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A 19-Month Climatology of Marine Aerosol-Cloud-Radiation Properties Derived From DOE ARM AMF Deployment at the Azores: Part I: Cloud Fraction and Single-Layered MBL Cloud Properties

A 19-month record of total, and single-layered low (0-3 km), middle (3-6 km), and high (> 6 km) cloud fractions (CFs), and the single-layered marine boundary layer (MBL) cloud macrophysical and microphysical properties has been generated from ground-based measurements taken at the ARM Azores site between June 2009 and December 2010. It documents the most comprehensive and longest dataset on marine cloud fraction and MBL cloud properties to date. The annual means of total CF, and single-layered low, middle, and high CFs derived from ARM radar-lidar observations are 0.702, 0.271, 0.01 and 0.106, respectively. More total and single-layered high CFs occurred during winter, while single-layered low CFs were greatest during summer. The diurnal cycles for both total and low CFs are stronger during summer than during winter. The CFs are bimodally distributed in the vertical with a lower peak at approx. 1 km and higher one between 8 and 11 km during all seasons, except summer, when only the low peak occurs. The persistent high pressure and dry conditions produce more single-layered MBL clouds and fewer total clouds during summer, while the low pressure and moist air masses during winter generate more total and multilayered-clouds, and deep frontal clouds associated with midlatitude cyclones.

Dong, Xiquan↗

The Version 8.6 SBUV Ozone Data Record: An Overview

Under a NASA program to produce long-term data records from instruments on multiple satellites, data from a series of nine Solar Backscatter Ultraviolet (SBUV and SBUV2) instruments have been re-processed to create a coherent ozone time series. Data from the BUV instrument on Nimbus 4, SBUV on Nimbus 7, and SBUV2 instruments on NOAA 9, 11, 14, 16, 17, 18, and 19 covering the period 1970-1972 and 1979-2011 were used to create a long-term data set. The goal is an ozone Earth Science Data Record - a consistent, calibrated ozone time series that can be used for trend analyses and other studies. In order to create this ozone data set, the radiances were adjusted and used to re-process the entire data records for each of the nine instruments. Inter-instrument comparisons during periods of overlap as well as comparisons with data from other satellite and ground-based instruments were used to evaluate the consistency of the record and make calibration adjustments as needed. Additional improvements in this version 8.6 processing included the use of the Brion, Daumont, and Malicet ozone cross sections, and a cloud-height climatology derived from Aura OMI measurements. Validation of the re-processed ozone shows that total column ozone is consistent with the Brewer Dobson network to within about 1 for the new time series. Comparisons with MLS, SAGE, sondes, and lidar show that ozone at individual levels in the stratosphere is generally consistent to within 5 percent.

ozone↗

Aerosol Optical Depths over Oceans: a View from MISR Retrievals and Collocated MAN and AERONET in Situ Observations

In this study, aerosol optical depths over oceans are analyzed from satellite and surface perspectives. Multiangle Imaging SpectroRadiometer (MISR) aerosol retrievals are investigated and validated primarily against Maritime Aerosol Network (MAN) observations. Furthermore, AErosol RObotic NETwork (AERONET) data from 19 island and coastal sites is incorporated in this study. The 270 MISRMAN comparison points scattered across all oceans were identified. MISR on average overestimates aerosol optical depths (AODs) by 0.04 as compared to MAN; the correlation coefficient and root-mean-square error are 0.95 and 0.06, respectively. A new screening procedure based on retrieval region characterization is proposed, which is capable of substantially reducing MISR retrieval biases. Over 1000 additional MISRAERONET comparison points are added to the analysis to confirm the validity of the method. The bias reduction is effective within all AOD ranges. Setting a clear flag fraction threshold to 0.6 reduces the bias to below 0.02, which is close to a typical ground-based measurement uncertainty. Twelve years of MISR data are analyzed with the new screening procedure. The average over ocean AOD is reduced by 0.03, from 0.15 to 0.12. The largest AOD decrease is observed in high latitudes of both hemispheres, regions with climatologically high cloud cover. It is postulated that the screening procedure eliminates spurious retrieval errors associated with cloud contamination and cloud adjacency effects. The proposed filtering method can be used for validating aerosol and chemical transport models.

AERONET↗

Cloud Climate Data Records from Geostationary Satellites to Support CERES: Challenges and Recent Progress

Cloud properties are critical for understanding the Earth’s radiation budget and cloud feedbacks. At NASA Langley Research Center, the Satellite ClOud and Radiative Property retrieval System (SatCORPS) provides real-time and historical analyses of clouds derived from Geostationary satellite (GEOsat) data for weather and climate applications. For the Clouds and the Earth’s Radiant Energy System (CERES) program, the global constellation of GEOsats has been analyzed since 2000 to help characterize and account for the diurnal cycle of clouds and their radiative impacts in the CERES climate data record. Obtaining consistent cloud properties over the GEOsat data record at all times of day during the CERES era is a major objective but a significant challenge considering the diversity of imaging capabilities deployed during that time. A brief overview of the current CERES/GEO cloud property data record constructed from three generations of GEOsat imagers for CERES Edition-4 is presented. In this version, different algorithms were applied to different satellites to take advantage of as much spectral information as possible for each satellite. Under this approach, the derived cloud properties were found to become accurate (and more similar to MODIS) for the GEOsat imagers with more spectral information. However, this approach also led to some discontinuities in cloud properties across platforms. Significant differences were also found between daytime and nighttime cloud properties. This paper will highlight the major issues in the Edition-4 record and discuss new strategies and early results from the next version of the SatCORPS GEOsat cloud property time series in development for CERES Edition-5 with the goal of improving day-night and cross-platform consistency during the CERES record.

clouds↗

9+ Years of CALIOP PSC Data: An Evolving Climatology

Polar stratospheric clouds (PSCs) play key roles in the springtime chemical depletion of ozone at high latitudes. PSC particles provide sites for heterogeneous chemical reactions that transform stable chlorine and bromine reservoir species into highly reactive ozone-destructive forms. Furthermore, large nitric acid trihydrate (NAT) PSC particles can irreversibly redistribute odd nitrogen through gravitational sedimentation, which prolongs the ozone depletion process by slowing the reformation of the stable chlorine reservoirs. However, there are still significant gaps in our understanding of PSC processes, particularly concerning the details of NAT particle formation. Spaceborne observations from the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) lidar on the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) satellite are providing a rich new dataset for studying PSCs on unprecedented vortex-wide scales. In this paper, we examine the vertical and spatial distribution of PSCs in the Antarctic and Arctic on vortex-wide scales for entire PSC seasons over the more than nine-year data record.

Pitts, Michael C.↗

9+ Years of CALIPSO PSC Observations: An Evolving Climatology

Polar stratospheric clouds (PSCs) play a crucial role in the springtime chemical depletion of ozone at high latitudes. PSC particles (primarily supercooled ternary solution, or STS droplets) provide sites for heterogeneous chemical reactions that transform stable chlorine and bromine reservoir species into highly reactive ozone-destructive forms. Furthermore, large nitric acid trihydrate (NAT) PSC particles can irreversibly redistribute odd nitrogen through gravitational sedimentation (a process commonly known as denitrification), which prolongs the ozone depletion process by slowing the reformation of the stable chlorine reservoirs. Spaceborne observations from the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) lidar on the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) satellite are providing a rich new dataset for studying PSCs. CALIPSO is an excellent platform for studying polar processes with CALIOP acquiring, on average, over 300,000 backscatter profiles daily at latitudes between 55o and 82o in both hemispheres. PSCs are detected in the CALIOP backscatter profiles using a successive horizontal averaging scheme that enables detection of strongly scattering PSCs (e.g., ice) at the finest possible spatial resolution (5 km), while enhancing the detection of very tenuous PSCs (e.g., low number density NAT) at larger spatial scales (up to 135 km). CALIOP PSCs are separated into composition classes (STS; liquid/NAT mixtures; and ice) based on the ensemble 532-nm scattering ratio (the ratio of total-to-molecular backscatter) and 532-nm particulate depolarization ratio (which is sensitive to the presence of non-spherical, i.e. NAT and ice particles). In this paper, we will provide an overview of the CALIOP PSC detection and composition classification algorithm and then examine the vertical and spatial distribution of PSCs in the Arctic and Antarctic on vortex-wide scales for entire PSC seasons over the more than nine-year data record from 2006- 2015.

Pitts, Michael C.↗

Cloud Impacts on Photochemistry: Building a Climatology of Photolysis Rates from the Atmospheric Tomography Mission

Measurements from actinic flux spectroradiometers on board the NASA DC-8 during the Atmospheric Tomography (ATom) mission provide an extensive set of statistics on how clouds alter photolysis rates (J values) throughout the remote Pacific and Atlantic Ocean basins. J values control tropospheric ozone and methane abundances, and thus clouds have been included for more than three decades in tropospheric chemistry modeling. ATom made four profiling circumnavigations of the troposphere capturing each of the seasons during 2016–2018. This work examines J values from the Pacific Ocean flights of the first deployment, but publishes the complete Atom-1 data set (29 July to 23 August 2016). We compare the observed J values (every 3 s along flight track) with those calculated by nine global chemistry– climate/transport models (globally gridded, hourly, for a mid-August day). To compare these disparate data sets, we build a commensurate statistical picture of the impact of clouds on J values using the ratio of J -cloudy (standard, sometimes cloudy conditions) to J -clear (artificially cleared of clouds). The range of modeled cloud effects is inconsistently large but they fall into two distinct classes: (1) models with large cloud effects showing mostly enhanced J values aloft and or diminished at the surface and (2) models with small effects having nearly clear-sky J values much of the time. The ATom-1 measurements generally favor large cloud effects but are not precise or robust enough to point out the best cloud-modeling approach. The models here have resolutions of 50–200 km and thus reduce the occurrence of clear sky when averaging over grid cells. In situ measurements also average scattered sunlight over a mixed cloud field, but only out to scales of tens of kilometers. A primary uncertainty remains in the role of clouds in chemistry, in particular, how models average over cloud fields, and how such averages can simulate measurements.

actinic flux spectroradiometers↗

Satellite Remote Sensing of Cirrus: An Overview

The determination of cirrus properties over relatively large spatial and temporal scales will, in most instances, require the use of satellite data. Global coverage, at resolutions as high as several meters are attainable with Landsat, while temporal coverage at 1-min intervals is now available with the latest Geostationary Operational Environmental Satellite (GOES) imagers. Cirrus can be analyzed via interpretation of the radiation that they reflect or emit over a wide range of the electromagnetic spectrum. Many of these spectra and high-resolution satellite data can be used to understand certain aspects of cirrus clouds in particular situations. Production of a global climatology of cirrus clouds, however, requires compromises in spatial, temporal, and spectral coverage. This paper summarizes the state of the art and the potential for future passive remote sensing systems for both understanding cirrus formation and acquiring sufficient statistics to constrain and refine weather and climate models.

Minnis, Patrick↗

Quasi-Two-Day and Diurnal Cloud Variation Timescales over Convectively Active Regions

Climatological features of the cloud variability on quasi-two-day (Q2D) and diurnal cycle (DC) timescales are investigated by utilizing the high-resolution satellite infrared brightness temperature (IRBT) observations from January 1998 to December 2019. A distinct land-sea contrast between the distributions of Q2D and DC signals is evident. Diurnally driven cloud activity mainly occurs over land and mountainous regions, and the Q2D timescale is more prominent over tropical ocean basins and land where organized convection is usually observed, e.g., Congo and Amazon Rainforests, the U.S. and subtropical South America during warm seasons. The long-term relationship between the Q2D variability and sea surface temperature (SST) shows that the clouds are more active on Q2D timescales over higher SST environments. The Q2D variability correlates well with both the Indian Ocean Dipole (IOD) and El Niño/Southern Oscillation (ENSO) from 1998 to 2019. The cloud variability associated with a range of convective available potential energy (CAPE) values is analyzed. The result over land shows that increased Q2D cloud variability emerges with higher CAPE, suggesting the coincidence of Q2D and organized convection, particularly given that this effect is strongest over regions with frequent mesoscale convective systems (MCSs) around the world. The cloud variability and the Q2D timescale analyses provide an alternative perspective to understand the global features of mesoscale convective systems. Overall, this study objectively examines the global variability of convective timescales related to the diurnal cycle and longer-lived convective systems to provide a greater understanding of how the global convection population varies in space and time.

54 ENVIRONMENTAL SCIENCES↗

Fixed-Site KAZR b1 Data Processing Report: 2025

The U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) User Facility has been operating Ka-band ARM Zenith Radars (KAZRs) at each of its permanent observatories for at least the past 10 years. Data collected by the KAZRs is used to explore various cloud processes in different climatological regimes including marine stratocumulus clouds at the Eastern North Atlantic (ENA) site, arctic clouds at the North Slope of Alaska (NSA) site, and mid-latitude continental clouds at the Southern Great Plains (SGP) site.

54 ENVIRONMENTAL SCIENCES↗

Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO 2 ) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer

Dimethyl sulfide (DMS) is the major sulfur species emitted from the ocean. The gas-phase oxidation of DMS by hydroxyl radicals proceeds through the stable, soluble intermediate hydroperoxymethyl thioformate (HPMTF), eventually forming carbonyl sulfide (OCS) and sulfur dioxide (SO 2 ). Recent work has shown that HPMTF is efficiently lost to marine boundary layer (MBL) clouds, thus arresting OCS and SO 2 production and their contributions to new-particle formation and growth events. To date, no long-term field studies exist to assess the extent to which frequent cloud processing impacts the fate of HPMTF. Here, we present 6 weeks of measurements of the cloud fraction and the marine sulfur species methanethiol, DMS, and HPMTF made at the Atmospheric Radiation Measurement (ARM) research facility on Graciosa Island, Azores, Portugal. Using an observationally constrained chemical box model, we determine that cloud loss is the dominant sink of HPMTF in this region of the MBL during the study, accounting for 79 %–91 % of HPMTF loss on average. When accounting for HPMTF uptake to clouds, we calculate campaign average reductions in DMS-derived MBL SO 2 and OCS of 52 %–60 % and 80 %–92 % for the study period. Using yearly measurements of the site- and satellite-measured 3D cloud fraction and DMS climatology, we infer that HPMTF cloud loss is the dominant sink of HPMTF in the eastern North Atlantic during all seasons and occurs on timescales faster than what is prescribed in global chemical transport models. Accurately resolving this rapid loss of HPMTF to clouds has important implications for constraining drivers of MBL new-particle formation.

54 ENVIRONMENTAL SCIENCES↗

Better calibration of cloud parameterizations and subgrid effects increases the fidelity of the E3SM Atmosphere Model version 1

Abstract. Realistic simulation of the Earth's mean-state climate remains a major challenge, and yet it is crucial for predicting the climate system in transition. Deficiencies in models' process representations, propagation of errors from one process to another, and associated compensating errors can often confound the interpretation and improvement of model simulations. These errors and biases can also lead to unrealistic climate projections and incorrect attribution of the physical mechanisms governing past and future climate change. Here we show that a significantly improved global atmospheric simulation can be achieved by focusing on the realism of process assumptions in cloud calibration and subgrid effects using the Energy Exascale Earth System Model (E3SM) Atmosphere Model version 1 (EAMv1). The calibration of clouds and subgrid effects informed by our understanding of physical mechanisms leads to significant improvements in clouds and precipitation climatology, reducing common and long-standing biases across cloud regimes in the model. The improved cloud fidelity in turn reduces biases in other aspects of the system. Furthermore, even though the recalibration does not change the global mean aerosol and total anthropogenic effective radiative forcings (ERFs), the sensitivity of clouds, precipitation, and surface temperature to aerosol perturbations is significantly reduced. This suggests that it is possible to achieve improvements to the historical evolution of surface temperature over EAMv1 and that precise knowledge of global mean ERFs is not enough to constrain historical or future climate change. Cloud feedbacks are also significantly reduced in the recalibrated model, suggesting that there would be a lower climate sensitivity when it is run as part of the fully coupled E3SM. This study also compares results from incremental changes to cloud microphysics, turbulent mixing, deep convection, and subgrid effects to understand how assumptions in the representation of these processes affect different aspects of the simulated atmosphere as well as its response to forcings. We conclude that the spectral composition and geographical distribution of the ERFs and cloud feedback, as well as the fidelity of the simulated base climate state, are important for constraining the climate in the past and future.

54 ENVIRONMENTAL SCIENCES↗

Development of a climatological data base to help forecast cloud cover conditions for shuttle landings at the Kennedy Space Center

The Space Shuttle is an extremely weather sensitive vehicle with very restrictive constraints for both launches and landings. The most important difference between Shuttle and normal aircraft landings is that the Shuttle has no go-around capability once it begins its decent into the earth's atmosphere. The de-orbit burn decision is generally made approximately 90 minutes before landing requiring a forecast with little room for error. Because of the Shuttle's rapid re-entry to earth, the pilot must be able to see all runway and visual navigation aids from high altitude to land the Shuttle. In addition, the heat resistant tiles which are used to protect the Shuttle during its re-entry into the earth's atmosphere are extremely sensitive to any type of precipitation. Extensive damage to these tiles could occur if the Shuttle passes through any cloud that contains precipitation size particles. To help guard against changing weather conditions or any type of weather problems that might occur prior to landing, flight rules have been developed as guidelines for all landings. Although the rules vary depending on the location of the landing (Kennedy Space Center or Edwards AFB), length of mission, and weight of vehicle, most of the rules can be condensed into 4 major groupings. These are: (1) Cloud ceilings should not be less than 3048 m (10,000 feet), (2) Visibility should not be less than 13 km (7 nm), (3) Cross-wind no greater than 5-8 m/s (10-15 knots); and (4) No showers or thunderstorms at or within 56 km (30 nm) of the Shuttle Landing Facility. This study consisted of developing a climatological database of the Shuttle Landing Facility (SLF) surface observations and performing an analysis of observed conditions one and two hours subsequent to given conditions at the SLF to help analyze the 0.2 cloud cover rule. Particular emphasis was placed on Shuttle landing weather violations and the amounts of cloud cover below 3048 m (10,000 ft.). This analysis has helped to determine the best and worst times to land the Shuttle at KSC. In addition, nomograms have been developed to help forecasters make cloud cover forecasts for End of Mission (EOM) and Return to Launch Site (RTLS) at KSC. Results of categorizing this data by month, season, time of day, and surface and upper-air wind direction are presented.

Atchison, M. Kevin↗

Wintertime synoptic patterns of midlatitude boundary layer clouds over the western North Atlantic: Climatology and insights from in-situ ACTIVATE observations

The winter synoptic evolution of the western North Atlantic and its influence on the atmospheric boundary layer is described by means of a regime classification based on Self Organizing Maps applied to 12 year of data (2009-2020). The regimes are classified into categories according to daily 600-hPa geopotential height: dominant ridge, trough to ridge eastward transition (trough-ridge), dominant trough, and ridge to trough eastward transition (ridge-trough). A fifth synoptic regime resembles the winter climatological mean. Coherent changes in sea-level pressure and large-scale winds are in concert with the synoptic regimes: 1) the ridge regime is associated with a well-developed anticyclone; 2) the trough-ridge gives rise to a low pressure center over the ocean, ascents, and northerly winds over the coastal zone; 3) trough is associated with the eastward displacement of a cyclone, coastal subsidence, and northerly winds, all representative characteristics of cold-air outbreaks; 4) the ridge-trough regime features the development of an anticyclone and weak coastal winds. Low clouds are characteristic of the trough regime, with both trough and trough-ridge featuring synoptic maxima in cloud droplet number concentration (N d ). The N d increase is primarily observed near the coast, concomitant with strong surface heat fluxes exceeding by more than 400 W m -2 compared to fluxes further east. Five consecutive days of aircraft observations collected during the ACTIVATE campaign corroborates the climatological characterization, confirming the occurrence of high N d for days identified as trough. This study emphasizes the role of boundary-layer dynamics and aerosol activation and their roles in modulating cloud microphysics.

54 ENVIRONMENTAL SCIENCES↗

Florida Thunderstorms: A Faucet of Reactive Nitrogen to the Upper Troposphere

During the NASA Cirrus Regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) enhanced mixing ratios of nitric oxide were measured in the anvils of thunderstorms and in clear air downwind of storm systems on flights of a Wl3-57F high-altitude aircraft. Mixing ratios greater than l0 - 20 times background were readily observed over distances of 25-120 km due to lightning activity. In many of the Florida storms deposition of NO occurred up to near the tropopause but major deposition usually occurred 1 - 2 km below the tropopause, or mostly within the visible anvil volume formed prior to storm decay. Observations from two storms of very different anvil size and electrical activity allowed estimates of the total mass of NO, vented to the middle and upper troposphere. Using the cloud-to ground (CG) flash accumulations from the National Lightning Detection Network, climatological intra-cloud (IC) to CG ratios, and assuming that CG and IC flashes were of equivalent efficiency for NO production, the ranges of production per flash for a moderate-sized and a large storm were (0.51 - 1.0) x l0(exp 26) and (2.3 - 3.1) x 10(exp 26) molecules NO/flash, respectively. Using the recently determined average global flash rate of 44 8, a gross extrapolation of these two storms to represent possible global annual production rates yield 1.6 - 3.2 and 7.3 - 9.9 Tg(N)/yr, respectively. If the more usual assumption is made that IC efficiency is l/l0th that of CG activity, the ranges of production for the moderate-sized and large storm were (1.3 - 2.7) x l0(exp 26) and (6.0 - 8.1) x l0(exp 26) molecules NO/CG flash, respectively. The estimates from the large storm may be high because there is indirect evidence that the IC/CG ratio was larger than would be derived from climatology. These two storms and others studied did not have flash rates that scaled as approx. H(sup 5) where H is the cloud top altitude. The observed CG flash accumulations and NO(x) mass production estimate for the month of July over the Florida area were compared with a representative 3D global Chemistry-Transport Model (CTMJ that uses the Price et al. lightning parameterization. For two land grid points representing the Florida peninsula the model compared well with the observations: CG flash rates were low by only a factor of approx. 2. When the model grid points included the coastal regions of Florida the flash accumulations were lower than observed by a factor of 3.4 - 4.6. It is recommended that models using the Price et al. parameterization allow any global coastal grid point to maintain the land rather than the marine flash rate parameterization. The convection in this CTM underestimated the actual cloud top heights over Florida by 1 - 2 km and thus the total lightning flash rates and the altitude range of reactive nitrogen deposition. Broad scale (20 - 120 km) median mixing ratios of NO within anvils over Florida were significantly larger than in storms previously investigated over Colorado and New Mexico.

Ridley, B.↗

Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE) Science Plan

Coastal cities provide the opportunity to characterize marine clouds and the substantial effects of manmade particles on cloud properties and processes. La Jolla lies to the north of San Diego, California, but it is often about a day directly downwind of the major pollution sources located in the ports of Los Angeles and Long Beach. The large dynamic range of aerosol particle concentrations combined with the multi-hour to multi-day persistence of stratocumulus cloud layers makes the site ideal for investigating the seasonal changes in cloud and aerosol properties as well as the quantitative relationships between cloud and aerosol properties. The focus of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE) is to characterize the extent, radiative properties, aerosol interactions, and precipitation characteristics of stratocumulus clouds in the Eastern Pacific across all four seasons at a coastal location, the Scripps Pier and the Scripps Mt. Soledad sites in La Jolla. An important enhancement to this study will be the collection of simultaneous in-cloud aerosol and droplet measurements to investigate the differences in these cloud properties during regional polluted and clean marine conditions. The combined observations will provide an unprecedented set of constraints for the following questions: 1. Cloud and Aerosol Climatology: What are the seasonal and diurnal cycles of marine stratocumulus cloud and aerosol properties on the northeastern Pacific coast? 2. Cloud Radiative Fluxes: How do cloud properties, including the ratio of direct-to-diffuse radiation, change as coastal clouds are advected inland? 3. Aerosol-Cloud Interactions: Will retrieved cloud properties reflect the regional signatures of aerosol?

Eastern Pacific Cloud Aerosol Precipitation Experi↗