Study of Vehicle Attitude Effect on Shuttle Radiation Measurements
This paper reports on the evaluation of the effect of shuttle attitude on data collected by a miniature radiation spectrometer that flew on the STS-95 in October 1998.
Guillet, N.↗
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Effects of Shuttle environment on instrument performance
Examination of the OSTA-1 payload instruments carried in the shuttle bay during the 54.25 hour mission of STS-2 indicates that the shuttle environment has no measurable effect on the Earth-viewing experiments. Operation of the payload shows that flight simulations are essential and experiment replanning practice is needed. Ground control of experiments is desirable since malfunctions of totally automated experiments cannot be fixed in flight. Alarm limits for experiments must be realistic since the crew loses interest after a few alarms. The quality and number of hours of data obtained for each experiment are listed.
Potter, A. E.↗
Space Shuttle Environmental Effects: The First 5 Flights
Environmental effects associated with the first five Space Shuttle flights were monitored by the National Aeronautics and Space Administration (NASA) and the U.S. Air Force (USAF). Results and interpretations from this effort were reported at the December 1982 joint NASA-USAF conference. The conference proceedings are presented in this document. Most of the monitoring activity was focused on the launch cloud, emphasizing surface effects on the biota and air quality, model prediction of surface concentrations of HCl gas and Al2O3 dust, and airborne measurements of cloud composition. In general, assessments and predictions made in the April 1978 Final Environmental Impact Statement for the Space Shuttle Program were verified. Fallout of acidic mist and dust within 3 mi to 5 mi of the launch pad was the only unexpected effect of the launch. Atomization of deluge water in the Shuttle exhaust is considered to be the most probable cause of this effect. Sonic booms were monitored for several landings at Edwards Air Force Base, California; results agreed well with model predictions.
Potter, A.↗
Effects of Shuttle bay environment on UV sensitive photographic film - Instrumentation for Get-Away-Special
An account is given of a Get-Away-Special experiment flown on Space Shuttles 7 and 8 investigating the effect of the space environment on Shumann emulsions. Shumann emulsions, having low gelatin content and no protective gelatin overcoating, are useful detectors of ultraviolet radiation shorter than 2200 angstroms but are extremely sensitive to environmental conditions and handling. The instrument required no interface with the Shuttle. It was turned on by an aneroid switch at an altitude of 50,000 feet. After that, its operation was controlled completely by a CMOS digital controller. Each hour, two temperatures and one voltage were read and stored in a CMOS programmable read only memory. At intervals, valves were opened and closed to expose SO 652 film strips of three sensitivities to the cargo bay environment for various time periods. The design and operation of the instrument package is described.
Kreplin, R. W.↗
Manned space flight - The effects of Shuttle perturbations on orbital trajectory
Orbit determination and trajectory prediction for the National Space Transportation System program is complicated by trajectory perturbations that are unique to the Shuttle. Orbital energy changes are seen during extended hold periods as well as during unmodeled attitude maneuvers. While a portion of these changes are due to dynamical mismodeling, the majority of the changes are due to dynamics that are unique to the Shuttle. The ability to take these previously unmodeled effects into account will allow a more accurate preflight and real-time prediction of the orbital trajectory to support payload requirements. This paper deals with the determination of the databases used to determine preflight and real-time energy growth and the results of using the databases to accurately predict energy growth for future flights.
Barrett, Charles P.↗
An evaluation of noise and its effects on shuttle crewmembers during STS-50/USML-1
High noise levels can lead to physiological, psychological, and performance effects in man, ranging from irritability, annoyance, and sleep interference to interference with verbal communication and fatigue, and to temporary or permanent threshold shift at more extreme levels. The current study evaluated the acoustic environment of the STS50/USML-1 mission. The major objectives were to gain subjective assessments of the STS-50 noise levels, document impacts of noise upon crewmember performance, collect inflight sound level measurements, compare noise levels across missions, evaluate the current Shuttle acoustic criterion, and to make recommendations regarding noise specifications for SSF and other long-duration manned space missions. Sound measurements indicated that background noise levels were 60, 64, and 61 A-weighted decibels, respectively, on the Orbiter middeck, flight deck, and Space lab. All levels were rated acceptable, with the Spacelab environment rated the most favorably. Sleep stations afforded attenuation from airborne noise sources, although all crewmembers reported being awakened by crew activity on the middeck. Models of distance for acceptable speech communications were generated, identifying situations of compromised verbal communications to be avoided.
Koros, Anton↗
Solvent Dynamics in Gel Polymer Electrolytes for Lithium–Sulfur Batteries
Li−sulfur (Li−S) batteries are promising as the next-generation energy storage technology but face challenges due to sluggish sulfur redox reaction (SRR) kinetics and a sulfur shuttling effect. While many studies have explored polycaprolactone (PCL)-based gel polymer electrolytes (GPEs) to address these issues, the influence of solvent properties, including dielectric constant (ϵ) and donor and acceptor numbers (DN and AN), remain unexplored despite their critical impact on performance and full-scale implementation. This study systematically compares three distinct electrolytes, dimethoxyethane (DME), dimethyl sulfoxide (DMSO), and tetraethylene glycol dimethyl ether (TEGDME)-paired with PCL, to correlate the varied solvent properties and their effects on the physical properties of the GPE, in terms of Li + transport and solvation, and polysulfide’s confinement. Among them, the DME-based GPE, with an intermediate DN, exhibited the lowest crystallinity (2.31%), highest ionic conductivity (7.49 mS/cm), and high Li + transference number (0.77). As a result, it achieved a specific capacity of 795 mAh/g sulfur and an average Coulombic efficiency of 97.5% after 120 cycles at C/5, outperforming its competitors. Operando Raman and UV−vis spectroscopy confirmed that PCL effectively confines long-chain polysulfides within its network, mitigating the shuttle effect and facilitating reversible polysulfide conversion. These findings demonstrate that GPEs with moderate DN values and balanced ϵ significantly enhance stability, extend cycle life, and improve rate performance for Li−S batteries. This work provides valuable insights into the design of advanced electrolyte systems for practical energy storage applications.
25 ENERGY STORAGE↗
Computational discovery of a novel double transition metal nitride MXene and its applications as an anchoring and catalytic material in Li–Se batteries
Double transition metal (DTM) nitride MXenes offer enhanced electrical conductivity and tunable catalytic properties compared to conventional carbide-based MXenes. In this study, we employed first-principles density functional theory (DFT) calculations to discover and computationally validate a novel DTM nitride MXene, Nb 2 TiN 2 , derived from its MAX phase precursor and investigated its potential as an anchoring material (AM) for Li–Se batteries. This newly proposed MXene expands the compositional landscape of DTM nitrides and opens new avenues for functional material design. We performed a comprehensive analysis of the thermodynamic and electronic properties of Nb 2 TiAlN 2 , and the MAX phase precursor to Nb 2 TiN 2 to assess its structural stability and exfoliation potential. Exfoliation energy calculations confirmed the feasibility of synthesizing Nb 2 TiN 2 from Nb 2 TiAlN 2 . We then explored the functionalized form, Nb 2 TiN 2 S 2 , evaluating its capability to serve as an effective anchoring material (AM) in Li–Se batteries by analyzing the reaction mechanisms and kinetics of the selenium reduction reaction (SeRR). Our results indicate that Nb 2 TiN 2 S 2 exhibits a strong binding affinity for lithium polyselenides (Li 2 Se n ), effectively suppressing the shuttle effect. Gibbs free energy calculations for the rate-limiting step of the SeRR reveal favorable kinetics and reduced reaction barriers. Overall, this study provides a detailed evaluation of the structural and electronic properties of a newly proposed DTM nitride MXene and its S-functionalized derivative and the catalyzing effect of Nb 2 TiN 2 S 2 in accelerating the reaction kinetics in Li–Se batteries. These findings underscore the potential importance of the further exploration of MXenes to address current challenges in high-performance Li–Se batteries.
25 ENERGY STORAGE↗
Parametric evaluation of the cost effectiveness of Shuttle payload vibroacoustic test plans
Consideration is given to alternate vibroacoustic test plans for sortie and free flyer Shuttle payloads. Statistical decision models for nine test plans provide a viable method of evaluating the cost effectiveness of alternate vibroacoustic test plans and the associated test levels. The methodology is a major step toward the development of a useful tool for the quantitative tailoring of vibroacoustic test programs to sortie and free flyer payloads. A broader application of the methodology is now possible by the use of the OCTAVE computer code.
Stahle, C. V.↗
Fe-single atom catalysts facilitate fast electron transfer with MoS 2 /SnS 2 cathodes in lithium–sulfur batteries
Lithium–sulfur batteries (LSBs) emerge as promising next-generation energy storage systems offering cost-effectiveness, environmental friendliness, and high theoretical energy density. The practical implementation of LSBs faces significant hindrances due to the shuttle effect and sluggish redox reactions. To address these challenges, single-atom catalyst (SAC) based combination materials from d-block elements can offer increased active catalytic sites, rapid charge transfer, accelerated electron migration, and fast sulfur redox conversion kinetics of lithium polysulfides (LiPSs). In this study, we fabricated three different LSB cathodes: pure S, S@MoS 2 /SnS 2 , and S@Fe–MoS 2 /SnS 2 . These cathodes were then used to explore the cycle life, capacity, rate capability, and redox kinetic reactions of LiPSs while assessing the influence of Fe-SACs on their performance. As a result, LSBs with S@Fe–MoS 2 /SnS 2 cathodes demonstrate an extended cycle life of 1000 cycles at a C-rate of 0.2C, maintaining a capacity close to 500 mA h g −1 , the highest initial discharge capacity of 1622 mA h g −1 and 1066 mA h g −1 at 0.05C and 0.2C, and excellent rate capabilities of 708 mA h g −1 and 558 mA h g −1 at 1C and 2C, respectively. The synergistic effect of the Fe-SAC-based combination cathode (S@Fe–MoS 2 /SnS 2 ) creates plentiful adsorptive and highly active catalytic sites, resulting in substantially enhanced capacity for adsorbing soluble long-chain LiPSs. This facilitates ultra-fast redox kinetics, surpassing the performance of the S@MoS 2 /SnS 2 and pure S cathodes. In the ex situ analysis, results from powder X-ray diffraction (XRD) to observe the new phase, soft X-ray absorption spectroscopy (XAS) to investigate the electronic structure, and hard X-ray photoelectron microscopy (HAXPES) with different energies (900 eV, 2000 eV, and 6000 eV) to track the chemical-state evolution of Fe-SACs in MoS 2 /SnS 2 cathodes displayed notable electrochemical reversibility involving S 8 ⇄ LiPSs ⇄ Li 2 S conversion even after 1000 cycles. Additionally, in situ, operando Raman analysis can unveil a novel catalytic mechanism of Fe-SACs in MoS 2 /SnS 2 “facilitating rapid electron transfer” during the discharge and charge processes of LSBs involving the conversion of S 8 ⇄ long-chain LiPSs ⇄ Li 2 S 2 /Li 2 S. This study elucidates the working mechanism of Fe-SAC cathodes, offering insights into overcoming the shuttle effect and facilitating sulfur redox kinetics to advance commercial LSBs.
36 MATERIALS SCIENCE↗
Fe-single-atom catalyst nanocages linked by bacterial cellulose-derived carbon nanofiber aerogel for Li-S batteries
Li-S battery (LSB) is promising for achieving high capacity. Still, its development is hindered by the complex redox process with sluggish kinetics and particularly the resulting lithium polysulfides (LiPS) shuttle effects. Single-atom catalysts (SACs), with their maximized atom utilization, could effectively chemisorb soluble LiPSs and expedite the sulfide conversion reaction kinetics. Here we report incorporating Fe single metal atom catalyst (Fe-SAC) in the sulfur cathode design and its electrocatalytic effects. Fe-doped ZIF-8 nanocages were introduced into a cheap biomass bacteria cellulose. A pyrolysis process converted them into an aerogel structure with Fe-SAC-functionalized N-doped carbon nanocages linked by a carbon nanofiber network (FeSA-NC@CBC), which was applied as a scaffold to fabricate freestanding and binder-free sulfur cathodes. He we conducted electrochemical measurements to reveal Fe-SAC functions including lowering energy barriers for S 8 reduction to liquid-phase LiPSs and further to solid-phase Li 2 S 2 /Li 2 S and accelerating Li 2 S 2 /Li 2 S nucleation and deposition, as corroborated by our theoretical calculation results. Benefiting from the synergistic effects of highly active Fe-SAC and three-dimensional conductive network, the sulfide reaction kinetics is improved, which can diminish LiPS shuttle effects and therefore improve LBS rate performance and cycling stability. Accordingly, the fabricated FeSA-NC@CBC composite cathode delivers an excellent rate capability at 2C with a reversible capacity of 840 mAh/g and a long-term cyclic stability of 800 mAh/g at 1C after 500 cycles.
25 ENERGY STORAGE↗
Revealing the working mechanism of a multi-functional block copolymer binder for lithium-sulfur batteries
The lithium-sulfur (Li-S) battery is one of the most promising substitutes for current energy storage systems because of its low cost, high theoretical capacity, and high energy density. However, the high solubility of intermediate products (i.e., lithium polysulfides) and the resultant shuttle effect lead to rapidly fading capacity and a low coulombic efficiency, which hinder the practical application of Li-S batteries. In this study, block copolymers are constructed with both an ethylene oxide unit and a styrene unit and then used as binders for Li-S batteries. Electrochemical performance improvements are attributed to the synergistic effects contributed by the different units of the block copolymer. Here, the ethylene oxide unit traps polysulfide, which bonds strongly with the intermediate lithium polysulfide, and enhances the transport of lithium ions to reach high capacity. Meanwhile, the styrene unit maintains cathode integrity by improving the mechanical properties and elasticity of the constructed block copolymer to accommodate the large volume changes. By enabling multiple functions via different units in the polymer chain, high sulfur utilization is achieved, polysulfide diffusion is confined, and the shuttle effect is suppressed during the cycle life of Li-S batteries, as revealed by operando ultraviolet–visible spectroscopy and S K-edge X-ray absorption spectroscopy.
25 ENERGY STORAGE↗
Multifunctional transitional metal-based phosphide nanoparticles towards improved polysulfide confinement and redox kinetics for highly stable lithium-sulfur batteries
The shuttle effect and the sluggish redox kinetics of lithium polysulfides (LiPSs) are the major issues impeding the practical applications of lithium-sulfur batteries (LSBs). Herein, a highly-efficient Ni 2 P electrocatalyst supported on N, P co-doped graphene (Ni 2 P@NPG) is developed via a simple “recrystallization-self-assembly” method to address the above issues. Here, the ultrafine Ni 2 P nanoparticles ensure abundant adsorption-diffusion-conversion interfaces for accelerating LiPSs transformation and Li 2 S deposition, which extremely decreases the accumulation of LiPSs in the electrolyte and therefore prevents the migration of LiPSs. Their superior catalytic performance is demonstrated by reduced Gibbs free energy changes of rate-limiting step based on the systematic theoretical calculations and the reduced shuttle effect is tested by the three-dimensional reconstructions of Raman depth profiles. Benefiting from these synergistic effects, the LSBs with Ni 2 P@NPG modified separators present a superior cycling performance with an average capacity decay rate of 0.048 % per cycle at 1C around the 400 cycles and a high-rate capacity of 731 mAh/g at 2C. Even with a high-sulfur loading of 3.53 mg cm –2 , the cell can still contain a reversible capacity of 809 mAh/g at 0.2C with a remarkable columbic efficiency of 98.4 %.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
A lithium-sulfur battery with a solution-mediated pathway operating under lean electrolyte conditions
Lithium-sulfur (Li-S) battery is one of the most promising candidates for the next generation energy storage systems. However, several barriers, including polysulfide shuttle effect, the slow solid-solid surface reaction pathway in the lower discharge plateau, and corrosion of Li anode still limit its practical applications, especially under the lean electrolyte condition required for high energy density applications. Here, we propose a solution-mediated sulfur reduction pathway to improve the capacity and reversibility of the sulfur cathode and suppress dendrite growth on the Li metal anode simultaneously. With this method, a high coulombic efficiency (99%) and stable cycle life over 100 cycles were achieved under application-relevant conditions (S loading: 6.2 mg cm-2; electrolyte to sulfur ratio: 3 mLE gs-1; sulfur weigh ratio: 72 wt%). This result is enabled by a specially designed Li2S4-rich electrolyte, in which Li2S is formed through a chemical disproportionation reaction instead of electrochemical routes. A diglyme solvent was used to obtain electrolytes with the optimum range of Li2S4 concentration. Operando X-ray absorption spectroscopy confirms the solution pathway in a practical Li-S cell. This solution pathway not only introduces a new electrolyte regime for practical Li-S batteries, but also provides a new perspective for bypassing the inefficient surface pathway for other electrochemical processes.
Wang, Hui↗
Feedline dynamic effects on shuttle POGO stability
The transmission parameters for the dynamic characteristics of a feedline were approximated using both power and product series expansions. The feedline transfer functions of a shuttle orbiter feedline configuration were obtained using power and product series approximations of 60th, 120th, 180th, and 240th, order. Bode plots using the above polynomial approximations were obtained and the results compared with the exact solution. The exact solution to the feedline transfer function was obtained by using the transcendental terms appearing in the transmission parameters. The results show that the shuttle orbiter feedline may be modeled adequately by using polynomial approximations for the transcendental functions appearing in the transmission parameters. The power series approach was shown to be preferable to the product series method.
Dimaggio, O. D.↗
Dispersion model studies for Space Shuttle environmental effects activities
The NASA/MSFC REED computer code was developed for predicting concentrations, dosage, and deposition downwind from rocket vehicle launches. The calculation procedures and results of nine studies using the code are presented. Topics include plume expansion, hydrazine concentrations, and hazard calculations for postulated fuel spills.
Source record↗
Specular effects of Shuttle Orbiter radiators on a typical payload
(Previously cited in issue 17, p. 2894, Accession no. A81-39083)
Turner, L. D.↗
Satellite drag prediction effects on Shuttle mission planning
Long-term factors, along with Shuttle performance limitations, are considered in order to illustrate the need for more reliable long-term drag (meaning 'solar cycle') prediction techniques. Such techniques would make it possible to confidently plan dual-objective Shuttle flights, which maximize Shuttle cargo loadings and thus reduce costs. In describing the coupled mission concept, it is pointed out that by deploying one payload while retrieving or servicing another, the Space Transportation System can maximize the usefulness of the Shuttle and reduce the cost per customer. It is shown here that the proposed mission coupling LDEF (Long Duration Exposure Facility) with ST (Space Telescope) must be rejected since the Shuttle performance limitations prohibit deployment of the ST at even 315 n mi with a subsequent LDEF retrieval. If, however, it were possible to predict solar cycles, then, depending on the prediction, a mission of this type could be feasible.
Young, K. A.↗