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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
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NASA NTRS1981

Nitridation of silicon

Silicon powders with three levels of impurities, principally Fe, were sintered in He or H2. Non-densifying mechanisms of material transport were dominant in all cases. High purity Si showed coarsening in He while particle growth was suppressed in H2. Lower purity powder coarsened in both He and H2. The same three Si powders and Si /111/ single crystal wafers were nitrided in both N2 and N2/H2 atmospheres. Hydrogen increased the degree of nitridation of all three powders and the alpha/beta ratio of the lower purity powder. Some Si3N4 whiskers and open channels through the surface nitride layer were observed in the presence of Fe, correlating with the nitridation-enhancing effects of Fe. Thermodynamic calculations showed that when SiO2 is present on the Si, addition of H2 to the nitriding atmosphere decreases the amount of SiO2 and increases the partial pressure of Si-containing vapor species, that is, Si and SiO. Large amounts of NH3 and SiH4 were also predicted to form.

Shaw, N. J.↗
NASA NTRS1981

Atlas of absorption lines from 0 to 17 900 cm(-1)

Plots of absorption line strength versus line position for wavenumbers from 0 to 17,900 cm(-1) are shown for 20 atmospheric gases (H2O, CO2, O3, N2O, CO, CH4, O2, NO, SO2, NO2, NH3, HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, H2CO). Also shown are similar plots of lower-state energy values for adsorption lines for the strongly adsorbing atmospheric gases (H2O, CO2, O3, and CH4) for wavenumbers from 0 to 5000 cm(-1).

Park, J. H.↗
NASA NTRS1981

Evolutionary variations of solar luminosity

Theoretical arguments for a 30% increase in the solar luminosity over the past 4.7 billion years are reviewed. A scaling argument shows that this increase can be predicted without detailed numerical calculations. The magnitude of the increase is independent of nuclear reaction rates, as long as conversion of hydrogen to helium provides the basic energy source of the Sun. The effect of the solar luminosity increase on the terrestrial climate is briefly considered. It appears unlikely that an enhanced greenhouse effect, due to reduced gases (NH3, CH4), can account for the long-term paleoclimatic trends.

Endal, A. S.↗
NASA NTRS1982

Evolutionary variations of solar luminosity

The Theoretical arguments for a 30% increase in the solar luminosity over the past 4.7 billion years are reviewed. A scaling argument shows that this increase can be predicted without detailed numerical calculations. The magnitude of the increase is independent of nuclear reaction rates, as long as conversion of hydrogen to helium provides the basic energy source of the Sun. The effect of the solar luminosity increase on the terrestrial climate is briefly considered. It appears unlikely that an enhanced greenhouse effect, due to reduced gases (NH3, CH4), can account for the long-term paleoclimatic trends.

Endal, A. S.↗
NASA NTRS1982

Low NO subx heavy fuel combustor concept program. Phase 1A: Coal gas addendum

The performance and emissions from a rich-lean combustor fired on simulated coal gas fuels were investigated using a 12.7-cm diameter axially-staged burner originally designed for operation with high heating value liquid fuels. A simple, tubular fuel injector was substituted for the liquid fuel nozzle; no other combustor modifications were made. Four test fuels were studied including three chemically bound nitrogen-free gas mixtures with higher heating values of 88, 227, and 308 kj/mol (103, 258 and 349 Btu/scf), and a 227 kj/mol (258 Btu/scf) heating value doped with ammonia to produce a fuel nitrogen content of 0.5% (wt). Stable, ultra-low nitrogen oxide, smoke-free combustion was attained for the nitrogen-free fuels. Results with the doped fuel indicated that less than 5% conversion of NH3 to nitrogen oxide levels below Environmental Protection Agency limits could be achieved. In some instances, excessive CO levels were encountered. It is shown that use of a burner design employing a less fuel-rich primary zone than that found optimum for liquid fuels would yield more acceptable CO emissions.

Rosfjord, T.↗
NASA NTRS1982

Jupiter and Saturn from 2 to 6 microns

Earth based spectroscopic observations that support current compositional and structural analyses of planetary atmospheres are summarized. The overview of Jupiter's IR spectrum illustrates a fundamental constraint to observations of the outer planets: atmospheric studies are restricted to narrow, isolated windows defined by the planetary absorbers H2, CH4, NH3, and PH3. Some of these planetary windows, such as at 1.6 micron are accessible in ground based observations, but others, such as at 1.9 and 2.7 micron are totally obscured by terrestrial H2O. For this reason, high altitude sites, such as aircraft, balloons, and spacecraft, are essential for IR spectral studies of the outer planets.

Larson, H. P.↗
NASA NTRS1982

Tropospheric passive remote sensing: Introduction

Measurement needs regarding chemical and transport parameters were identified. Measurement of those gases involved in tropospheric photochemistry (O3, CO, CH4, NOx, HNO3, SO2, NH3, and CH3CCl3) and quantification of their sources and sinks, as well as a fundamental understanding of atmospheric chemical transformations were discussed. The photochemistry of OH and its role as a sink are summarized. The concentrations and lifetimes of the tropospheric gases were considered. Major concerns in tropospheric transport are the making of representative remote measurements of trace gases and aerosols and the dependence of these measurements on structural differences in the atmosphere.

Source record↗
NASA NTRS1981

Where is the ice in comets

JHKL photometry of comets P/Tuttle, Meier 1980q, P/Stephan-Oterma, and Bowell 1980b has yielded J-H and H-K colors, uncontaminated by thermal emission, which are nearly identical for all four comets. The colors are inconsistent with the reflection spectrum from a cloud of icy particles, if the particles are composed primarily of any of the ices (H2O, CO2, CH4, or NH3) commonly assumed to be present in the nuclei of comet. Circular variable filter spectra of comet Stephan-Oterma confirm the absence of any absorption features due to these ices. The reflection spectra of these comets appear most like those of Cand S-type asteroids and the ring of Jupiter. Mie calculations for core-mantle particles suggest that ices could be present as thin mantles on inherently reddish, refractory cores, such as magnetite.

Ahearn, M. F.↗
NASA NTRS1981

Chemical abundances in comets

Photoelectric filter photometry and spectrophotometry undertaken to establish homogeneous, quantitative data on chemical abundances in comets is discussed. Absolute column densities of a particular species were derived from a comparison of the absolute flux of an emission feature due to the species with a fluorescence calculation, and converted into species production rates by the use of a Haser model and the species lifetime. Observations of C2 and CN reveal a constant production rate ratio at heliocentric distances up to 1.5-2.0 AU, which implies a compositional homogeneity with depth and the formation of most comets from a homogeneous volume in the solar nebula. Observations of the trace species C3 indicate no apparent variation in relative abundances, while observations of low levels of NH2 and CH imply that NH3 and CH4 are not abundant species. H2O is considered to be the most abundant species based on detections of O, H and OH, while variations in CO or CO2 content may account for the very large differences in cometary gas-to-dust ratios and morphologies.

Ahearn, M. F.↗
NASA NTRS1981

Molecules in interstellar clouds

The physical conditions and chemical compositions of the gas in interstellar clouds are reviewed in light of the importance of interstellar clouds for star formation and the origin of life. The Orion A region is discussed as an example of a giant molecular cloud where massive stars are being formed, and it is pointed out that conditions in the core of the cloud, with a kinetic temperature of about 75 K and a density of 100,000-1,000,000 molecules/cu cm, may support gas phase ion-molecule chemistry. The Taurus Molecular Clouds are then considered as examples of cold, dark, relatively dense interstellar clouds which may be the birthplaces of solar-type stars and which have been found to contain the heaviest interstellar molecules yet discovered. The molecular species identified in each of these regions are tabulated, including such building blocks of biological monomers as H2O, NH3, H2CO, CO, H2S, CH3CN and H2, and more complex species such as HCOOCH3 and CH3CH2CN.

Irvine, W. M.↗
NASA NTRS1981

The detection of HCN on Jupiter

The detection of HCN on Jupiter is reported. Three R-branch lines of the nu-2 fundamental of HCN near 13.5 microns were observed in absorption, from which the HCN column density is inferred to be 0.005 cm-am with an uncertainty of a factor of two. If emission from the stratosphere exists, then the derived column density is only a lower limit. It is suggested that the Jovian HCN most likely originates from the photolysis of CH4 and NH3 in the lower stratosphere and upper troposphere. In addition, an upper limit of 0.025 cm-am was established for the column density of HCN on Saturn.

Tokunaga, A. T.↗
NASA NTRS1981

Constraints on the origin and interior structure of the major planets

Fitting models to the external gravity field of the major planets (Uranus, Neptune, Jupiter, and Saturn), it is found that certain interior characteristics may be common to all four. For Uranus and Neptune, a model with a central iron-silicate core of approximately four earth masses, an 'ice' layer of H2O, CH4, and NH3 in solar proportions of about 10 earth masses, and an H2-He atmosphere of about 1-2 earth masses gives a good fit to available constraints, including heat flow measurements. Models of Jupiter and Saturn have cores very similar to those of Uranus and Neptune; the H2-He layer, however, is markedly more extensive. Modes of origin that are consistent with these features are discussed. Models of this type predict a considerable enrichment of deuterium relative to primordial solar abundances in Uranus and Neptune. Such enrichment is not observed in Uranus; implications are discussed for interior structure and origin.

Hubbard, W. B.↗
NASA NTRS1981

Longitudinal variability of methane and ammonia bands on Saturn

A total of 129 spectra of the center of the disk of Saturn were obtained in March 1980 in order to search for possible longitudinal variations in the CH4 6190 and NH3 6450 bands. The spectra were reduced to reflectivities, and the band equivalent widths were measured using a blind, automated continuum fitting technique. The methane and ammonia equivalent widths are well correlated with each other. There are some latitude regions in which both bands show enhanced absorption and some latitudes in which both bands are weaker than the average. The continuum reflectivity is quite constant with latitude and shows no apparent correlation with molecular band equivalent width. The observed variations may be explained by a longitudinal variation in the altitude of the top of the thick cloud of about + or - 2 km from the mean.

Cochran, A. L.↗
NASA NTRS1982

Stability of ammonia in the primitive terrestrial atmosphere

The rate at which ammonia would have been destroyed in the earth's atmosphere under assumed NH3 mixing ratio conditions of 10 to the -8th to 0.0001 is calculated by a one-dimensional photochemical model, and the destruction rates are compared with possible biotic and abiotic ammonia sources. It is found that, while the mixing ratio of 10 to the -8th needed for the evolution of life could have been maintained by abiotic sources, the value of 0.00001 needed for the production of significant greenhouse warming could not have been sustained abiotically. The increase of atmospheric ammonia due to biological activities during the Archean is also considered lower than the level required for the generation of measurable thermal effects.

Kasting, J. F.↗
NASA NTRS1982

A model of a comet coma with interstellar molecules in the nucleus

The coma of a comet is modeled assuming the icy nucleus contains interstellar molecules. This composition overcomes discrepancies between observation and earlier model predictions for CN, C2, C3, and NH2 abundances. It is found that the abundances of CN, C2, and C3-bearing compounds in the nucleus must be constrained to trace amounts in order to account for the observed column densities. NH3 also cannot be abundant by more than about 1%. The model gives good agreement with observed relative ranges of neutral species in the coma as well as with their observed relative intensity dependence on heliocentric distance. The size of the nucleus and the heliocentric ranges considered are relevant to comet Halley.

Biermann, L.↗
NASA NTRS1982

Theory of metal atom-water interactions and alkali halide dimers

Theoretical studies of the interactions of metal atoms with water and some of its isoelectronic analogs, and of the properties of alkali halides and their aggregates are discussed. Results are presented of ab initio calculations of the heats of reaction of the metal-water adducts and hydroxyhydrides of Li, Be, B, Na, Mg, and Al, and of the bond lengths and angles an; the heats of reaction for the insertion of Al into HF, H2O, NH3, H2S and CH3OH, and Be and Mg into H2O. Calculations of the electron affinities and dipole moments and polarizabilities of selected gas phase alkali halide monomers and dimers are discussed, with particular attention given to results of calculations of the polarizability of LiF taking into account electron correlation effects, and the polarizability of the dimer (LiF)2.

Jordan, K. D.↗
NASA NTRS1982

Volcanism and igneous processes in small icy satellites

Evidence for the production of endogenic processes of the small Saturnian satellites by igneous activity of low melting point NH3-H2O magma heated radiogenically is presented. An initial state of the inner satellites is modeled as a homogeneous mixture of particulate silicates and ices. Conductive transport is assumed to have either combined with heat capacity in a mixture of crystalline phases, or to have been reduced by the presence of dust, defects, vitreous or amorphous phases, and clathrates. The extent to which a eutectic melt could form is calculated in terms of the volume percentage of melt, with all heating above 175 K going toward overcoming the latent heat of the eutectic mix. Mimas and Enceladus were treated as free from radiogenic heat sources, which were significant for Tethys, Dione, Rhea, and Iapetus. The migrations of inner materials to form surface structures and seal off the interiors of the moons are described.

Stevenson, D. J.↗
NASA NTRS1982

Suspension restraint - Induced hypokinesia and antiorthostasis as a simulation of weightlessness

Muscle, renal, fluid and electrolyte responses were measured in suspended rats; the hind limbs are non-load bearing and the front limbs can be used for feeding and grooming. Hind limb hypokinesia reverses after removal from the suspension harness. This suspension system is adjustable for a head-down tilt to produce antiorthostatic responses which are also reversible. Responses to hypokinesia or antiorthostatic hypokinesia for up to 14 days were measured, e.g., muscle atrophy: soleus greater than gastrocnemius equals plantaris greater than extensor digitorum longus, kaliuresis, and increased excretion of urea, NH3, and 3 methylhistidine. Muscle protein loss, a response to a reduction in RNA, is also reversible. A head-down tilt for 7-14 days results in diuresis and natriuresis. These changes are reversed within 24 hours after removal from the restraint harness. Physiological effects of suspension restraint can be used to simulate and predict responses to microgravity exposure.

Musacchia, X. J.↗