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At least 397 records · Page 22

Analysis of inner and outer zone: OGO-1 and OGO-2 electron spectrometer and ion chamber data

The dynamic processes governing the acceleration and loss of electrons in the radiation zones are investigated. The radial diffusion coefficient was determined for a McIlwain parameter between 1.6 and 2.2 for electrons having a first adiabatic invariant of 12 MeV/gauss. The coefficient is larger than earlier values and suggests that there exists a lower limit to the fluxes in the inner zone. The agreement between observed and calculated magnetic fields and particle fluxes is improved by using solar wind pressure as input to the magnetic field models. Changes in the plasma pressure can cause apparent local time asymmetries in particle flux. A comparison of the magnetic field models with observed location of the trapping boundary also indicates the need for including distributed currents within the magnetosphere. The high latitude trapping boundary is only weakly dependent on A sub p, and the trapping boundary data are improved by including in the models a stand-off distance which varies with the plasma pressure.

Pfitzer, K. A.↗

Mesoscale waves as a probe of Jupiter's deep atmosphere

Images from the Voyager north/south mapping sequences were searched for waves. A remarkable class of mesoscale waves was identified, with the following features: (1) the wavetrains are usually aligned zonally, i.e., wavecrests are north-south; (2) the average wavelength is 300 km with a standard deviation of only 20%; (3) the wavetrains are long; (4) the waves occur within 25 degrees of the equator, the bulk being at the equator itself; (5) the waves are centered at the extrema (in latitude) of the zonal flow; and (6) the meridional extent of the waves is typically 1 degree of latitude. These observations are interpreted as evidence of gravity waves propagating vertically within a leaky duct. A three-level model is assumed composed of a stable duct which extends up to the base of the NH3 cloud deck near 600 mb. Above this is a thin wave-trapping region characterized by a Richardson number Ri less than 1/4 and containing a critical level, where the local value of the zonal flow velocity equals the phase speed of the wave. This in turn is overlain by a stable region, representing the tropopause region and stratosphere.

Flaser, F. M.↗

Counter-streaming electrons at the geomagnetic equator near 9 earth radii

AMPTE/CEE observations are used to study short-lived, highly anisotropic electron distributions in the region of the equatorial magnetosphere bewtween 6.6 earth radii and the CCE apogee at 8.8 earth radii. Intense bursts of highly collimated counterstreaming electrons were observed at keV energies with durations of a few tens of seconds to a few minutes near the geomagnetic equator on L-shells that intersect the high-latitude ionosphere in the region normally associated with the auroral zone. It is found that the counterstreaming electrons at energies below the peak energy are accompanied by simultaneous deep depressions of the locally mirroring fluxes. It is suggested that these equatorial electrons may result from the release of auroral electrons trapped beneath the auroral accelerating potentials at lower altitudes along the same magnetic flux tubes.

Klumpar, D. M.↗

Structured plasma sheet thinning observed by Galileo and 1984-129

On December 8, 1990, the Galileo spacecraft used the Earth for a gravity assist on its way to Jupiter. Its trajectory was such that it crossed geosynchronous orbit at approximately local midnight between 1900 and 2000 UT. At the same time, spacecraft 1984-129 was also located at geosynchronous orbit near local midnight. Several flux dropout events were observed when the two spacecraft were in the near-Earth plasma sheet in the same local time sector. Flux dropout events are associated with plasma sheet thinning in the near-profile of the near-Earth plasma sheet while 1984-129 provided an azimuthal profile. With measurements from these two spacecraft we can distinguish between spatial structures and temporal change. Our observations confirm that the geosynchronous flux dropout events are consistent with plasma sheet thinning which changes the spacecraft's magnetic connection from the trapping region to the more distant plasma sheet. However, for this period, thinning occurred on two spatial and temporal scales. The geosynchronous dropouts were highly localized phenomena of 30 min duration superimposed on a more global reconfiguration of the tail lasting approximately 4 hours.

Reeves, G. D.↗

Structure-Based Exciton Hamiltonian and Dynamics for the Reconstituted Wild-type CP29 Protein Antenna Complex of the Photosystem II

Here we provide an analysis of the pigment composition of reconstituted wild type CP29 complexes. The obtained stoichiometry of 9 ± 0.6 Chls a and 3 ± 0.6 Chls b per complex, with some possible heterogeneity in the carotenoid binding, is in agreement with 9 Chls a and 3.5 Chls b revealed by the modeling of low-temperature optical spectra. We find that ~50% of Chl b614 is lost during the reconstitution/purification procedure, while Chls a are almost fully retained. The excitonic structure and the nature of the low-energy (low-E) state(s) are addressed via simulations (using Redfield theory) of 5 K absorption and fluorescence/nonresonant hole-burned (NRHB) spectra obtained at different excitation/burning conditions. We show that, depending on laser excitation frequency, reconstituted complexes display two (independent) low-E states (i.e., the A and B traps) with different NRHB and emission spectra. The red-shifted state A near 682.4 nm is assigned to a minor (~10%) subpopulation (Sub. II) that most likely originates from an imperfect local folding occurring during protein reconstitution. Its lowest energy state A (localized on Chl a604) is easily burned with λ B = 488.0 nm and has a red-shifted florescence origin band near 683.7 nm that is not observed in native (isolated) complexes. Prolonged burning by 488.0 nm light reveals a second low-E trap at 680.2 nm (state B) with a fluorescence origin-band ~681 nm which is also observed when using a direct lowfluence excitation near 650 nm. The latter state is mostly delocalized over the a611, a612, a615 Chl trimer, and corresponds to the lowest energy state of the major (~90%) subpopulation (Sub. I) which exhibits a lower hole-burning quantum yield. Thus, we suggest that major Sub. I correspond to the native folding of CP29, whereas the red-shift of the Chl a604 site energy observed in the minor Sub. II occurs only in reconstituted complexes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Electromagnetic radiation trapped in the magnetosphere above the plasma frequency

An electromagnetic noise band is frequently observed in the outer magnetosphere by the Imp 6 spacecraft at frequencies from about 5 to 20 kHz. This noise band generally extends throughout the region from near the plasmapause boundary to near the magnetopause boundary. The noise typically has a broadband field strength of about 5 microvolts/meter. The noise band often has a sharp lower cutoff frequency at about 5 to 10 kHz, and this cutoff has been identified as the local electron plasma frequency. Since the plasma frequency in the plasmasphere and solar wind is usually above 20 kHz, it is concluded that this noise must be trapped in the low-density region between the plasmapause and magnetopause boundaries. The noise bands often contain a harmonic frequency structure which suggests that the radiation is associated with harmonics of the electron cyclotron frequency.

Gurnett, D. A.↗

Quantum Photon Sources in WSe 2 Monolayers Induced by Weakly Localized Strain Fields

Quantum emitters in semiconductor transition metal dichalcogenide (TMD) monolayers hold great promise for many quantum optics applications due to the intriguing properties afforded by the host materials. The creation of localized excitonic states in two-dimensional semiconductors is also fundamentally interesting. Local strain engineering of TMD monolayers has been attested to be a viable approach for creating quantum emitters. However, despite the ubiquitous existence of local topography variations in the structures used to create strain gradients in the TMD monolayers, an understanding of their influence on the strain fields and exciton trapping is notably lacking, especially on the nanoscale. In this study, we investigate WSe 2 monolayers deposited on the edges of asfabricated trenches, which are deemed to induce 1D delocalized strain profiles in the monolayers, and observe optical signatures of weakly confined excitonic states supporting biexciton emission. Here, our numerical simulations of the strain distributions suggest that the quantum emitters originate from quasi-1D like localized strain profiles induced by local topography variations at the trench edges. These findings have strong implications toward the controlled creation of quantum emitters in TMD monolayers and their efficient coupling to photonic structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Engineering of slow Bloch modes for optical trapping

In the present paper, we propose an approach based on slow Bloch mode microcavity that enables the optical trapping of small nanoparticles over a broad surface. A specific design based on a double-period photonic crystal is presented. It enables an easy coupling using a wide free-space Gaussian beam and the cavity Q factor can be tuned at will. Moreover, the microcavity mode is mainly localized within the photonic crystal holes, meaning that each hole of the microcavity behaves as efficient nanotweezers. Experimental studies have shown that 200 nm and 100 nm particles can be trapped within the microcavity, in a spatial region that corresponds to the size of one hole (200 nm wide). The experimental trap stiffness has been extracted. It shows that this approach is among the most performant ones if we take into account the size of the cavity.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Segregation and trapping of oxygen vacancies near the SrTiO 3 Σ3 (112) [110] tilt grain boundary

In nanocrystalline materials, structural discontinuities at grain boundaries (GBs) and the segregation of point defects to these GBs play a key role in defining the structural stability of a material, as well as its macroscopic electrical/mechanical properties. In this study, the segregation of oxygen vacancies near the Σ3 (1 1 2) [¯110] tilt GB in SrTiO 3 is explored using density functional theory. We find that oxygen vacancies segregate toward the GB, preferring to reside within the next nearest-neighbor layer. This oxygen vacancy segregation is found to be crucial for stabilizing this tilt GB. Furthermore, we find that the migration barriers of oxygen vacancies diffusing toward the first nearest-neighbor layer of the GB are low, while those away from this layer are very high. Furthermore, the segregation and trapping of the oxygen vacancies in the first nearest-neighbor layer of GBs are attributed to the large local distortions, which can now accommodate the preferred sixfold coordination of Ti. These results suggest that the electronic, transport, and capacitive properties of SrTiO 3 can be engineered through the control of GB structure and grain size or layer thickness.

36 MATERIALS SCIENCE↗

Short Communication: Observation of Initial Burst Release of Fission Gas from High-Burnup UO 2 Nuclear Fuel During Thermal Transient

A system was developed and tested to provide a deeper understanding of the fission gas release kinetics from nuclear fuel during thermal transients. Pressure, temperature, spectral data, and optical images were simultaneously collected during resistive sample heating, and all released gases were collected in liquid nitrogen-cooled charcoal traps. Standup testing was performed with a high-burnup nuclear fuel segment from rod section with an average local burnup of 77 GWd/tU. During heating, the segment released approximately 6 ± 2% of generated fission gas inventory after ramp heating to 460°C. Here, heating ceased when the sample ejected from the holder, as observed by constant imaging.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A charge carrier transport model for donor-acceptor blend layers

Highly efficient organic solar cells typically comprise donor-acceptor blend layers facilitating effective splitting of excitons. However, the charge carrier mobility in the blends can be substantially smaller than in neat materials, hampering the device performance. Currently, available mobility models do not describe the transport in blend layers entirely. Here, we investigate hole transport in a model blend system consisting of the small molecule donor zinc phthalocyanine (ZnPc) and the acceptor fullerene C{sub 60} in different mixing ratios. The blend layer is sandwiched between p-doped organic injection layers, which prevent minority charge carrier injection and enable exploiting diffusion currents for the characterization of exponential tail states from a thickness variation of the blend layer using numerical drift-diffusion simulations. Trap-assisted recombination must be considered to correctly model the conductivity behavior of the devices, which are influenced by local electron currents in the active layer, even though the active layer is sandwiched in between p-doped contacts. We find that the density of deep tail states is largest in the devices with 1:1 mixing ratio (E{sub t} = 0.14 eV, N{sub t} = 1.2 × 10{sup 18 }cm{sup −3}) directing towards lattice disorder as the transport limiting process. A combined field and charge carrier density dependent mobility model are developed for this blend layer.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The role of defect charge, crystal chemistry, and crystal structure on positron lifetimes of vacancies in oxides

Density functional theory based positron lifetime (PL) calculations for cation and oxygen monovacancies in a range of oxides—hematite, magnetite, hercynite, and alumina—have been conducted to compare the impact of defect chemistry and crystal structure on the predicted lifetimes. The role of defect charge state has also been examined. A comparison across the same type of crystalline structure but different composition shows that oxygen vacancies only induce a slight increase in the positron-electron overlap and thus barely modify the PL as compared to the bulk. A much more substantial increase of PL is observed for cation monovacancies, regardless of crystal structure or the elemental nature of the vacancy, which we ascribe to an enhanced localization of charge density around the vacant site. The structural and compositional richness of the oxide leads to longer defect PLs, with defected hercynite exhibiting the longest PLs. The charge state of cation monovacancies modifies only by a small percentage the positron localization, relegating to secondary importance the metal defect's oxidation state in modifying the lifetime of positrons within vacancy traps.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Glue in hadrons at medium resolution and the QCD instanton vacuum

We discuss a general framework for the evaluation of the gluonic form factors in light hadrons at low momentum transfer, in the QCD instanton vacuum. At medium resolution of the order of the inverse mean instanton size, the glue is mostly localized in single or pairs of pseudoparticles and globally constrained by the fluctuations of their topological charges. These pseudoparticles trap light quarks, giving rise to emerging multiflavor ’t Hooft interactions. We explicitly evaluate the gluonic scalar, pseudoscalar, energy-momentum tensor (EMT), and the leading C -odd and C -even three-gluon hadronic form factors, at next to leading order in the instanton density, including molecular clusters of like and unlike instantons. We use the results for the EMT to address the contribution of the gluons in Ji’s mass and spin sum rules, at low resolution. When evolved, our results for the mass and spin composition of the nucleon are shown to be in good agreement with the recently reported lattice results at higher resolution. Published by the American Physical Society 2024

Astronomy & Astrophysics↗

Effect of the Crystal Structure on the Electrical Properties of Thin-Film PZT Structures

A new method of two-stage crystallization of lead zirconate–titanate (PZT) films using a seed sublayer with a low excess lead content has been proposed and realized. A seed layer with a strong texture of perovskite Pe(111) grains is formed from a solution with a lead excess of 0–5 wt %; the fast growth of the grains is provided by the deposition of the main film from a solution with high lead content. As a result, a strong Pe(111) texture with complete suppression of the Pe(100) orientation forms. An analysis of current–voltage dependences of the transient currents and the distributions of the local conductivity measured by the contact AFM method reveals two various mechanisms of current percolation that are determined by traps in the bulk and at the perovskite grain interfaces.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The effect of injection location on the spectrum of energetic magnetospheric particles

The role of local particle injections and accelerations in determining energetic particle spectra used as an indication of the radial diffusion of trapped magnetospheric particles is assessed. An idealized one-dimensional steady-state model of magnetospheric radial transport in which diffusion is balanced against particle sources and sinks is used to illustrate the effects of particle injection at a point and over a band of radii in which the observation point is immersed in particle spectra. For an injection spectrum uniformly distributed in space and a step function in energy, it is shown that the energy dependence of the measured spectrum is determined not only by adiabatic energization of the input spectrum but by the spatial structure of the injection and the radial dependence of the diffusion coefficient as well. The relevance of the results for observations of particle spectra in the terrestrial and Jovian magnetospheres is also considered

Birmingham, T. J.↗

Chemical structure of interfaces

The interfacial structure of silicon/dielectric and silicon/metal systems is particularly amenable to analysis using a combination of surface spectroscopies together with a variety of chemical structures of Si/SiO2, Si/SiO2Si3N4, Si/Si2N2O, Si/SiO2/Al, and Si/Native Oxide interfaces using high resolution (0.350 eV FWHM) X ray photoelectron spectroscopy. The general structure of these dielectric interfaces entails a monolayer chemical transition layer at the Si/dielectric boundary. Amorphous Si substrates show a wide variety of hydrogenated Si and Si(OH) sub x states that are not observed in thermal oxidation of single crystal material. Extended SiO2 layers greater than 8 A in thickness are shown to be stoichiometric SiO2, but to exhibit a wide variety of local network structures. In the nitrogen containing systems, an approach to stoichiometric oxynitride compounds with interesting impurity and electron trapping properties are seen. In native oxides, substantial topographical nonuniformity in oxide thickness and composition are found. Analysis of metal/oxide interfacial layers is accomplished by analytical removal of the Si substrate by UHV XeF2 dry etching methods.

Grunthaner, F. J.↗

Hydrogen masers and cesium fountains at NRC

The NRC masers H-3 and H-4 have been operating since June 1993 with cavity servo control. These low-flux active H masers are showing stabilities of about 10(exp -15) from 1 hour to several days. Stability results are presented, and the current and planned uses of the masers are discussed. A cesium fountain primary frequency standard project has been started at NRC. Trapping and launching experiments with the goal of 7 m/s launches are beginning. We discuss our plans for a local oscillator and servo that exploit the pulsed aspect of cesium fountain standards, and meet the challenge of 10(exp -14) tau(exp -1/2) stability without requiring masers. At best, we expect to run this frequency standard initially for periods of hours each working day rather than continuously for years, and so frequency transfer to outside laboratories has been carefully considered. We conclude that masers (or other even better secondary clocks) are required to exploit this potential accuracy of the cesium fountain. We present and discuss our conclusion that it is feasible to transfer frequency in this way with a transfer-induced uncertainty of less than 10(exp -15), even in the presence of maser frequency drift and random walk noise.

Boulanger, J.-S.↗

Lower hybrid current drive in a tokamak for correlated passes through resonance

Standard quasilinear descriptions are based on the constant magnetic field form of the quasilinear operator so improperly treat the trapped electron modifications associated with tokamak geometry. Moreover, successive poloidal transits of the Landau resonance during lower hybrid current drive in a tokamak are well correlated, and these geometrical details must be properly retained to account for the presence of trapped electrons that do not contribute to the driven current. The recently derived quasilinear operator in tokamak geometry accounts for these features and finds that the quasilinear diffusivity is proportional to a delta function with a transit or bounce averaged argument (rather than a local Landau resonance condition). The new quasilinear operator is combined with the Cordey ( Nucl. Fusion , vol. 16, 1976, pp. 499–507) eigenfunctions to properly derive a rather simple and compact analytic expression for the trapped electron modifications to the driven lower hybrid current and the efficiency of the current drive.

Physics↗