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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Split HPWHs as an Efficient Solution for Multifamily Buildings with In-Unit Water Heaters: Preprint

A quarter of all housing units in the country are found in multifamily buildings but few efficiency innovations have been made to improve electric water heating systems in this building type. Domestic hot water in multifamily buildings can either be provided by a large central water heater or smaller in-unit water heaters. Integrated heat pump water heaters that are installed in single family homes are often a poor fit for individual multifamily units since the water heaters are often located in small internal closets. This confined space can limit the air flow to the heat pump and the cold exhaust air can cause discomfort and reduced efficiency. Split CO2 HPWHs separate the tank from the heat pump, which allows for installation location flexibility. Further, CO2 heat pumps can operate under colder ambient conditions, making them a better fit for multifamily units across a wide range of climate regions. As part of a larger project to characterize split HPWH performance, we evaluated the feasibility of installing an additional, parallel tank that could provide hot water to a second housing unit using a single CO2 heat pump. This approach would reduce the first costs of these more expensive units. Based on the high draw volume that we imposed on both tanks, the same heat pump may be able to support more tanks, depending on hot water usage. This paper will describe the split CO2 HPWH technology, how the two-tank system was controlled, and results from our laboratory evaluation.

CO2 HPWH↗
NASA NTRS2023

Design Status of Gondola for High-Altitude Planetary Science (GHAPS)

The Gondola for High-Altitude Planetary Science (GHAPS) project was initiated to develop a balloon platform to meet planetary science goals and objectives as outlined in the NASA decadal survey. GHAPS is a first-generation reusable platform design optimized for multiple long-duration flights and planetary science. The gondola design was intended to accommodate infrared (IR) and ultraviolet/visible (UV-Vis) observations, supporting detection of water and carbon dioxide and allowing for long-duration flights to enable time-based studies. It was anticipated that the GHAPS gondola design would evolve over time with changing science demands. This report describes the as-designed configuration and capabilities of the GHAPS gondola.

Planetary Science↗
NASA NTRS2011

The NASA Soil Moisture Active Passive (SMAP) Mission Formulation

The Soil Moisture Active Passive (SMAP) mission is one of the first-tier projects recommended by the U.S. National Research Council Committee on Earth Science and Applications from Space. The SMAP mission is in formulation phase and it is scheduled for launch in 2014. The SMAP mission is designed to produce high-resolution and accurate global mapping of soil moisture and its freeze/thaw state using an instrument architecture that incorporates an L-band (1.26 GHz) radar and an L-band (1.41 GHz) radiometer. The simultaneous radar and radiometer measurements will be combined to derive global soil moisture mapping at 9 [km] resolution with a 2 to 3 days revisit and 0.04 [cm3 cm-3] (1 sigma) soil water content accuracy. The radar measurements also allow the binary detection of surface freeze/thaw state. The project science goals address in water, energy and carbon cycle science as well as provide improved capabilities in natural hazards applications.

microwave↗
DOE OSTI2026

Terrestrial laser scanning data (Levels 0 and 1) from Urban Biogeochemistry Pilot Project sites, Knoxville, Tennessee, Jul 2024 - Jul 2025

This data package contains data from terrestrial laser scanning (TLS) at five urban park sites in Knoxville, Tennessee, USA. All parks include open-grown and/or closed-canopy trees and mixed nearby land use. These study sites were established as part of the Urban Biogeochemistry Pilot Project, which has an overall goal of better understanding how hydrobiogeochemical cycling is altered within the human environment. These five sites represent a gradient of urbanization, and were instrumented to understand hydrological and biogeochemical cycling (e.g., soil moisture, soil physical properties and biogeochemistry, tree transpiration, species type). The TLS data archived here were collected to provide detailed, three-dimensional information about forest structure. Specifically, data were collected to allow tree- and stand-level characterization of woody structure and leaf area. TLS scans were placed to capture the area around trees with sap flow sensors, and as much of a 50 m radius area around the meteorological station as possible given site property limits. Derived products will allow upscaling of water content and transpiration data. This data package contains the following data: - High-level files document further details of the campaign and data package: 1_CampaignSummary.csv provides details about the campaign and study site, 2_ScanAreasDetail.csv provides details about each separate scan area (groups of scans post-processed into a single point cloud), 3_TerrestrialLidarSensor.csv provides further technical details about the Riegl VZ-400i TLS sensor, TLS_CSV_dd.csv is a CSV Data Dictionary providing information about the fields in CSV files following the ESS-DIVE CSV File Formatting Guidelines Reporting Format, TLS_flmd.csv is a File Level Metadata file providing information about each file in the data package following the ESS-DIVE File Level Metadata Reporting Format, and README.txt is a text file describing the overall project and file structure. - Level 0 data are the raw data (.PROJ folders) as recorded by the Riegl VZ-400i TLS instrument before scan co-registration and post-processing with the Riegl's proprietary RiSCAN PRO software, which requires a license. - Level 1 data contain post-processed, co-registered data from each scan area. The "PointClouds" folder for each scan area contains a .las file with 1 cm resolution point cloud data exported from RiSCAN PRO. These are the main files likely to be of interest to most users and can be further processed with any software capable of manipulating .las files (e.g. Python, R CloudCompare). The "Project Information" folder contains log files from post-processing in RiSCAN PRO that may be of interest to users who want to see detailed records of post-processing, including all PDF reports generated by RiSCAN PRO. The "ScanPositions" folder contains information about the final position of all TLS scans, after post-processing, in multiple formats. The file ScanPositions_*.csv provides final geo-referenced scan positions, and the file SOP_backup_*.csv can be used in RiSCAN PRO to restore the co-registered scan positions if users wish to re-process raw data (Level 0 .PROJ folders) with RiSCAN PRO software (e.g., subsample to a different resolution, exclude a certain scan position, or apply different filters on reflectance or deviation values) without redoing time-consuming co-registration steps.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Improved subseasonal-to-seasonal precipitation prediction of climate models with nudging approach for better initialization of Tibetan Plateau-Rocky Mountain Circumglobal wave train and land surface conditions

Abstract Reliable subseasonal-to-seasonal (S2S) precipitation prediction is highly desired due to the great socioeconomical implications, yet it remains one of the most challenging topics in the weather/climate prediction research area. As part of the Impact of Initialized Land Temperature and Snowpack on Sub-seasonal to Seasonal Prediction (LS4P) project of the Global Energy and Water Exchanges (GEWEX) program, twenty-one climate models follow the LS4P protocol to quantify the impact of the Tibetan Plateau (TP) land surface temperature/subsurface temperature (LST/SUBT) springtime anomalies on the global summertime precipitation. We find that nudging towards reanalysis winds is crucial for climate models to generate atmosphere and land surface initial conditions close to observations, which is necessary for meaningful S2S applications. Simulations with nudged initial conditions can better capture the summer precipitation responses to the imposed TP LST/SUBT spring anomalies at hotspot regions all over the world. Further analyses show that the enhanced S2S prediction skill is largely attributable to the substantially improved initialization of the Tibetan Plateau-Rocky Mountain Circumglobal (TRC) wave train pattern in the atmosphere. This study highlights the important role that initial condition plays in the S2S prediction and suggests that data assimilation technique (e.g., nudging) should be adopted to initialize climate models to improve their S2S prediction.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Fundamental Studies on the Recovery of Rare Earth Elements from Coal and Coal Byproducts (Final Product Report)

The objective of this project was to collect fundamental information that can be used to develop disruptive physical and chemical separation methods that may be used to extract the rare earth elements (REEs) from coal-based feedstocks in a highly efficient, cost-effective, and environmentally benign manner. To meet the stated objective, a set of interrelated fundamental studies have been conducted. The project has been subdivided into three broad areas of tasks as follows, (1) measurement of surface forces in the thin liquid films (TLFs) of water confined between two macroscopic surfaces to establish the optimal conditions for efficiently collecting the ultrafine particles of rare earth minerals (REMs) present in the coal-based feedstocks using the flotation and/or the hydrophobic-hydrophilic separation process(es), (2) identification of the fundamental mechanisms by which REE ions adsorb and desorb on clay minerals present in coal byproducts, and the characterization of the ion-adsorption clays (IACs) present in U.S. coals, and (3) developing methods of extracting the REEs from the REMs and IACs present in US coal byproducts in a cost-effective and sustainable manner.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1986

Thermal emission from the dust coma of Comet Bowell and a model for the grains

An analysis of the physical characteristics of Comet Bowell is presented based on 10 and 20 microns emissions observed with the NASA 3 m IR telescope during 1981-82. Numerical models are defined for quantifying the number of dust particles at a given radius and at a given angular distance from the nucleus, the contribution of icy grains to the 20 microns flux and the average albedo, and the dust distribution in the coma. Large, dirty ice grains are judged to be responsible for production of OH at a rate of about 10 to the 29th mol/sec during the spring of 1981. The total surface area of the dirty ice grains is projected to be 10 to the 15th sq cm. The coma in 1982 would therefore have consisted of nonvolatile grains, i.e., old dirty ice grains. Further observations of other, similar comets are needed to identify the composition of the emitted grains and the heliocentric distance at which high water production is initiated.

Hanner, M. S.↗
NASA NTRS1999

An Intercomparison of Radiation Codes for Retrieving Upper Tropospheric Humidity in the 6.3-micron Band: A Report from the 1st GVaP Workshop

An intercomparison of radiation codes used in retrieving upper tropospheric humidity (UTH) from observations in the v2 (6.3 microns) water vapor absorption band was performed. This intercomparison is one part of a coordinated effort within the GEWEX Water Vapor Project (GVaP) to assess our ability to monitor the distribution and variations of upper tropospheric moisture from space-borne sensors. A total of 23 different codes, ranging from detailed line-by-line (LBL) models, to coarser resolution narrow-band (NB) models, to highly-parameterized single-band (SB) models participated in the study. Forward calculations were performed using a carefully selected set of temperature and moisture profiles chosen to be representative of a wide range of atmospheric conditions. The LBL model calculations exhibited the greatest consistency with each other, typically agreeing to within 0.5 K in terms of the equivalent blackbody brightness temperature (T(sub b)). The majority of NB and SB models agreed to within +/- 1 K of the LBL models, although a few older models exhibited systematic T(sub b) biases in excess of 2 K. A discussion of the discrepancies between various models, their association with differences in model physics (e.g. continuum absorption), and their implications for UTH retrieval and radiance assimilation is presented.

Soden, B.↗
DOE OSTI2026

OC6 Project Phase IV: Validation of Numerical Models for Novel Floating Offshore Wind Support Structures

The fourth phase of the Offshore Code Comparison, Collaboration, Continued, with Correlation and unCertainty (OC6) aims to assess the ability of the tools to model a novel floating wind design. The design that was selected for this project is the TetraSpar designed by Stiesdal Offshore Technologies. The platform is a unique design that features a spar like stability with a very low center of gravity, but does not require deep-water ports. This combination is achieved with a system made of two separate steel structures, a hull at the water’s surface that supports the wind turbine tower, and a keel that is suspended below the main body. This lower keel has a very high density and drives the total platform’s low center of gravity. Scaled model tests of the TetraSpar design were performed in 2018-2019 by the University of Maine. The tests were performed with 1:43 Froude scaling. The data collected in the model tests provide a detailed description of the response of the platform in various controlled and relatively well understood conditions. Comparison with these data provides a good opportunity for validation of numerical models. The OC6 Phase IV work will focus on the specific parameters used in these scaled model tests. The load cases (LC) considered in this project are as follows: LC 1.X - Equilibrium and Static Offset Tests LC 2.X - Platform Free Decays LC 3.X - Turbine Thrust (Wind Only) LC 4.X - Regular and Irregular Waves (Wave only) LC 5.X - Combined Wind and Wave Loading

17 WIND ENERGY↗
DOE OSTI2026

Climate-Driven Divergence in Biophysical and Economic Impacts of Agrivoltaics

Increasing global demands for food and energy necessitate innovative land-use solutions. Agrivoltaics, colocating solar photovoltaics with agriculture, shows promise, but its widespread adoption faces complex biophysical and economic trade-offs in a changing climate. Here, we develop an integrated biophysical-economic modeling framework to quantify how agrivoltaics affect biophysical and economic impacts across the Midwestern United States under both current and project climate conditions. We find strong regional divergences driven by climate gradients. In the humid eastern Midwest, solar panel shading limits photosynthesis, leading to reduced yields (maize -24%; soybean -16%) and lower farmers' profitability (maize -16%; soybean -2%) compared to conventional agriculture. Conversely, in the semiarid western region, shading alleviates heat and water stress, moderating yield reductions for maize (-12%) and even boosting soybean yields (+6%), resulting in improved economic returns (-6% for maize; +9% for soybean), for a scenario with 33% photovoltaic ground coverage ratio. Although agrivoltaics generate substantial electrical energy across all regions, high upfront installation costs challenge solar developers compared to standalone solar photovoltaics. However, our analysis identifies “win-win” opportunities where soybean-based agrivoltaics in the semiarid region produce economic benefits for both farmers and solar developers, highlighting the necessity for region-specific designs tailored to local climate conditions. Critically, future climate projections indicate eastward expansion of semiarid conditions, broadening areas where agrivoltaics can mitigate crop yield penalties (even boosting yield) and improve overall profitability, especially under high-emission scenarios. The results provide a mechanistic and economically integrated understanding essential for developing evidence-based and region-specific strategies to scale agrivoltaics in a changing climate.

14 SOLAR ENERGY↗
NASA NTRS2022

Tracking the Impacts of Precipitation Phase Changes Through the Hydrologic Cycle in Snowy Regions: From Precipitation to Reservoir Storage

Cool season precipitation plays a critical role in regional water resource management in the western United States. Throughout the twenty-first century, regional precipitation will be impacted by rising temperatures and changing circulation patterns. Changes to precipitation magnitude remain challenging to project; however, precipitation phase is largely dependent on temperature, and temperature predictions from global climate models are generally in agreement. To understand the implications of this dependence, we investigate projected patterns in changing precipitation phase for mountain areas of the western United States over the twenty-first century and how shifts from snow to rain may impact runoff. We downscale two bias-corrected global climate models for historical and end-century decades with the Weather Research and Forecasting (WRF) regional climate model to estimate precipitation phase and spatial patterns at high spatial resolution (9 km). For future decades, we use the RCP 8.5 scenario, which may be considered a very high baseline emissions scenario to quantify snow season differences over major mountain chains in the western U.S. Under this scenario, the average annual snowfall fraction over the Sierra Nevada decreases by >45% by the end of the century. In contrast, for the colder Rocky Mountains, the snowfall fraction decreases by 29%. Streamflow peaks in basins draining the Sierra Nevada are projected to arrive nearly a month earlier by the end of the century. By coupling WRF with a water resources model, we estimate that California reservoirs will shift towards earlier maximum storage by 1–2 months, suggesting that water management strategies will need to adapt to changes in streamflow magnitude and timing.

Melissa L. Wrzesien↗
DOE OSTI2021

Advanced PGM-free Cathode Engineering for High Power Density and Durability

Polymer electrolyte fuel cells (PEFCs) are among the most promising technologies for future electric vehicles by using clean H2 with much-improved energy conversion efficiency, longer range, and rapid refueling. However, due to a large amount of platinum group metal (PGM) catalyst used in their electrodes, their prohibitively high cost hinders broad commercialization of PEFCs for transportation. Therefore, there is a critical need to develop low-cost, high-performance PGM-free cathode catalysts that have the potential to dramatically transform the economics of PEFC commercialization by reducing catalyst costs by one to two orders of magnitude. However, before PGM-free cathodes become viable, several technical challenges associated with PGM-free cathodes must be addressed, including insufficient activity and stability of the catalysts, as well as severe water flooding and large transport losses in the electrodes. Overcoming those barriers and ultimately meeting the challenging automotive PEFC performance targets was the focus of this comprehensive research and development effort on new PGM-free cathodes. To this end, we assembled a team including leading researchers from universities and industry with different but complementary expertise and capabilities. The project combined three novel and promising approaches: Advanced metal-organic framework (MOF)-derived M-N-C catalysts with a high activity and impressive durability, Novel PGM-free specific cathode architectures and fabrication strategies capable of addressing the substantial flooding and transport resistances in thicker cathodes by introducing engineered hydrophobicity through additives and support layers, and Advanced electrode ionomers with high proton conductivity for low ohmic losses across the electrode and more uniform catalyst utilization. The implementation of these new materials and electrode designs was supported by a suite of advanced experimental and simulation tools that allows us to identify performance and durability bottlenecks, devise solutions, and establish rational material design and synthesis targets. These methods include advanced electrochemical characterization, high-resolution imaging, and multi-scale modeling. In addition, the project team leveraged a broad cross-section of the ElectroCat consortium’s national laboratory facilities and expertise in advancing these materials and design strategies. Finally, the industry partners on the project facilitated the evaluation of scaled-up synthesis and manufacturing in the United States. Over its four-year period, the project made significant year-over-year advances in PGM-free cathode performance and viability. A combination of high activity and highly durable catalysts were developed through novel catalyst synthesis strategies, which met several performance and durability targets. More specifically, a catalyst prepared from MOFs and Fe2O3 nanoparticles with ammonium chloride and chemical vapor deposition treatments yielded a significant advancement in PGM-free cathode durability. Several novel strategies for fabricating cathodes were demonstrated, including those designed to reduce flooding and thickness of the cells for significantly increased volumetric power density. An optimized cathode with high conductivity ionomer and tuned ink processing for hydrophobicity yielded high fuel cell performance with new levels power density and maximum current. The scientific studies and modeling assessment also provided an outlook for future efforts, including a focus on catalysts with an increased density of the highly stable active sites developed in this project.

08 HYDROGEN↗
DOE OSTI2024

ORNL Campus Sustainability and Decarbonization using Waste Heat Recovery from the Oak Ridge Leadership Computing Facility’s High-Performance Computing Data Center

Heat pumps are a clean and efficient technology that can be powered by renewable electricity to transfer heat using a refrigerant from one place to another by different heat sources, making buildings clean and environmentally friendly. With the support of the ORNL Laboratory Modernization Division, this project explored and evaluated an innovative solution that uses water-water cost-effective midtemperature heat pump (MTHP) technology to leverage the low-grade waste heat from ORNL Frontier and the data center to deliver 85°C hot water, which replaces hot steam generated using natural gas combustion boilers for water heating or space heating in the buildings of ORNL campus. Two scenarios were studied. In the first scenario, which considered the 5600-5700-5800 complex only, Carrier’s commercial 1,000 kW MTHP technology achieves more than 6,640 MWh/year energy savings, an emission reduction of 858 TCO2e/year CO2, and a payback time of 4.85 years. In the second scenario, which considered the 5600-5700-5800 complex and Buildings 5100, 5200, and 5300, the CO2 emission reduction is 1,483 TCO2e/year, the operating cost savings are $0.21 million annually, and the payback time is 3.74 years. Additionally, a comprehensive HP ShowCase Tool was developed for evaluating the optimal solution to improve sustainability and decarbonization of the buildings on the ORNL campus. The tool is an Excel-based tool integrated with VBA (Visual Basic for Applications) coding. The tool includes collected ORNL campus building information and an MTHP library, which comprises collected commercial and ORNL-defined MTHPs. The tool was used to evaluate the sustainability and decarbonization of the ORNL campus. The tool can be widely used or referenced for heat pump solutions and building decarbonization renovation strategies to modernize ORNL facilities and energy use–intensive equipment to enable efficient, sustainable, and resilient operations in the future.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2004

Time Changes of the European Gravity Field from GRACE: A Comparison with Ground Measurements from Superconducting Gravimeters and with Hydrology Model Predictions

We investigate the time-variable gravity changes in Europe retrieved from the initial GRACE monthly solutions spanning a 18 month duration from April 2002 to October 2003. Gravity anomaly maps are retrieved in Central Europe from the monthly satellite solutions we compare the fields according to various truncation levels (typically between degree 10 and 20) of the initial fields (expressed in spherical harmonics to degree 120). For these different degrees, an empirical orthogonal function (EOF) decomposition of the time-variable gravity field leads us to its main spatial and temporal characteristics. We show that the dominant signal is found to be annual with an amplitude and a phase both in agreement with predictions in Europe modeled using snow and soil-moisture variations from recent hydrology models. We compare these GRACE gravity field changes to surface gravity observations from 6 superconducting gravimeters of the GGP (Global Geodynamics Project) European sub-network, with a special attention to loading corrections. Initial results suggest that all 3 data sets (GRACE, hydrology and GGP) are responding to annual changes in near-surface water in Europe of a few microGal (at length scales of approx.1000 km) that show a high value in winter and a summer minimum. We also point out that the GRACE gravity field evolution seems to indicate that there is a trend in gravity between summer 2002 and summer 2003 which can be related to the 2003 heatwave in Europe and its hydrological consequences (drought). Despite the limited time span of our analysis and the uncertainties in retrieving a regional solution from the network of gravimeters, the calibration and validation aspects of the GRACE data processing based on the annual hydrology cycle in Europe are in progress.

Hinderer, J.↗
NASA NTRS2017

An Overview of Communications Technology and Development Efforts for 2015 SBIR Phase I

This report highlights innovative SBIR 2015 Phase I projects specifically addressing areas in Communications Technology and Development which is one of six core competencies at NASA Glenn Research Center. There are fifteen technologies featured with emphasis on a wide spectrum of applications such as novel solid state lasers for space-based water vapor dial; wide temperature, high voltage and energy density capacitors for aerospace exploration; instrument for airborne measurement of carbonyl sulfide; high-power tunable seed laser for methane Lidar transmitter; ROC-rib deployable ka-band antenna for nanosatellites; a SIC-based microcontroller for high-temperature in-situ instruments and systems; improved yield, performance and reliability of high-actuator-count deformable mirrors; embedded multifunctional optical sensor system; switching electronics for space-based telescopes with advanced AO systems; integrated miniature DBR laser module for Lidar instruments; and much more. Each article in this booklet describes an innovation, technical objective, and highlights NASA commercial and industrial applications. space-based water vapor dial; wide temperature, high voltage and energy density capacitors foraerospace exploration; instrument for airborne measurement of carbonyl sulfide; high-power tunable seed laser formethane Lidar transmitter; ROC-rib deployable ka-band antenna for nanosatellites.

space-based water vapor dial; wide temperature↗
NASA NTRS2020

Central Valley Water Resources: Improving California Groundwater Assessments using GRACE and InSAR Datasets for Water Resource Management

California’s Central Valley is one of the most productive agricultural areas in the world, producing approximately $20 billion in crops annually. The recent California droughts of 2007-2010 and 2012-2019 resulted in increased groundwater pumping in the Central Valley to adequately irrigate farmland. Overdrafting of the Central Valley aquifer results in groundwater depletion, land subsidence, and permanent loss of groundwater storage. In 2014, depletion of groundwater led the state of California to enact the Sustainable Groundwater Management Act (SGMA),requiring critically overdrafted, high, and medium priority sub-basins to reach sustainable levels of groundwater pumping and recharge by 2042. SGMA allows local Groundwater Sustainability Agencies (GSAs) the authority to create Groundwater Sustainability Plans (GSPs) at the sub-basin level. To assist California’s Department of Water Resources (DWR), this project quantified groundwater change and land subsidence in Central Valley sub-basins with sparse or unreliable well and Geographic Positioning Systems (GPS) data. This was done using NASA’s Gravity Recovery and Climate Experiment (GRACE), GRACE FollowOn (GRACE-FO), and interferograms derived from Sentinel-1 C-band Synthetic Aperture Radar (C-SAR) and Advanced Land Observing Satellite 2 (ALOS-2)Phased Array L-band Synthetic Aperture Radar 2 (PALSAR-2). Time series of the GRACE and InSAR data were compared with well and GPS data in data-dense sub-basins to determine the feasibility of these datasets for groundwater storage and subsidence monitoring. We found that GRACE and InSAR data are effective tools for determining groundwater change and land subsidence and can be used on their own to monitor sub-basins in the absence of well and GPS data

Water Resources↗
DOE OSTI2023

Advanced Mineral Separations with Novel Simulated Moving Beds

Lithium is a critical mineral that is widely used in batteries and energy storage applications, making it increasingly important in the next few decades. To meet the growing demand for lithium and secure domestic supply chains, there is a need to exploit unconventional lithium resources. However, utilizing current lithium extraction processes is challenging due to the high salinity in those resources. Thus, it is essential to develop energy-efficient, and less chemical-intensive separation processes that can exploit high-salinity lithium resources. Accordingly, this project aims to design a novel zwitterionic stationary phase and use it to develop a continuous chromatography process to recover LiCl minerals from traditionally unexploited domestic saline resources. The developed zwitterionic stationary phase allows fractionating minerals based on their different sorbent affinities under water elution. A systematically designed continuous process can separate lithium from other minerals, reducing the risk of material fouling and the overall chemical consumption to produce battery-grade lithium. This approach is expected to significantly enhance the efficiency and sustainability of the lithium extraction process while also reducing the environmental impact associated with traditional processes. At the end of the project, the technology will be demonstrated in continuous mode using a simulated moving bed (SMB) to recover >100 g of LiCl from real resource waters. The U.S.-based resources that this project targets for LiCl recovery are formation water, oil-produced water, and geothermal brines, supplied by Standard Lithium Ltd. and Shell Inc, respectively.

critical minerals↗
DOE OSTI2021

The implications of future climate change on the blue water footprint of hydropower in the contiguous US

As the largest renewable energy source, hydropower is essential to the sustainability of the global energy market. However, a considerable amount of water can be lost in the form of evaporation from the associated multipurpose reservoirs, and hence enlarge the blue water footprint (BWF) of hydropower in a warming climate. To facilitate the sustainable management of both water and energy resources under the impact of climate change in the contiguous United States (CONUS), the BWF values of 143 major multipurpose reservoirs were evaluated during the historical period (1985–2014) and two future periods (2020–2049 and 2070–2099). The historical reservoir evaporation loss was calculated using the Landsat-based reservoir surface area and a new evaporation rate algorithm that considers the heat storage effect. Future projections of runoff availability, hydropower generation, and reservoir evaporation were estimated based on the downscaled climate model ensemble from phase 5 of the Coupled Model Intercomparison Project (CMIP5). It was found that the BWF for the CONUS is highly spatially heterogeneous, with an average value of 26.2 m 3 /MWh in the historical period. In the future, the BWF values are projected to increase under both Representative Concentration Pathway (RCP) 4.5 and 8.5 scenarios. This is especially noticeable under RCP 8.5, which has an average BWF value of 30.2 m 3 /MWh for 2070–2099 (increasing by 15.3% from 26.2 m 3 /MWh). The uncertainty ranges increase even more, from 3.4 m 3 /MWh during 2020–2049 to 5.7 m 3 /MWh during 2070–2099. These findings can benefit water and energy resources management in identifying suitable environmental, economic, operational, and investment strategies for multipurpose reservoirs in a changing environment.

13 HYDRO ENERGY↗