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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Scanless laser waveform measurement in the near-infrared

Field-resolved measurements of few-cycle laser waveforms allow access to ultrafast electron dynamics in light–matter interactions and are key to future lightwave electronics. Recently, sub-cycle gating based on nonlinear excitation in active pixel sensors has allowed the first single-shot measurements of mid-infrared optical fields. Extending the techniques to shorter wavelengths, however, is not feasible using silicon-based detectors with bandgaps in the near-infrared. Here, we demonstrate an all-optical sampling technique for near-infrared laser fields, wherein an intense fundamental field generates a sub-cycle gate through nonlinear excitation of a wide-bandgap crystal, in this case, ZnO, which can sample the electric field of a weak perturbing pulse. By using a crossed-beam geometry, the temporal evolution of the perturbing field is mapped onto a transverse spatial axis of the nonlinear medium, and the waveform is captured in a single measurement of the spatially resolved fluorescence emission from the crystal. The technique is demonstrated through field-resolved measurements of the field reshaping during nonlinear propagation in the ZnO detection crystal.

Truong, Tran-Chau (ORCID:0000000348940635)↗

Boson Fermion Nucleus Explanation for Violation of Parity in the Radioactive Decay of Cobalt-60: Monograph #12

In 1957, Chien-Shuing Wu subjected cobalt-60 to supercooled temperatures and a strong magnetic field while measuring radioactive decay. This experiment showed violation of parity— a long-held, fundamental precept in physics stating that nuclear radioactive-decay emission flux will not vary in the solid angle about the nucleus. During Wu’s experiment, beta particles (electrons) exhibited asymmetry, preferentially exiting the cobalt-60 nuclei in the polar region opposite the applied magnetic field. Gamma-ray emissions were anisotropic, preferring to exit the nucleus around the equatorial region. The boson fermion nucleus (BFN) explains the origins of these observed phenomena, where the nuclear structure is pinned in the strong magnetic field with minimal motion in supercooled conditions, while beta particles and gamma rays are emitted from specific locations within the nuclear structure.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Predicting Emission Source Terms in a Reduced-Order Fire Spread Model—Part 1: Particulate Emissions

A simple, easy-to-evaluate, surrogate model was developed for predicting the particle emission source term in wildfire simulations. In creating this model, we conceptualized wildfire as a series of flamelets, and using this concept of flamelets, we developed a one-dimensional model to represent the structure of these flamelets which then could be used to simulate the evolution of a single flamelet. A previously developed soot model was executed within this flamelet simulation which could produce a particle size distribution. Executing this flamelet simulation 1200 times with varying conditions created a data set of emitted particle size distributions to which simple rational equations could be tuned to predict a particle emission factor, mean particle size, and standard deviation of particle sizes. These surrogate models (the rational equation) were implemented into a reduced-order fire spread model, QUIC-Fire. Using QUIC-Fire, an ensemble of simulations were executed for grassland fires, southeast U.S. conifer forests, and western mountain conifer forests. Resulting emission factors from this ensemble were compared against field data for these fire classes with promising results. Also shown is a predicted averaged resulting particle size distribution with the bulk of particles produced to be on the order of 1 μm in size.

54 ENVIRONMENTAL SCIENCES↗

Voltage-Dependent Photoluminescence of Carbon Dots

Carbon dots are fluorescent carbon-based nanoparticles with great potential in bioimaging because they offer multiple imaging windows owing to their excitation dependent emission features. A recent theory study shows that emission of graphene quantum dots responds to external elec. field due to Stark effect. Inspired by this work, we have demonstrated here the first exptl. study of the Stark effect of fluorescent carbon dots synthesized via a soft-template method. The carbon dots exhibit excitation-dependent emission covering blue to orange emission range. After being encapsulated in artificial lipid bilayers, the carbon dots show voltage-sensitivity of fluorescence. The fluorescence intensity change per mV is comparable with that of com. membrane potential sensing dyes. Our results demonstrate the great potential of carbon dots in membrane voltage sensing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Creation of Single-Photon Emitters in WSe 2 Monolayers Using Nanometer-Sized Gold Tips

Due to their tunable bandgaps and strong spin-valley locking, transition metal dichalcogenides constitute a unique platform for hosting single-photon emitters. Here, we present a versatile approach for creating bright single-photon emitters in WSe 2 monolayers by the deposition of gold nanostars. Our molecular dynamics simulations reveal that the formation of the quantum emitters is likely caused by the highly localized strain fields created by the sharp tips of the gold nanostars. The surface plasmon modes supported by the gold nanostars can change the local electromagnetic fields in the vicinity of the quantum emitters, leading to their enhanced emission intensities. Moreover, by correlating the emission energies and intensities of the quantum emitters, we are able to associate them with two types of strain fields and derive the existence of a low-lying dark state in their electronic structures. The findings here are highly relevant for the development and understanding of single-photon emitters in transition metal dichalcogenide materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamics of the collapse of a ferromagnetic skyrmion in a centrosymmetric lattice

We report time dependence of the size and chirality of a ferromagnetic skyrmion in a Heisenberg model with the magnetic field on a square lattice has been studied analytically and numerically. The lattice and the magnetic field generate strong time dependence of the skyrmion chirality. Due to nonlinearity, the lattice alone also generates strong intrinsic damping that leads to the skyrmion collapse via the emission of spin waves. In the absence of the magnetic field, the collapse is slow for a large skyrmion, but it becomes exponentially fast in the presence of the Landau-Lifshitz damping when the field is turned on. Magnons emitted by a collapsing skyrmion must have a discrete spectrum due to the quantization of the skyrmion magnetic moment.

2-dimensional systems↗

Rye-soybean double-crop: planting method and N fertilization effects in the North Central US

Double-cropping winter rye cover crops (CC) with soybean in the North Central US could help with the global effort to sustainably intensify agriculture. Studies addressing the management of these systems are limited. Therefore, a field study was conducted from 2017 to 2019 in Central Iowa, US to evaluate winter rye CC biomass production, aboveground N accumulation, estimated economics, estimated within-field energy balance and estimated greenhouse gas (GHG) emissions under three N application rates (0, 60, 120 kg N ha –1 ) and three planting methods (pre- and post-harvest broadcast and post-harvest drilling). Averaged over N rates, all planting methods resulted in >5.0 Mg ha –1 year –1 rye aboveground biomass dry matter. Averaged over the 2-year study and compared with unfertilized treatments, applying 60 kg N ha –1 produced 1.1 Mg ha –1 more aboveground biomass (6.1 vs 5.0 Mg ha –1 ), accumulated 30 kg ha –1 more N in aboveground biomass (88 vs 58 kg N ha –1 ), and led to 20 GJ ha –1 more net energy. Biomass production was not significantly higher with 120 kg N ha –1 compared with the 60 kg N ha –1 rate. Even when accounting for an estimated 0.75 Mg ha –1 of above ground rye biomass left in the field after harvesting, more N was removed than applied at the 60 kg N ha –1 rate. The minimum rye prices over the 2-year study needed for double-cropping winter rye CC to be profitable (breakeven prices) averaged $117 and $104 Mg –1 for the 0 and 60 kg N ha –1 rates, which factors in estimated soybean yield reductions in 2019 compared with local averages but not off-site transportation. GHG emissions were estimated to increase approximately threefold between the unfertilized and 60 kg N ha –1 rates without considering bioenergy offsets. While environmental tradeoffs need further study, results suggest harvesting fertilized rye CC biomass before planting soybean is a promising practice for the North Central US to maximize total crop and net energy production.

59 BASIC BIOLOGICAL SCIENCES↗

Nanosecond Repetitively Pulsed (NRP) Plasmas: Relationship Between Induced Flow and Plasma Characteristics at Atmospheric Pressure (Final Technical Report)

The local flow fields induced by plasma discharges at atmospheric pressure can play a critical role in aerodynamic flow and combustion control and have significant implications for plasma-based technologies in medicine and environmental engineering. However, the coupling between the plasma characteristics, the geometry and the induced flow field is not well understood. The primary goal of this work is to determine the relationship between the plasma characteristics and the induced flow field for nanosecond pulsed discharges at atmospheric pressure. A comprehensive experimental investigation of plasmas produced by nanosecond high-voltage pulses in a pin-to-pin electrode configuration was conducted, employing several measurement techniques including microwave and laser Rayleigh scattering, optical emission spectroscopy, and high-speed imaging. The flow field induced by the nanosecond plasma was measured and characterized using measurements of the velocity (particle image velocimetry) and density (background oriented schlieren) with unprecedented spatiotemporal resolution. The experimental measurements were complemented by development of a one-dimensional model of the plasma discharge and a high-fidelity computational fluid dynamics (CFD) simulation of the subsequent plasma-induced flow field.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Standing shock prevents propagation of sparks in supersonic explosive flows

Abstract Volcanic jet flows in explosive eruptions emit radio frequency signatures, indicative of their fluid dynamic and electrostatic conditions. The emissions originate from sparks supported by an electric field built up by the ejected charged volcanic particles. When shock-defined, low-pressure regions confine the sparks, the signatures may be limited to high-frequency content corresponding to the early components of the avalanche-streamer-leader hierarchy. Here, we image sparks and a standing shock together in a transient supersonic jet of micro-diamonds entrained in argon. Fluid dynamic and kinetic simulations of the experiment demonstrate that the observed sparks originate upstream of the standing shock. The sparks are initiated in the rarefaction region, and cut off at the shock, which would limit their radio frequency emissions to a tell-tale high-frequency regime. We show that sparks transmit an impression of the explosive flow, and open the way for novel instrumentation to diagnose currently inaccessible explosive phenomena.

58 GEOSCIENCES↗

Pair Cascades in Magnetar Magnetospheres

Resonant inverse Compton scattering (RICS) of soft thermal photons by relativistic particles on closed magnetic field loops has been proposed to explain the hard emission observed up to and beyond 200 keV from magnetars. If particles injected at the base of the loops have Lorentz factors ≳10 2 , the RICS spectra will be attenuated by both one-photon pair production and photon splitting in the ultrastrong magnetar fields, producing additional spectral components from pair synchrotron radiation and split photons that produce further generations of pairs and split photons. We investigate such cascades initiated by the primary injected electrons through a Monte Carlo simulation, and study the cascade spectra and pair distributions. For most observer angles, the pair synchrotron and split-photon spectra dominate the RICS primary spectra and produce complex polarization signals. In particular, the synchrotron spectra are highly polarized with degree 40%–80%, are softer than the RICS spectra, and may account for the high polarization of some magnetar spectra observed by the Imaging X-ray Polarimetry Explorer above 3 keV.

79 ASTRONOMY AND ASTROPHYSICS↗

Atmospheric Escape From TOI-700 d: Venus versus Earth Analogs

The recent discovery of an Earth-sized planet (TOI-700 d) in the habitable zone of an early-type M-dwarf by the Transiting Exoplanet Survey Satellite constitutes an important advance. In this Letter, we assess the feasibility of this planet to retain an atmosphere – one of the chief ingredients for surface habitability – over long timescales by employing state-of-the-art magnetohydrodynamic models to simulate the stellar wind and the associated rates of atmospheric escape. We take two major factors into consideration, namely, the planetary atmospheric composition and magnetic field. In all cases, we determine that the atmospheric ion escape rates are potentially a few orders of magnitude higher than the inner Solar system planets, but TOI-700 d is nevertheless capable of retaining a 1 bar atmosphere over gigayear timescales for certain regions of the parameter space. The simulations show that the unmagnetized TOI-700 d with a 1 bar Earth-like atmosphere could be stripped away rather quickly (< 1 gigayear), while the unmagnetized TOI-700 d with a 1 bar CO 2 -dominated atmosphere could persist for many billions of years; we find that the magnetized Earth-like case falls in between these two scenarios. We also discuss the prospects for detecting radio emission of the planet (thereby constraining its magnetic field) and discerning the presence of an atmosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

The motional Stark effect diagnostic for ITER

An overview of the plans for the motional Stark effect (MSE) diagnostic installation on the International Thermonuclear Experimental Reactor (ITER) is presented. The MSE diagnostic uniquely provides spatially localized magnetic field measurements inside the plasma. These are used to constrain equilibrium reconstructions to determine q(r), the safety factor as a function of minor radius. Meeting the system requirements to deliver q-profiles and related quantities with the specified radial resolution of 20 points over the minor radius, 10 ms time resolution, and better than 10% accuracy is challenging. MSE systems observe the D/H-α emission near 656.3 nm from neutral beams. As the beam atoms traverse the magnetic field, B⃗, at high velocity, v⃗, they experience a Lorentz electric field, v⃗×B⃗, which causes the spectral emission to be split and polarized due to the Stark effect. Traditional MSE-LP (line polarization) measurements determine the direction of the magnetic field in the observation volume using polarimetric analysis of the detected light. The harsh conditions of ITER are expected to deposit thin films of contaminants on the first mirror, which would alter the polarization state of reflected light significantly. On ITER, the combination of high magnetic field strength and high energy beams makes the Stark spectrum resolution suitable for the determination of the magnetic field magnitude from the line shift, so this approach has been selected. Every aspect of the measurement system must be planned for the burning plasma environment and carefully analyzed ahead of time. Current status and plans for the system are presented.

Instruments & Instrumentation↗

Multiple emission components in the Cygnus cocoon detected from Fermi -LAT observations

Star-forming regions may play an important role in the life cycle of Galactic cosmic rays (CRs), notably as home to specific acceleration mechanisms and transport conditions. Gamma-ray observations of Cygnus X have revealed the presence of an excess of hard-spectrum gamma-ray emission, possibly related to a cocoon of freshly accelerated particles. We seek an improved description of the gamma-ray emission from the cocoon using ~13 yr of observations with the Fermi-Large Area Telescope (LAT) and use it to further constrain the processes and objects responsible for the young CR population. We developed an emission model for a large region of interest, including a description of interstellar emission from the background population of CRs and recent models for other gamma-ray sources in the field. Thus, we performed an improved spectro-morphological characterisation of the residual emission including the cocoon. The best-fit model for the cocoon includes two main emission components: an extended component FCES G78.74+1.56, described by a 2D Gaussian of extension r 68 = 4.4° ± 0.1° -0.1° +0.1° and a smooth broken power law spectrum with spectral indices 1.67 ± 0.05 -0.01 +0.02 and 2.12 ± 0.02 -0.01 +0.00 below and above 3.0 ± 0.6 -0.2 +0.0 GeV, respectively; and a central component FCES G80.00+0.50, traced by the distribution of ionised gas within the borders of the photo-dissociation regions and with a power law spectrum of index 2.19 ± 0.03 -0.01 +0.00 that is significantly different from the spectrum of FCES G78.74+1.56. An additional extended emission component FCES G78.83+3.57, located on the edge of the central cavities in Cygnus X and with a spectrum compatible with that of FCES G80.00+0.50, is likely related to the cocoon. For the two brightest components FCES G80.00+0.50 and FCES G78.74+1.56, spectra and radial-azimuthal profiles of the emission can be accounted for in a diffusion-loss framework involving one single population of non-thermal particles with a flat injection spectrum. Particles span the full extent of FCES G78.74+1.56 as a result of diffusion from a central source, and give rise to source FCES G80.00+0.50 by interacting with ionised gas in the innermost region. For this simple diffusion-loss model, viable setups can be very different in terms of energetics, transport conditions, and timescales involved, and both hadronic and leptonic scenarios are possible. The solutions range from long-lasting particle acceleration, possibly in prominent star clusters such as Cyg OB2 and NGC 6910, to a more recent and short-lived release of particles within the last 10–100 kyr, likely from a supernova remnant. The observables extracted from our analysis can be used to perform detailed comparisons with advanced models of particle acceleration and transport in star-forming regions.

79 ASTRONOMY AND ASTROPHYSICS↗

Dynamic magneto-chiral instability in photoexcited tellurium

In systems of charged chiral fermions out of equilibrium, an electric current parallel to a magnetic field can generate a dynamic instability that amplifies electromagnetic waves. Whether this mechanism also operates in chiral solid-state systems has remained uncertain. Here we observe signatures of a dynamic magneto-chiral instability in elemental tellurium, a structurally chiral crystal, using time-domain terahertz emission spectroscopy. Under transient photoexcitation in a moderate magnetic field, we observe terahertz radiation with coherent modes that grow in amplitude over time. We present a theoretical model that describes this behaviour based on a dynamic instability of electromagnetic waves interacting with infrared-active oscillators of acceptor states in tellurium, giving rise to an amplifying polariton. These results demonstrate that magneto-chiral instabilities can emerge in solid-state systems and establish a mechanism for terahertz-wave amplification in chiral materials.

42 ENGINEERING↗

Reduction of Methane Leaks through Corrosion Mitigation Pre-treatments for Pipelines with Field Applied Coatings

Corrosion of buried, coated steel pipelines transporting natural gas is a significant source of methane emissions, from pipeline venting required for maintenance and repairs and from pipeline leaks and incidents. Corrosion of steel under field applied coatings is an important safety concern for the pipeline industry. This project investigates the application of a field applied alloy over girth welds to mitigate external corrosion of buried coated steel pipelines. Various metallic coating options were considered, which were required to meet several criteria: (1) it must resist corrosion under open-circuit or mild cathodic protection conditions, (2) it must protect the substrate steel, and (3) it must not negatively affect the adhesion of the field coating. Finite element models and lab testing were performed of alloy coating compositions to identify promising alloy types underneath disbonded coatings. Polarization curves of coating alloys were generated to provide the boundary conditions for the COMSOL model to compute potential and current distributions around coated areas. Sacrificial and corrosion-resistant metal alloy coatings were evaluated and optimized using corrosion modeling and laboratory electrochemical testing, where aluminum alloy 5356 (5% Mg) and steel alloy B9 (9% Cr) were selected. Corrosion test coupons were designed and fabricated using thermal spray aluminum 5356 and welded B9 steel overlays on API 5L grade X42 line pipe steel. The corrosion test coupons, with simulated pipe coating damage, were tested in a laboratory soil box and a field pipeline site in Texas for 3-months. Corrosion test coupons were then tested for 6-months at field pipeline sites in Texas and Tennessee to quantify corrosion rates and performance of the aluminum and steel alloys under polyethylene tape and 2-part epoxy coatings, various coating holidays, and with and without cathodic protection.

03 NATURAL GAS↗

Diagnostics for Burning Plasmas

Here, recent progress in the design and manufacturing development of in-vessel diagnostic components by the U.S. ITER team is reported. Design and manufacturing choices are driven by engineering challenges stemming from ITER’s burning plasma mission, which entails levels of plasma neutron emission, pulse lengths, and size scales well beyond the existing database. Challenges include port access limitations, neutron irradiation and activation risks, nuclear heating of components, complex interfaces, remote handling compatibility, and constraints on component and processing materials. Responses to these challenges are presented using examples from the low field side reflectometer, toroidal interferometer polarimeter, and electron cyclotron emission diagnostics. Relevance of the experience from ITER diagnostics engineering to the design of future integrated fusion facilities based on burning plasmas is addressed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Attosecond synchronization of extreme ultraviolet high harmonics from crystals

The interaction of strong near-infrared (NIR) laser pulses with wide-bandgap dielectrics produces high harmonics in the extreme ultraviolet (XUV) wavelength range. These observations have opened up the possibility of attosecond metrology in solids, which would benefit from a precise measurement of the emission times of individual harmonics with respect to the NIR laser field. In this work, we show that, when high-harmonics are detected from the input surface of a magnesium oxide crystal, a bichromatic probing of the XUV emission shows a clear synchronization largely consistent with a semiclassical model of electron–hole recollisions in bulk solids. On the other hand, the bichromatic spectrogram of harmonics originating from the exit surface of the 200 μm-thick crystal is strongly modified, indicating the influence of laser field distortions during propagation. Our tracking of sub-cycle electron and hole re-collisions at XUV energies is relevant to the development of solid-state sources of attosecond pulses.

74 ATOMIC AND MOLECULAR PHYSICS↗

Polar Bear™ – Innovative Capture of Storage Tank Vapors

Polar Bear™ is a patented technology developed by the Energy & Environmental Research Center (EERC) to capture storage tank vapors and eliminate methane emissions from upstream oil- and gas-producing facilities. Sparked by early commercial investment, the EERC licensed the technology and extended the intellectual property to storage tanks. Polar Bear™ is uniquely engineered and adapted to individual lower-producing facilities where there is otherwise no economic alternative for capturing tank vapors. A high number of small producing oil and gas wells are distributed across the country. The aggregate contributes to a significant volume of emissions. Because of the lack of economy of scale, gas volumes from these facilities are typically not recovered and contribute to methane emissions. Polar Bear™ provides a fit-for-purpose compression solution that addresses cost by reducing complexity with respect to conventional vapor recovery units and eliminating oil changes. Unique to Polar Bear™ is the capability to separate oxygenated gas from storage tank vapors. Storage tanks are designed to “breathe,” allowing gas to enter and escape during internal level and temperature changes. This infiltration of air into the tank headspace imparts undesirable oxygen content with respect to pipeline gathering. Polar Bear™ separates the vapor stream, allowing oxygen-rich gas to be used as fuel on-site while recovering the liquids-rich portion of the gas where oxygen content is minimized. A prototype system was tested to verify process models, evaluate operational performance, and advance the technology readiness level from 5 to 6. Results provide a good match between experimental measurements and process models, indicating the models are useful for future scale-up and field design. Various mixtures of nitrogen and liquefied petroleum gas were tested to understand the mass balance of nitrogen and how it relates to the potential control of oxygen content. Findings indicate that less than 2000 ppm of oxygen is likely to remain in the liquid portion of the gas in field applications. The research and development prepare the technology for field implementation to eliminate routine and fugitive methane emissions from storage tanks.

02 PETROLEUM↗