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NASA NTRS1983

Measurements and predictions for nonevaporating sprays in a quiescent environment

Yule et al. (1982) have conducted a study of vaporizing sprays with the aid of laser techniques. The present investigation has the objective to supplement the measurements performed by Yule et al., by considering the limiting case of a spray in a stagnant environment. Mean and fluctuating velocities of the continuous phase are measured by means of laser Doppler anemometry (LDA) techniques, while Fraunhofer diffraction and slide impaction methods are employed to determine drop sizes. Liquid fluxes in the spray are found by making use of an isokinetic sampling probe. The obtained data are used as a basis for the evaluation of three models of the process, including a locally homogeneous flow (LHF) model, a deterministic separated flow (DSF) model, and a stochastic separated flow (SSF) model. It is found that the LHF and DSF models do not provide very satisfactory predictions for the test sprays, while the SSF model does provide reasonably good predictions of the observed structure.

Solomon, A. S. P.↗

NASA NTRS1988

Mars sampling strategy and aeolian processes

It is critical that the geological context of planetary samples (both in situ analyses and return samples) be well known and documented. Apollo experience showed that this goal is often difficult to achieve even for a planet on which surficial processes are relatively restricted. On Mars, the variety of present and past surface processes is much greater than on the Moon and establishing the geological context of samples will be much more difficult. In addition to impact hardening, Mars has been modified by running water, periglacial activity, wind, and other processes, all of which have the potential for profoundly affecting the geological integrity of potential samples. Aeolian, or wind, processes are ubiquitous on Mars. In the absence of liquid water on the surface, aeolian activity dominates the present surface as documented by frequent dust storms (both local and global), landforms such as dunes, and variable features, i.e., albedo patterns which change their size, shape, and position with time in response to the wind.

Greeley, Ronald↗

NASA NTRS1990

Scattered-light scanner measurements of cryogenic liquid-jet breakup

The effect of highly turbulent Mach 1 gas flow and high thermal gradients on drop size measurements was investigated with a scattered light scanner. The instrument, developed at NASA-Lewis, was used to measure characteristic drop diameters or cyrogenic liquid sprays. By correcting for gas turbulence and thermal gradient affects, it was possible to obtain good reproducible data with the scattered light scanner. Tests were conducted primarily in the aerodynamic-stripping regime of liquid atomization and it was found that the loss of small droplets due to vaporization and dispersion had a marketed effect on drop size measurements. The nitrogen gas flow rate exponent of 1.33 is the same as that predicted by atomization theory for liquid jet breakup in high velocity gas flow. However, when the sprays were sampled farther downstream of the atomizer, at axial distances of 2.5 and 4.5 cm, the exponent for W sub n decreased 1.2 and 0.9, respectively. This was attributed to the loss of small droplets due to vaporization when values of downstream axial distances exceeded 1.3 cm.

Ingebo, Robert D.↗

NASA NTRS1991

Solar heating of common lunar minerals for the production of oxygen

The purpose of this work was to demonstrate the feasibility of vapor-phase reduction (pyrolysis) of lunar materials to produce oxygen. Solar furnace experiments were conducted on two common lunar minerals, ilmenite and anorthite. Thermodynamic equilibrium calculations predicted that ilmenite should show a larger pressure increase than anorthite under conditions of the experiments and this was confirmed by the experiments. The measured mass loss of the ilmenite sample was consistent with loss of oxygen by reduction of iron in the liquid phase; this result was also predicted from equilibrium calculations. Based on preliminary experiments and equilibrium calculations, the temperatures needed for pyrolysis are expected to be in the range of 2000 to 2500 K, giving total gas pressures of 0.01 to 1 torr. Bulk regolith can be used as a feedstock without extensive beneficiation. Further, selective condensation of metal-containing species from the gas phase may yield metallic iron and silicon as byproducts from the process.

Senior, C. L.↗

NASA NTRS1991

Observations of the freeze/thaw performance of lithium fluoride by motion picture photography

To gain direct observation of the molten salt phase change, a novel containerless technique was developed where the high surface tension of lithium fluoride was used to suspend a bead of the molten salt inside a specially designed wire cage. By varying the current passing through the wire, the cage also served as a variable heat source. In this way, the freeze/thaw performance of the lithium fluoride could be photographed by motion picture photography without the influence of container walls. The motion picture photography of the lithium fluoride sample revealed several zones during the phase change, a solid zone and a liquid zone, as expected, and a slush zone that was predicted by thermal analysis modeling.

Jaworske, D. A.↗

NASA NTRS1993

Semiempirical fragmentation models on galactic cosmic ray transport calculations with hydrogen target

Nuclear fragmentation cross sections of Silberberg and Tsao that are more accurate for a hydrogen target were implemented in the data base to replace those of Rudstam for a galactic cosmic ray transport code (HZETRN). Sample calculations were made for the transported galactic cosmic ray flux through a liquid hydrogen shield at solar minimum condition to determine the effect of such a change. The transported flux based on the Silberberg-Tsao semiempirical formalism contains fewer high-LET (linear energy transfer) components but more low-LET components than the results based on Rudstam's formalism: and this disparity deepens as the shield thickness increases. A comparison of the results obtained from using both energy-dependent and energy-independent cross sections of Silberberg and Tsao indicates that the energy-independent assumption results in an underestimation of high-LET flux above 100 keV/micron by approximately 40 percent for a 15-g/cm(sup 2) thickness of liquid hydrogen. Similar results were obtained in a previous study when both energy-dependent and energy-independent cross sections of Rudstam were considered. Nonetheless, the present study found that an energy-independent calculation would be best accomplished by using Rudstam's cross sections as done in the past for various engineering applications.

Shinn, Judy L.↗

NASA NTRS1998

Gravitational Role in Liquid Phase Sintering

To comprehensively understand the gravitational effects on the evolution of both the microstructure and the macrostructure during liquid phase sintering, W-Ni-Fe alloys with W content varying from 35 to 98 wt.% were sintered in microgravity. Compositions that slump during ground-based sintering also distort when sintered under microgravity. In ground-based sintering, low solid content alloys distort with a typical elephant-foot profile, while in microgravity, the compacts tend to spheroidize. This study shows that microstructural segregation occurs in both ground-based as well as microgravity sintering. In ground-based experiments, because of the density difference between the solid and the liquid phase, the solid content increases from top to the bottom of the sample. In microgravity, the solid content increases from periphery to the center of the samples. This study also shows that the pores during microgravity sintering act as a stable phase and attain anomalous shapes.

Upadhyaya, Anish↗

NASA NTRS1993

Temperature Gradients on the Cell Wall in the Critical Viscosity Experiment

Because of the diverging susceptibility delta rho/delta Tau near the liquid-vapor critical point, temperature gradients must be kept small to maintain adequate sample homogeneity. In our Science Requirements Document we paid particular attention to radial density gradients caused by equilibration of the xenon sample. Axial density gradients were addressed through the requirement that the cell's copper wall have a gradient less than 22 microK/m. This report re-examines the cell wall's temperature distribution in more detail by estimating all known significant contributions to temperature differences on the cell's wall.

Berg, Robert F.↗

NASA NTRS2000

Diffusing Wave Spectroscopy Used to Study Foams

The white appearance of familiar objects such as clouds, snow, milk, or foam is due to the random scattering of light by the sample. As we all know, pure water is clear and easily passes a beam of light. However, tiny water droplets, such as those in a cloud, scatter light because the air and water droplet have different indexes of refraction. When many droplets, or scattering sites, are present, the incident light is scattered in random directions and the sample takes on a milky white appearance. In a glass of milk, the scattering is due to small colloidal particles. The white appearance of shaving cream, or foam, is due to the scattering of light at the water-bubble interface. Diffusing wave spectroscopy (DWS) is a laser light-scattering technique used to noninvasively probe the particle dynamics in systems that strongly scatter light. The technique takes advantage of the diffuse nature of light, which is reflected or transmitted from samples such as foams, dense colloidal suspensions (such as paint and milk), emulsions, liquid crystals, sandpiles, and even biological tissues.

Zimmerli, Gregory A.↗

NASA NTRS2008

Enigmatic Isovaline: Investigating the Stability, Racemization, and Formation of a Non-biological Meteoritic Amino Acid

Among the Murchison meteoritic amino acids, isovaline stands out as being both nonbiological (non-protein) and having a relatively high abundance. While approximately equal amounts of D- and L-isovaline have been reported in Murchison and other CM meteorites, the molecule's structure appears to prohibit its racemization in aqueous solutions. We recently have investigated the low-temperature solid-phase chemistry of both isovaline and valine with an eye toward each molecule's formation, stability, and possible interconversions of D and L enantiomers. Ion-irradiated isovaline- and valinecontaining ices were examined by IR spectroscopy and highly-sensitive liquid chromatography/time-of-flight mass spectral methods to assess both amino acid destruction and racemization. Samples were studied in the presence and in the absence of water-ice, and the destruction of both isovaline and valine was measured as a function of radiation dose. In addition, we have undertaken experiments to synthesize isovaline, valine, and their amino acid isomers by solid-phase radiation-chemical pathways other than the oft-invoked Strecker process. This presentation will review and summarize some of our recent findings. -- Our work has been supported by a grant to the Goddard Center for Astrobiology through the NASA Astrobiology Institute. Experiments were performed in the Cosmic Ice Laboratory (RLH, MHM, AL) and the Astrobiology Analytical Laboratory (JPD, DPG) at the NASA Goddard Space Flight Center.

Hudson, Reggie↗

NASA NTRS2006

Ion-Exclusion Chromatography for Analyzing Organics in Water

A liquid-chromatography technique has been developed for use in the quantitative analysis of urea (and of other nonvolatile organic compounds typically found with urea) dissolved in water. The technique involves the use of a column that contains an ion-exclusion resin; heretofore, this column has been sold for use in analyzing monosaccharides and food softeners, but not for analyzing water supplies. The prior technique commonly used to analyze water for urea content has been one of high-performance liquid chromatography (HPLC), with reliance on hydrophobic interactions between analytes in a water sample and long-chain alkyl groups bonded to an HPLC column. The prior technique has proven inadequate because of a strong tendency toward co-elution of urea with other compounds. Co-elution often causes the urea and other compounds to be crowded into a narrow region of the chromatogram (see left part of figure), thereby giving rise to low chromatographic resolution and misidentification of compounds. It is possible to quantitate urea or another analyte via ultraviolet- and visible-light absorbance measurements, but in order to perform such measurements, it is necessary to dilute the sample, causing a significant loss of sensitivity. The ion-exclusion resin used in the improved technique is sulfonated polystyrene in the calcium form. Whereas the alkyl-chain column used in the prior technique separates compounds on the basis of polarity only, the ion-exclusion-resin column used in the improved technique separates compounds on the basis of both molecular size and electric charge. As a result, the degree of separation is increased: instead of being crowded together into a single chromatographic peak only about 1 to 2 minutes wide as in the prior technique, the chromatographic peaks of different compounds are now separated from each other and spread out over a range about 33 minutes wide (see right part of figure), and the urea peak can readily be distinguished from the other peaks. Although the analysis takes more time in the improved technique, this disadvantage is offset by two important advantages: Sensitivity is increased. The minimum concentration of urea that can be measured is reduced (to between 1/5 and 1/3 of that of the prior technique) because it is not necessary to dilute the sample. The separation of peaks facilitates the identification and quantitation of the various compounds. The resolution of the compounds other than urea makes it possible to identify those compounds by use of mass spectrometry.

Sauer, Richard↗

NASA NTRS2012

NASA's New High Intensity Solar Environment Test Capability

Across the world, new spaceflight missions are being designed and executed that will place spacecraft and instruments into challenging environments throughout the solar system. To aid in the successful completion of these new missions, NASA has developed a new flexible space environment test platform. The High Intensity Solar Environment Test (HISET) capability located at NASA fs Marshall Space Flight Center provides scientists and engineers with the means to test spacecraft materials and systems in a wide range of solar wind and solar photon environments. Featuring a solar simulator capable of delivering approximately 1 MW/m2 of broad spectrum radiation at maximum power, HISET provides a means to test systems or components that could explore the solar corona. The solar simulator consists of three high-power Xenon arc lamps that can be operated independently over a range of power to meet test requirements; i.e., the lamp power can be greatly reduced to simulate the solar intensity at several AU. Integral to the HISET capability are charged particle sources that can provide a solar wind (electron and proton) environment. Used individually or in combination, the charged particle sources can provide fluxes ranging from a few nA/cm2 to 100s of nA/cm2 over an energy range of 50 eV to 100 keV for electrons and 100 eV to 30 keV for protons. Anchored by a high vacuum facility equipped with a liquid nitrogen cold shroud for radiative cooling scenarios, HISET is able to accommodate samples as large as 1 meter in diameter. In this poster, details of the HISET capability will be presented, including the wide ]ranging configurability of the system.

Schneider, Todd A.↗

NASA NTRS2018

Potential High Priority Subaerial Environments for Mars Sample Return

Subaerial environments of interest for Mars Sample Return include surface or near-surface sites not covered by a body of water, but having direct access to water from precipitation, snow melt, or ambient-temperature groundwater. This includes soils, wetlands, ephemeral ponds, cold springs, and periglacial/glacial environments, with paleosol profiles as a high priority collection site. Such soils can be topped by aqueously deposited sediments and precipitates from wetlands, ephemeral ponds, and springs. The composition and morphology of paleosols preserve evidence of past climate, aqueous conditions, and life. Key topics addressed by samples collected from subaerial environments include: 1) Constrain the duration of interaction with liquid water by investigating a weathering profile from the surface to unaltered parent material. 2) Assess the characteristics of past liquid water, and how it has changed through time. 3) Investigate weathered materials such as soils, paleosols, sediments, weathering rinds or rock coatings to assess past climate. 4) Examine characteristics of past aeolian and atmospheric processes.

Source record↗

NASA NTRSDate not supplied

Human Thermal Assessment of Traverse and Geology Task Iterations During Simulated Lunar Extravehicular Activity

Spacewalks or extravehicular activities (EVA) in microgravity are mentally and physically demanding. Current microgravity EVAs are predominantly focused on upper body tasks on engineered surfaces; however, the introduction of gravity means that crew members during future lunar EVAs will be required to perform tasks that generate full body workloads such as navigating natural lunar terrain while conducting geological sampling. To date, only 12 people have walked on the surface of the Moon resulting in limited knowledge of suited thermal regulation under lunar-relevant physical workloads. To address this gap, a study is underway to focus on spacesuit operations with simulated lunar EVA workloads. This study presents methodology for collecting standard thermal measures during suit testing. In this pilot study, two suited subjects underwent simulated lunar EVAs using the NASA Active Response Gravity Offload System (ARGOS) to simulate the effects of partial gravity. Each lunar EVA, lasting three to five hours, included various metabolically demanding EVA tasks. Subjects donned the NASA Mark III (MK III) space suit and were offloaded to 1/6th G (lunar gravity). A subset task circuit from one of these simulations replicated an EVA traverse to a lunar crater, taking a geological sample, and returning to base. The suited subject walked one 1500 m (0% grade) and three 500 m traverses at three different grades (10, 20, 30%). Between each traverse, subjects performed geology sampling tasks (0 and 10% grade). Thermal measurements included core and skin temperature, liquid cooling garment (LCG) inlet and outlet temperature, and spacesuit gas inlet and outlet temperature and humidity. Compared to baseline core temperature (S1 = 37.07±0.32 °C, S2 = 37.27±0.01 °C) and mean skin temperature (S1 = 32.38±0.34 °C, S2 = 33.62±0.03 °C), after a 1500 m traverse, each suited subject showed an increased core temperature (S1 = 37.23±0.12 °C, S2 = 37.41±0.11°C) and decreased mean skin temperature (S1 = 32.16±0.17 °C, S2 = 31.53±1.15 °C) at a delta LCG temperature (S1 = 1.86±0.24 °C, S2 = 2.20±0.76 °C) and delta suit humidity (S1 = 9.66±1.49 %, S2 = 11.50±1.58 %). Core temperature continued to increase from compounding traverse and geology tasks (S1 = 38.04±0.03 °C, S2 = 38.1±0.02 °C) accompanied by an increase in delta LCG temperature (S1 = 2.24±0.13 °C, S2 = 2.67±0.12 °C) and delta suit humidity (S1 = 28±2.42 %, S2 = 31±2.13 %). Conversely, as the circuit progressed, mean skin temperature continued to decrease due to sustained LCG heat rejection (S1 = 30.08±0.15 °C, S2 = 30.28±0.07 °C). During the simulated EVA circuit core temperature increased to elevated values and remained elevated as heat was retained while mean skin temperature decreased due to peripheral heat offloaded to the LCG. The thermal measures collected during this study provided critical heat loading dynamics during lunar EVA tasks. Including core and skin temperatures along with suited thermal measures provides a standard data collection scheme for human thermal metrics during EVA task management. Data collected in this configuration can be used to build future lunar EVA task circuits and human thermal predictions.

Bradley Hoffmann↗

NASA NTRS1978

Experimental partitioning of rare earth elements and scandium among armalcolite, ilmenite, olivine and mare basalt liquid

An experimental study was carried out to measure partition coefficients for two rare-earth elements (Sm and Tm) and Sc among armalcolite, ilmenite, olivine and liquid coexisting in a system modeled on high-Ti mare basalt 74275. This 'primitive' sample was chosen for study because its major and trace element chemistry as well as its equilibrium phase relations at atmospheric pressure are known from previous studies. Beta-track analytical techniques were used so that partition coefficients could be measured in an environment whose bulk trace element composition is similar to that of the natural basalt. Partition coefficients for Cr and Mn were determined in the same experiments by microprobe analysis. The only equilibrium partial melting model appears to be one in which ilmenite is initially present in the source region but is consumed by melting before segregation of the high-Ti mare basalt liquid from the residue.

Irving, A. J.↗

NASA NTRS2016

Submersion Quenching of Undercooled Liquid Metals in an Electrostatic Levitator

The NASA Marshall Space Flight Center (MSFC) electrostatic levitation (ESL) laboratory has a long history of providing materials research and thermophysical property data. The laboratory has recently added a new capability, a rapid quench system. This system allows samples to be dropped into a quench vessel that can be filled with a low melting point material, such as a gallium or indium alloy. Thereby allowing rapid quenching of undercooled liquid metals and alloys. This is the first submersion quench system inside an electrostatic levitator. The system has been tested successfully with samples of zirconium, iron-cobalt alloys, titanium-zirconium-nickel alloys, and silicon-cobalt alloys. This rapid quench system will allow materials science studies of undercooled materials and new materials development, including studies of metastable phases and transient microstructures. In this presentation, the system is described and some initial results are presented.

SanSoucie, Michael P.↗

NASA NTRSDate not supplied

Insights From Routine Microbiological Monitoring of Air in Astromaterials Curation Cleanrooms

NASA maintains nine separate cleanrooms at the Johnson Space Center to curate and preserve astromaterials samples. Routine microbial monitoring of the surfaces in these cleanrooms began in 20181. Until recently, materials compatibility requirements prevented monitoring airborne biological particles in all but one of these cleanrooms. New astromaterials collections from carbon rich asteroids are more susceptible to biological degradation than previous collections. Therefore, it is important to monitor the bioburden in the air and on surfaces in these labs. Establishing a comprehensive microbial monitoring program will help inform the monitoring and curation plans for Mars sample return which will include samples that are extremely biologically sensitive. In April of 2022 we began routinely collecting air samples in seven of the nine curation cleanrooms (Meteorite ISO 7 equivalent, Lunar ISO 6 equivalent, Stardust, Hayabusa2, OSIRIS-REx ISO 5 equivalent, and Genesis ISO 4 equivalent) using a sampling device that collects airborne biological particles on an electret filter instead conventional sampler that collect cells in a liquid media or onto organic rich Petri dishes. Electret is a generic term for electrostatically charged media. The charge on these materials increases particle trapping when compared to non-charged filters of similar thickness. N95 respirators also use electret filters. This dry sample collection method allows us to meet materials requirements for all the curation labs and reduces the risk of inadvertently introducing contamination as part of our monitoring effort. This method also allows us to preserve a portion of each sample for DNA extraction and next generation sequencing. DNA sequencing helps us to characterize the portion of the cleanroom microbiome that we cannot culture. We will present the results of our first 8 months of monitoring, compare these results to particle counts in the labs and to measurements made directly onto Petri dishes when possible. We will also make recommendations for modifications to the sampling method to improve sampling efficiency and preserve diversity.

A. B. Regberg↗

NASA NTRS2021

Semiconductor to Metal Transition in the Solids/Melts of Te and Pseudo-Binary of Hg1-xCdxTe for x = 0, 0.1 and 0.2

This paper reports the experimentally measured thermal and electrical conductivities from which the Lorenz numbers as functions of temperature were derived for the solids and melts of elemental Te and samples of Hg1-xCdxTe of x = 0, 0.1 and 0.2. The structural changes in the vicinity of the solid-liquid phase transition of elemental Te and various Hg1-xCdxTe solid solutions were assessed by closely examining these experimental properties and the derived Lorenz numbers. The values of Lorenz numbers for the solids of these samples were higher than the value of L0, i.e., the Lorenz number for the free electron gas derived by Sommerfeld, implying the characteristics of non-degenerate semiconductor. With the increasing value of x, or the larger bandgap, the materials become more non-degenerate with larger deviation from L0. As the solids started to melt, the measured values of Lorenz number for all samples started to decrease and eventually reached and maintained at values close to L0 at higher temperatures. The trend of the Lorenz number indicates that the transition from non-degenerate semiconductor of the solid samples to metal or degenerate semiconductor when the samples temperature reached above their liquidus temperatures.

thermal conductivity↗