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At least 451 records · Page 25

Embedding Sensors in 3D Printed Metal Structures

The Transformational Challenge Reactor (TCR) program is leveraging recent advances in modeling and simulation, materials, and additive manufacturing (AM) technologies to design a modern nuclear reactor. Some of the main TCR technologies include in situ monitoring and the integration of sensors during the manufacturing of quality-significant nuclear reactor components. This report describes the general procedure and process optimization for embedding sensors within generic stainless steel 316 (SS316) components using laser powder bed fusion (LPBF). A more detailed, quality-significant test plan and supporting procedures are available upon request (ORNL/TM-2021/2127). LPBF involves the use of a scanning laser to selectively melt regions of a powder bed, additively building a part layer by layer. This report describes the LPBF processing technique and discusses the effects of LPBF processing parameters on the success of the sensor embedding process. Experiments used machined cavities in the form of channels in an SS316 base for the sensors to lay in while material is additively built over the top, thereby embedding them in an SS316 matrix. A preliminary investigation involved using empty SS316 sheaths as surrogates to explore the effects of various LPBF processing parameters and the dimensional requirements of the machined channels. Microstructural investigations showed that a smaller channel width/depth combination closer to the sensor’s diameter was best for the embedding process. After the desired parameters were selected, Type-K thermocouples were embedded and evaluated post-embedding using nondestructive thermal testing, as well as destructive sectioning and microscopy. Post-build characterization showed that the thermocouples were well-bonded to the SS316 matrix and were fully functional after embedding. During thermal testing to temperatures up to 500 °C, the embedded thermocouples read consistently with one another and deviated only slightly from the readings of a nonembedded thermocouple located within the furnace. This slight discrepancy was most likely due to differences in the thermal time constants for a nonembedded thermocouple vs. a thermocouple embedded in a solid SS316 block. The results presented in this report will serve as the foundation for future work that will focus on embedding sensors in relevant TCR reactor components and eventually testing those components under neutron irradiation.

36 MATERIALS SCIENCE↗

Radial Deconsolidation and Leach-Burn-Leach of AGR-3/4 Compacts 8-4 and 7-4

The Advanced Gas Reactor (AGR) Fuel Development and Qualification Program’s third and fourth irradiation experiments (AGR-3/4), originally planned as separate tests, were combined into one test train for irradiation in the Advanced Test Reactor at Idaho National Laboratory (INL). The irradiation test began on December 14, 2011, and ended on April 12, 2014 (Collin 2016). The originally planned AGR-3 and AGR-4 irradiation experiments were both to be focused on obtaining fission product transport data to support improvements in modeling. The AGR-3 experimental plan was focused on gaseous and metallic fission product release from the kernels and diffusion in the coatings during irradiation and postirradiation safety testing. The AGR-4 experimental plan was focused on diffusivities and sorptivities in the compact matrix and reactor graphite (Petti et al. 2005). These goals were combined in the AGR-3/4 irradiation experiment, which consisted of twelve independently monitored capsules that each contained four AGR-3/4 compacts in a single stack surrounded by an inner ring of matrix or graphite and an outer ring of graphite. There were two capsule types: a standard capsule and a fuel body, in which the outer graphite ring included a floor and cap to fully enclose the fuel (Stempien et al. 2018a). The fuel body design supported post-irradiation safety testing of the intact fuel and ring assembly to obtain data on fission product transport and release from matrix and graphite at accident temperatures (Demkowicz 2017).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Biota Modeling in EPA’s Preliminary Remediation Goal and Dose Compliance Concentration Calculators for Use in EPA Superfund Risk Assessment: Explanation of Intake Rate Derivation, Transfer Factor Compilation, and Mass Loading Factor Sources

The Preliminary Remediation Goal (PRG) and Dose Compliance Concentration (DCC) calculators are screening level risk assessment tools that set forth the Environmental Protection Agency’s (EPA) recommended approaches and currently available risk assessment guidance for response actions at Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites, commonly known as Superfund. The environmental screening levels derived by the PRG and DCC calculators are used to identify isotopes contributing the highest risk and dose as well as establish preliminary remediation goals. Each calculator has residential gardening and subsistence farmer exposure scenarios that model transfer of contaminants from soil and water into various types of biota (crops and animal products). New publications of human intake rates of biota; farm animal intakes of water, soil, and fodder; and soil to plant interactions require updates be implemented into the PRG and DCC calculators. Recent improvements in the biota modeling for these calculators include newly derived biota intake rates, enhanced soil mass loading factors (MLFs), and more comprehensive soil to plant transfer factors (BV’s) and soil to tissue transfer factors (TFs) for animals. New biota have been added in both the produce and animal products categories that greatly improve the accuracy and utility of the PRG and DCC calculators and encompass greater geographic diversity on a national and international scale.

54 ENVIRONMENTAL SCIENCES↗

Mechanical Properties of Additively Manufactured 316L Stainless Steel Before and After Neutron Irradiation (FY21)

This report presents the materials property data of additively manufactured (AM) 316L stainless steel (SS) accumulated for the assessment of core materials in the Transformational Challenge Reactor (TCR) program. The TCR manufacturing approach includes using the laser powder bed fusion (LPBF) method for metallic (316L and Inconel 718) components. To assess the mechanical performance of printed components in reactor-relevant conditions and build a property database for the AM materials, mechanical tests and evaluations were performed before and after neutron irradiation. Miniature tensile specimens were irradiated in the High Flux Isotope Reactor to 0.2, 2, 8, and 10 dpa at target temperatures of 300 and 600°C. Postirradiation evaluation for the 0.2 and 2 dpa specimens was performed during FY20 and FY21, and the results are presented and discussed in this document.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Diagnostic and predictive capabilities of the TCR digital platform

The Transformational Challenge Reactor program is leveraging additive manufacturing technologies to fabricate the nuclear components required to assemble a microreactor core. Compared with traditional manufacturing processes, additive manufacturing allows for direct observation of the interior of the component during manufacturing. This unique capability promises significant possibilities for creating a new paradigm for nuclear component qualification by leveraging in-situ process data. This report describes FY21 efforts to predict material tensile properties based on data collected during the laser powder bed fusion printing process. The primary focus of this report is the test campaign designed to generate the large quantities of training data required to implement artificial intelligence algorithms that can predict these material properties. Preliminary prediction results and a demonstration of the overall data collection, analysis, and visualization pipeline are also provided.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Effective Permeability of a Nuclear Fuel Assembly

This report aids in the development of models to perform characterization studies of aerosol dispersal and deposition within a spent fuel cask system. Due to the complex geometry in a spent-fuel canister, direct simulation of buoyancy-driven flow through the fuel assemblies to model aerosol deposition within the fuel canister is computationally expensive. Identification of an effective permeability as given in this work for a nuclear fuel assembly greatly simplifies the requirements for thermal hydraulic computations. The results of computations performed using OpenFOAM® to solve the Navier-Stokes Equations for laminar flow are used to determine an effective permeability by applying Darcy's Law. The computations are validated against an analytical solution for the special case of an infinite array of pins for which the numerical and analytical solutions have excellent agreement. The effective permeability of a 1717 PWR nuclear fuel assembly in a basket without spacer grids is numerically determined to be 1.85010 -6 m 2 for the range of fluid viscosities and pressure drops expected in a spent fuel storage canister. However, the flow is not uniform on the scale of multiple pins. Instead, significantly higher velocities are attained in the space between the assembly and the basket walls compared to the flow between the fuel pins within the assembly. Comparison with an analytical solution for fully developed flow through an infinite array of pins shows that the larger spacing near the basket walls results in about a 20% larger permeability compared to the analytical solution which does not include the enhanced flow in the space between the assembly and basket wall, or entrance and exit effects. A preliminary assessment of turbulence effects shows that with a k-epsilon model, significantly higher flow velocities are attained between the fuel pins within the assembly compared to the flow velocity in the space between the assembly and the basket walls. This is the opposite of what is determined for laminar flow.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Identification and Resolution of Gaps in Mechanistic Source Term and Consequence Analysis Modeling for Molten Salt Reactors Salt Spill Scenarios

This report represents an assessment of the gaps in Mechanistic Source Term (MST) and consequence assessment modeling for Molten Salt Reactors (MSRs). The current capabilities for MELCOR and the MELCOR Accident Code System (MACCS) are discussed, along with updates needed in order to address specific needs for MSRs. A test plan developed by Argonne National Laboratories is discussed as addressing some of these gaps, while some will require additional attention. Further recommendations are made on addressing these gaps. This report satisfies the DOE NE Milestone M2RD-21SN0601061 to leverage MELCOR and MACCS to identify parameters of importance for source term assessments for salt spill experiments.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

The Motional Stark Effect Diagnostic for NSTX-U

This report describes the development of the motional Stark Effect diagnostic for NSTX. The MSE concept relies upon observation of the Balmer-alpha (n=3 to n=2) emission from a neutral hydrogen beam traversing a plasma. As a beam at high velocity, $\vec{ν}$, passes through the magnetic field in the plasma, $\vec{B}$, it experiences in its reference frame a Lorentz electric field, $\vec{E}$ = $\vec{ν}$ x $\vec{B}$. This electric field causes the spectral emission to be split and polarized as described by the Stark effect. The transition is separated into a set of lines in which the line spacing is linearly proportional to the electric field magnitude, and the line polarization is dependent on the electric field direction. Traditionally, MSE has used polarimetry to determine the polarization angle of the light, and related that to the magnetic field pitch angle in the plasma. The MSE diagnostic was developed under high magnetic field ($>$ 1~T) conditions, and the lower fields of recent high-beta experiments such as NSTX posed challenges to the technique. At low magnetic fields Doppler broadening effects mask the Stark effect. With the use of a narrow bandwidth filter MSE measurements at very low magnetic fields have been obtained.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

MELCOR Accident Progression and Source Term Demonstration Calculations for a FHR

MELCOR is an integrated thermal hydraulics, accident progression, and source term code for reactor safety analysis that has been developed at Sandia National Laboratories for the United States Nuclear Regulatory Commission (NRC) since the early 1980s. Though MELCOR originated as a light water reactor (LWR) code, development and modernization efforts have expanded its application scope to include non-LWR reactor concepts. Current MELCOR development efforts include providing the NRC with the analytical capabilities to support regulatory readiness for licensing non-LWR technologies under Strategy 2 of the NRC's near- term Implementation Action Plans. Beginning with the Next Generation Nuclear Project (NGNP), MELCOR has undergone a range of enhancements to provide analytical capabilities for modeling the spectrum of advanced non-LWR concepts. This report describes the generic plant model developed to demonstrate MELCOR capabilities to perform fluoride-salt-cooled high-temperature reactor (FHR) safety evaluations. The generic plant model is based on publicly-available FHR design information. For plant aspects (e.g., reactor building leak rate and details of the cover-gas system) that are not described in the FHR references, the analysts made assumptions needed to construct a MELCOR full-plant model. The FHR model uses a TRi-structural ISOtropic (TRISO)-particle fuel pebble-bed reactor with a primary system rejecting heat to two coiled tube air heat ex changers. Three passive direct reactor auxiliary cooling systems provide heat removal to supplement or replace the emergency secondary system heat removal during accident conditions. Surrounding the reactor vessel is a low volume reactor cavity that insulates the reactor with fire bricks and thick concrete walls. A refractory reactor liner system provides water cooling to reduce the concrete wall temperatures. Example calculations are performed to show the plant response and MELCOR capabilities to characterize a range of accident conditions. The accidents selected for evaluation consider a range of degraded and failed modes of operation for key safety functions providing reactivity control, the primary system decay heat removal and also a piping leak of the line to the coolant drain tank.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

MELCOR Code Change History: Revision 18019 to 21402

This document summarily provides brief descriptions of the MELCOR code enhancement made between code revision number 18019and 21440. Revision 18019 represents the previous official code release; therefore, the modeling features described within this document are provided to assist users that update to the newest official MELCOR code release, 21440. Along with the newly updated MELCOR Users’ Guide [2] and Reference Manual [3], users are aware and able to assess the new capabilities for their modeling and analysis applications.

97 MATHEMATICS AND COMPUTING↗

Front-End Engineering Design for Piperazine with the Advanced Stripper

This Department of Energy (DOE) funded project was executed with the goal of preparing a Front-End Engineering Design (FEED) for the capture and compression of 90% of the CO2 that would normally be emitted from an existing natural gas combined cycle (NGCC) plant. The FEED focused on the application of the piperazine advanced stripper (PZAS) process at Mustang Station of the Golden Spread Electric Cooperative (GSEC), which consists of two gas turbines with common heat recovery steam generator (HRSG). The University of Texas at Austin (UT) served as the prime contractor, and subcontracted AECOM Technical Services and Trimeric Corporation to support FEED development. This project team has worked together to advance PZAS for more than a decade. ExxonMobil, Chevron, and Total provided project co-funding. The objectives of this work included: 1. To advance engineering design such that a comprehensive estimate for the total installed cost of a full-scale PZAS CO2 Capture Plant with CO2 compression can be developed on an existing NGCC power plant. a. These detailed costs can also be used to qualify PZAS and other related second generation (2G) amine scrubbing processes for use on cogeneration facilities in refineries and chemical plants that use gas turbines with HRSGs to produce steam. b. These detailed costs will help qualify 2G amine scrubbing for use on NGCC power plants and establish a more accurate baseline cost to be used as a target by other capture technologies. 2. To provide cost details to be used in the economic optimization of the process features of PZAS and other 2G amine scrubbing processes. 3. To provide DOE with a more detailed understanding of carbon capture costs in a commercial application, enabling DOE to better design its R&D program to improve the economics for carbon capture. 4. To provide the host site and cost share partners with the information necessary to determine whether a commercial project to capture and use CO2 for enhanced oil recovery (EOR) or for sequestration can be justified (when accounting for the 45Q tax credit). A key component of the FEED is the estimated total installed cost, which provides a basis for the likely capital investment necessary to implement the PZAS carbon capture process at this location and scale. In combination with the included economic analysis, which accounts for potential revenue from the produced CO2, potential avenues to profitability are explored. The major findings of the FEED are as follows: The Mustang Station PZAS CO2 Capture Plant estimated total project cost of $698 MM of which $384 MM was direct costs. The annual operating costs were $32.6 MM. The total investment for a PZAS facility at Mustang Station is $725 MM. This estimate includes owner’s cost of $25 million and a contingency of $110 MM. • The study estimated the CO2 capture plant at Mustang Station would generate CO2 at $110/tonne for EOR, assuming a 12% IRR (internal rate of return) and an 85% capacity factor. For CO2 storage, the same case would achieve a 12% IRR at about $114/tonne. At a capacity factor of 52%, the storage and EOR cases would break even when carbon is priced ~$150/tonne. The economic analysis determined that the capacity factor and utility pricing, among other variable factors, had a significant effect on the economics and will need additional studied. • The energy penalty of the PZAS plant would be about 46 MW in connected power and 35 MW in operating load. The natural gas requirement (for the Gas Boiler package) would be about 354 MMBTU/hr. • The FEED revealed no major risks in process maturity. However, some areas were outlined for further engineering during detailed design, which included the Gas Boiler system, general arrangement and site layout, air coolers, schedule development, and optimization of the process for higher CO2 removal. • If PZAS were to be implemented at another host site, additional opportunities for cost reduction for would include cost reduction through use of cooling water and steam extraction.

03 NATURAL GAS↗

Improving the Economic Viability of Biological Utilization of Coal Power Plant CO 2 by Improved Algae Productivity and Integration with Wastewater Treatment

The overall goal of this project was to improve the cost-effectiveness of systems using algae to capture and beneficially utilize CO 2 from the flue gas of coal-fired power plants. Algal biomass cultivation is an attractive alternative for carbon capture and utilization because it can uptake more CO 2 per land area than any other photosynthetic crop. Also, the resulting biomass can be used to make valuable large-market commodity products, such as biofuels and animal feed. However, the use of algal carbon capture has been limited by several factors including: (1) high costs for growing algae (>$\$1,300$/ton), (2) large land requirements for algae cultivation, and (3) environmental concerns about the large amount of water and nutrient inputs needed for growing algae. This project has taken direct aim at resolving these key limitations and demonstrated several viable approaches to improve the economic and environmental feasibility of algal carbon capture. In particular, this project demonstrated a significant increase in average annual algal productivity from baseline values of 8 g/m 2 -day to above 20 g/m 2 -day. This supports a much lower projected cost of algae production (<$\$500$/ton) and reduces land requirements by more than 50%. Additionally, this project confirmed the ability to grow multiple algae species with wastewater nutrients, which facilitates the potential for substantial new revenue streams for algae cultivation based on tipping fees for nutrient laden wastewater. This study highlighted that there is more potential value in wastewater nutrient treatment credits than in the primary commodity products made from algae. The use of wastewater inputs also mitigates the concerns associated with the large amount of water needed for growing algae. The algal biomass grown for this project using wastewater and simulated flue gas inputs were characterized for potential use as an animal feed ingredient. The algae had a protein content in the range of 35-40%, which is between some common commodity animal feed products— distiller’s grains (~25-30% protein) and soybean meal (45-50% protein). In-vitro digestion tests using cattle rumen fluids, showed that this algae biomass was best suited for use as “bypass protein”, which is digested in the animal intestine. Based on the protein content and amino acid profile of the algae grown in this study, it was estimated to have market value in the range of $\$190$-$\$280$/ton. There is potential for higher value feed products if the algae content of omega-3 fatty acids or antioxidants is accounted for. This project also did small scale demonstration of forward osmosis algae dewatering and nanofiltration of hydrothermal liquefaction aqueous products, which were shown to improve the cost and energy balance for producing algal products. When all the improvements demonstrated in this study were included in techno-economic analysis, it showed there was a viable pathway to profitable algal CO 2 utilization with a payback period in the range of six to ten years.

01 COAL, LIGNITE, AND PEAT↗

Safety Testing of AGR-5/6/7 Compacts 2-2-2 and 2-2-4

Compacts 2-2-2 and 2-2-4 from the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program’s final irradiation campaign (AGR-5/6/7) were each separately subjected to a thermal soak at 1600°C for 300 h under flowing helium to simulated conditions experienced during a postulated high-temperature gas-cooled reactor (HTGR) depressurization conduction cooldown event. The safety testing of the fuel compacts’ performance under accident conditions was conducted in the Oak Ridge National Laboratory (ORNL) Core Conduction Cooldown Test Facility (CCCTF), which utilizes a stand-alone hot cell at the Irradiated Fuels Examination Laboratory (IFEL). The CCCTF heats fuel to temperatures up to 1900°C in a non-oxidizing environment while continuously monitoring the sweep gas for radioactive 85 Kr to detect release levels associated with hermetic failure of the tristructural-isotropic (TRISO) coating surrounding each fuel kernel. In addition, certain metallic radionuclides that escape the fuel compact are collected on deposition cups that are periodically exchanged with a new cup to obtain information on the overall retention behavior of the TRISO coating layers. Because cesium can diffuse through intact pyrocarbon layers, abnormal degradation of the silicon carbide (SiC) layer in the absence of holistic TRISO coating failure is indicated by release of 134 Cs at levels equivalent to an individual particle inventory in the absence of significant 85 Kr release (Hunn et al. 2014). Additional description of the CCCTF system is provided in Appendix A.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Radial Deconsolidation and Leach-Burn-Leach of AGR-3/4 Compacts 1-3, 4-3, 10-1, and 10-2

The Advanced Gas Reactor (AGR) Fuel Development and Qualification Program’s third and fourth irradiation experiments (AGR-3/4), originally planned as separate tests, were combined into one test train for irradiation in the Advanced Test Reactor at Idaho National Laboratory (INL). The irradiation test began on December 14, 2011 and ended on April 12, 2014 (Collin 2016). The originally planned AGR-3 and AGR-4 irradiation experiments were both focused on obtaining data on fission product transport to support modeling improvement. The AGR-3 experimental plan was focused on gaseous and metallic fission product release from the kernels and diffusion in the coatings during irradiation and post-irradiation safety testing. The AGR-4 experimental plan was focused on diffusivities and sorptivities in the compact matrix and reactor graphite (Petti et al. 2005). These two goals were combined in the AGR-3/4 irradiation, which consisted of twelve independently monitored capsules that each contained four AGR-3/4 compacts in a single stack surrounded by an inner ring of matrix or graphite and an outer ring of graphite. There were two capsule types: a standard capsule and a fuel body in which the outer graphite ring included a floor and cap that fully enclosed the fuel (Stempien et al. 2018a). The fuel body design supported post-irradiation safety testing of the intact fuel and ring assembly to provide data on fission product transport and release from matrix and graphite at accident temperatures (Demkowicz 2017)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Characterizing Human Performance: Detecting Targets at High False Alarm Rates [Slides]

Analysts develop a “no threat” bias with high false alarms. If only shown alarms for actual attacks, may never actually see an alarm. We see this in the laboratory, but not often studied in applied environments. (TSA is an exception.) In this work, near-operational paradigms are useful, but difficult to construct well. Pilot testing is critical before engaging time-limited professionals. Experimental control is difficult to balance with operational realism. Grounding near-operational experiments in basic research paradigms has both advantages and disadvantages. Despite shortcomings in our second experiment, we now have a platform for experimental investigations into the human element of physical security systems.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗