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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Ultrafast optical modulation of vibrational strong coupling in ReCl(CO) 3 (2,2-bipyridine)

Polaritons – hybrid light-matter states formed from the strong coupling of a bright molecular transition with a confined photonic mode – may offer new opportunities for optical control of molecular behavior. Vibrational strong coupling (VSC) has been reported to impact ground-state chemical reactivity, but its influence on electronic excited-state dynamics remains unexplored. Here, we take a first step towards excited-state VSC by demonstrating optical modulation of the ReCl(CO) 3 (bpy), (bpy = 2,2-bipyridine) complex under VSC using femtosecond ultraviolet (UV)-pump/infrared (IR)-probe spectroscopy. We establish ground-state VSC of ReCl(CO) 3 (bpy) in a microfluidic Fabry-Pérot cavity equipped with indium tin oxide (ITO)-coated mirrors. ITO is effectively dichroic as it is reflective in the IR and transmissive in the UV-visible and therefore minimizes optical interference. Excitation with UV pump light drives ReCl(CO) 3 (bpy) into a manifold of electronic excited states that subsequently undergo non-radiative relaxation dynamics. We probe the transient response of the strongly-coupled system in the mid-IR, observing both Rabi contraction and cavity-filtered excited-state absorption signatures. We reconstruct the intrinsic response of intracavity molecules from the transient cavity transmission spectra to enable quantitative comparison with extracavity control experiments. We report no changes in the excited-state dynamics of ReCl(CO) 3 (bpy) under ground-state VSC. However, we do observe significant amplification of transient vibrational signals due to classical cavity-enhanced optical effects. This effort lays the groundwork to pursue direct excited-state VSC aimed at modulating photochemical reactivity.

cavity-enhanced spectroscopy↗
DOE OSTI2016

Interfacial thermal conductance between few to tens of layered-MoS 2 and c-Si: Effect of MoS 2 thickness

We report a systematic investigation of interfacial thermal conductance (G k ) between few to tens -layered mechanical exfoliated molybdenum disulfide (MoS 2 ) and crystalline silicon (c-Si). Based on Raman spectroscopy, we find G k at room temperature increases with increased layer numbers of MoS 2 from 0.974 MW m -2 K -1 to 68.6 MW m -2 K -1 . The higher G k of thicker samples reveals their better interface contact with the substrate, leading to accordingly improved interfacial energy coupling. Molecular dynamics (MD) simulations are conducted to interpret and compare with the experimental observations. MD simulations predict a thermal conductance in the range of 53–77 MW m -2 K -1 , which agrees well with the upper bound G k measured in our work. The thickness dependence of measured G k reflects the improved interface spacing for thicker MoS 2 samples. This phenomenon is further confirmed by the Raman intensity enhancement study by the interface spacing and local optical interference calculations.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Efficient Colorful Perovskite Solar Cells Using a Top Polymer Electrode Simultaneously as Spectrally Selective Antireflection Coating

Organometal halide perovskites have demonstrated excellent optoelectronic properties and have been used to demonstrate a variety of semiconductor devices. Colorful solar cells are desirable for photovoltaic integration in buildings and other aesthetically appealing applications. Yet, the realization of colorful perovskite solar cells is challenging because of their broad and large absorption coefficient that commonly leads to cells with dark-brown colors. Herein, for the first time, we report a simple and efficient strategy to achieve colorful perovskite solar cells by using the transparent conducting polymer (poly(3,4-ethylenedioxythiophene):poly- (styrenesulfonate), PEDOT:PSS) as a top electrode and simultaneously as an spectrally selective antireflection coating. Vivid colors across the visible spectrum are attained by engineering optical interference effects among the transparent PEDOT:PSS polymer electrode, the hole-transporting layer and the perovskite layer. The colored perovskite solar cells display power conversion efficiency values from 12.8 to 15.1% (from red to blue) when illuminated from the FTO glass side and from 11.6 to 13.8% (from red to blue) when illuminated from the PEDOT:PSS side. The new method offers an advanced solution for fabricating colorful perovskite solar cells with easy processing and high efficiency.

42 ENGINEERING↗
DOE OSTI2025

Spontaneous Formation of Single-Crystalline Spherulites in a Chiral 2D Hybrid Perovskite

In two-dimensional (2D) chiral metal-halide perovskites (MHPs), chiral organic spacers induce structural chirality and chiroptical properties in the metal-halide sublattice. This structural chirality enables reversible crystalline-glass phase transitions in (S-NEA) 2 PbBr 4 , a prototypical chiral 2D MHP where NEA + represents 1-(1-naphthyl)ethylammonium. Here, in this study, we investigate two distinct spherulite states of (S-NEA) 2 PbBr 4 , exhibiting either radial-like or stripe-like banded patterns depending on the annealing conditions of the amorphous film. Despite similarities in optical absorption and photoluminescence, the stripe-like, banded spherulite exhibits higher crystallinity and improved optical transparency compared to those of radial-like spherulite. X-ray nanoprobe measurements reveal tilting-angle modulations in the octahedral plane of stripe-like spherulites, correlating with the film’s surface geometry. Transfer matrix calculations indicate that the optical contrast in stripe-like patterns, seen in bright-field optical microscopy, arises from optical interference effects, differing from the contrast mechanism observed in polymer spherulites. Ultrafast carrier dynamics experiments suggest that the stripe-like spherulites resemble single crystals more closely than radial-like spherulites, while electrical conductivity measurements show enhanced charge carrier transport in stripe-like spherulites. These findings offer insights into MHP spherulite states with a single composition but different morphologies, previously observed only in polymers, highlighting their potential for optoelectronic applications.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Single-shot on-chip spectral sensors based on photonic crystal slabs

Miniaturized spectrometers have significant potential for portable applications such as consumer electronics, health care, and manufacturing. These applications demand low cost and high spectral resolution, and are best enabled by single-shot free-space-coupled spectrometers that also have sufficient spatial resolution. Here, we demonstrate an on-chip spectrometer that can satisfy all of these requirements. Our device uses arrays of photodetectors, each of which has a unique responsivity with rich spectral features. These responsivities are created by complex optical interference in photonic-crystal slabs positioned immediately on top of the photodetector pixels. The spectrometer is completely complementary metal–oxide–semiconductor (CMOS) compatible and can be mass produced at low cost.

42 ENGINEERING↗
DOE OSTI2017

Performance Analysis of Electrodynamic Screens Based on Residual Particle Size Distribution

Dust accumulation on the optical surfaces of solar collectors causes significant losses in their energy yield. Fine dust particles, compared with coarse ones, contribute significantly more in the performance loss, assuming identical surface mass concen- tration. This study examines the performance of different electro- dynamic screen (EDS) prototypes, operated under different con- ditions, in removing fine dust particles in the laboratory environ- ment. After going through several cycles of dust deposition and cleaning using EDS, the dust residue left on each EDS prototype is collected and analyzed using a Horiba particle size distribution (PSD) analyzer. The PSD analyses determine which EDS design has performed superior in removing a given size range and in which operational condition. Here, the results are advantageous in the optimization procedure of EDS to attain maximum dust removal efficiency and minimum optical interference.

14 SOLAR ENERGY↗
DOE OSTI2017

Effect of Low-Cycle Fatigue on Fracture Mechanics Parameters According to Speckle Interferometry

Evolution of parameters of fracture mechanics at various stages of low-cycle damage is studied. The developed approach is based on elaboration of optical interference measurements of the deformation response to a small crack length increment. Three sequential symmetrical notches simulate the fatigue crack growth process across the cumulative fatigue damage zone caused by low-cycle fatigue. The values of tangential components of displacement that are measured at several points on cut edges by electronic speckle interferometry are initial experimental information. The coefficients of stress intensity (SIC) and T strains are determined on the basis of the Williams solution. Values of opening and coefficients of stress intensity (SIC) and T strains for cracks of different length with fixed values of preloading cycles N{sub c} equal 0, 100, 1000, 1800, 2500, and 3300 are obtained. The dependences of the parameters of fracture mechanics for cracks of the fixed length on N{sub c} are constructed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Study of the Structural and Morphological Properties of HPHT Diamond Substrates

The morphological and structural properties of a series of high-pressure high-temperature (HPHT) single-crystal diamond substrates are comprehensively studied by white-light optical interference microscopy, atomic-force microscopy, and X-ray diffraction analysis. Procedures that provide a means for characterizing the substrate parameters most critical for epitaxial application with the laboratory equipment are described. It is shown that the jewelry-type characterization of diamond substrates is insufficient to assess the possibility of their use for the epitaxial growth of chemical-vapor-deposited (CVD) diamond.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Temporal and spatial laser intensification within nodular defects overcoated with multilayer dielectric mirrors over a wide range of defect geometries

The nodular defect shape and the laser incidence angle have a dramatic impact on the spatial distribution of light intensification within the nodule as well as how the laser light is drained from the defect. Nodular defect geometries unique to ion beam sputtering, ion-assisted deposition, and electron-beam (e-beam) deposition, respectively, are modeled in this parametric study over a wide range of nodular inclusion diameters and layer count for optical interference mirror coatings constructed with quarter-wave thicknesses and capped with a half wave of the low index material. It was found for hafnia ($n$=1.9) and silica ($n$=1.45) multilayer mirrors that the light intensification in nodular defects with a $C$ factor of 8, typical of e-beam deposited coatings deposited with a wide range of deposition angles, was maximized for a 24-layer design. For intermediate size inclusion diameters, increasing the layer count for normal incidence multilayer mirrors reduced the light intensification within the nodular defect. A second parametric study explored the impact of the nodule shape on the light intensification for a fixed number of layers. In this case, there is a strong temporal trend for the different nodule shapes. Narrow nodules tend to drain more laser energy through the bottom of the nodule into the substrate while wide nodules tend to drain more laser energy through the top of the nodule when irradiated at normal incidence. Further, at a 45° incidence angle, waveguiding is an additional method to drain laser energy from the nodular defect. Finally, laser light resonates within nodular defects longer than within the adjacent nondefective multilayer structure.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Pulsed Magnetic Gradiometry in Earth's Field [Poster]

We describe a novel pulsed magnetic gradiometer based on the optical interference of sidebands generated using two spatially separated alkali vapor cells. In contrast to traditional magnetic gradiometers, our approach provides a direct readout of the gradient field without the intermediate step of subtracting the outputs of two spatially separated magnetometers. Operation of the gradiometer in multiple field orientations is discussed. The noise floor is measured as low as 25$\frac{fT}{\sqrt{Hz-cm}}$ in a room without magnetic shielding.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

The LSST Camera (LSSTCam)

The LSST Camera is the sole instrument for the NSF-DOE Vera C. Rubin Observatory and consists of a 3.2 gigapixel focal plane mosaic with in-vacuum controllers, dedicated guider and wavefront CCDs, a three-element corrector whose largest lens is 1.55m in diameter, six optical interference filters covering a 320-1050nm band pass with an out-of-plane filter exchange mechanism, and camera slow control and data acquisition systems capable of digitizing each image in 2 seconds.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Highly efficient small molecule multi-junction organic photovoltaic cells

A highly efficient multi junction photovoltaic device, such as a two, three, or four junction device, is disclosed. The multi-junction device may include a first subcell comprising a first photoactive region and a second subcell comprising a second photoactive region. The first and second photoactive regions are designed to minimize spectral overlap and maximize photocurrent across a broad absorption spectra, such as wavelengths ranging from 400 nm to 900 nm. The device may further include an inter-connecting layer, disposed between the first subcell and the second subcell, that is at least substantially transparent. By introducing a transparent interconnecting layer, a dual element (tandem) cell achieves a power conversion efficiency of 10.0±0.5%. By adding an additional (3rd) sub-cell that absorbs at the second order optical interference maximum within the stack. The triple junction cell significantly improves the quantum efficiency at shorter wavelengths, achieving a power conversion efficiency of 11.1±0.5%. Adding additional sub-cells has been shown to increase power conversion efficiency above 12%.

Che, Xiaozhou↗
DOE OSTI2024

A Microwave Photonics Optical Fiber Method for Measuring Distributed Strain for Hydrologic Applications in the Vadose and Saturated Zones

Distributed strain measurements appear to hold significant potential for monitoring hydrologic processes. Coherence-length-gated Microwave Photonics Interferometry (CMPI) is a distributed sensing technique that measures strain in an optical fiber by reading optical interference phase changes in the microwave domain. The technique provides 10nε resolution when cm spatial resolution is applied. CMPI was used to measure the strain caused by small periodic variations in air pressure (25 Pa amplitude and 4 Hz) in a sand-filled laboratory column used to represent barometric loading in the vadose zone. The strain varied as a periodic function with an amplitude that decreased and a phase that increased with depth. The distribution of amplitude and phase of the strain depended on the water saturation, permeability, and presence of a barrier at the top of the sand. A theoretical analysis suggests that the air pressure diffusivity estimated from pressure data is similar to the diffusivity estimated from the distributed strain. These results indicated that the CMPI distributed strain measurement system could be used to improve monitoring and characterization of the vadose and underlying saturated zone.

Hua, Liwei↗
DOE OSTI2018

Observations of Coherent Optical Transition Radiation Interference Fringes Generated by Laser Plasma Accelerator Electron Beamlets

We report initial observations of coherent optical transition radiation interferometry (COTRI) patterns generated by microbunched electrons from laser-driven plasma accelerators (LPAs). These are revealed in the angular distribution patterns obtained by a CCD camera with the optics focused at infinity, or the far-field, viewing a Wartski two-foil interferometer. The beam divergences deduced by comparison to results from an analytical model are sub-mrad, and they are smaller than the ensemble vertical beam divergences measured at the downstream screen of the electron spectrometer. The transverse sizes of the beamlet images were obtained with focus at the object, or near field, and were in the few-micron regime as reported by LaBerge et al. [8]. The enhancements in intensity are significant relative to incoherent optical transition radiation (OTR) enabling multiple cameras to view each shot. We present two-foil interferometry effects coherently enhanced in both the 100-TW LPA at 215 MeV energy at Helmholtz-Zentrum Dresden-Rossendorf and the PW LPA at 1.0-GeV energy at the University of Texas-Austin. A transverse emittance estimate is reported for a microbunched beamlet example generated within the plasma bubble.

43 PARTICLE ACCELERATORS↗
DOE OSTI2019

Metasurface-generated complex 3-dimensional optical fields for interference lithography

Significance Fast submicrometer-scale 3D printing techniques are of interest for various applications ranging from photonics and electronics to tissue engineering. Interference lithography is a versatile 3D printing method with the ability to generate complicated nanoscale structures. Its application, however, has been hindered by either the complicated setups in multibeam lithography that cause sensitivity and impede scalability or the limited level of control over the fabricated structure achievable with mask-assisted processes. Here, we show that metasurface masks can generate complex volumetric intensity distributions with submicrometer scales for fast and scalable 3D printing. These results push the limits of optical devices in controlling the light intensity distribution and significantly increase the realm of possibilities for 3D printing.

Science & Technology - Other Topics↗
DOE OSTI2020

Quantum interference between the optical Stark effect and resonant harmonic generation in WS 2

An applied field can modulate optical signals by resonance shifting via the Stark effect. The optical Stark effect uses ultrafast light in the transparency region of a material to shift resonances with speeds limited by the pulse duration or system coherence. In this Rapid Communication, we investigate the optical Stark effect in resonant optical harmonic generation using the A exciton transition of WS 2 . Multidimensional pump-harmonic-probe measurements, in which the probe is second- or third-harmonic emission, reveal not only large Stark shifts that are commensurate with the large optical susceptibilities common to WS 2 excitons, but also behaviors more complex than simple optical Stark effect treatments predict. We show how another manifestation of the Stark effect, brought forth by coherent photon exchange between the pump and harmonic generation fundamental fields, can strongly enhance or suppress harmonic generation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Pulse duration dependent effects of ultrafast laser induced damage on a 1030 nm multi-layer dielectric mirror for high repetition rate, high average power laser systems

High repetition rate, high peak, and average power laser systems are crucial for next-generation particle accelerators, inertial confinement fusion, and secondary particle sources. These applications demand durable laser optics, particularly interference coatings on optics lasting millions of shots at high fluence. This study focuses on designing, testing, and simulating multi-layer dielectric (MLD) mirrors for pulse durations of 260 fs, 77 fs, and 25 fs at 1030 nm wavelength and 45-degree incidence angle with p -polarization. S-on-1 laser-induced damage thresholds (LIDT) for varying pulse numbers were determined, with single-shot LIDT values of 0.98 Jcm -2 , 1.63 Jcm -2 , and 2.3 Jcm -2 for 25 fs, 77 fs, and 260 fs respectively. A strong correlation between blister shape and local fluence was observed, implying that the layer expansion in a blister depends on local fluence. We have also examined mechanisms responsible for laser-induced stress generation and energy release rates in blister formation. Damage mechanisms are further explored by finite-difference time-domain (FDTD) simulations, incorporating Keldysh strong field ionization, whose predictions were in excellent agreement with the onset of damage determined experimentally. These findings offer insights for enhancing MLD coating technology, promising more efficient and resilient laser systems for diverse scientific and industrial applications.

Noor, Mohamed Yaseen (ORCID:000000021036644X)↗