hydrogenation of MgB 2 is a significant step towards overcoming its chemical inertness allowing its development as a practical onboard hydrogen storage material. However, the exact nature of the modification(s) of MgB 2 that is responsible for its activation towards hydrogenation is completely unknown. This situation is not unique, as efforts to develop hydrogen storage materials typically have a narrow focus rather than a comprehensive approach that takes atomic level bonding and structure; molecular dynamics; long range, nano- and mesoscale-structure and their interconnection all into account. The goal of this project was the development of a comprehensive, multi-scale computational model of reversible hydrogenation of MgB 2 to Mg(BH 4 ) 2 that can be utilized for development of higher performance versions of the modified material. Development of the model requires determination of: 1) the bulk, nano-scale, and meso-scale structural changes occurring at elevated pressure following mechano-chemical modification of MgB 2 ; 2) the reaction pathway of the reversible hydrogenation of MgB 2 to Mg(BH 4 ) 2 ; 3) the effect of elevated pressure and mechano-chemical modification on the chemical reaction pathways; 4) the interactions at solid-gas interfaces; and particle surfaces; and 5) the kinetics and thermodynamic parameters associated with each step of the hydrogenation reaction pathway. This investigation required advanced techniques as preliminary, standard XRD, 11 B NMR, and FTIR analysis showed no signs of material modification. In order to gain this level of understanding of modified MgB 2 , required the teaming of a diverse group of experts and state-of-the art experimental capabilities at the University of Hawaii at Manoa (UHM) and collaborating National Laboratories: Craig Jensen , Department of Chemistry (PI and Project Director), solid state, solution, and high pressure NMR spectroscopy; solid-state synthesis; and high pressure hydrogenation (collaboration with SNL); Godwin Severa , Hawaii Natural Energy Institute (co-PI) calorimetry; infrared and Raman spectroscopy (collaboration with NREL); Dera , high pressure X-ray diffraction including in situ experiments (collaboration with ANL); Hope Ishii , Hawaii Institute of Geophysics electron microscopy investigations (collaboration with LBNL); and Joe Brown , Mechanical Engineering , material electronic structure and electric field effects.
The nonlinear hysteretic behavior of rocks under cyclic loading is a crucial area of study in geomechanics. The macroscopic response of a variety of materials has been found to be contingent upon the behavior of the micro-scale structure. This project aims to develop a functional and maintainable software package for generating a multi-phase numerical mesh and accompanying simulation files for finite element modeling used in computational mechanics solvers. Meshes generated from images often lack key preprocessing that reduces noise and prevents mesh element distortion that can increase computational cost. By incorporating user feedback throughout, grain2mesh ensures a high-fidelity mesh that can be used to model grain-scale interactions such as shearing, crack propagation, and interfacial material contrast. Scientific applications of this software include material fracturing, stress-strain analysis for natural and engineered materials, and nonlinear meso-scale analysis.
During fiscal years 2024 and 2025, the U.S. Department of Energy’s Hanford Field Office commissioned Pacific Northwest National Laboratory to conduct applied research aimed at reducing the cost, time, and uncertainty associated with in situ treatment of vadose zone contaminants at the Hanford Site. This report outlines the integration of three key research efforts into a meso-scale demonstration designed to advance field-scale solutions that aim to (1) optimize the delivery of chemical amendments to contaminated soils, (2) reduce uncertainty in amendment delivery performance assessment using advanced monitoring techniques, and (3) provide real-time insights into when and where amendment-induced precipitation reactions occur in the subsurface. To achieve these objectives, the tank-scale (~ 1 cubic meter) Geophysical Imaging of Flow and Transport (GIFT) system was developed. GIFT enables experimental testing of amendment delivery while incorporating automated multi-modal monitoring approaches, including pressure measurements, direct fluid sampling, and remote time-lapse geophysical imaging. The data generated from these monitoring techniques will serve as inputs for a generative artificial-intelligence-driven digital twin – a numerical simulation model designed to honor observed data while quantifying uncertainty in simulation accuracy. Using this simulator, researchers will refine an amendment injection strategy to maximize delivery efficiency within a low-permeability soil zone. Monitoring data will be interpreted through simulated outputs to enhance understanding of the injection process. The efficacy of this integrated approach will be evaluated through direct sampling at the conclusion of the experiment.
Additively manufactured (AM) eutectic high-entropy alloys (EHEAs), such as nano-lamellar AlCoCrFeNi 2.1 , have excellent strength, ductility, and wear resistance even at elevated temperatures, but their corrosion behavior in aggressive acids at different length scales remain poorly understood. This work investigates the corrosion behavior of laser powder bed–fused (L-PBF) AlCoCrFeNi 2.1 as a function of annealing temperatures, probing degradation mechanisms from nanoscopic to macroscopic length scales. The alloy is dual phase consisting of a ductile FCC L1 2 phase and a high-strength BCC B2 phase. Rapid solidification during L-PBF produces a far-from-equilibrium nano-lamellar structure with nearly homogeneous elemental distribution, which tends to evolve upon annealing toward Cr/Co/Fe-enriched FCC and Al/Ni-enriched B2. Three conditions were studied: as-printed, 600 °C/5 h, and 1000 °C/1 h, over which B2 lamellae coarsen, lamellar spacing increases, and elemental segregation becomes more prominent. Microstructure and chemistry were characterized by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS), while in-situ electrochemical atomic force microscopy (EC-AFM) was used to link early (<5 h) local dissolution to microstructure after exposure in sulfuric acid. EC-AFM highlights preferential dissolution of the BCC/B2 phase where the surrounding matrix is Cr-depleted and directly quantifies the dissolution rates within individual phases, tracks the transition from early nano-scale attack to partial repassivation, to correlate height differences with current and impedance responses. To monitor longer-term behavior (up to 96 h), ex-situ AFM, SEM, and confocal imaging were combined with conventional bulk electrochemical tests, bridging nanoscale observations to micro/meso-scale damage morphologies. At the meso-scale, the deepest dissolution channels align with the build-direction lamellae and melt-pool boundaries, indicating that printing directionality guides the propagation of these localized corrosion sites. Annealing modifies corrosion by restructuring BCC/FCC phase fractions, lamellar spacing, and Cr/Al segregation, thereby changing the cathode/anode ratio and passive film stability. The results clarify how as-printed and annealed nano-lamellar architectures differ in their susceptibility to selective dissolution; how elemental segregation competes with residual stresses along the build direction. With these insights, future work will use CALPHAD-guided alloy modification to stabilize higher Cr contents in the B2 phase while retaining a dominant FCC+B2/BCC microstructure, with the goal of designing mechanically robust, corrosion-resistant EHEAs for safety-critical applications to leverage the LLNL’s broader national and global security mission.
The primary methodology during the grant period has been the use of micro or meso-scale simulations to address specific questions concerning magnetospheric processes related to the aurora and substorm morphology. This approach, while useful in providing some answers, has its limitations. Many of the problems relating to the magnetosphere are inherently global and kinetic. Effort during the last year of the grant period has increasingly focused on development of a global-scale hybrid code to model the entire, coupled magnetosheath - magnetosphere - ionosphere system. In particular, numerical procedures for curvilinear coordinate generation and exactly conservative differencing schemes for hybrid codes in curvilinear coordinates have been developed. The new computer algorithms and the massively parallel computer architectures now make this global code a feasible proposition. Support provided by this project has played an important role in laying the groundwork for the eventual development or a global-scale code to model and forecast magnetospheric weather.
The propagation of shock waves through target materials is strongly influenced by the presence of small-scale structure, fractures, physical and chemical heterogeneities. Pre-existing fractures often create craters that appear square in outline (e.g. Meteor Crater). Reverberations behind the shock from the presence of physical heterogeneity have been proposed as a mechanism for transient weakening of target materials. Pre-existing fractures can also affect melt generation. In this study, we are attempting to bridge the gap in numerical modeling between the micro-scale and the continuum, the so-called meso-scale. To accomplish this, we are developing a methodology to be used in the shock physics hydrocode (CTH) using Monte-Carlo-type methods to investigate the shock properties of heterogeneous materials. By comparing the results of numerical experiments at the micro-scale with experimental results and by using statistical techniques to evaluate the performance of simple constitutive models, we hope to embed the effect of physical heterogeneity into the field variables (pressure, stress, density, velocity) allowing us to directly imprint the effects of micro-scale heterogeneity at the continuum level without incurring high computational cost.