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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Geometrical effects on the measured neutron residual stress in additively manufactured cold spray AA6061

Aluminum cold spray additive builds were made with varying wall widths and geometries to explore the effects of build geometry on residual stress development in the additively sprayed material. Deposition rates of over 750 g/hr were achieved without any cracking or delamination of the additively manufactured components. Neutron residual stress measurements revealed a maximum tensile residual stress of 41 MPa at the interface of the substrate and a maximum compressive residual stress of −35 MPa in the cold sprayed material. While there was not found to be significant residual stress changes between the cold sprayed walls, the cold sprayed cylinder had varying residual stress throughout the diameter with the outer diameter having a higher tensile residual stress than the interior. The low residual stress and minimal geometrical dependency demonstrate further part size is possible without concerns for component failure in AA6061. The application of common coating residual stress models to full scale additive builds is evaluated and discussed. The lack of residual stress evolution was studied by in-situ coating property measurement that revealed that the deposition stress of the AA6061 sprays reduced with increased layer thickness. In conclusion, this study provides insight into the evolution of residual stress in cold spray additive components and how both the mechanics and material responses differ from coatings.

Additive manufacturing↗

Nanoconfinement-induced shift in photooxidative degradation pathway of polystyrene

Polymer nanocomposites with high concentrations of nanoparticles (NPs) possess exceptional mechanical, transport, and thermal properties. To enable their widespread use in structural applications and functional coatings, it is crucial to understand how nanoconfinement and the polymer-NP interface influence polymer degradation under various environmental conditions, including prolonged UV exposure. In this study, we investigate the photooxidative degradation of polystyrene (PS)-confined in the interstices of SiO 2 NP films. These nanocomposite films are prepared by the capillary rise infiltration (CaRI) of PS into interstices of SiO 2 NP packings, and subsequently subjected to UV irradiation. Our investigation reveals that PS degradation progresses uniformly across the thickness, with degradation initiating from the center of the NP interstitial pores and extending towards the NP surface. We rationalize this degradation mechanism based on the disparity in the surface energies of PS and the NP surface, as well as slow oxygen diffusion through confined PS. Here, we also demonstrate that packing smaller NPs at a given thickness or thicker packing of a specific NP size facilitates photooxidative degradation, highlighting the critical role of the number of interstitial pores in influencing degradation processes.

36 MATERIALS SCIENCE↗

Sustainable, degradable and malleable low-dielectric-constant thermosets derived from biomass for recyclable green electronics

In view of their excellent thermal and chemical resistance, favorable adhesion properties, high tensile strength, and other advantages, epoxy thermosets have numerous industrial applications such as coating, adhesive, and composite material production. However, bisphenol A (BPA)-based resins, which account for a significant fraction of the above thermosets, adversely affect human health by interfering with the normal functioning of the endocrine system and cannot be easily decomposed and recycled. Herein, degradable and sustainable bio-based epoxy thermosets with crosslinked network structures are prepared by the epoxidation of isosorbide with epichlorohydrin and the curing of the produced isosorbide diglycidyl ether (ISDGE) with cyclic lactones through a cationic ring-opening reaction. The ISDGE thermosets fully decompose into soluble and recyclable products under mildly basic conditions within three days, which is ascribed to the presence of ester moieties within the polymer network structure. Compared to a representative BPA-based epoxy, ISDGE-based thermosets exhibit lower dielectric constants and are more flexible. Moreover, the glass fibers in ISDGE-based prepregs can be fully recovered after on-demand degradation. Furthermore, our work provides promising eco-friendly alternatives to conventional epoxy thermosets and paves the way for the reduction of plastic waste generation and the development of recyclable green electronics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Multilayer refractory nozzles produced by plasma-spray process

Multilayer rocket nozzles formed by plasma spraying have good thermal shock resistance and can be reheated in an oxidizing environment without loss of coating adherence. Suggested application of this process are for the production of refractory components, which can be formed as surfaces of revolution.

Bliton, J. L.↗

Protective overcoating of films

Kodak Film Type SO-212 was emulsion overcoated with gelatin and lacquer to evaluate the feasibility of application of the coatings, any image degradation, and the relative protection offered against abrasion. Evaluated were: Eastman motion picture film lacquer Type 485, water solutions of Eastman purified Calfskin gelatin, and experimental Eastman gelatin stripping film of 4 and 6 microns. Conclusions reached were: (1) All coatings can be applied with relative ease with the only limitation being that of equipment. (2) None of the coatings degrade the processed image. (3) All of the coatings provide protection to the emulsion. These conclusions apply to any film which may be considered for overcoating.

Maas, K. A.↗

Silicon germanium technology program at JPL

Review of the results of a program aimed at obtaining a better understanding of the long-term performance of a thermoelectric generator using silicon germanium. The results obtained concern the contact resistivity of the thermoelectric couples, the electrical resistance of the multifoil thermal insulation, and the application of resistance coatings to the unicouples in order to prevent the loss of output power due to internal shunting paths.

Stapfer, G.↗

Surface lubrication of magnetic tape

Friction minimization between magnetic media (tape, cards, drums, etc.) and magnetic transducer (heads, etc.) is a key requirement in recording systems. Results are presented for an investigation intended to eliminate previously encountered shortcomings of friction-reducing treatments by a deposition of an inert liquid film on a fully manufactured (cured) magnetic medium. The film contains no particles, represents a compound characterized by good lubricating and thermal properties, is inert with respect to the normal formulation constituents, and has low surface tension and vapor pressure characteristics. The deposited film need only be molecularly thin to impart adequate lubricating properties to the tape. The discussion covers the characteristics of the surface lubricant, method of application, and surface coated magnetic media test results. Greater than 5 million passes of the 3M 900 tape on a loop tester are achieved with no apparent effect on the tape and with head wear decreased by as much as a factor of ten

Wright, C. D.↗

Coatings in space environment

The behavior in space environment of evaporated Al uncoated and coated with reactively deposited silicon oxide (SiOx), electron beam evaporated SiO2 and Al2O3, and Al and Ag coated with double layers of Al2O3 + SiOx is compared with metallized Teflon and Kapton, anodized Al (Alzak), and white paints. Flight data from three calorimetric experiments and one reflectometer flown in different orbital environments are compared with laboratory test data. The results demonstrate that evaporated thin films are extremely versatile and stable coatings for space applications. Through the use of control samples studied in different laboratory tests and monitored for up to 12,000 hours of solar exposure in different orbits, a classification of orbital severity and an estimate of laboratory simulation accuracy is obtained.

Triolo, J. J.↗

Plasma deposition and surface modification techniques for wear resistance

The ion-assisted or plasma coating technology is discussed as it applies to the deposition of hard, wear resistant refractory compound films. Of the many sputtering and ion plating modes and configurations the reactive magnetron sputtering and the reactive triode ion plating techniques are the preferred ones to deposit wear resistant coatings for tribological applications. Both of these techniques incorporate additional means to enhance the ionization efficiency and chemical reaction to precision tailor desirable tribological characteristics. Interrelationships between film formation, structure, and ribological properties are strictly controlled by the deposition parameters and the substrate condition. The enhanced ionization contributes to the excellent adherence and coherence, reduced internal stresses and improved structural growth to form dense, cohesive, equiaxed grain structure for improved wear resistance and control.

Spalvins, T.↗

Carbide/Fluoride/Silver Self-Lubricating Composite

Bearing coatings survive at operating temperatures up to 870 degrees C. PS200 composite self-lubricating coating for bearing applications operating at temperatures above failure points of traditional solid lubricants. Excellent friction and wear performance in oxidizing atmospheres up to 1,600 degrees F and reducing atmospheres up to 1,400 degrees F. Performance needed for development of advanced heat engines as adiabatic diesel and Stirling engine.

Sliney, Harold E.↗

Frontiers of technology

An evaluation is made of the Space Station technology assessment efforts conducted by NASA under its Advanced Development Program, which has over the last three years enlisted 14 different disciplines in the refinement of every aspect of Space Station interior and exterior design. Major investigations have delved into the application of novel coatings to materials subjected to prolonged exposure to radiation, the design of berthing and docking mechanisms, the demonstration of EVA structural assembly methods in a neutral buoyancy water tank, and an investigation of the effects of meteoroids and space debris on EVA garments, which have prompted the development of a novel 'hard' suit.

Carlisle, R.↗

Porosity determination of thermal barrier coatings

Coating porosity is believed to be a critical factor for the thermal conductivity of thermal barrier coatings (TBCs). A number of different techniques have been used to determine the porosities of thermal barrier coatings for diesel applications as part of a NASA/DOE sponsored study. A comparison is made between methods based on water immersion, optical microscopy, eddy current thickness measurements, and Archimedes principle for TBC porosity determination.

Van Roode, Mark↗

Transmittance measurements of ultra violet and visible wavelength interference filters flown aboard LDEF

A set of ten interference filters for the UV and VIS spectral region were flown on the surface of the Long Duration Exposure Facility (LDEF) Tray B-8 along with earth radiation budget (ERB) components from the Eppley Laboratory. Transmittance changes and other degradation observed after the return of the filters to Barr are reported. Substrates, coatings, and (where applicable) cement materials are identified. In general, all filters except those containing lead compounds survived well. Metal dielectric filters for the UV developed large numbers of pinholes which caused an increase in transmittance. Band shapes and spectral positioning, however, did not change.

Mooney, Thomas A.↗

Molecular-Weight-Controlled, End-Capped Polybenzimidazoles

Novel molecular-weight-controlled end-capped poly(arylene ether benzimidazole)s (PAEBI's) prepared by nucleophilic displacement reaction of di(hydroxyl)benzimidazole monomers with activated aromatic dihalides. Polymers prepared at various molecular weights by upsetting stoichiometry of monomers and end-capped with monohydroxybenzimidazole. Exhibit favorable physical and mechanical properties, improved solubility in polar aprotic solvents and better compression moldability. Potential applications as adhesives, coatings, films, fibers, membranes, moldings, and composite matrix resins.

Connell, John W.↗

Design and analysis of a fast, two-mirror soft-x-ray microscope

During the past several years, a number of investigators have addressed the design, analysis, fabrication, and testing of spherical Schwarzschild microscopes for soft-x-ray applications using multilayer coatings. Some of these systems have demonstrated diffraction limited resolution for small numerical apertures. Rigorously aplanatic, two-aspherical mirror Head microscopes can provide near diffraction limited resolution for very large numerical apertures. The relationships between the numerical aperture, mirror radii and diameters, magnifications, and total system length for Schwarzschild microscope configurations are summarized. Also, an analysis of the characteristics of the Head-Schwarzschild surfaces will be reported. The numerical surface data predicted by the Head equations were fit by a variety of functions and analyzed by conventional optical design codes. Efforts have been made to determine whether current optical substrate and multilayer coating technologies will permit construction of a very fast Head microscope which can provide resolution approaching that of the wavelength of the incident radiation.

Shealy, D. L.↗

Transparent conducting thin films for spacecraft applications

Transparent conductive thin films are required for a variety of optoelectronic applications: automotive and aircraft windows, and solar cells for space applications. Transparent conductive coatings of indium-tin-oxide (ITO)-magnesium fluoride (MgF2) and aluminum doped zinc oxide (AZO) at several dopant levels are investigated for electrical resistivity (sheet resistance), carrier concentration, optical properties, and atomic oxygen durability. The sheet resistance values of ITO-MgF2 range from 10(exp 2) to 10(exp 11) ohms/square, with transmittance of 75 to 86 percent. The AZO films sheet resistances range from 10(exp 7) to 10(exp 11) ohms/square with transmittances from 84 to 91 percent. It was found that in general, with respect to the optical properties, the zinc oxide (ZnO), AZO, and the high MgF2 content ITO-MgF2 samples, were all durable to atomic oxygen plasma, while the low MgF2 content of ITO-MgF2 samples were not durable to atomic oxygen plasma exposure.

Perez-Davis, Marla E.↗