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At least 397 records · Page 22

Airborne Sunphotometer Measurements of Aerosol Optical Depth and Water Vapor in ACE-Asia and Their Comparisons to Correlative Measurements

In the Spring 2001 phase of the Asian Pacific Regional Aerosol Characterization Experiment (ACE-Asia), the 6-channel NASA Ames Airborne Tracking Sunphotometer (AATS-6) operated on 15 of the 19 research flights of the NCAR C-130, while its 14-channel counterpart (AATS-14) flew successfully on all 19 research flights of the CIRPAS Twin Otter. ACE-Asia studied aerosol outflow from the Asian continent to the Pacific basin. It was designed to integrate suborbital and satellite measurements and models to reduce the uncertainty in calculations of the climate forcing due to aerosols. AATS-6 and AATS-14 measured solar beam transmission at six and 14 wavelengths (380-1021 and 354-1558 nm, respectively), yielding aerosol optical depth (AOD) spectra and columnar water vapor (CWV). Vertical differentiation in profiles yielded aerosol extinction spectra and water vapor concentration. In this paper, we plan to present examples of the following, preliminary findings that are based in part on our airborne sunphotometer measurements: (1) The wavelength dependence of sunphotometer-derived AOD and extinction indicates that supermicron dust was often a major component of the aerosol, frequently extending to high altitudes. The percentage of full-column AOD (525 nm) that Jay above 3 km was typically 34+/-13%. In contrast, the analogous percentage of columnar water vapor was only 10+/-4%; (2) Initial comparison studies between AOD data obtained by AATS-6 and AATS-14 during coordinated low-level flight legs show agreement well within the instruments' error bars; (3) Aerosol extinction has been derived from airborne in situ measurements of scattering (nephelometers) and absorption (particle soot/ absorption photometer, PSAP) or calculated from particle size distribution measurements (mobility analyzers and aerodynamic particle sizers). Comparison with corresponding extinction values derived from the Ames airborne sunphotometer measurements shows good agreement for the vertical distribution of aerosol layers. However, the level of agreement in absolute magnitude of the derived aerosol extinction/optical depth varied among the aerosol layers sampled; (4) Initial comparisons of sunphotometer and satellite-derived AOD using SeaWiFS, MISR and AVHRR show promising results. We also plan to include comparisons with MODIS and TOMS: (5) Initial comparisons of sunphotometer-derived AOD and aerosol extinction profiles with lidars in Tokyo and on a ship show reasonable agreement.

Schmid, B.↗

Cleaning Genesis Solar Wind Collectors with Ultrapure Water: Residual Contaminant Particle Analysis

Additional experience has been gained in removing contaminant particles from the surface of Genesis solar wind collectors fragments by using megasonically activated ultrapure water (UPW)[1]. The curatorial facility has cleaned six of the eight array collector material types to date: silicon (Si), sapphire (SAP), silicon-on-sapphire (SOS), diamond-like carbon-on-silicon (DOS), gold-on-sapphire (AuOS), and germanium (Ge). Here we make estimates of cleaning effectiveness using image analysis of particle size distributions and an SEM/EDS reconnaissance of particle chemistry on the surface of UPW-cleaned silicon fragments (Fig. 1). Other particle removal techniques are reported by [2] and initial assessment of molecular film removal is reported by [3].

Allton, J. H.↗

Lagrangian Trajectory Modeling of Lunar Dust Particles

Apollo landing videos shot from inside the right LEM window, provide a quantitative measure of the characteristics and dynamics of the ejecta spray of lunar regolith particles beneath the Lander during the final 10 [m] or so of descent. Photogrammetry analysis gives an estimate of the thickness of the dust layer and angle of trajectory. In addition, Apollo landing video analysis divulges valuable information on the regolith ejecta interactions with lunar surface topography. For example, dense dust streaks are seen to originate at the outer rims of craters within a critical radius of the Lander during descent. The primary intent of this work was to develop a mathematical model and software implementation for the trajectory simulation of lunar dust particles acted on by gas jets originating from the nozzle of a lunar Lander, where the particle sizes typically range from 10 micron to 500 micron. The high temperature, supersonic jet of gas that is exhausted from a rocket engine can propel dust, soil, gravel, as well as small rocks to high velocities. The lunar vacuum allows ejected particles to travel great distances unimpeded, and in the case of smaller particles, escape velocities may be reached. The particle size distributions and kinetic energies of ejected particles can lead to damage to the landing spacecraft or to other hardware that has previously been deployed in the vicinity. Thus the primary motivation behind this work is to seek a better understanding for the purpose of modeling and predicting the behavior of regolith dust particle trajectories during powered rocket descent and ascent.

Lane, John E.↗

Informing Algorithms from Ground Validation: The GPM Combined Algorithm

Ground validation (GV) for the Global Precipitation Measurement (GPM) mission encompasses in-situ (e.g., gauge, disdrometer) measurements, ground radar products, and comprehensive datasets from dedicated airborne field campaigns. These datasets are used for direct validation of the precipitation products from GPM as well as to inform assumptions used by the algorithms that produce these products. This presentation will focus on current and potential such uses of GV data in the GPM combined radar-radiometer algorithm.The GPM combined algorithm, by virtue of using data from the Dual-frequency Precipitation Radar (DPR) and GPM Microwave Imager (GMI), is the most well-constrained instantaneous precipitation product from GPM. It also plays an important in role the passive microwave algorithms as a basis for the construction of brightness temperature-precipitation profile databases and is a calibrator for the multi- satellite gridded product IMERG. Since both radar and radiometer data are used as observational inputs, and even with these data the retrievals are underconstrained, microphysical properties of the hydrometeor profile that are relevant over the range of GMI and DPR wavelengths and incidence angles need to be assumed by the algorithm forward models. Such properties include the normalized intercept parameter (N w ) and shape parameter () of the particle size distribution, ice size-density relationship, and particle size-aspect ratio relationships. The sub-beam variability must also be prescribed in order to accurately simulate the observed radar reflectivity profiles without introducing significant biases. The sensitivity of the algorithm to these parameters, along with their mean values and variability, will be discussed. Examples of future directions include refinement with new data (particularly the assumptions related to ice), and seeking relationships between assumptions and observable or environmental data.

Munchak, Joe.↗

Apparatus and method for noninvasive particle detection using doppler spectroscopy

An apparatus and method for noninvasively detecting the presence of solid particulate matter suspended in a fluid flowing through a pipe or an oil and gas wellbore are described. Fluid flowing through a conduit containing the particulate solids is exposed to a fixed frequency (>1 MHz) of ultrasonic vibrations from a transducer attached to the outside of the pipe. The returning Doppler frequency shifted signal derived from the scattering of sound from the moving solid particles is detected by an adjacent transducer. The transmitted signal and the Doppler signal are combined to provide sensitive particulate detection. The magnitude of the signal and the Doppler frequency shift are used to determine the particle size distribution and the velocity of the particles. Measurement of the phase shift between the applied frequency and the detected Doppler shifted may be used to determine the direction of motion of the particles.

47 OTHER INSTRUMENTATION↗

Catalyst containing oxygen transport membrane

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

36 MATERIALS SCIENCE↗

Retrieval of Normalized Gamma Size Distribution Parameters Using Precipitation Imaging Package (Pip) Snowfall Observations During Ice-Pop 2018

Parameters of the normalized gamma particle size distribution (PSD) have been retrieved from the Precipitation Image Package (PIP) snowfall observations collected during the International Collaborative Experiment - PyeongChang Olympics and Paralympic (ICE-POP 2018). Two of the gamma PSD parameters, the mass weighted particle diameter (Dmass) and the normalized intercept parameter NW, have median values of 1.15-1.31 mm and 2.84-3.04 log(mm-1 m-3), respectively. This range arises from the choice of the relationship between the maximum versus equivalent diameter, Dmx-Deq, and the relationship between the Reynolds and Best numbers, Re-X. Normalization of snow water equivalent rate (SWER) and ice water content (W) by NW reduces the range in NW resulting in well fitted power law relationship, between SWER/NW and Dmass and between W/NW and Dmass. The bulk descriptors of snowfall are calculated from PIP observations and from the gamma PSD with values of the shape parameter (μ) ranging from -2 to 10. NASA’s Global Precipitation Measurement (GPM) mission, which adopted the normalized gamma PSD, assumes μ = 2 and μ = 3 in its two separate algorithms. The mean fractional bias (MFB) of the snowfall parameters changes with μ, where the functional dependence on μ depends on the specific snowfall parameter of interest. The MFB of the total concentration was underestimated by 0.23-0.34 when μ = 2 and by 0.29-0.40 when μ = 3, while the MFB of SWER had a much narrower range (-0.03 to 0.04) for the same μ values.

Snowfall↗

Understanding the Global Three-Dimensional Distribution of Precipitation Mean Particle Size with the Global Precipitation Measurement Mission

This study addresses the global distribution of precipitation mean particle size using data from the Global Precipitation Measurement (GPM) mission. The mass-weighted mean diameter Dm is a characteristic parameter of the precipitation particle size distribution (PSD), estimated from the GPM Combined Radar–Radiometer Algorithm (CORRA) using data from GPM’s dual-frequency precipitation radar and microwave imager. We examine Dm in individual precipitation systems in different climate regimes and investigate a 6-yr (2014–20) global climatology within 70°N–70°S. The vertical structure of Dm is demonstrated with cases of deep convection, frontal rain and snow, and stratocumulus light rain. The Dm values, detectable by GPM, range from ~0.7 mm in stratocumulus precipitation to >3.5 mm in the ice layers of intense convection. Within the constraint of the 12-dBZ detectability threshold, the smallest annual mean Dm (~0.8 mm) are found in the eastern oceans, and the largest values (~2 mm) occur above the melting levels in convection over land in summer. The standard deviation of the annual mean is generally <0.45 mm below 6 km. Climate regimes are characterized with Dm annual/seasonal variations, its convective/stratiform components, and vertical variabilities (2–10 km). The U.S. Central Plains and Argentina are associated with the largest Dm in a deep layer. Tropical Africa has larger Dm and standard deviation than Amazon. Large convective Dm occurs at high latitudes of Eurasia and North America in summer; the Southern Hemisphere high latitudes have shallower systems with smaller Dm. Oceanic storm tracks in both hemispheres have relatively large Dm, particularly for convective Dm in winter. Relatively small Dm occurs over tropical oceans, including ITCZ, requiring further investigation.

Mei Han↗

An experiment-informed discrete element modelling study of knife milling for flexural biomass feedstocks

A discrete element method (DEM) based approach is used to study the relationships between material attributes (MAs), processing parameters (PPs), and quality attributes (QAs) for the knife milling of maize stalks. An approximate DEM shape model was conceptualized based on real maize stalks and calibrated based on experimental bending test data for flexural properties (elastic bending stiffness, elastic bending angle limit, elastoplastic ratio, etc.). DEM simulations of maize stalk comminution in a Jordan Reduction Solutions (“JRS”) knife mill were performed to investigate the relationships between the MAs (maize stalk size and breakage stress limit), PPs (impeller rotational speed), and QAs (mass throughput and output particle size distribution (PSD)). The DEM results suggest that stalk length has little influence on mass throughput and PSD, whilst stalks with larger cross sections tend to generate larger sizes of milled particles given the same breakage stress limit. Both the DEM and experimental results show that faster impeller rotation (or higher power) does not necessarily generate higher throughput or smaller output PSD, especially for maize stalks of higher breakage stress limit. The correlations between these MAs, PPs and QAs are found highly stochastic, though breakage stress limit dictates mass throughput, regardless of stalk size. The DEM-predicted output particle size tended to match the experimental data with coarse PSDs based on sieve size but showed weakened fidelity with finer material, indicating the potential for further model improvement.

09 BIOMASS FUELS↗

Particle Morphology and Size Results from the Smoke Aerosol Measurement Experiment-2

Results are presented from the Reflight of the Smoke Aerosol Measurement Experiment (SAME-2) which was conducted during Expedition 24 (July-September 2010). The reflight experiment built upon the results of the original flight during Expedition 15 by adding diagnostic measurements and expanding the test matrix. Five different materials representative of those found in spacecraft (Teflon, Kapton, cotton, silicone rubber and Pyrell) were heated to temperatures below the ignition point with conditions controlled to provide repeatable sample surface temperatures and air flow. The air flow past the sample during the heating period ranged from quiescent to 8 cm/s. The smoke was initially collected in an aging chamber to simulate the transport time from the smoke source to the detector. This effective transport time was varied by holding the smoke in the aging chamber for times ranging from 11 to 1800 s. Smoke particle samples were collected on Transmission Electron Microscope (TEM) grids for post-flight analysis. The TEM grids were analyzed to observe the particle morphology and size parameters. The diagnostics included a prototype two-moment smoke detector and three different measures of moments of the particle size distribution. These moment diagnostics were used to determine the particle number concentration (zeroth moment), the diameter concentration (first moment), and the mass concentration (third moment). These statistics were combined to determine the diameter of average mass and the count mean diameter and, by assuming a log-normal distribution, the geometric mean diameter and the geometric standard deviations can also be calculated. Overall the majority of the average smoke particle sizes were found to be in the 200 nm to 400 nm range with the quiescent cases producing some cases with substantially larger particles.

Urban, David L.↗

Laser-driven hydrothermal process studied with excimer laser pulses

Previously, we discovered [Mariella et al., J. Appl. Phys. 114, 014904 (2013)] that modest-fluence/modest-intensity 351-nm laser pulses, with insufficient fluence/intensity to ablate rock, mineral, or concrete samples via surface vaporization, still removed the surface material from water-submerged target samples with confinement of the removed material, and then dispersed at least some of the removed material into the water as a long-lived suspension of nanoparticles. We called this new process, which appears to include the generation of larger colorless particles, “laser-driven hydrothermal processing” (LDHP) [Mariella et al., J. Appl. Phys. 114, 014904 (2013)]. Now, we report that we have studied this process using 248-nm and 193-nm laser light on submerged concrete, quartzite, and obsidian, and, even though light at these wavelengths is more strongly absorbed than at 351 nm, we found that the overall efficiency of LDHP, in terms of the mass of the target removed per Joule of laser-pulse energy, is lower with 248-nm and 193-nm laser pulses than with 351-nm laser pulses. Given that stronger absorption creates higher peak surface temperatures for comparable laser fluence and intensity, it was surprising to observe reduced efficiencies for material removal. We also measured the nascent particle-size distributions that LDHP creates in the submerging water and found that they do not display the long tail towards larger particle sizes that we had observed when there had been a multi-week delay between experiments and the date of measuring the size distributions. This is consistent with transient dissolution of the solid surface, followed by diffusion-limited kinetics of nucleation and growth of particles from the resulting thin layer of supersaturated solution at the sample surface.

36 MATERIALS SCIENCE↗

Direct indication of particle size in fluidized beds

Differential pressure measurements indicate particle size and particle size distribution in fluidized beds. The technique is based on the relationship between bed particle size and the intensity and frequency of fluctuations. By measuring the fluctuations, an estimate of average particle size of the fluid-bed material can be made.

Knudsen, I. E.↗

Water absorption and shrinkage behaviour of early-age cement in wellbore annulus

Controlling cement shrinkage in a wellbore is well-known as being important in maintaining its integrity. Although numerous laboratory experiments on the water absorption and shrinkage behaviour of oil well cement have been reported in the past, such behaviour in the wellbore annulus with consideration of pore water migration from the surrounding formation has seldom been examined. In this study, using a cement shrinkage model calibrated against available experimental data, a coupled hydromechanical finite element analysis of a cement-formation model is conducted to simulate the water migration, absorption and shrinkage behaviour of early-age cement placed in the annulus of a wellbore. The objectives of this study are (i) to identify the threshold permeability value of the formation above which there is no longer a bottleneck for pore water to flow into the cement and (ii) to estimate a reasonable range of cement bulk shrinkage volume in wellbore annulus geometry. Results show that the threshold permeability of the formation would be around 0.1 mD for three different types of cement examined in this study: Class G cement, rapid setting (RS) cement and Schlumberger optimized particle size distribution (OPSD) technology cement. The bulk shrinkage volume varies from 0.01% to 2.4% depending on cement type and formation permeability (1 mD to 0.1 μD). Finally, the proposed methodology facilitates the simulation of water migration/absorption and shrinkage behaviour of well cement in different formations.

02 PETROLEUM↗

Thermo-Optical Properties of Lunar Dust Simulants

Lunar dust coverage can significantly impact the thermo-optical properties of external surfaces for spacecraft and systems operating in the Lunar orbit or on the Lunar surface. This impacts the thermal control of these vehicles. Testing must be done to determine how much surface optics are affected by varying levels of lunar dust coverage. Optics and Particle Size Distributions (PSDs) of the dust simulant used in these tests are critical to the results. Many lunar dust simulants are available for testing, but their thermooptical properties are not well characterized. To resolve this unknown, 13 different lunar dust simulants’ IR emissivity and solar absorptivity were measured and are presented with their PSDs here.

lunar dust↗

Thermo-Optical Properties of Lunar Dust Simulants

Lunar dust coverage can significantly impact the thermo-optical properties of external surfaces for spacecraft and systems operating in the Lunar orbit or on the Lunar surface. This impacts the thermal control of these vehicles. Testing must be done to determine how much surface optics are affected by varying levels of lunar dust coverage. Optics and Particle Size Distributions (PSDs) of the dust simulant used in these tests are critical to the results. Many lunar dust simulants are available for testing, but their thermooptical properties are not well characterized. To resolve this unknown, 13 different lunar dust simulants’ IR emissivity and solar absorptivity were measured and are presented with their PSDs here.

lunar dust↗

Individual Aerosol Particles from Biomass Burning in Southern Africa: Compositions and Size Distributions of Carbonaceous Particles - 1

Individual aerosol particles in smoke plumes from biomass fires and in regional hazes in southern Africa were studied using analytical transmission electron microscopy (TEM), which allowed detailed characterization of carbonaceous particle types in smoke and determination of changes in particle properties and concentrations during smoke aging. Based on composition, morphology, and microstructure, three distinct types of carbonaceous particles were present in the smoke: organic particles with inorganic (K-salt) inclusions, tar ball particles, and soot. The relative number concentrations of organic particles were largest in young smoke, whereas tar balls were dominant in a slightly aged (1 hour) smoke from a smoldering fire. Flaming fires emitted relatively more soot particles than smoldering fires, but soot was a minor constituent of all studied plumes. Further aging caused the accumulation of sulfate on organic and soot particles, as indicated by the large number of internally mixed organic/sulfate and soot/sulfate particles in the regional haze. Externally mixed ammonium sulfate particles dominated in the boundary layer hazes, whereas organic/sulfate particles were the most abundant type in the upper hazes. Apparently, elevated haze layers were more strongly affected by biomass smoke than those within the boundary layer. Based on size distributions and the observed patterns of internal mixing, we hypothesize that organic and soot particles are the cloud-nucleating constituents of biomass smoke aerosols. Sea-salt particles dominated in the samples taken in stratus clouds over the Atlantic Ocean, off the coast of Namibia, whereas a distinct haze layer above the clouds consisted of aged biomass smoke particles.

Posfai, Mihaly↗

Saturn's rings - Structure, dynamics, and particle properties

The current state of knowledge of Saturn's rings is reviewed. A brief historical introduction is given, followed by a discussion of the radial profile of the rings, ring dynamics, features without azimuthal symmetry, ring particle size distribution, and the physical properties of ring particles. The direction for future analysis and observation is considered.

Esposito, L. W.↗