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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

The Apollo 17 'melt sheet' - Chemistry, age and Rb/Sr systematics

Major, minor, and trace-element compositions, age data, and Rb/Sr systematics of Apollo 17 boulders have been compiled, and additional analyses performed on a norite breccia clast (77215) included in the Apollo 17, Station 7 boulder. The Apollo 17 boulders are found to be identical or nearly so in major, minor, and trace-element composition, suggesting that they all originated as an impact melt analogous to melt sheets found in larger terrestrial craters. The matrix dates (Ar-40/Ar-39) and Rb/Sr systematics available suggest that this impact melt formed by a single impact about 4 billion years ago. This impact excavated, shocked, brecciated, and melted norites, norite cumulates, and possibly anorthositic gabbros and dunites about 4.4 billion years old. The impact was likely a major one, possibly the Serenitatis basin-forming event.

Winzer, S. R.↗

Evaluation of thermal data for geologic applications

Sensitivity studies using thermal models indicated sources of errors in the determination of thermal inertia from HCMM data. Apparent thermal inertia, with only simple atmospheric radiance corrections to the measured surface temperature, would be sufficient for most operational requirements for surface thermal inertia. Thermal data does have additional information about the nature of surface material that is not available in visible and near infrared reflectance data. Color composites of daytime temperature, nighttime temperature, and albedo were often more useful than thermal inertia images alone for discrimination of lithologic boundaries. A modeling study, using the annual heating cycle, indicated the feasibility of looking for geologic features buried under as much as a meter of alluvial material. The spatial resolution of HCMM data is a major limiting factor in the usefulness of the data for geologic applications. Future thermal infrared satellite sensors should provide spatial resolution comparable to that of the LANDSAT data.

Kahle, A. B.↗

Electron energy deposition in CO2.

Semiempirical cross sections of Strickland and Green (1969) are compared with and supplemented by more recent data. The composite set is used in the energy degradation calculation of electrons with emphasis on energies below 100 ev. Good agreements are obtained with accepted values of the loss function and the average electron volts per ion pair at high energies. Efficiencies associated with various loss channels are obtained. The relationship with the recent Mariner UV data is discussed.

Sawada, T.↗

Analysis of stress-rupture data from S-glass composites.

Both composite and free strands have been tested to study matrix effectiveness. Glass from different lots were used, and processing parameters were varied to demonstrate the effects of material variability. The statistical patterns that emerge from these experiments show that lifetime distributions are characteristically skewed. As a class, the lifetime distributions are well approximated by the reduced form of the Weibull distribution. The strength retention data display little early degradation. The retained-strength distributions can also be classed as Weibull distributions. A statistical model applied to the data gives predictions of progressive failure, strength retention path, and expected life for two basic types of internal fracture processes.

Robinson, E. Y.↗

The ionospheric contribution to the plasma environment in near-earth space

SCATHA and ISEE 1 satellite ion mass spectrometer data on ion composition near GEO are reviewed. The data were gathered during and close to magnetic storm activity to assess the characteristics of ion composition variations in order to predict the effects of hot GEO plasma on spacecraft instruments. Attention is given to both substorms and storms, the former being associated, at high latitudes, with auroral activity, the latter with ring currents. The ionosphere was found to supply hot H(+), O(+) and He(+) ions to the GEO magnetosphere, while the solar wind carried H(+) and He(+) ions. The ionosphere was the dominant source in both quiet and storm conditions in the inner magnetosphere.

Sharp, R. D.↗

Sulfur in Cometary Dust

The computer-intensive project consisted of the analysis and synthesis of existing data on composition of comet Halley dust particles. The main objective was to obtain a complete inventory of sulfur containing compounds in the comet Halley dust by building upon the existing classification of organic and inorganic compounds and applying a variety of statistical techniques for cluster and cross-correlational analyses. A student hired for this project wrote and tested the software to perform cluster analysis. The following tasks were carried out: (1) selecting the data from existing database for the proposed project; (2) finding access to a standard library of statistical routines for cluster analysis; (3) reformatting the data as necessary for input into the library routines; (4) performing cluster analysis and constructing hierarchical cluster trees using three methods to define the proximity of clusters; (5) presenting the output results in different formats to facilitate the interpretation of the obtained cluster trees; (6) selecting groups of data points common for all three trees as stable clusters. We have also considered the chemistry of sulfur in inorganic compounds.

Fomenkova, M. N.↗

Data for Immediate Impacts of Soybean Cover Crop on Bacterial Community Composition and Diversity in Soil Under Long-Term Saccharum Monoculture

Saccharum yield decline results from long-term monoculture practices. Changes in cropping management can improve soil health and productivity. Below-ground bacterial community diversity and composition across soybean (Glycine max (L.) Merr) cover crop, Saccharum monoculture (30+ year) and fallowed soil were determined. Near full length (~1,400 base pairs) of 16S rRNA gene sequences were extracted from the rhizospheres of sugarcane and soybean and fallowed soil were compared. Higher soil bacterial diversity was observed in the soybean cover crop than sugarcane monoculture across all measured indices (observed operationational taxonomic units, Chao1, Shannon, reciprocal Simpson and Jackknife). Acidocateria, Proteobacteria, Bacteroidetes and Planctomycetes were the most abundant bacterial phyla across the treatments. Indicator species analysis identified nine indicator phyla. Planctomycetes, Armatimonadetes and candidate phylum FBP were associated with soybean; Proteobacteria and Firmicutes were linked with sugarcane and Gemmatimonadetes, Nitrospirae, Rokubacteria and unclassified bacteria were associated with fallowed soil. Non-metric multidimensional scaling analysis showed distinct groupings of bacterial operational taxonomic units (97% identity) according to management system (soybean, sugarcane or fallow) indicating compositional differences among treatments. This is confirmed by the results of the multi-response permutation procedures (A = 0.541, p = 0.00045716). No correlation between soil parameters and bacterial community structure was observed according to Mantel test (r = 211865, p = 0.14). Use of soybean cover-crop fostered bacterial diversity and altered community structure. This indicates cover crops could have a restorative effect and potentially promote sustainability in long-term Saccharum production systems.

Field Data↗

LABQ3: Bayesian method for quantification of mineral compositions and nano-scale elemental mapping of 3D synchrotron XCT data

Quantitative analysis of mineral compositions is essential in understanding geochemical, mineralogical and environmental processes. Fine-resolution 3D imaging is widely done using synchrotron X-ray computed tomography (XCT), but existing analyses are limited to visualization and segmentation. This paper presents a new method, Linear Attenuation Bayesian Quantitative 3D-mapper (LABQ3), based on the linearity of X-ray attenuation with respect to elemental concentrations. To address the random variability in attenuation measurements, LABQ3 employs Bayesian decision theory to minimize classification error, using reference attenuation distributions from scans of pure mineral standards. To demonstrate LABQ3 and test its performance, we studied precipitated carbonate samples. XCT scans were done at multiple energies using the transmission X-ray microscope (TXM) at beamline 32-ID-C of the Advanced Photon Source at Argonne National Laboratory. The reconstructed 3D images have a voxel size of 20 nm. Analyses revealed rich nano-scale compositional heterogeneity within individual particles. A mixture of calcium and cadmium produced an overall stoichiometric composition of (Ca 0.78 ,Cd 0.22 )CO 3 , with some voxels containing nearly pure CdCO 3 . The addition of zinc led to an overall stoichiometric composition of 33% Ca, 28% Cd, 39% Zn, with a nearly pure CaCO 3 core and compositional zonation through the rim. These compositional gradients are related to temporal sequences of carbonate mineral formation where Cd precipitated at the beginning in (Ca,Cd)CO 3 , while Cd and Zn precipitated at the end in (Ca, Cd,Zn)CO 3 . Results differ from bulk analyses using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS), showing that LABQ3 provides particle-specific insights. LABQ3 distinguishes itself by quantifying chemical compositions along a continuum, making it different from XCT analyses based on segmentation. LABQ3 allows simultaneous acquisition of morphology and chemical composition in 3D, facilitating the interpretation of chemical gradients of trace elements, quantification of solid solution compositions, inferences about temporal sequences of mineral precipitation, and addressing other concerns about solid-phase chemistry.

58 GEOSCIENCES↗

Glass-contact refractory of the nuclear waste vitrification melters in the United States: a review of corrosion data and melter life

The performance of the refractory lining in glass melters used for nuclear waste vitrification is critical to the melter reliability for long-term continuous operation. Monofrax® K-3, a high Cr 2 O 3 fused cast refractory material, has been widely used to build the liners of nuclear waste glass melters in the United States. Corrosion behaviour of Monofrax® K-3 refractory has been evaluated based on crucible-scale testing, inspection of the refractory components following scaled melter testing, and inspections of the Defense Waste Processing Facility (DWPF) melter refractory after service. The literature generally consists of empirical models based on short-term testing to describe refractory corrosion dependence on glass composition. Corrosion data from tests with longer testing times, at various temperatures, in the presence of molten salts, and with different redox reactions in the plenum atmosphere exist, may be insufficient to provide accurate refractory service life estimates. Additionally, the corrosion data collected under actual and scaled melter operating conditions are limited. Recommendations to achieve more direct correlation between the laboratory refractory corrosion data predictions and the observed melter service life are discussed to allow for more accurate predictions of the useful life of melter refractory linings.

Jin, Tongan↗

Long-life assessment of graphite epoxy materials for Space Station Freedom pressure vessels

Graphite/epoxy composite overwrapped pressure vessels are being considered for use on Space Station Freedom because of their light weight and high efficiency. These composite pressure vessels weigh roughly one-third of comparable all-metal aluminum pressure vessels, and could result in a 15,000-lb weight saving for the propulsion and fluid management and distribution systems. These vessels must resist failures under sustained pressure loads for crew safety considerations and adequate protection of the space structure during their 30-yr life. Weibull statistical analysis techniques have been applied, and a model developed, for predicting long-term stress-rupture behavior based on published short-term test data on composite strands and pressure vessels. Graphite/epoxy materials are calculated to have a 99.99-percent probability of surviving stress rupture for 30 yr under a sustained load of 50 percent ultimate failure strength. Stress-rupture lifetimes are predicted to increase as the size of the pressure vessels increases in support of the viscoelastic load-transfer mechanism proposed for stress rupture of fiber/epoxy composite materials.

Thomas, Donald A.↗

Large Enhancements in the O/N2 Ratio in the Evening Sector of the Winter Hemisphere During Geomagnetic Storms

In this paper, we have looked for enhancements of the O/N2 ratio in data measured by the Dynamics Explorer 2 (DE 2) satellite in the middle latitudes of the winter hemisphere, based on a prediction that was made by the National Center for Atmospheric Research thermosphere/tonosphere general circulation model (NCAR-TIGCM) that such increases occur. The NCAR-TIGCM predicts that these enhancements should be seen throughout the low latitude region and in many middle latitude locations, but that the enhancements in O/N2 are particularly strong in the middle-latitude, evening-to-midnight sector of the winter hemisphere. When this prediction was used to look for these effects in DE 2 NACS (neutral atmosphere composition spectrometer) data, large enhancements in the O/N2 ratio (approx. 50 to 90%) were seen. These enhancements were observed during the main phase of a storm that occurred on November 24, 1982, and were seen in the same region of the winter hemisphere predicted by the NCAR-TIGCM. They are partially the result of the depletion of N2 and, as electron loss is dependent on dissociative recombination at F(sub 2) altitudes, they have implications for electron densities in this area. Parcel trajectories, which have been followed through the NCAR-TIGCM history file for this event, show that large O/N2 enhancements occur in this limited region in the winter hemisphere for two reasons. First, these parcels of air are decelerated by the antisunward edge of the ion convection pattern; individual parcels converge and subsidence occurs. Thus molecular-nitrogen-poor air is brought from higher to lower heights. Because neutral parcels that are found a little poleward of the equatorial edge of the eveningside convection pattern are swept inward toward the center of the auroral oval, the enhancements occur only in a very limited range of latitudes. Second, nitrogen-poor air is transported from regions close to the magnetic pole in the winter hemisphere. During geomagnetic storms, enhanced meridional winds are driven by the increased pressure-gradient force that is associated with intensified Joule heating in the auroral oval. These pressure-driven winds decrease rapidly on the dayside beyond the auroral oval where the parcels originate, limiting the region into which the parcels can be transported. Thus these two processes drive values of O/N2 in a limited region of the winter hemisphere, and reinforce only in the evening sector, causing large changes in this region.

Burns, A. G.↗

Characteristics of maximum-value composite images from temporal AVHRR data

Red and near-infrared satellite data from the Advanced Very High Resolution Radiometer sensor have been processed over several days and combined to produce spatially continuous cloud-free imagery over large areas with sufficient temporal resolution to study green-vegetation dynamics. The technique minimizes cloud contamination, reduces directional reflectance and off-nadir viewing effects, minimizes sun-angle and shadow effects, and minimizes aerosol and water-vapor effects. The improvement is highly dependent on the state of the atmosphere, surface-cover type, and the viewing and illumination geometry of the sun, target and sensor. An example from southern Africa showed an increase of 40 percent from individual image values tothe final composite image. Limitations associated with the technique are discussed, and recommendations are given to improve this approach.

Holben, Brent N.↗

Source abundances and propagation of relativistic cosmic rays up to Z equals 30 - HEAO 3 results

Results from the cosmic ray isotope experiment on board the HEAO 3 satellite are reviewed, noting their impact on astrophysics. The gamma ray telescope comprised 5 Cerenkov detectors and a flash tube hodoscope with 4 trays, and collected data on 7 million events in the energy range 0.7-20 GeV/nucleon during the 1.6 yr mission duration. Three ranges of momentum were detected, and it was found that the ratios of secondary to primary species decreased steeply with increasing energy. A progressive steepening of the energy dependence of abundance ratios from Al/Si and K/Fe was observed, which has been interpreted as a progressive decrease of the amount of primary component from Al to Na and K. The secondary to primary ratios are accounted for with an exponential pathlength distribution from Fe down to Na and N. Comparisons are made of elemental abundances in cosmic ray sources, the local galactic environment, and the solar energetic particle composition. The data is noted to be compatible with a model of an injection of cosmic ray particles by stellar flares in a two-stage acceleration process.

Koch-Miramond, L.↗

Tensile, Compression, Open-Hole Compression and Double Cantilever Beam Fracture Toughness Testing of Multiple NASA Langley Research Center Composite Materials

The attached data summarizes the work performed by the Composite Materials Research Group at the University of Wyoming funded by the NASA LaRC Research Grant NAG-1-1294. The work consisted primarily of tension, compression, open-hole compression and double cantilever beam fracture toughness testing performed an a variety of NASA LaRC composite materials. Tests were performed at various environmental conditions and pre-conditioning requirements. The primary purpose of this work was to support the LaRC material development efforts. The data summaries are arranged in chronological order from oldest to newest.

Adams, Donald F.↗

Phase equilibria and microstructure evolution in the Ni-rich region of binary Ni-Ce and ternary Ni-Ce-X (X=Al, Nb, Cr, Ti) systems at 900 °C

The equilibrium compositions of all phases in the Ni-rich region of binary Ni-Ce and ternary Ni-Ce-X (X=Al, Nb, Cr, Ti) systems at 900 °C were determined experimentally through isothermal annealing for up to 500 h and compared with currently available computational thermodynamic descriptions. Additionally, the study examined how adding a third element to the binary system affects the microstructure by analyzing changes in the volume fraction of the intermetallic phase in the eutectic region. It was observed that Nb and Ti addition lowered the intermetallic fraction in the eutectic region while Al and Cr addition did the opposite. The fraction of intermetallic phase in the eutectic region is very important because it contributes to extreme brittleness of these alloys. Also, Al, Nb and Ti addition promoted different precipitates upon annealing when added in sufficient amounts. The collected data on composition and phase equilibria provides crucial information for improving the thermodynamic assessments of the binary and ternary alloy systems.

energy dispersive spectrometry↗

Flammability of Epoxy Resins Containing Phosphorus

As part of a program to develop fire-resistant exterior composite structures for future subsonic commercial and general aviation aircraft, flame-retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured neat epoxy formulations were characterized by thermogravimetric analysis, propane torch test, elemental analysis, microscale combustion calorimetry, and fire calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness and compressive strength of several cured formulations showed no detrimental effect due to phosphorus content. The chemistry and properties of these new epoxy formulations are discussed.

Flammability studies↗