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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

A Business Case for Nuclear Plant Control Room Modernization

This paper presents a generic business case for implementation of technology that supports Control Room Modernization (CRM). The analysis presented in two forms; 1) a standalone technology upgrade, and 2) a technology upgrade that is built upon and incremental to a prior business case created for Mobile Work Packages (MWP). The business case contends that advanced communication and networking and analytical technologies will allow NPP to conduct control room operations with improved focus by reducing human factors and redundant manpower, and therefore operate with fewer errors. While some labor savings can be harvested in terms of overtime, the majority of savings are demonstrated as reduced time to take the plant off line and bring back on line in support of outages. The benefits are quantified to a rough order of magnitude that provides directional guidance to NPPs that are interested in developing a similar business case. This business case focuses on modernization of the operator control room and does not consider a complete overhaul and modernization of a plants instrument and control systems. While operators may be considering such an investment at their plants, the sizable capital investment required is not likely supported by a cost/benefit analysis alone. More likely, it is driven by obsolescence and reliability issues, and requires consideration of mechanical condition of plant systems, capital depreciation, financing, relicensing and overall viability of the plant asset over a 20-year horizon in a competitive market. Prior studies [REF] have indicated that such a modernization of plant I&C systems, alone or as part of a larger modernization effort, can yield very significant reductions in O&M costs. However, the depth of research and analysis required to develop a meaningful business case for a plant modernization effort is well beyond the scope of this study. While CRM as considered in this study can be easily integrated as part of grander plant modernization effort, it can also be considered as a stand-alone project, implemented as a supervisorial layer over and above existing systems. CRM is enabled by a suite of technologies, which are described in further detail in the body of this report. They include: • Modernized control room with interactive displays • High-bandwidth wireless networks • Mobile devices • Component identification technology • Mobile wireless video cameras • Smart or task based operator displays • Computer-Based Procedures (CBP)/Automated Mobile Work Packages (MWP) • Intelligent plant configuration • Advanced data analytics An analysis was conducted to determine how these technologies might impact outage operations at an NPP. The analysis concluded that outage management capabilities would be improved with application of these technologies, and result in annual benefits for the plant. These improved capabilities were identified and described in further detail in this report. • Reduction in need redundant manpower (verification, etc) • Improved critical path shutdown and restart duration during outages • Reduction in human factors and errors • Remote watches • Paperless outage coordination • Bulk work optimization

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2014

ALMA observations of warm molecular gas and cold dust in NGC 34

We present Atacama Large Millimeter Array (ALMA) Cycle-0 observations of the CO (6-5) line emission (rest-frame frequency = 691.473 GHz) and of the 435 μm dust continuum emission in the nuclear region of NGC 34, a local luminous infrared galaxy at a distance of 84 Mpc (1'' = 407 pc) which contains a Seyfert 2 active galactic nucleus (AGN) and a nuclear starburst. The CO emission is well resolved by the ALMA beam (0.''26 × 0.''23), with an integrated flux of f {sub CO(6-5)} = 1004 (± 151) Jy km s{sup –1}. Both the morphology and kinematics of the CO (6-5) emission are rather regular, consistent with a compact rotating disk with a size of 200 pc. A significant emission feature is detected on the redshifted wing of the line profile at the frequency of the H{sup 13}CN (8-7) line, with an integrated flux of 17.7 ± 2.1(random) ± 2.7(systematic) Jy km s{sup –1}. However, it cannot be ruled out that the feature is due to an outflow of warm dense gas with a mean velocity of 400 km s{sup –1}. The continuum is resolved into an elongated configuration, and the observed flux corresponds to a dust mass of M {sub dust} = 10{sup 6.97±0.13} M {sub ☉}. An unresolved central core (radius ≅ 50 pc) contributes 28% of the continuum flux and 19% of the CO (6-5) flux, consistent with insignificant contributions of the AGN to both emissions. Both the CO (6-5) and continuum spatial distributions suggest a very high gas column density (≳ 10{sup 4} M {sub ☉} pc{sup –2}) in the nuclear region at radius ≲ 100 pc.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Ab initio calculations for Be-isotopes with JISP16

We present recent results from no-core configuration interaction calculations for 8 Be, 10 Be, and 12 Be using the phenomenological two-body interaction JISP16. We calculate the binding energies of the ground state and the excitation energies of the low-lying positive-parity states. We discuss the contributions from the proton and neutron intrinsic spin and orbital motion to the total spin for several states, and use this to identify states which may be dominated by α-cluster configurations. In addition, we also calculate other observables such as dipole and quadrupole moments, as well as transition rates for select E2 transitions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Extended Interacting Boson Model with Configuration Mixing Description For 98 Mo

An extended version of the interacting boson model (IBM), encompassing two-particle–two-hole (2p-2h) excitations originating from below a valence shell and one-particle–one-hole (1p-1h) excitations extending to the upper next-nearest major shell, is developed to investigate cross-shell excitation effects in the transitional nucleus 98 Mo. This extended IBM framework is utilized to reproduce experimentally observed properties such as low-lying positive-parity level energies, 𝐵⁡(𝐸⁢2) values, and the electric quadrupole moment of the 2$^{+}_{1}$ state, 𝜌 2 ⁡(𝐸⁢0, 0$^{+}_{2}$ → 0$^{+}_{g}$), as well as the strength functions of the isoscalar giant monopole resonance (ISGMR) and the isoscalar giant quadrupole resonance (ISGQR) in 98 Mo. It is shown that the extended consistent-𝑄 IBM, incorporating configuration mixing of both 2p-2h excitations from below the valence shell and 1p-1h excitations to the upper next-nearest major shell, describes the low-lying structural properties and the ISGMR and ISGQR strength distributions of 98 Mo quite well, with the ISGMR and the ISGQR strength distributions comparable to the results of the self-consistent quasiparticle random-phase approximation with Skyrme interactions.

90 ≤ A ≤ 149↗
DOE OSTI2014

Resonance ionization laser ion sources for on-line isotope separators (invited)

A Resonance Ionization Laser Ion Source (RILIS) is today considered an essential component of the majority of Isotope Separator On Line (ISOL) facilities; there are seven laser ion sources currently operational at ISOL facilities worldwide and several more are under development. The ionization mechanism is a highly element selective multi-step resonance photo-absorption process that requires a specifically tailored laser configuration for each chemical element. For some isotopes, isomer selective ionization may even be achieved by exploiting the differences in hyperfine structures of an atomic transition for different nuclear spin states. For many radioactive ion beam experiments, laser resonance ionization is the only means of achieving an acceptable level of beam purity without compromising isotope yield. Furthermore, by performing element selection at the location of the ion source, the propagation of unwanted radioactivity downstream of the target assembly is reduced. Whilst advances in laser technology have improved the performance and reliability of laser ion sources and broadened the range of suitable commercially available laser systems, many recent developments have focused rather on the laser/atom interaction region in the quest for increased selectivity and/or improved spectral resolution. Much of the progress in this area has been achieved by decoupling the laser ionization from competing ionization processes through the use of a laser/atom interaction region that is physically separated from the target chamber. A new application of gas catcher laser ion source technology promises to expand the capabilities of projectile fragmentation facilities through the conversion of otherwise discarded reaction fragments into high-purity low-energy ion beams. A summary of recent RILIS developments and the current status of laser ion sources worldwide is presented.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

A structure-based mechanism for displacement of the HEXIM adapter from 7SK small nuclear RNA

Productive transcriptional elongation of many cellular and viral mRNAs requires transcriptional factors to extract pTEFb from the 7SK snRNP by modulating the association between HEXIM and 7SK snRNA. In HIV-1, Tat binds to 7SK by displacing HEXIM. However, without the structure of the 7SK-HEXIM complex, the constraints that must be overcome for displacement remain unknown. Furthermore, while structure details of the Tat NL4-3 -7SK complex have been elucidated, it is unclear how subtypes with more HEXIM-like Tat sequences accomplish displacement. Here we report the structures of HEXIM, Tat G , and Tat Fin arginine rich motifs in complex with the apical stemloop-1 of 7SK. While most interactions between 7SK with HEXIM and Tat are similar, critical differences exist that guide function. First, the conformational plasticity of 7SK enables the formation of three different base pair configurations at a critical remodeling site, which allows for the modulation required for HEXIM binding and its subsequent displacement by Tat. Furthermore, the specific sequence variations observed in various Tat subtypes all converge on remodeling 7SK at this region. Second, we show that HEXIM primes its own displacement by causing specific local destabilization upon binding — a feature that is then exploited by Tat to bind 7SK more efficiently.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

A dual wavelength imaging system for plasma-surface interaction studies on the National Spherical Torus Experiment Upgrade

A two-channel spectral imaging system based on a charge injection device radiation-hardened intensified camera was built for studies of plasma-surface interactions on divertor plasma facing components in the National Spherical Torus Experiment Upgrade (NSTX-U) tokamak. By means of commercially available mechanically referenced optical components, the two-wavelength setup images the light from the plasma, relayed by a fiber optic bundle, at two different wavelengths side-by-side on the same detector. Remotely controlled filter wheels are used for narrow bandpass and neutral density filters on each optical path allowing for simultaneous imaging of emission at wavelengths differing in brightness up to 3 orders of magnitude. Applications on NSTX-U will include the measurement of impurity influxes in the lower divertor strike point region and the imaging of plasma-material interaction on the head of the surface analysis probe MAPP (Material Analysis and Particle Probe). The diagnostic setup and initial results from its application on the lithium tokamak experiment are presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2017

Role of atomic-level defects and electronic energy loss on amorphization in LiNbO 3 single crystals

Understanding complex non-equilibrium defect processes, where multiple irradiation mechanisms may take place simultaneously, is a long standing subject in material science. The separate and combined effects of elastic and inelastic energy loss are a very complicated and challenging topic. In this work, LiNbO 3 has been irradiated with 0.9 MeV Si + and 8 MeV O 3+ , which are representative of regimes where nuclear (S n ) and electronic (S e ) energy loss are dominant, respectively. The evolution of damage has been investigated by Rutherford backscattering spectrometry (RBS) in channeling configuration. Pristine samples were irradiated with 0.9 MeV Si + ions to create different pre-existing damage states. Below the threshold (S e,th = 5–6 keV nm –1 ) for amorphous track formation in this material, irradiation of the pristine samples with a highly ionizing beam of 8 MeV O 3+ ions, with nearly constant S e of about 3 keV nm –1 , induces a crystalline to amorphous phase transition at high ion fluences. In the pre-damaged samples, the electronic energy loss from the 8 MeV O 3+ ions interacts synergistically with the pre-existing damage, resulting in a rapid, non-linear increase in damage production. There is a significant reduction in the incubation fluence for rapid amorphization with the increasing amount of pre-existing damage. Here, these results highlight the important role of atomic-level defects on increasing the sensitivity of some oxides to amorphization induced by electronic energy loss. Controlling the nature and amount of pre-damage may provide a new approach to tuning optical properties for photonic device applications.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Solution structure of the N-terminal domain of proteasome lid subunit Rpn5

The 26S proteasome is the major protein degradation machinery in living cells. The Rpn5 protein is one scaffolding subunit in the lid subcomplex of the 19S regulatory particle in the proteasome holoenzyme. Herein we report the solution structure of the N-terminal domain (NTD) of yeast Rpn5 at high resolution by NMR spectroscopy. The results show that Rpn5 NTD adopts α-solenoid-like fold in right-handed superhelical configuration formed by a number of α-helices. Structural comparisons with currently available cryo-EM structures reveal local structural differences in the first three helices between yeast and human Rpn5. The results further highlight the conformational flexibility in three possible protein interaction sites. Moreover, the structures of the NTD show large variations among different PCI-containing Rpn subunits. Our current results provide atomic-level structural basis for further investigations of protein-protein interactions and the proteasome assembly pathway.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2013

Comparison Between Numerical and Experimental Results on Mechanical Stirrer and Bubbling in a Cylindrical Tank - 13047

The process of vitrification in a cold crucible heated by direct induction is used in the fusion of oxides. Its feature is the production of high-purity materials. The high-level of purity of the molten is achieved because this melting technique excludes the contamination of the charge by the crucible. The aim of the present paper is to analyze the hydrodynamic of the vitrification process by direct induction, with the focus in the effects associated with the interaction between the mechanical stirrer and bubbling. Considering the complexity of the analyzed system and the goal of the present work, we simplified the system by not taking into account the thermal and electromagnetic phenomena. Based in the concept of hydraulic similitude, we performed an experimental study and a numerical modeling of the simplified model. The results of these two studies were compared and showed a good agreement. The results presented in this paper in conjunction with the previous work contribute to a better understanding of the hydrodynamics effects resulting from the interaction between the mechanical stirrer and air bubbling in the cold crucible heated by direct induction. Further works will take into account thermal and electromagnetic phenomena in the presence of mechanical stirrer and air bubbling. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Sudoku Online Testing Framework v.0.2

The Sudoku Online Testing Framework provides a configurable basis for testing user interactions to solve visualization-related problems with sudoku puzzles and games. It consists of a server, a client, and test code. The python server implements sudoku puzzle logic and board selection functions. The JavaScript client implements a graphical user interface (GUI) front-end to display the puzzles and facilitate interactions with users. Within the GUI, logical rules may be selected. Cells may be selected to “pivot” on to make a board for each possible value in the cell. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525. SAND2021-6409 O

Leger, Michelle↗
NASA NTRS2017

Advanced Stirling Convertor Control Unit Testing at NASA Glenn Research Center in the Radioisotope Power Systems System Integration Laboratory

Future NASA missions could include establishing Lunar or Martian base camps, exploring Jupiters moons and travelling beyond where generating power from sunlight may be limited. Radioisotope Power Systems (RPS) provide a dependable power source for missions where inadequate sunlight or operational requirements make other power systems impractical. Over the past decade, NASA Glenn Research Center (GRC) has been supporting the development of RPSs. The Advanced Stirling Radioisotope Generator (ASRG) utilized a pair of Advanced Stirling Convertors (ASC). While flight development of the ASRG has been cancelled, much of the technology and hardware continued development and testing to guide future activities. Specifically, a controller for the convertor(s) is an integral part of a Stirling-based RPS. For the ASRG design, the controller maintains stable operation of the convertors, regulates the alternating current produced by the linear alternator of the convertor, provides a specified direct current output voltage for the spacecraft, synchronizes the piston motion of the two convertors in order to minimize vibration as well as manage and maintain operation with a stable piston amplitude and hot end temperature. It not only provides power to the spacecraft but also must regulate convertor operation to avoid damage to internal components and maintain safe thermal conditions after fueling. Lockheed Martin Coherent Technologies has designed, developed and tested an Engineering Development Unit (EDU) Advanced Stirling Convertor Control Unit (ACU) to support this effort. GRC used the ACU EDU as part of its non-nuclear representation of a RPS which also consists of a pair of Dual Advanced Stirling Convertor Simulator (DASCS), and associated support equipment to perform a test in the Radioisotope Power Systems System Integration Laboratory (RSIL). The RSIL was designed and built to evaluate hardware utilizing RPS technology. The RSIL provides insight into the electrical interactions between as many as 3 radioisotope power generators, associated control strategies, and typical electric system loads. The first phase of testing included a DASCS which was developed by Johns Hopkins UniversityApplied Physics Laboratory and simulates the operation and electrical behavior of a pair of ASCs in real time via a combination of hardware and software. Testing included the following spacecraft electrical energy storage configurations: capacitive, battery, and supercapacitor. Testing of the DASCS and ACU in each energy storage configuration included simulation of a typical mission profile, and transient voltage and current data during load turn-on/turn-off. Testing for these devices also included the initiation of several system faults such as short circuits, electrical bus over-voltage, under-voltage and a dead bus recovery to restore normal power operations. The goal of this testing was to verify operation of the ACU(s) when connected to a spacecraft electrical bus.

Dugala, Gina M.↗
DOE OSTI2015

Apparatuses for large area radiation detection and related method

Apparatuses and a related method relating to radiation detection are disclosed. In one embodiment, an apparatus includes a first scintillator and a second scintillator adjacent to the first scintillator, with each of the first scintillator and second scintillator being structured to generate a light pulse responsive to interacting with incident radiation. The first scintillator is further structured to experience full energy deposition of a first low-energy radiation, and permit a second higher-energy radiation to pass therethrough and interact with the second scintillator. The apparatus further includes a plurality of light-to-electrical converters operably coupled to the second scintillator and configured to convert light pulses generated by the first scintillator and the second scintillator into electrical signals. The first scintillator and the second scintillator exhibit at least one mutually different characteristic for an electronic system to determine whether a given light pulse is generated by the first scintillator or the second scintillator.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Method, apparatus and system for low-energy beta particle detection

An apparatus, method, and system relating to radiation detection of low-energy beta particles are disclosed. An embodiment includes a radiation detector with a first scintillator and a second scintillator operably coupled to each other. The first scintillator and the second scintillator are each structured to generate a light pulse responsive to interaction with beta particles. The first scintillator is structured to experience full energy deposition of low-energy beta particles, and permit a higher-energy beta particle to pass therethrough and interact with the second scintillator. The radiation detector further includes a light-to-electrical converter operably coupled to the second scintillator and configured to convert light pulses generated by the first scintillator and the second scintillator into electrical signals. The first scintillator and the second scintillator have at least one mutually different characteristic to enable an electronic system to determine whether a given light pulse is generated in the first scintillator or the second scintillator.

36 MATERIALS SCIENCE↗
DOE OSTI2023

PERLE: A novel facility for ERL development and applications in multi-turn configuration and high-power regime

The development of ERLs has been recognized as one of the five main pillars of accelerators R&D in support of the European Strategy for Particle Physics (ESPP). The international panel in charge of the ERL Roadmap definition recognized PERLE project as “a central part of the roadmap for the development of energy-recovery linacs”, with milestones to be achieved by the next ESPP in 2026. PERLE project is aiming at the construction of a novel ERL facility for the development and application of the energy recovery technique in multi-turn configuration, high current and large energy regime. It will operate in a 3-turns mode, first at 250 MeV, then upgraded to 500 MeV with 20mA beam current. Such challenging parameters make PERLE a unique multi-turn ERL facility operating at an unexplored operational power regime (10MW), studying and validating a broad range of accelerator phenomena, paving the way for the future larger scale ERLs. PERLE will be the necessary demonstrator for the future HEP machine (LHeC / FCC-eh), with which it shares the same technological choices and beam parameters. Furthermore, PERLE opens a new frontier for the physics of “the electromagnetic probe”. It will be the first ERL dedicated to Nuclear Physics for studying the eN interaction with radioactive nuclei. Here we will report on the project status, introduce the main ongoing achievements and describe the staged strategy we will adopt toward the construction of PERLE machine at its nominal performances.

Kaabi, Walid↗
DOE OSTI2013

Concepts and Tests for the Remote-Controlled Dismantling of the Biological Shield and Form work of the KNK Reactor - 13425

The compact sodium-cooled nuclear reactor facility Karlsruhe (KNK), a prototype Fast Breeder, is currently in an advanced stage of dismantling. Complete dismantling is based on 10 partial licensing steps. In the frame of the 9. decommissioning permit, which is currently ongoing, the dismantling of the biological shield is foreseen. The biological shield consists of heavy reinforced concrete with built-in steel fitments, such as form-work of the reactor tank, pipe sleeves, ventilation channels, and measuring devices. Due to the activation of the inner part of the biological shield, dismantling has to be done remote-controlled. During a comprehensive basic design phase a practical dismantling strategy was developed. Necessary equipment and tools were defined. Preliminary tests revealed that hot wire plasma cutting is the most favorable cutting technology due to the geometrical boundary conditions, the varying distance between cutter and material, and the heavy concrete behind the steel form-work. The cutting devices will be operated remotely via a carrier system with an industrial manipulator. The carrier system has expandable claws to adjust to the varying diameter of the reactor shaft during dismantling progress. For design approval of this prototype development, interaction between manipulator and hot wire plasma cutting was tested in a real configuration. For the demolition of the concrete structure, an excavator with appropriate tools, such as a hydraulic hammer, was selected. Other mechanical cutting devices, such as a grinder or rope saw, were eliminated because of concrete containing steel spheres added to increase the shielding factor of the heavy concrete. Dismantling of the biological shield will be done in a ring-wise manner due to static reasons. During the demolition process, the excavator is positioned on its tripod in three concrete recesses made prior to the dismantling of the separate concrete rings. The excavator and the manipulator carrier system will be operated alternately. Main boundary condition for all the newly designed equipment is the decommissioning housing of limited space within the reactor building containment. To allow for a continuous removal of the concrete rubble, an additional opening on the lowest level of the reactor shaft will be made. All equipment and the interaction of the tools have to be tested before use in the controlled area. Therefore a full-scale model of the biological shield will be provided in a mock-up. The tests will be performed in early 2014. The dismantling of the biological shield is scheduled for 2015. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2025

Seismic response of vertical dry storage casks under three-dimensional earthquake motions

Ensuring the long-term seismic safety of dry storage casks (DSCs) is becoming increasingly critical as these systems evolve from temporary to de facto permanent repositories for spent nuclear fuels. Traditional seismic soil–structure interaction (SSI) assessment methods use one-dimensional deconvolution or simplified boundary conditions to model incident waves. Although computationally appealing, simplifying assumptions may alter the seismic risk by neglecting the full complexity of three-dimensional (3D) wave propagation effects. To address this challenge, this paper introduces a novel high-fidelity computational framework that leverages the Domain Reduction Method (DRM) with perfectly matched layers (PML) to accurately transfer complex, 3D seismic wavefields from regional-scale fault-rupture simulations into local-scale finite element models of DSCs. Using broadband, physics-based ground motions from a generic M w 7.0 strike-slip event, both single-cask and multi-cask configurations were investigated under near- and far-field conditions. Emphasis is placed on capturing complex SSI, spatial variability in the ground motion, and nonlinear phenomena such as cask rocking and sliding. Numerical results demonstrate that near-field conditions, where forward directivity and fling-step effects dominate, lead to significantly higher DSC rocking and sliding. Far-field cases, by contrast, generally exhibit modest responses. Incorporating SSI tends to amplify or alter DSC response spectra and introduce response variability, which underscores the need for site-specific evaluations and robust modeling approaches to ensure the seismic integrity of DSCs in interim spent fuel storage installations.

Das, Tonmoy↗
DOE OSTI2021

Valence shell photoelectron angular distributions and vibrationally resolved spectra of imidazole: A combined experimental–theoretical study

Linearly polarized synchrotron radiation has been used to record polarization dependent valence shell photoelectron spectra of imidazole in the photon energy range 21–100 eV. These have allowed the photoelectron angular distributions, as characterized by the anisotropy parameter β, and the electronic state intensity branching ratios to be determined. Complementing these experimental data, theoretical photoionization partial cross sections and β-parameters have been calculated for the outer valence shell orbitals. The assignment of the structure appearing in the experimental photoelectron spectra has been guided by vertical ionization energies and spectral intensities calculated by various theoretical methods that incorporate electron correlation and orbital relaxation. Strong orbital relaxation effects have been found for the 15a', nitrogen lone-pair orbital. The calculations also predict that configuration mixing leads to the formation of several low-lying satellite states. The vibrational structure associated with ionization out of a particular orbital has been simulated within the Franck–Condon model using harmonic vibrational modes. The adiabatic approximation appears to be valid for the X 2A" state, with the β-parameter for this state being independent of the level of vibrational excitation. However, for all the other outer valence ionic states, a disparity occurs between the observed and the simulated vibrational structure, and the measured β-parameters are at variance with the behavior expected at the level of the Franck–Condon approximation. Furthermore, these inconsistencies suggest that the excited electronic states may be interacting vibronically such that the nuclear dynamics occur over coupled potential energy surfaces.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗