Bandpass filters for the ultraviolet.
UV band pass filter consisting of aluminum film, dielectric stack and its sandwich
ULTRAVIOLET FILTER↗
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Disinfection of Spacecraft Potable Water Systems by Photocatalytic Oxidation Using UV-A Light Emitting Diodes
Ultraviolet (UV) light has long been used in terrestrial water treatment systems for photodisinfection and the removal of organic compounds by several processes including photoadsorption, photolysis, and photocatalytic oxidation/reduction. Despite its effectiveness for water treatment, UV has not been explored for spacecraft applications because of concerns about the safety and reliability of mercury-containing UV lamps. However, recent advances in ultraviolet light emitting diodes (UV LEDs) have enabled the utilization of nanomaterials that possess the appropriate optical properties for the manufacture of LEDs capable of producing monochromatic light at germicidal wavelengths. This report describes the testing of a commercial-off-the-shelf, high power Nichia UV-A LED (250mW A365nnJ for the excitation of titanium dioxide as a point-of-use (POD) disinfection device in a potable water system. The combination of an immobilized, high surface area photocatalyst with a UV-A LED is promising for potable water system disinfection since toxic chemicals and resupply requirements are reduced. No additional consumables like chemical biocides, absorption columns, or filters are required to disinfect and/or remove potentially toxic disinfectants from the potable water prior to use. Experiments were conducted in a static test stand consisting of a polypropylene microtiter plate containing 3mm glass balls coated with titanium dioxide. Wells filled with water were exposed to ultraviolet light from an actively-cooled UV-A LED positioned above each well and inoculated with six individual challenge microorganisms recovered from the International Space Station (ISS): Burkholderia cepacia, Cupriavidus metallidurans, Methylobacterium fujisawaense, Pseudomonas aeruginosa, Sphingomonas paucimobilis and Wautersia basilensis. Exposure to the Nichia UV-A LED with photocatalytic oxidation resulted in a complete (>7-log) reduction of each challenge bacteria population in <180 minutes of contact time. With continued advances in the design and manufacture of UV-A LEDs and semi-conducting photocatalysts, LED activated photochemical process technology promises to extend its application to spacecraft environmental systems.
Birmele, Michele N.↗
Pre-Ionization Controlled Laser Plasma Formation for Ignition Applications (Final Scientific/Technical Report)
This report consists of three grand funded papers. Abstracts for each follow. 1) In this work, we present experimental and modeling studies of air pre-ionization using ultraviolet (UV) laser pulses and its effect on laser breakdown of an overlapped near-infrared (NIR) pulse. Experimental studies are conducted with a 266 nm beam (fourth harmonic of Nd:YAG) for UV pre-ionization and an overlapped 1064 nm NIR beam (fundamental of Nd:YAG), both having pulse duration of 10 ns. Results show that the UV beam produces a pre-ionized volume which assists in breakdown of the NIR beam, leading to reduction in NIR breakdown threshold by factor of >2. Numerical modeling is performed to examine the ionization and breakdown of both beams. The modeled breakdown threshold of the NIR, including assist by pre-ionization, is in reasonable agreement with the experimental results. 2) The present contribution compares the energy absorption, optical emission, temperature, and fluid dynamics of ultraviolet (UV) λ = 266 nm and near infrared (NIR) λ = 1064 nm nanosecond laser induced plasmas in ambient air. For UV pulses at the conditions studied, energy absorption by the plasmas increases relatively gradually with laser pulse energy starting at delivered energy of E~8 mJ. Corresponding measurements of plasma luminosity show that the absorption of UV radiation does not necessarily result in visible plasma emission. For the NIR induced plasmas, the energy absorption profile is far more abrupt and begins at ~55 mJ. In contrast with UV, the absorption of NIR radiation is always accompanied by intense optical emission. The temperatures of both types of plasma have been measured with Rayleigh scattering thermometry (at times after the Thomson signal sufficiently diminishes). The UV plasmas can attain a wider range of temperatures, including lower temperatures, depending on the pulse energy (e.g., T ~400–2000K for E ~7–35 mJ at Δt = 10 μs after the pulse) while the NIR plasmas show only hotter temperatures (e.g., T ~ 12 000 K for E = 75 mJ at Δt = 10 μs after the pulse) as is consistent with the literature. Differences in the fluid dynamics for UV versus NIR pulses are shown with Schlieren imaging. In this work, the contrast in the UV and NIR plasma threshold behavior is attributed to differing roles of avalanche ionization and multiphoton ionization as is also illustrated by a simple numerical model. 3) The present contribution examines the impact of plasma dynamics and plasma-driven fluid dynamics on the flame growth of laser ignited mixtures and shows that a new dual-pulse scheme can be used to control the kernel formation process in ways that extend the lean ignition limit. We perform a comparative study between (conventional) single-pulse laser ignition (λ = 1064 nm) and a novel dual-pulse method based on combining an ultraviolet (UV) pre-ionization pulse (λ = 266 nm) with an overlapped near-infrared (NIR) energy addition pulse (λ = 1064 nm). We employ OH* chemiluminescence to visualize the evolution of the early flame kernel. For single-pulse laser ignition at lean conditions, the flame kernel separates through third lobe detachment, corresponding to high strain rates that extinguish the flame. In this work, we investigate the capabilities of the dual-pulse to control the plasma-driven fluid dynamics by adjusting the axial offset of the two focal points. In particular, we find there exists a beam waist offset whereby the resulting vorticity suppresses formation of the third lobe, consequently reducing flame stretch. With this approach, we demonstrate that the dual-pulse method enables reduced flame speeds (at early times), an extended lean limit, increased combustion efficiency, and decreased laser energy requirements.
Mechanical engineering↗
IRIS Observations of Magnetic Interactions in the Solar Atmosphere Between Preexisting and Emerging Magnetic Fields. II. UV Emission Properties
Multiwavelength ultraviolet (UV) observations by the Interface Region Imaging Spectrograph satellite in active region NOAA 12529 have recently pointed out the presence of long-lasting brightenings, akin to UV bursts, and simultaneous plasma ejections occurring in the upper chromosphere and transition region during secondary flux emergence. These signatures have been interpreted as evidence of small-scale, recurrent magnetic reconnection episodes between the emerging flux region (EFR) and the preexisting plage field. Here we characterize the UV emission of these strong, intermittent brightenings and study the surge activity above the chromospheric arch filament system (AFS) overlying the EFR. We analyze the surges and the cospatial brightenings observed at different wavelengths. We find an asymmetry in the emission between the blue and red wings of the Si iv λ1402 Å and Mg ii k λ2796.3 lines, which clearly outlines the dynamics of the structures above the AFS that form during the small-scale eruptive phenomena. We also detect a correlation between the Doppler velocity and skewness of the Si iv λλ1394 and 1402 line profiles in the UV burst pixels. Finally, we show that genuine emission in the Fe xii λ1349.4 line is cospatial to the Si iv brightenings. This definitely reveals a pure coronal counterpart to the reconnection event.
Guglielmino, Salvo L.↗
Thin metal film and multilayers experiment (A0138-3)
The sources of degradation of in state of the art and newly developed components and testing the usefulness of the concept of storing experiment samples in dry nitrogen under launch and space vacuum conditions during reentry mission phase were investigated. Ultraviolet (UV) and extreme ultraviolet (EUV) experiments suffer degradations during space missions of even 1 month duration. It is suggested that the degradation is due to condensation of outgassing products, followed by solar induced polymerization, however, penetrating charged particles are also known to produce volume effects. Degradation may also start immediately after manufacturing of the component due to oxidation, moisture, or chemical corrosion by atmospheric constituents such as CO2 and SO2. When the filters are used as windows for gas absorption cells or gas filters, or when they define the instrumental bandwidth by themselves. The effects of mechanical degradation by thermal cycling and/or dust may cause a dramatic impact.
Delaboudiniere, J. P.↗
Solar Cycle #24 and the Solar Dynamo
We focus on two solar aspects related to flight dynamics. These are the solar dynamo and long-term solar activity predictions. The nature of the solar dynamo is central to solar activity predictions, and these predictions are important for orbital planning of satellites in low earth orbit (LEO). The reason is that the solar ultraviolet (UV) and extreme ultraviolet (EUV) spectral irradiances inflate the upper atmospheric layers of the Earth, forming the thermosphere and exosphere through which these satellites orbit. Concerning the dynamo, we discuss some recent novel approaches towards its understanding. For solar predictions we concentrate on a solar precursor method, in which the Sun s polar field plays a major role in forecasting the next cycle s activity based upon the Babcock- Leighton dynamo. With a current low value for the Sun s polar field, this method predicts that solar cycle #24 will be one of the lowest in recent times, with smoothed F10.7 radio flux values peaking near 130+ 30 (2 4, in the 2013 timeframe. One may have to consider solar activity as far back as the early 20th century to find a cycle of comparable magnitude. Concomitant effects of low solar activity upon satellites in LEO will need to be considered, such as enhancements in orbital debris. Support for our prediction of a low solar cycle #24 is borne out by the lack of new cycle sunspots at least through the first half of 2007. Usually at the present epoch in the solar cycle (-7+ years after the last solar maximum), for a normal size following cycle, new cycle sunspots would be seen. The lack of their appearance at this time is only consistent with a low cycle #24. Polar field observations of a weak magnitude are consistent with unusual structures seen in the Sun s corona. Polar coronal holes are the hallmarks of the Sun s open field structures. At present, it appears that the polar coronal holes are relatively weak, and there have been many equatorial coronal holes. This appears consistent with a weakening polar field, but coronal hole data must be scrutinized carefully as observing techniques have changed. We also discuss new solar dynamo ideas, and the SODA (Solar Dynamo Amplitude) index, which provides the user with the ability to track the Sun s hidden, dynamo magnetic fields throughout the various stages of the Sun s cycle. Our solar dynamo ideas are a modernization and rejuvenation of the Babcock-Leighton original idea of a shallow solar dynamo, using modem observations that appear to support their shallow dynamo viewpoint. We are in awe of being able to see an object the size of the Sun undergoing as dramatic a change as our model provides in a few short years. The Sun, however, has undergone changes as rapid as this before! The weather on the Sun is at least as fickle as the weather on the Earth.
Pesnell, W. Dean↗
Solar Cycle #24 and the Solar Dynamo
We focus on two solar aspects related to flight dynamics. These are the solar dynamo and long-term solar activity predictions. The nature of the solar dynamo is central to solar activity predictions, and these predictions are important for orbital planning of satellites in low earth orbit (LEO). The reason is that the solar ultraviolet (UV) and extreme ultraviolet (EUV) spectral irradiances inflate the upper atmospheric layers of the Earth, forming the thermosphere and exosphere through which these satellites orbit. Concerning the dynamo, we discuss some recent novel approaches towards its understanding. For solar predictions we concentrate on a solar precursor method, in which the Sun's polar field plays a major role in forecasting the next cycle s activity based upon the Babcock-Leighton dynamo. With a current low value for the Sun s polar field, this method predicts that solar cycle #24 will be one of the lowest in recent times, with smoothed F10.7 radio flux values peaking near 130 plus or minus 30 (2 sigma), in the 2013 timeframe. One may have to consider solar activity as far back as the early 20th century to find a cycle of comparable magnitude. Concomitant effects of low solar activity upon satellites in LEO will need to be considered, such as enhancements in orbital debris. Support for our prediction of a low solar cycle #24 is borne out by the lack of new cycle sunspots at least through the first half of 2007. Usually at the present epoch in the solar cycle (approx. 7+ years after the last solar maximum), for a normal size following cycle, new cycle sunspots would be seen. The lack of their appearance at this time is only consistent with a low cycle #24. Polar field observations of a weak magnitude are consistent with unusual structures seen in the Sun s corona. Polar coronal holes are the hallmarks of the Sun's open field structures. At present, it appears that the polar coronal holes are relatively weak, and there have been many equatorial coronal holes. This appears consistent with a weakening polar field, but coronal hole data must be scrutinized carefully as observing techniques have changed. We also discuss new solar dynamo ideas, and the SODA (SOlar Dynamo Amplitude) index, which provides the user with the ability to track the Sun's hidden, dynamo magnetic fields throughout the various stages of the Sun's cycle. Our solar dynamo ideas are a modernization and rejuvenation of the Babcock-Leighton original idea of a shallow solar dynamo, using modern observations that appear to support their shallow dynamo viewpoint. We are in awe of being able to see an object the size of the Sun undergoing as dramatic a change as our model provides in a few short years. The Sun, however, has undergone changes as rapid as this before! The weather on the Sun is at least as fickle as the weather on the Earth.
Schatten, Kenneth↗
Demonstration of the First 4H-SiC EUV Detector with Large Detection Area
Ultraviolet (UV) and Extreme Ultraviolet (EUV) detectors are very attractive in astronomy, photolithography and biochemical applications. For EUV applications, most of the semiconductor detectors based on PN or PIN structures suffer from the very short penetration depth. Most of the carries are absorbed at the surface and recombined there due to the high surface recombination before reach the depletion region, resulting very low quantum efficiency. On the other hand, for Schottky structures, the active region starts from the surface and carriers generated from the surface can be efficiently collected. 4H-Sic has a bandgap of 3.26eV and is immune to visible light background noise. Also, 4H-Sic detectors usually have very good radiation hardness and very low noise, which is very important for space applications where the signal is very weak. The E W photodiodes presented in this paper are based on Schottky structures. Platinum (Pt) and Nickel (Ni) are selected as the Schottky contact metals, which have the highest electron work functions (5.65eV and 5.15eV, respectively) among all the known metals on 4H-Sic.
Xin, Xiaobin↗
Extended Accelerated Stress Testing (EAST) of Glass/Glass, Glass/Backsheet and Glass/Transparent Backsheet PV Modules: Influence of EVA and POE Encapsulants: Preprint
This paper presents the indoor extended accelerated stress testing (EAST) results of glass/glass (GG), glass/backsheet (GB) and glass/transparent backsheet (GT) modules having identical cells and two different encapsulant types, ethyl-vinyl-acetate (EVA) and polyolefin-elastomer (POE). Six 4-cell modules having the above-mentioned construction combinations were subjected to extended ultraviolet (UV; 600 kWh/m2), damp-heat (DH; 2000 hours) and thermal-cycling (TC; 600 cycles) tests. The post-stress UV fluorescent imaging, electroluminescent imaging, reflectance spectrophotometry and colorimetry results indicated that the grid finger degradation and encapsulant browning are slightly higher in the GG modules compared to the GB modules. The post-stress IV test results indicated, in general, that the GG/EVA modules tend to perform inferior to the GG/POE modules with the EAST evaluation.
EVA↗
Ultraviolet Photooxidation of Smectite-Bound Fe(II) and Implications for the Origin of Martian Nontronites
Clay minerals detected with orbital and in situ instruments in ancient Martian terrains constrain Mars' climate and aqueous alteration history. Early in its history, Mars experienced an atmospheric redox change and iron-bearing clay minerals may preserve the effects of that transition. Ferrous smectites, the thermodynamically predicted product of chemical weathering of basalts under anoxic conditions, may have undergone oxidation by exposure to chemical oxidants in the atmosphere or regolith, or by direct photooxidation at the surface. To assess these potential oxidation pathways, ferrous trioctahedral smectites of varying initial iron content were synthesized and subjected to oxidation by ultraviolet (UV) irradiation. Experimental UV irradiation under an anoxic atmosphere equivalent to approximately 7 years of flux on the Martian surface caused partial oxidation of smectite-bound Fe (Fe3+/ΣFe = 16–18%) and octahedral sheet contraction. Metal-OH vibrational bands in visible/near infrared (VNIR) reflectance spectra of oxidized smectites changed in band depth and asymmetry with higher iron content. X-ray diffraction patterns of UV irradiated samples indicate the formation of a mixed di- and trioctahedral smectite or a secondary nontronite phase, possibly on the surfaces of higher iron content smectites. These experiments suggest that UV irradiation is able to oxidize structurally bound iron in smectites without the presence of other chemical oxidants. Photooxidation may have influenced the mineralogy, both syndepositionally and postdepositionally, of Martian alteration assemblages formed near the surface and this process needs not be limited to one part of their formation history. Plain Language Summary: Martian mineral assemblages observed with orbiters and rover instruments allow us to understand the planet's past climate and aqueous activity. Hydrated minerals that contain Fe(II) are of particular interest as they would have been affected by the early atmosphere becoming more oxidizing overtime, changing the structural iron into Fe(III). In this study, we synthesized Fe(II) smectites with varying iron content and irradiated them with an ultraviolet (UV) light source to test whether they could be photooxidized. Iron in the smectite minerals was incompletely oxidized by UV radiation after being exposed for the equivalent of approximately 7 years of exposure on the early Mars surface. The smectites with higher iron content showed more changes with photooxidation in their visible/near infrared spectra as well as in their X-ray diffraction patterns, two datasets collected by instruments on currently active Martian missions. These results suggest that UV photooxidation is a plausible contributor to the mineralogy and redox state of clay mineral assemblages observed at the Martian surface.
V. B. Rivera Banuchi↗
Degradation in Photovoltaic Encapsulant Transmittance: Results of the Second PVQAT TG5 Artificial Weathering Study
The optical degradation of encapsulants from ultraviolet (UV) radiation has historically resulted in a significant loss in performance throughout the life of a photovoltaic (PV) module. International Electrotechnical Commission (IEC) test methods have recently been developed to screen for PV encapsulants prone to loss in optical performance. The present study was performed to benchmark polymeric packaging materials relative to IEC 62788-1-4 (covering the measurement of optical transmittance) and IEC 62788-1-7 (on the durability of transmittance), provide feedback toward improvement of the methods, and develop insight regarding optical degradation. Contemporary materials were examined, including poly(ethylene-co-vinyl acetate) (EVA), thermoplastic polyolefin (TPO), polyolefin elastomer (POE), and polyvinyl butyral (PVB) encapsulants; a poly(ethene-co-tetrafluoroethene)/poly(ethylene terephthalate) (ETFE/PET) transparent backsheet; and a polystyrene (PS) working reference material. The use of silica-, specialty-, and rolled-glass was also compared in laminated coupons. Specimen size was separately examined from 2.5 to 12.5 cm. Weathering was performed with a xenon source, using IEC TS 62788-7-2 methods A2, A3, A4, and A5 (chamber temperature of 55 degrees C, 65 degrees C, 75 degrees C, or 85 degrees C), respectively. Characterizations were made using a UV-visible-near-infrared (UV-VIS-NIR) spectrophotometer (transmittance and reflectance, with and without an integrating sphere), a UV-VIS fluorescence spectrophotometer, a camera, and an optical microscope. Performance was analyzed, including solar weighted transmittance, yellowness index, UV cut-off wavelength, and haze (scattering). Separate Arrhenius analyses were performed to assess retention of transmittance and changes in yellowness index. The activation energy for both characteristics was found to range from 15-80 kJ mol-1, with an average of 48 kJ mol-1, similar to the average of 45 kJ mol-1 identified in the previous international PV Quality Assurance Task Force (PVQAT) Task Group 5 (TG5) study of more traditional encapsulants. The separate degradation modes of discoloration and scattering were distinguished in the encapsulants using a comprehensive spectral characterization. Based on these results, the IEC 62788-1-7 pass/fail criteria of 5% change in transmittance was confirmed to identify a known bad encapsulant.
durability↗
UV-SCOPE: Ultraviolet Spectroscopic Characterization of Planets and Their Environments
No abstract provided
Swain, Mark↗
The Indirect Effect of UV: Some Good News for Microbes?
Ultraviolet (UV) radiation is of great concern because its biological effects are predominantly harmful. UV damage may be direct or indirect, the latter mediated through the photochemical production of reactive oxygen species such as hydrogen peroxide. We measured the effect of H2O2 on various microbes both in the lab and in nature. At our study site in Yellowstone National Park, there is a UV-induced diurnal fluctuation of H2O2 extending up to one micron. Levels of DNA synthesis resulting from exposure to H2O2 were measured in several algal mats. Within naturally-occurring concentrations of H2O2, DNA synthesis increased. Laboratory studies showed that similar concentrations of H2O2 induce mitosis. We hypothesize that the low levels of H2O2 encountered in nature are inducing mitotic division. At higher levels of H2O2 a second peak in DNA synthesis was found which we interpret to represent DNA damage repair. These experiments suggest that in nature, the low levels of H2O2 produced may have a mitogenic rather than damaging effect. Assuming early levels of UV radiation were substantially higher at the time protists evolved, differential mitogenic effects could have influenced protistan evolution. With H2O2 likely to be present on such bodies as Mars and Europa, the response of organisms will be concentration-dependent and not linear.
Rothschild, Lynn J.↗
A New UV Spot Test for Quality Control
Here, we present a fast, low-cost ultraviolet (UV) spot test to screen photovoltaic modules for UV-induced degradation (UVID). The measurement is based on a fiber-coupled arc lamp that delivers a highly accelerated local UV dose-approximately five years of equivalent field exposure in less than a day. Spot-exposed areas are evaluated using electroluminescence imaging. We test a “known bad” product, which was observed to experience UVID in the field, and a “known good” product which did not exhibit UVID in the field. Results indicate that the method may be useful as a quick and relatively inexpensive quality control screening tool for customers and manufacturers.
14 SOLAR ENERGY↗
Accurate and Simple Parametrization to Estimate Solar UV from GHI and Other Accessible Variables
This study is part of a broader program that aims to generate reliable ultraviolet (UV) data for several applications. This work presents a simple and fast parametrization to estimate UV solar irradiation at the ground level from global horizontal irradiance (GHI) information. The work focuses on UVB (280-315 nm) and erythemic UV (UVE) irradiance weighted by the average skin response.
GHI↗
An ESR study of the UV degradation of FEP
Spacecraft in low earth orbit are subjected to significant levels of high energy radiation, including ultraviolet (UV) and visible ultraviolet (VUV) wavelengths. The effects of UV radiation are enhanced over those at the surface of the earth, where the only incident wavelengths are greater than 290 nm. In low earth orbit the incident UV wavelengths extend below 290 nm into the VUV region, where the Lyman alpha-emissions of atomic hydrogen occur at 121 nm. In addition to electromagnetic radiation, in low earth orbit polymer materials may also be subjected to atomic oxygen particle radiation, which will result in direct oxidation of the polymer.
George, G. A.↗
Distribution and nature of UV absorbers on Trition's surface
Substantial evidence suggests that a UV (ultraviolet) Spectrally Absorbing Material (UV-SAM) exists on Triton's surface. This evidence is found in the positive slope in Triton's spectrum from the UV to the near-IR, and the increasing contrast in Triton's light curve in the blue and UV. Although it is now widely-thought that UV-SAM's exist on Triton, little is known about their distribution and spectral properties. The goal of this NDAP Project is to determine the spatial distribution and geological context of the UV-SAM material. We hope to determine if UV-SAM's on Triton are correlated with geologic wind streaks, craters, calderas, geomorphic/topographic units, regions containing (or lacking) volatile frosts, or some other process (e.g., magnetospheric interactions). Once the location and distribution of UV-SAM's has been determined, further constraints on their composition can be made by analyzing the spectrographic data set. To accomplish these goals, various data sets will be used, including Voyager 2 UV and visible images of Triton's surface, IUE and HST spectra of Triton, and a geologic map of the surface based on Voyager 2 and spectrophotometric data. The results of this research will be published in the planetary science literature.
Stern, S. Alan↗
Formation of the UV Spectrum of Molecular Hydrogen in the Sun
Ultraviolet (UV) lines of molecular hydrogen have been observed in solar spectra for almost four decades, but the behavior of the molecular spectrum and its implications for solar atmospheric structure are not fully understood. Data from the High-Resolution Telescope Spectrometer (HRTS) instrument revealed that H2 emission forms in particular regions, selectively excited by a bright UV transition region and chromospheric lines. We test the conditions under which H2 emission can originate by studying non-LTE models, sampling a broad range of temperature stratifications and radiation conditions. Stratification plays the dominant role in determining the population densities of H2, which forms in greatest abundance near the continuum photosphere. However, opacity due to the photoionization of Si and other neutrals determines the depth to which UV radiation can penetrate to excite the H2. Thus the majority of H2 emission forms in a narrow region, at about 650 km in standard one dimensional (1D) models of the quiet Sun, near the tau = 1 opacity surface for the exciting UV radiation, generally coming from above. When irradiated from above using observed intensities of bright UV emission lines, detailed non-LTE calculations show that the spectrum of H2 seen in the quiet-Sun Solar Ultraviolet Measurement of Emitted Radiation atlas spectrum and HRTS light-bridge spectrum can be satisfactorily reproduced in 1D stratified atmospheres, without including three-dimensional or time-dependent thermal structures. A detailed comparison to observations from 1205 to 1550 Angstroms is presented, and the success of this 1D approach to modeling solar UV H2 emission is illustrated by the identification of previously unidentified lines and upper levels in HRTS spectra.
Jaeggli, S. A.↗