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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Application of Linear Additive Conditions for Near-Infrared Diffuse Reflectance Absorption Spectroscopy

Determining the homogeneity of material mixing in real time during product processing is critical for quality control. According to the Kubelka–Munk (K-M) function of diffuse reflectance absorption spectrum, absorbance (A) is approximately linear with the content of the components when the sample scattering coefficient (S) is in a certain range. The S is determined by the particle size of powder samples. Therefore, this study determined particle size ranges that satisfy linear additivity in near-infrared diffuse reflectance spectroscopy (NIRDRS). Thus, the proposed NIRDRS analysis technique can be used to determine the homogeneity of material mixes or analyze the percentages of the components in the mixture. In this study, vitamin B3 and vitamin C were used for preparing mixed samples with varying percentages. The experimental results revealed that linear additivity is satisfied when the powder particle size is in the range of less than 280, 280–450, and 450–900 μm. When the confidence level is 0.01, the actual mixed spectra are not significantly different from the “simulated mixed spectra” constructed by linear addition, with their relative deviations less than 1.08%. The absolute errors of the actual and analytic percentages were within 2.98% for each component in the mixtures. The above conclusions also hold for sorghum, which has a complex material composition. Statistical models cannot analyze the percentages of components in the mixture. In contrast, linear addition and direct calibration approach avoids the use of a large number of samples for statistical modeling and analyze the percentages of mixed samples. Meanwhile, it can be used to discriminate and analyze the material mixing uniformity by building a mechanistic model.

Feng, Zhiyue↗
NASA NTRS1988

Confusion-limited galaxy fields. I - Simulated optical and near-infrared images

Techniques for simulating images of galaxy fields are presented that extend to high redshifts and a surface density of galaxies high enough to produce overlapping images. The observed properties of galaxies and galaxy-ensembles in the 'local' universe are extrapolated to high redshifts using reasonable scenarios for the evolution of galaxies and their spatial distribution. This theoretical framework is then employed with Monte Carlo techniques to create fairly realistic two-dimensional distributions of galaxies plus optical and near-infrared sky images in a variety of model universes, using the appropriate density, luminosity, and angular size versus redshift relations.

Chokshi, Arati↗
DOE OSTI2023

Manipulating Interlayer Excitons for Near-Infrared Quantum Light Generation

Interlayer excitons (IXs) formed at the interface of van der Waals materials possess various novel properties. In parallel development, strain engineering has emerged as an effective means for creating 2D quantum emitters. Here, exploring the intersection of these two exciting areas, we use MoS2/WSe2 heterostructure as a model system and demonstrate how strain, defects, and layering can be utilized to create defect-bound IXs capable of bright, robust, and tunable quantum light emission in the technologically important near-infrared spectral range. Our work presents defect-bound IXs as a promising platform for pushing the performance of 2D quantum emitters beyond their current limitations.

2D heterostructures↗
NASA NTRS2008

Monitoring Delamination of Thermal Barrier Coatings by Near-Infrared and Upconversion Luminescence Imaging

Previous work has demonstrated that TBC delamination can be monitored by incorporating a thin luminescent sublayer that produces greatly increased luminescence intensity from delaminated regions of the TBC. Initial efforts utilized visible-wavelength luminescence from either europium or erbium doped sublayers. This approach exhibited good sensitivity to delamination of electron-beam physical-vapor-deposited (EB-PVD) TBCs, but limited sensitivity to delamination of the more highly scattering plasma-sprayed TBCs due to stronger optical scattering and to interference by luminescence from rare-earth impurities. These difficulties have now been overcome by new strategies employing near-infrared (NIR) and upconversion luminescence imaging. NIR luminescence at 1550 nm was produced in an erbium plus ytterbium co-doped yttria-stabilized zirconia (YSZ) luminescent sublayer using 980-nm excitation. Compared to visible-wavelength luminescence, these NIR emission and excitation wavelengths are much more weakly scattered by the TBC and therefore show much improved depth-probing capabilities. In addition, two-photon upconversion luminescence excitation at 980 nm wavelength produces luminescence emission at 562 nm with near-zero fluorescence background and exceptional contrast for delamination indication. The ability to detect TBC delamination produced by Rockwell indentation and by furnace cycling is demonstrated for both EB-PVD and plasma-sprayed TBCs. The relative strengths of the NIR and upconversion luminescence methods for monitoring TBC delamination are discussed.

Eldridge, J. I.↗
NASA NTRS1998

Simple Refractometers for Index Measurements by Minimum Deviation Method from Far-ultraviolet to Near Infrared

The focal shift of an optical filter used in non-collimated light depends directly on substrate thickness and index of refraction. The HST Advanced Camera for Surveys (ACS) requires a set of filters whose focal shifts are tightly matched. Knowing the index of refraction for substrate glasses allows precise substrate thicknesses to be specified. Two refractometers have been developed at the Goddard Space Flight Center (GSFC) to determine the indices of refraction of materials from which ACS filters are made. Modem imaging detectors for the near infrared, visible, and far ultraviolet spectral regions make these simple yet sophisticated refractometers possible. A new technology, high accuracy, angular encoder also developed at GSFC makes high precision index measurement possible in the vacuum ultraviolet.

Leviton, Douglas B.↗
NASA NTRS1982

Skylab near-infrared observations of clouds indicating supercooled liquid water droplets

Orographically-induced lee-wave clouds were observed over New Mexico by a multichannel scanning radiometer on Skylab during December 1973. Channels centered at 0.83, 1.61 and 2.125 microns were used to determine the cloud optical thickness, thermodynamic phase and effective particle size. An additional channel centered at 11.4 microns was used to determine cloud-top temperature, which was corroborated through comparison with the stereographically determined cloud top altitudes and conventional temperature soundings. Analysis of the measured near-infrared reflection functions at 1.61 and 2.125 microns are most easily interpreted as indicating the presence of liquid-phase water droplets. This interpretation is not conclusive even after considerable effort to understand possible sources for misinterpretation. However, if accepted the resulting phase determination is considered anomalous due to the inferred cloud-top temperatures being in the -32 to -47 C range. Theory for the homogeneous nucleation of pure supercooled liquid water droplets predicts very short lifetimes for the liquid phase at these cold temperatures. A possible explanation for the observations is that the wave-clouds are composed of solution droplets. Impurities in the cloud droplets could decrease the homogeneous freezing rate for these droplets, permitting them to exist for a longer time in the liquid phase, at the cold temperatures found.

Curran, R. J.↗
DOE OSTI2023

Biomimetic tissue phantoms for neurosurgical near-infrared fluorescence imaging

Neurosurgical fluorescence imaging is a well-established clinical approach with a growing range of indications for use. However, this technology lacks effective phantom-based tools for development, performance testing, and clinician training. Our primary aim was to develop and evaluate 3D-printed phantoms capable of optically and morphologically simulating neurovasculature under fluorescence angiography. Volumetric digital maps of the circle of Willis with basilar and posterior communicator artery aneurysms, along with surrounding cerebral tissue, were generated. Phantoms were fabricated with a stereolithography printer using custom photopolymer composites, then visualized under white light and near-infrared fluorescence imaging. Feature sizes of printed components were found to be within 13% of digital models. Phantoms exhibited realistic optical properties and convincingly recapitulated fluorescence angiography scenes. Methods identified in this study can facilitate the development of realistic phantoms as powerful new tools for fluorescence imaging.

3D modeling↗
NASA NTRS2010

A Near-Infrared Spectrometer to Measure Zodiacal Light Absorption Spectrum

We have developed a high throughput infrared spectrometer for zodiacal light fraunhofer lines measurements. The instrument is based on a cryogenic dual silicon Fabry-Perot etalon which is designed to achieve high signal to noise Fraunhofer line profile measurements. Very large aperture silicon Fabry-Perot etalons and fast camera optics make these measurements possible. The results of the absorption line profile measurements will provide a model free measure of the zodiacal Light intensity in the near infrared. The knowledge of the zodiacal light brightness is crucial for accurate subtraction of zodiacal light foreground for accurate measure of the extragalactic background light after the subtraction of zodiacal light foreground. We present the final design of the instrument and the first results of its performance.

Kutyrev, A. S.↗
NASA NTRS1995

Near-infrared spectra of compact stellar wind sources at the Galactic center

We present high- and low-resolution, H- and K-band spectra on nine compact 2.2 micrometers Galactic center sources in which we clearly detect He I 2.058 micrometers emission, including the AF source, IRS 13, IRS 1W, IRS 16NE, IRS 16NW, IRS 16C, IRS 16SW, IRS 34, and IRS 6E. We have also obtained comparison spectra of both a luminous blue variable (LBV) and a WR star (P Cygni and HD 192163, respectively). Our H- and K-band spectrum of the LBV P Cygni strongly resembles the near-infrared spectra of known WN9/Ofpe stars. Our spectra of the Galactic center sources share many characteristics in common with our spectrum of P Cygni. The spectra all show emission lines of H I and He I with large He I/H line flux ratios. Some have permitted and forbidden lines of Fe II. Brackett line widths and ratios indicate the presence of strong stellar winds. In contrast to the spectrum of the WR star, none of the Galactic center sources show evidence of He II emission lines in their spectra, suggesting that none of the Galactic center sources are WR stars. Our high-resolution H-band spectrum of the AF source differs from previously published low-resolution H-band spectra in that it is rich in emission lines. Furthermore, we find two distinct spectral components to the AF source separated in space by a few arcseconds. We identify both the emission-line component of the AF source and an exciting source of IRS 13 as an LBV or WN9/Ofpe star. Our results, when combined with the results of others, also suggest that IRS 16NE, IRS 16C, IRS 16NW, IRS 34, and a component of IRS 6E are early-type, emission-line stars. The argument for IRS 16SW, however, is less compelling. We find no evidence for a compact He I emission-line source at IRS 1W. This result contradicts previous findings, suggesting that the He I source at IRS 1W may be variable. If the He I lines in IRS 1W are truly variable, a stellar component of IRS 1W may be an LBV, because LBVs are known to have variable line emission on short timescales. The nine Galactic center wind sources appear to contribute a significant fraction of the total luminosity of the central few parsecs of the Galaxy.

Libonate, S.↗
DOE OSTI2026

How Does Metal Spin State Affect Electronic Communication in Mixed-Valence Dimers? Insights from Ultrafast Near-Infrared and Soft X-ray Transient Absorption Spectroscopy

Recent advancements in photocatalysis, photovoltaics, and quantum information science take advantage of electron spin, and determining how spin multiplicity affects electron transfer is key to understanding these phenomena. Here, in this study, we examine how metal spin state affects electronic communication in an organometallic mixed-valence dimer, ferrocenyl cobaltocenium ([Fe II Cp 2 Co III Cp 2 ] + ). This complex can be photoexcited from its low-spin singlet Fe II ground state to form intermediate-spin triplet Fe II and high-spin quintet Fe II excited states. Using femtosecond optical transient absorption (OTA) spectroscopy with visible (vis), near-infrared (NIR), and short-wave IR (SWIR) probes, supported by time-dependent density functional theory (TD-DFT) calculations, we measure Fe II Co III →Fe III Co II intervalence charge transfer (IVCT) bands in each of the Fe II spin states. Mulliken–Hush analysis of the excited-state IVCT bands was used to compute the electronic coupling between the metal centers in all three spin states, which increased as quintet < triplet < singlet. Meanwhile, the peak energy of the bands, and thus the ΔG of the IVCT transition, increased as triplet < quintet < singlet. Then, to directly probe the electronic structure at each metal center, we employed picosecond soft X-ray transient absorption (XTA) spectroscopy at the Fe and Co L 3 edges. Our results show that the low-spin and high-spin states of [Fe II Cp 2 Co III Cp 2 ] + are valence-localized, while the intermediate-spin state is partially delocalized. The differences in charge delocalization are attributed to differences in orbital occupation and geometry that affect the free energy and superexchange coupling.

Burke, John H. [Univ. of Illinois at Urbana-Champa↗
NASA NTRS2023

X-Ray and Near-Infrared Observations of the Middle-aged Pulsar B1055-52, Its Multiwavelength Spectrum, and Proper Motion

Previous observations of the middle-aged γ-ray, X-ray, and radio pulsar B1055–52 indicated some peculiarities, such as a suspected changing of the X-ray flux and spectral parameters, a large excess of the alleged thermal component of the UV spectrum over the Rayleigh–Jeans extension of the X-ray thermal spectrum, and a possible double break in the nonthermal spectral component between the optical and X-ray bands. We observed PSR B1055–52 with the XMM-Newton observatory in X-rays and the Hubble Space Telescope in near-infrared (NIR). The analysis of the XMM-Newton observations does not support the notion of long-term changes in the X-ray flux and broadband X-ray spectrum of the pulsar. Using an observing mode less affected by background noise than the previous XMM-Newton observations, we constrain the power-law (PL) spectral index as X 0.57 0.25 0.26 a = - - + (Fν ∝ ν α ) in the energy band 3–10 keV. From the NIR–optical data we obtain a PL slope αO = −0.24 ± 0.10 for the color index E(B − V ) = 0.03 mag. The slopes and fluxes of the NIR–optical and X-ray nonthermal spectra suggest that the NIR through X-ray emission can be described by the same PL and is generated by the same mechanism, unlike the pulsar’s γ-ray emission. The excess of the UV thermal component over the extension of the X-ray thermal component became smaller but did not disappear, indicating a nonuniformity of the bulk surface temperature. The NIR data also enable us to measure the proper motion accurately, with values μα = 47.5 ± 0.7 mas yr−1 and μδ = −8.7 ± 0.7 mas yr−1 .

B Posselt↗
NASA NTRS1997

Study of SRM Critical Surfaces Using Near Infrared Optical Fiber Spectrometry

The measurement and control of cleanliness for critical surfaces during manufacturing and in service operations provides a unique challenge in the current thrust for environmentally benign processes. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants which are detrimental to the integrity of the bondline. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This paper will provide an introduction to the use of Near Infrared (NIR) optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. In a previous conference, experimental results for quantitative measurement of silicone and Conoco HD2 greases, and tape residues on solid rocket motor surfaces were presented. This paper will present data for metal hydroxides and discuss the use of the integrating sphere to minimize the effects of physical properties of the surfaces (such as surface roughness) on the results obtained from the chemometric methods used for quantitative analysis.

Workman, G. L.↗
NASA NTRS1995

A new Fabry-Perot spectrometer for observations of diffuse near-infrared line emission

We describe a new Fabry-Perot spectrometer that is optimized for the detection of extended, low-surface-brightness line emission from 1.4 to 2.4 microns. The instrument combines high throughput and high sensitivity, yet limits the background radiation falling on the detector. The instrument has a single 20 sec - 200 sec beam and a resolving power lambda/delta(lambda) approximately 2500. The system is background shot-noise limited in the K window and limited by a combination of read noise, dark-current shot noise, and fluctuations in the OH airglow lines in the H window. We present sample data of some of the lowest-surface-brightness H2 line emission in the near infrared obtained to date.

Luhman, M. L.↗
NASA NTRS2016

Near-Infrared Monitoring of Volatiles in Frozen Lunar Simulants While Drilling

In Situ Resource Utilization (ISRU) focuses on using local resources for mission consumables. The approach can reduce mission cost and risk. Lunar polar volatiles, e.g. water ice, have been detected via remote sensing measurements and represent a potential resource for both humans and propellant. The exact nature of the horizontal and depth distribution of the ice remains to be documented in situ. NASA's Resource Prospector mission (RP) is intended to investigate the polar volatiles using a rover, drill, and the RESOLVE science package. RP component level hardware is undergoing testing in relevant lunar conditions (cryovacuum). In March 2015 a series of drilling tests were undertaken using the Honeybee Robotics RP Drill, Near-Infrared Volatile Spectrometer System (NIRVSS), and sample capture mechanisms (SCM) inside a 'dirty' thermal vacuum chamber at the NASA Glenn Research Center. The goal of these tests was to investigate the ability of NIRVSS to monitor volatiles during drilling activities and assess delivery of soil sample transfer to the SCMs in order to elucidate the concept of operations associated with this regolith sampling method.

Neutron Spectrometer System↗
NASA NTRS2008

The (55)Fe X-ray Energy Response of Mercury Cadmium Telluride Near-Infrared Detector Arrays

The accurate determination of a detector's fundamental parameters, including read noise, dark current, and QE, relies on a proper measurement of a detector's conversion gain (e- ADU(exp -1)). Charge coupling effects, such as interpixel capacitance, attenuate photon shot noise and result in an overestimation of conversion gain when implementing the photon transfer technique. An approach involving (55)Fe X-rays provides a potentially straightforward measurement of conversion gain by comparing the observed instrumental counts (ADU) to the known charge (e-) liberated by the X-ray. This technique is already preferred within the CCD community, as the pair production energy for silicon is well established. In contrast, to date the pair production energy is unknown for HgCdTe, a material commonly used for near-infrared detectors. In this paper, we derive a preliminary calibration of the (55)Fe X-ray energy response of HgCdTe using 8 HST WFC3 1.7 micrometers flight grade detectors. Our conversion of the X-ray intensities from counts into electrons implements a technique that restores the 'true' gain via classical propagation of errors. For these detectors, our analysis yields preliminary results of good statistical precision: each Ka event generates 1849 +/- 46 electrons, which corresponds to a pair production energy of 3.21+/-f 0.08 eV. We are continuing to assess potential systematic effects to further refine the accuracy of this result.

Fox, Ori↗
NASA NTRS1995

Study of surfaces using near infrared optical fiber spectrometry

The measurement and control of cleanliness for critical surfaces during manufacturing and in service provides a unique challenge for fulfillment of environmentally benign operations. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This presentation will provide an introduction to the use of optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. Correlation of the Near Infrared (NIR) spectroscopic results with Optical Stimulated Electron Emission (OSEE) and ellipsometry will also be presented.

Workman, G. L.↗
DOE OSTI2025

Photonics Breakthroughs 2024: Narrow-Linewidth Lasers in the Visible and Near-Infrared

Narrow-linewidth lasers enable a variety of high-precision applications, such as sensing, optical clocks, and microwave frequency generation. Advances in photonic integration in the last decade led to the development of ultra-low-noise integrated semiconductor lasers, mostly in the telecom wavelength range. In recent years, the demand for high-performance lasers at shorter wavelengths skyrocketed, driven by applications in sensing and atom trapping. Low-noise lasers are of particular importance in this spectral range, as they are essential for optical clocks. Here, we will review recent progress in narrow-linewidth lasers at shorter wavelengths, present results on a hybrid-integrated low-noise laser at 780 nm and discuss the perspectives and challenges of high-performance semiconductor lasers in the visible and near-infrared.

Prokoshin, Artem [King Abdullah University of Scie↗
DOE OSTI2021

High-speed programmable photonic circuits in a cryogenically compatible, visible–near-infrared 200 mm CMOS architecture

Abstract Recent advances in photonic integrated circuits have enabled a new generation of programmable Mach–Zehnder meshes (MZMs) realized by using cascaded Mach–Zehnder interferometers capable of universal linear-optical transformations on N input/output optical modes. MZMs serve critical functions in photonic quantum information processing, quantum-enhanced sensor networks, machine learning and other applications. However, MZM implementations reported to date rely on thermo-optic phase shifters, which limit applications due to slow response times and high power consumption. Here we introduce a large-scale MZM platform made in a 200 mm complementary metal–oxide–semiconductor foundry, which uses aluminium nitride piezo-optomechanical actuators coupled to silicon nitride waveguides, enabling low-loss propagation with phase modulation at greater than 100 MHz in the visible–near-infrared wavelengths. Moreover, the vanishingly low hold-power consumption of the piezo-actuators enables these photonic integrated circuits to operate at cryogenic temperatures, paving the way for a fully integrated device architecture for a range of quantum applications.

47 OTHER INSTRUMENTATION↗