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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Effects of convection electric field on the distribution of ring current type protons

The topology of the boundaries of penetration (or, inversely, the boundaries of the forbidden regions) of 90-deg pitch-angle equatorial protons with energies less than 100 keV are explored for an equatorial convection E-field which is directed in general from dawn to dusk. Due to the dependence of drift path on energy (or magnetic moment), complex structural features are expected in the proton energy spectra detected by satellites since the penetration distance of a proton is not a monotonically increasing or decreasing function of energy. During a storm when the convection E is enhanced, model calculations predict elongations of the forbidden regions analogous to tail extensions of the plasmasphere. Following a reduction in the convection field, spiral-structured forbidden regions can occur. Structural features inherent to large-scale convection field changes may be seen in the nose-like proton spectrograms observed near dusk by instrumentation on Explorer 45. These nose events are modelled by using an electric field model developed originally by Volland (1973). The strength of the field is related to the Kp index through night-time equatorial plasmapause measurements.

Grebowsky, J. M.↗
NASA NTRS1994

Investigation of the stability and 1.0 MeV proton radiation resistance of commercially produced hydrogenated amorphous silicon alloy solar cells

The radiation resistance of commercial solar cells fabricated from hydrogenated amorphous silicon alloys is reported. A number of different device structures were irradiated with 1.0 MeV protons. The cells were annealing at 200 C. The annealing time was dependent on proton fluence. Annealing devices for one hour restores cell parameters or fluences below 1(exp 14) cm(exp -2); fluences above 1(exp 14) cm(exp -2) require longer annealing times. A parametric fitting model was used to characterize current mechanisms observed in dark I-V measurements. The current mechanisms were explored with irradiation fluence, and voltage and light soaking times. The thermal generation current density and quality factor increased with proton fluence. Device simulation shows the degradation in cell characteristics may be explained by the reduction of the electric field in the intrinsic layer.

Lord, Kenneth R., II↗
NASA NTRS1994

Investigation of the Stability and 1.0 MeV Proton Radiation Resistance of Commercially Produced Hydrogenated Amorphous Silicon Alloy Solar Cells

The radiation resistance of commercial solar cells fabricated from hydrogenated amorphous silicon alloys is reported. A number of different device structures were irradiated with 1.0 MeV protons. The cells were insensitive to proton fluences below 1E12 sq cm. The parameters of the irradiated cells were restored with annealing at 200 C. The annealing time was dependent on proton fluence. Annealing devices for one hour restores cell parameters for fluences below 1E14 sq cm fluences above 1E14 sq cm require longer annealing times. A parametric fitting model was used to characterize current mechanisms observed In dark I-V measurements. The current mechanism were explored with irradiation fluence, and voltage and light soaking times. The thermal generation current density and quality factor increased with proton fluence. Device simulation shows the degradation in cell characteristics may be explained by the reduction of the electric field in the intrinsic layer.

Lord, Kenneth R., II↗
DOE OSTI2025

Database of Nonaqueous Proton-Conducting Materials

This work presents the assembly of 48 papers, representing 74 different compounds and blends, into a machine-readable database of nonaqueous proton-conducting materials. SMILES was used to encode the chemical structures of the molecules, and we tabulated the reported proton conductivity, proton diffusion coefficient, and material composition for a total of 3152 data points. The data spans a broad range of temperatures ranging from -70 to 260 °C. To explore this landscape of nonaqueous proton conductors, DFT was used to calculate the proton affinity of 18 unique proton carriers. The results were then compared to the activation energy derived from fitting experimental data to the Arrhenius equation. It was found that while the widely recognized positive correlation between the activation energy and proton affinity may hold among closely related molecules, this correlation does not necessarily apply across a broader range of molecules. This work serves as an example of the potential analyses that can be conducted using literature data combined with emerging research tools in computation and data science to address specific materials design problems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

Approximations for neutron emission spectra from proton collisions between 20 and 500 MeV on nuclei of A greater than or equal to 12

When high energy protons from solar proton events or trapped radiation belts impinge on spacecraft structures, secondary particles are emitted. The most pernicious secondaries, from either a biological or physical standpoint, are the cascade and evaporation neutrons because of their reaction with matter leading to radioactive materials in the spacecraft structures. Empirically determined cascade and evaporation neutron emission spectra for protons of energy between 20 and 500 MeV incident on all materials at or above carbon in mass number are presented.

Burrell, M. O.↗
DOE OSTI2020

Physically Based Modeling of PEMFC Cathode Catalyst Layers: Effective Microstructure and Ionomer Structure–Property Relationship Impacts

Abstract This work presents a pseudo-two-dimensional proton exchange membrane fuel cell (PEMFC) model incorporating Nafion ionomer structure–property relationships in the cathode catalyst layer (CL) to capture and explain losses at low Pt loading. Structural data from neutron reflectometry and thin film Nafion conductivity measurements predict variations in the oxygen diffusion coefficient and ionic conductivity with changing CL ionomer thickness and Pt loading. By including these structure–property relationships, predicted polarization curves agree closely with previously published experimental data from cells with Pt loadings between 0.025 and 0.2 mg/cm2. Results demonstrate that structure–property relationships based on physically measurable ionomer and CL properties provide a feasible interpretation of PEMFC CL phenomena for a range of Pt loadings and help explain previously unaccounted-for losses at low Pt. Results also show that simulations must account for surface species coverage variations in order to properly capture the kinetic losses. Finally, results suggest that an increase in ionomer thickness surrounding the C/Pt surfaces may lead to improved cell performance due to improved ionic conductivity.

Electrochemistry↗
DOE OSTI2021

Simultaneous Observation of Two Isolated Proton Auroras at Subauroral Latitudes by a Highly Sensitive All-Sky Camera and Van Allen Probes

Isolated proton auroras (IPAs) appearing at subauroral latitudes are generated by energetic protons precipitating from the magnetosphere through interaction with electromagnetic ion cyclotron (EMIC) waves. An IPA thus indicates the spatial scale and temporal variation of wave-particle interactions in the magnetosphere. In this study, a unique event of simultaneous ground and magnetospheric satellite observations of two IPAs were conducted on March 16, 2015, using an all-sky imager at Athabasca, Canada and Van Allen Probes. The Van Allen Probes observed two isolated EMIC waves with frequencies of ~1 and 0.4 Hz at L ≈ 5.0 when the satellite footprint crossed over the two IPAs. This suggests that the IPAs were caused by localized EMIC waves. Proton flux at 5–20 keV increased locally when the EMIC waves appeared. Electron flux at energies below ~500 eV also increased. Temperature anisotropy of the energetic protons was estimated at 1.5–2.5 over a wide L-value range of 3.0–5.2. Electron density gradually decreased from L = 3.5 to 5.4, suggesting that the EMIC wave at L ≈ 5.0 was located in the gradual plasmapause. From these observations, we conclude that the localized IPAs and associated EMIC waves took place because of localized enhancement of energetic proton flux and plasma density structure near the plasmapause. Furthermore, the magnetic field observed by the satellite showed small variation during the wave observation, indicating that the IPAs were accompanied by the weak field-aligned current.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1987

Radiation performance of AlGaAs concentrator cells and expected performance of cascade structures

Aluminum gallium arsenide, GaAs, silicon and InGaAs cells have been irradiated with 1 MeV electrons and 37 MeV protons. These cells are candidates for individual cells in a cascade structure. Data is presented for both electron and proton irradiation studies for one sun and a concentration level of 100X AMO. Results of calculations on the radiation resistance of cascade cell structures based on the individual cell data are also presented. Both series connected and separately connected structures are investigated.

Curtis, Henry B.↗
NASA NTRS1987

Radiation performance of AlGaAs and InGaAs concentrator cells and expected performance of cascade structures

Aluminum gallium arsenide, GaAs, silicon and InGaAs cells have been irradiated with 1-MeV electrons and 37-MeV protons. These cells are candidates for individual cells in a cascade structure. Data are presented for both electron and proton irradiation studies for one sun and a concentration level of 100X AM0. Results of calculations on the radiation resistance of cascade cell structures based on the individual cell data are also presented. Both series-connected and separately connected structures are investigated.

Curtis, H. B.↗
NASA NTRS2006

Optimizing Crystal Volume for Neutron Diffraction

Neutron diffraction is uniquely sensitive to hydrogen positions and protonation state. In that context structural information from neutron data is complementary to that provided through X-ray diffraction. However, there are practical obstacles to overcome in fully exploiting the potential of neutron diffraction, Le. low flux and weak scattering. Several approaches are available to overcome these obstacles and we have investigated the simplest: increasing the diffracting volume of the crystals. Volume is a quantifiable metric that is well suited for experiment design and optimization techniques. By using response surface methods we have optimized xylose isomerase crystal volume, enabling neutron diffraction while we determined the crystallization parameters with the minimum of experiments. Our results suggest a systematic means of enabling neutron diffraction studies for a larger number of samples that require information on hydrogen position and/or protonation state.

Snell, Edward H.↗
DOE OSTI2026

Environmental Contributions to Proton Sharing in Protein Low-Barrier Hydrogen Bonds

Hydrogen bonds (H-bonds) are central to biomolecular structure and dynamics. Although H-bonds are typically characterized by well-defined proton positions, proton delocalization has been proposed to play a role in facilitating enzyme catalysis and allostery in some systems. Experimentally locating protons is difficult, hampering the study of proton mobility in H-bonds. We used neutron crystallography, atomic resolution X-ray bond length analysis, and large quantum mechanics/molecular mechanics-Born–Oppenheimer molecular dynamics (QM/MM-BOMD) simulations to comprehensively characterize the shared proton/deuteron in a Glu–Asp low-barrier hydrogen bond (LBHB) in the bacterial protein YajL that is a conventional H-bond in the homologous disease-associated human protein DJ-1. X-ray bond length analysis of protiated and perdeuterated DJ-1 and YajL shows no significant effect of deuteron substitution on these carboxylic acid-carboxylate H-bonds but does reveal an effect at the active site glutamic acid near a cysteine thiolate. Residues in an H-bonded network that might favor LBHB formation in YajL were interrogated by the mutation of homologous residues in DJ-1. A distal DJ-1 substitution increases proton delocalization in the Glu–Asp H-bond, demonstrating that mutations within extended H-bond networks can modulate proton transfer barriers in carboxylic acid-carboxylate H-bonds. In addition, proton mobility in the H-bond is correlated with dimer-spanning motions in the QM/MM-BOMD simulations of YajL and DJ-1. Our results show that proton delocalization can be tuned using combined bioinformatic, structural, and computational information, opening the possibility of using engineered proton delocalization as a probe of H-bonding environments and as a tool to test hypotheses about LBHB function.

Lin, Jiusheng [University of Nebraska, Lincoln, NE↗
NASA NTRS1985

Microscopic defect structures and equivalent electron fluence concepts

The lack of additivity of proton and electron exposure of GaAs solar cells has been established as due to macroscopic variations in defect densities. The difference in annealing in proton and electron exposure is herein related to the microscopic variation in defect structures. Electron equivalence can be established when annealing is present only for high energy electrons.

Stith, John J.↗
DOE OSTI2021

Incorporating bubble growth volume feedback to improve simulation of the response of a structure containing liquid and gas to sudden energy input

The SNS target module is a stainless-steel structure that contains and directs mercury. The mercury is struck with short, intense proton pulses to create neutrons. The pulses deposit energy and cause loads on the target structure and mercury cavitation. Helium bubbles are introduced into the mercury to reduce loads and cavitation. This gas complicates the prediction of the target module’s physical response. The current method used to simulate the structural response to the proton pulse incorporates a simple but effective approach to approximate mercury cavitation effects. This method cannot account for the changes from injected non-condensable gas. The ability to model the target vessel response is a prerequisite for estimating its life. Known approaches for simulating a bubbly fluid mixture’s response are computationally expensive and impractical for detailed engineering models. A constitutive model is proposed for target mercury with injected gas bubbles, with the intent of providing more accurate mercury–vessel response behavior without the computing costs required to track individual bubbles. The model’s assumptions and a computational model embodiment are described. The bubbly mercury computational model is subjected to test problems to assess its potential utility. Here, the model was able to better predict the effect of gas on wave propagation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1976

Structure of a quasi-parallel, quasi-laminar bow shock

A thick, quasi-parallel bow shock structure was observed with field and particle detectors of both HEOS 1 and OGO 5. The typical magnetic pulsation structure was at least 1 to 2 earth radii thick radially and was accompanied by irregular but distinct plasma distributions characteristic of neither the solar wind nor the magnetosheath. Waves constituting the large pulsations were polarized principally in the plane of the nominal shock, therefore also in the plane perpendicular to the average interplanetary field. A separate interpulsation regime detected between bursts of large amplitude oscillations was similar to the upstream wave region magnetically, but was characterized by disturbed plasma flux and enhanced noise around the ion plasma frequency. The shock structure appeared to be largely of an oblique, whistler type, probably complicated by counterstreaming high energy protons. Evidence for firehose instability-based structure was weak at best and probably negative.

Greenstadt, E. W.↗
NASA NTRS1983

NMR studies of electronic structure in crystalline and amorphous Zr2PdH/x/

The proton Knight shifts and spin-lattice relaxation times have been measured in crystalline and amorphous Ze2PdH(x). Core polarization from the Zr d-band dominates the proton hyperfine interactions. The density of Fermi level d-electron states is reduced in the amorphous phase relative to the electron density in crystalline Zr2PdH(x).

Bowman, R. C., Jr.↗
DOE OSTI2025

Quantification and evaluation of strain reduction from small-bubble gas injection in Spallation Neutron Source target vessels

Small-bubble gas injection has been routinely utilized in the operation of Spallation Neutron Source (SNS) mercury targets since 2017 to mitigate cavitation-induced erosion damage to target vessels. Strain measurements of target vessels collected in-situ during initial operation with gas injection were used to study the gas injection effect on the structural response of targets to proton pulses. A significant strain reduction owing to gas injection was found by comparing the strain measurement data during operation with and without gas injection. The research presented here focuses on quantifying strain reductions in SNS targets and evaluating the effect of small-bubble gas injection by comparing different bubbler types and target designs. The strain measurement results show the gas injection significantly reduced strain in SNS target vessels; strain values decreased by 30% to 80% for targets operating with gas injection. Stress and strain responses of SNS targets were simulated to numerically evaluate the gas injection effect. Based on the predicted stresses with and without gas injection, the fatigue lifetimes of SNS jet-flow design target were estimated using fe-safe fatigue analysis software. The simulations show these reductions should improve the fatigue life of target vessels and allow SNS targets to meet their fatigue design goal.

Fatigue life estimation↗
DOE OSTI2022

In Situ Nanoscale Dynamics Imaging in a Proton‐Conducting Solid Oxide for Protonic Ceramic Fuel Cells

Abstract Hydrogen fuel cells and electrolyzers operating below 600 °C, ideally below 400 °C, are essential components in the clean energy transition. Yttrium‐doped barium zirconate BaZr 0.8 Y 0.2 O 3‐d (BZY) has attracted a lot of attention as a proton‐conducting solid oxide for electrochemical devices due to its high chemical stability and proton conductivity in the desired temperature range. Grain interfaces and topological defects modulate bulk proton conductivity and hydration, especially at low temperatures. Therefore, understanding the nanoscale crystal structure dynamics in situ is crucial to achieving high proton transport, material stability, and extending the operating range of proton‐conducting solid oxides. Here, Bragg coherent X‐ray diffractive imaging is applied to investigate in situ and in 3D nanoscale dynamics in BZY during hydration over 40 h at 200 °C, in the low‐temperature range. An unexpected activity of topological defects and subsequent cracking is found on a nanoscale covered by the macroscale stability. The rearrangements in structure correlate with emergent regions of different lattice constants, suggesting heterogeneous hydration. The results highlight the extent and impact of nanoscale processes in proton‐conducting solid oxides, informing future development of low‐temperature protonic ceramic electrochemical cells.

25 ENERGY STORAGE↗