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At least 451 records · Page 25

Technical Guidance on Use of the Linseis Vertical Dilatometer L75

Linseis vertical Dilatometer L75 thermal expansion equipment is a complete system which can be used for measuring change of the absolute length of a sample, determination of the thermal expansion coefficient (CTE), shrinkage, and sintering. The 238 Pu Supply Program is interested in re-establishing the capability to determine CTE and measuring the change of the absolute length of various 237 Np Al/cermet samples during heating. The change in length of the measured sample is recorded using a highly sensitive Linear Variable Differential Transformer (LVDT). The dilatometer is user-friendly and simple to operate which will allow technicians to be trained easily on its use. This equipment was designed to be used specifically for ceramics. It has a highly vacuum tight push rod dilatometer, a high-resolution inductive transducer using innovative and comprehensive temperature controls which provide excellent performance as a measurement system yielding high accuracy, reproducibility, and long-term stability.

07 ISOTOPE AND RADIATION SOURCES↗

Application of Principal Component Analysis to Electrochemical Reprocessing PM and NMAC

In this report, data from an electrorefiner (ER) for nuclear fuel reprocessing is evaluated for process monitoring (PM) conclusions. This data comes from tests performed at the Idaho National Laboratory in 2022. Multivariate approaches utilizing methods of Principal Component Analysis (PCA) is applied. This is based off established work in process monitoring for fault detection in industrial facilities. This report will discuss the background, methods, and results of the application and some of the conclusions and applications that can be drawn from them. PCA is applied to two different electrorefiner (ER) operations that occurred at Idaho National Laboratory between August and October 2022. The first operation occurred with little incident while the second had several noted faults in the equipment in operational logs. The data from the first run was used to train the data for “normal” operations and applied to both sets of data to determine when operations were in an “off-normal” condition and identify where the fault occurs through PCA. PCA was able to identify off-normal events and identify the cause for off-normal operations. These identified off-normal events matched with the events and their causes in the operational logs. However, small amounts of variance in the data led to false detection of “off-normal” events. Thus, careful selection of training data and a-posteriori conclusions based off operator assessments will both be required for application of PCA to PM applications. This work demonstrated that multivariate approaches and latent variables are applicable to pyroprocessing PM applications and can be further expanded in future work as quality variables such as salt concentration from sensors and sampling become available.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Report on technical development in ANL for innovative creep testing and measurement

This report summarizes a research effort undertaken by Argonne National Laboratory to accelerate the development of creep data package for ASME code qualification. Progress on the fabrication of a 3-sample load train and the application of a direct current potential drop (DCPD) technique to measure large creep strains are reported. Specifically: (1) The 3-sample load train, with three sets of Linear Variable Differential Transformers (LVDT), has been fabricated and assembled. (2) A DCPD method for creep-strain measurement up to 50% has been demonstrated. The DCPD data matches very well to LVDT results, suggesting its potential application in future creep testing. The technical developments contribute towards shortening the time needed to generate a creep data package for an ASME code case of the laser powder bed fusion 316H stainless steel, an effort under the US Department of Energy’s Advanced Materials and Manufacturing Technologies (AMMT) program.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Radiocarbon measurements of ecosystem respiration and soil pore-space CO 2 in Utqiagvik (Barrow), Alaska

Radiocarbon measurements of ecosystem respiration and soil pore space CO 2 are useful for determining the sources of ecosystem respiration,identifying environmental controls on soil carbon cycling rates, and parameterizing and evaluating models of the carbon cycle. We measured flux rates and radiocarbon content of ecosystem respiration, as well as radiocarbon in soil profile CO 2 in Utqiagvik (Barrow), Alaska, during the summers of 2012, 2013, and 2014.We found that radiocarbon in ecosystem respiration(Δ 14 C Reco ) ranged from +60.5 to –160‰ with a median value of +23.3‰. Ecosystem respiration became more depleted in radiocarbon from summer to autumn, indicating increased decomposition of old soil organic carbon and/or decreased CO 2 production from fast-cycling carbon pools. Across permafrost features,ecosystem respiration from high-centered polygons was depleted in radiocarbon relative to other polygon types. Radiocarbon content in soil pore-space CO 2 varied between –7.1 and –280‰, becoming more negative with depth in individual soil profiles. These pore-space radiocarbon values correspond to CO 2 mean ages of 410 to 3350 years, based on a steady-state, one-pool model. Together, these data indicate that deep soil respiration was derived primarily from old, slow-cycling carbon, but that total CO 2 fluxes depended largely on autotrophic respiration and heterotrophic decomposition of fast-cycling carbon within the shallowest soil layers. The relative contributions of these different CO 2 sources were highly variable across microtopographic features and time in the sampling season. The highly negative Δ 14 C values in soil pore-space CO 2 and autumn ecosystem respiration indicate that when it is not frozen, very old soil carbon is vulnerable to decomposition.

54 ENVIRONMENTAL SCIENCES↗

High-Resolution Characterization of Comingled Contaminants in the Deep Vadose Zone, Hanford Site, Washington - 17387

The contaminated deep vadose zone in the Central Plateau of the Hanford Site in Washington state presents a unique challenge to remediation. The Comprehensive Environmental Response, Compensation, and Liability Act, commonly known as the CERCLA project responsible for addressing these deep contaminants is designated as the 200-Deep Vadose Zone Operable Unit (DV-1 project). The vadose zone is 55-82 meters (180-270 feet) thick and is contaminated with both radiological and chemical contaminants from multiple historical waste streams. The mobile contaminants from this waste are still present in the deep vadose zone and pose a potential threat to the groundwater. Characterizing the nature and extent of the comingled mobile contaminants is an important step before assessing possible remedial alternatives. One factor controlling the migration and distribution of subsurface contaminants is the lithologic heterogeneity of the vadose zone sediments. A sampling plan for the DV-1 project includes continuous sediment core collection and analysis to identify key lithologic factors (i.e., small-scale bedding and structural features) that act as barriers, preferential pathways or conduits for mobile contaminants migrating through the vadose zone. Over six hundred meters (2,000 feet) of intact sediment core from 26 boreholes were collected in 1.5 meters (5 feet) long, 10 centimeter (4-inch) diameter segments. These intact sediment samples provide significant improvement in the level of detail and understanding of mechanisms and features controlling contaminant distribution that is not possible with traditional homogenized drill cuttings or conventional split-spoon samples. Detailed geological descriptions and photographs of the intact core are correlated to high-resolution geophysical logs which aid in the development of a comprehensive contaminant distribution profile of the borehole. These lithologic interpretations are used to define specific depth intervals for sampling based on changes in moisture, lithology, and elevated gamma radiation. The selected samples are analyzed for contaminants of concern, geochemical parameters, and hydraulic properties. Significant lithologic features observed in the intact cores include sharp contact boundaries to graded bedding, iron-oxide and carbonate cementation, silty laminations, clastic dike intrusions, and soft sediment deformation. Preliminary geologic logs integrated with the sample analysis indicate features that correlate to the variable distribution of contaminants both laterally and vertically. Integration of measured hydraulic parameters to lithologic units in individual borehole profiles provide key inputs for more precise geo-framework and vadose zone flux models supporting the DV-1 project. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Tribological Behavior of Electrochemically Etched AISI 316 Stainless Steel with a Textured Surface

In this work, AISI 316 stainless steel (316 SS) was electrochemically etched in four NaCl solutions (10, 15, 20, and 25 wt.%) to form textured surfaces. Surface morphologies, three-dimensional surface topographies, and surface profiles of the textured 316 SS samples were obtained by scanning electron microscopy (SEM) and laser scanning confocal microscope (LSCM). Sliding friction tests of the textured 316 SS samples were conducted in air and under grease lubrication. The results suggested that the variable degrees of microtextured surfaces after electrochemical etching in 10, 15, and 20 wt.% NaCl solutions. The 316 SS samples etched in 15 and 20 wt.% NaCl solutions showed more promising tribological performance than other samples, as reflected by their friction coefficients, mass loss per unit distance traveled (mg/m), and wear morphologies.

36 MATERIALS SCIENCE↗

Extreme Variability Quasars from the Sloan Digital Sky Survey and the Dark Energy Survey

Here, we perform a systematic search for long-term extreme variability quasars (EVQs) in the overlapping Sloan Digital Sky Survey (SDSS) and 3-Year Dark Energy Survey (DES) imaging, which provide light curves spanning more than 15 years. We also identified 1000 EVQs with a maximum g band magnitude change of more than 1 mag over this period, about 10% of all quasars searched. The EVQs have L bol 10 45 - 10 47 erg s -1 and L=L Edd 0:01-1. Accounting for selection effects, we estimate an intrinsic EVQ fraction of 30-50% among all g.22 quasars over a baseline of 15 years. These EVQs are good candidates for so-called “changing-look quasars”, where a spectral transition between the two types of quasars (broad-line and narrow-line) is observed between the dim and bright states. We performed detailed multi-wavelength, spectral and variability analyses for the EVQs and compared to their parent quasar sample. We found that EVQs are distinct from a control sample of quasars matched in redshift and optical luminosity: (1) their UV broad emission lines have larger equivalent widths; (2) their Eddington ratios are systematically lower; and (3) they are more variable on all timescales. The intrinsic difference in quasar properties for EVQs suggest that internal processes associated with accretion are the main driver for the observed extreme long-term variability. In spit of their different properties, EVQs seem to be in the tail of a continuous distribution of quasar properties, rather than standing out as a distinct population. We speculate that EVQs are normal quasars accreting at relatively low accretion rates, where the accretion flow is more likely to experience instabilities that drive the factor of few changes in flux on multi-year timescales.

79 ASTRONOMY AND ASTROPHYSICS↗

CondiDiag1.0: a flexible online diagnostic tool for conditional sampling and budget analysis in the E3SM atmosphere model (EAM)

Abstract. Numerical models used in weather and climate prediction take into account a comprehensive set of atmospheric processes (i.e., phenomena) such as the resolved and unresolved fluid dynamics, radiative transfer, cloud and aerosol life cycles, and mass or energy exchanges with the Earth's surface. In order to identify model deficiencies and improve predictive skills, it is important to obtain process-level understanding of the interactions between different processes. Conditional sampling and budget analysis are powerful tools for process-oriented model evaluation, but they often require tedious ad hoc coding and large amounts of instantaneous model output, resulting in inefficient use of human and computing resources. This paper presents an online diagnostic tool that addresses this challenge by monitoring model variables in a generic manner as they evolve within the time integration cycle. The tool is convenient to use. It allows users to select sampling conditions and specify monitored variables at run time. Both the evolving values of the model variables and their increments caused by different atmospheric processes can be monitored and archived. Online calculation of vertical integrals is also supported. Multiple sampling conditions can be monitored in a single simulation in combination with unconditional sampling. The paper explains in detail the design and implementation of the tool in the Energy Exascale Earth System Model (E3SM) version 1. The usage is demonstrated through three examples: a global budget analysis of dust aerosol mass concentration, a composite analysis of sea salt emission and its dependency on surface wind speed, and a conditionally sampled relative humidity budget. The tool is expected to be easily portable to closely related atmospheric models that use the same or similar data structures and time integration methods.

58 GEOSCIENCES↗

Risk Ratio and Risk Difference Estimation in Case-cohort Studies

Background: In case-cohort studies with binary outcomes, ordinary logistic regression analyses have been widely used because of their computational simplicity. However, the resultant odds ratio estimates cannot be interpreted as relative risk measures unless the event rate is low. The risk ratio and risk difference are more favorable outcome measures that are directly interpreted as effect measures without the rare disease assumption. Methods: We provide pseudo-Poisson and pseudo-normal linear regression methods for estimating risk ratios and risk differences in analyses of case-cohort studies. These multivariate regression models are fitted by weighting the inverses of sampling probabilities. Also, the precisions of the risk ratio and risk difference estimators can be improved using auxiliary variable information, specifically by adapting the calibrated or estimated weights, which are readily measured on all samples from the whole cohort. Finally, we provide computational code in R (R Foundation for Statistical Computing, Vienna, Austria) that can easily perform these methods. Results: Through numerical analyses of artificially simulated data and the National Wilms Tumor Study data, accurate risk ratio and risk difference estimates were obtained using the pseudo-Poisson and pseudo-normal linear regression methods. Also, using the auxiliary variable information from the whole cohort, precisions of these estimators were markedly improved. Conclusion: The ordinary logistic regression analyses may provide uninterpretable effect measure estimates, and the risk ratio and risk difference estimation methods are effective alternative approaches for case-cohort studies. These methods are especially recommended under situations in which the event rate is not low.

60 APPLIED LIFE SCIENCES↗

A novel approach for characterizing the variability in mass–dimension relationships: results from MC3E

Abstract. Mass–dimension (m–D) relationships determining bulkmicrophysical properties such as total water content (TWC) and radarreflectivity factor (Z) from particle size distributions are used in bothnumerical models and remote sensing retrievals. The a and b coefficientsrepresenting m=aD b relationships, however, can vary significantlydepending on meteorological conditions, particle habits, the definition ofparticle maximum dimension, the probes used to obtain the data, techniquesused to process the cloud probe data, and other unknown reasons. Thus,considering a range of a,b coefficients may be more applicable for use innumerical models and remote sensing retrievals. Microphysical data collectedby two-dimensional optical array probes (OAPs) installed on the University ofNorth Dakota (UND) Citation aircraft during the Mid-latitude Continental ConvectiveClouds Experiment (MC3E) were used in conjunction with TWC data from aNevzorov probe and ground-based S-band radar data to determine a and busing a technique that minimizes the chi-square difference between the TWC andZ derived from the OAPs and those directly measured by a TWC probe andradar. All a and b values within a specified tolerance were regarded as equallyplausible solutions. Of the 16 near-constant-temperature flight legs analyzedduring the 25 April, 20 May, and 23 May 2011 events, the derived surfaces ofsolutions on the first 2 days where the aircraft-sampled stratiform cloudhad a larger range in a and b for lower temperature environments thatcorrespond to less variability in N(D), TWC, and Z for a flight leg.Because different regions of the storm were sampled on 23 May, differences inthe variability in N(D), TWC, and Z influenced the distribution ofchi-square values in the (a,b) phase space and the specified tolerance in away that yielded 2.8 times fewer plausible solutions compared to the flightlegs on the other dates. These findings show the importance of representingthe variability in a,b coefficients for numerical modeling and remotesensing studies, rather than assuming fixed values, as well as the need tofurther explore how these surfaces depend on environmental conditions inclouds containing ice hydrometeors.

54 ENVIRONMENTAL SCIENCES↗

Stochastic nonlinear analysis of unidirectional fiber composites using image-based microstructural uncertainty quantification

Here, we present a data-driven nonlinear uncertainty quantification and propagation framework to study the microstructure-induced stochastic performance of unidirectional (UD) carbon fiber reinforced polymer (CFRP) composites. The proposed approach integrates (1) microscopic image characterization, (2) stochastic microstructure reconstruction, and (3) efficient multiscale finite element simulations enabled by self-consistent clustering (SCA) analysis. To model the complex microstructural variability, the proposed UQ methods take the non-Gaussian uncertainty sources into account through a distribution-free sampling approach leveraging nonparametric and asymptotic statistical tools. A hierarchical conditional sampling strategy enables the simultaneous sampling of multiple sources of uncertainties. Our approach provides insights into the impact of microstructural variabilities, which are shown to have an increasing impact on the nonlinear responses of UD CFRP parts under progressive compression loading and ultimately on the failure rate over time. We discover that before CFRP parts start to fail, a characteristic time period emerges with distinctive uncertainty distributions specific to the microstructure variability and the probability of failure. Identifying the failure time period is crucial to the reliability prediction, which is an essential component of CFRP design.

36 MATERIALS SCIENCE↗

Integrated pre-feasibility study for CO 2 geological storage in the Cascadia Basin, offshore Washington State, British Columbia

The Cascadia CarbonSAFE project conducted a pre-feasibility study to evaluate technical and nontechnical aspects of storing 50 million metric tons (MMT) of carbon dioxide in a safe, ocean basalt reservoir offshore Washington State and British Columbia. Sub-seafloor basalts are very common on Earth and enable geological mineralization as a long-term storage mechanism, permanently sequestering the carbon in solid rock form. This project evaluated the offshore storage complex, developed potential industrial source/transport scenarios, built an inventory of existing geophysical/geological data and environmental monitoring capabilities, conducted laboratory studies and reservoir modeling to determine storage capacity, and analyzed economic factors, regulatory requirements, and project management risks. Our team included researchers at Columbia University in New York, Pacific Northwest National Laboratory (PNNL) in Washington, University of Victoria in British Columbia, University of California at Santa Cruz, and GHG Underground in Maine, as well as collaborators at University of Iceland in Reykjavik and University of Washington in Saint Louis. In the study region, large emitters (>100,000 MT/year) generate a total of approximately 40 MMT annually from stationary sources, such as power plants, refineries, ammonia production, and mineral processing plants. Five potential industry source/transport scenarios were identified (three in U.SA S. and two in Canada) to potentially provide 50 MMT of carbon dioxide to the offshore reservoir. One scenario included net carbon-negative sources that would reduce atmospheric levels. The inventory of existing data illustrated that basalt properties in the region are potentially beneficial for long-term storage. Permeability is on the order of 0.1 to 1 Darcies within the uppermost 600 m of ocean crust and density-derived porosity reaches 10–20% in thin layers that provide act as flow channels and provide access to porous and permeable basalt. Fine-grained sediments overlying basalt provide a low-permeability barrier separating the storage reservoir from the overlying ocean. Subsurface monitoring of the storage complex benefits from a unique opportunity close proximity of to the nearby NEPTUNE cabled seafloor observatory, which actively transmits data to shore and could be used to monitor reservoir properties. Injection pressure changes, reservoir chemistry, seismicity, well head corrosion, and potential leakage monitoring would be feasible in real time. Using existing data and published models, the STOMP-CO 2 modeling code developed at PNNL was used to simulate carbon dioxide injection, storage, and mineralization in the reservoir. Preliminary simulations indicate that a 50 MMT carbon dioxide plume injected over a 20-year period remains well within the reservoir area, both laterally and vertically, for at least a 50-year period of post-injection monitoring. Laboratory studies on core samples from Cascadia measured dissolution rates in CO 2 –basalt–seawater mixtures and indicated large variability in rates with the potential for complete mineralization. Compared to published data, the dissolution rate measured in these samples is faster, decreasing the time until full conversion to carbonate minerals would occur. Adding geochemical reactivity in the STOMP-CO 2 model indicates that carbon dioxide would be fully converted to carbonate minerals in 135 years or less after injection ceases. The project assessed the viability and costs for the five scenarios using either dedicated offshore pipelines or shipping vessels. Carbon dioxide capture costs were not considered. Shipping incurred lower upfront CAPEX costs, and because most viable sources were located near the shore and waterways, shipping is preferred; no dedicated carbon dioxide pipelines exist in the region. The project also considered potential risks from mixed-use impacts on surrounding lands and ocean areas, such as active use by commercial and recreational fisherman, and other community considerations in planning for public engagement in the future. Other project risks were identified, including project management, permitting and compliance, and financing, as well as technical issues such as long-term instrumentation, plume migration, and model development. Geological concerns like reservoir permeability, seal, and induced seismicity held relatively low risk. The regulatory framework for offshore storage in the U.S. and Canada may be covered by general legal/regulatory programs, but is not yet fully defined. Existing programs appear to restrict the transportation of carbon dioxide across national boundaries (e.g., Canada to U.S.) and its sub-seabed disposal in some circumstances. Our assessment suggests that developing specific and separate pilot projects will help to advance the technical feasibility and regulatory requirements in each country, and lessons learned from such activities may be transferable elsewhere around the globe.

42 ENGINEERING↗

Harmonizing solar induced fluorescence across spatial scales, instruments, and extraction methods using proximal and airborne remote sensing: A multi-scale study in a soybean field

Solar-induced chlorophyll fluorescence (SIF) has been widely used to track vegetation photosynthesis at different scales ranging from in-situ measurements to satellite products. Airborne platforms sample SIF data at a spatial scale intermediate between in-situ and satellite, matching that of ground measurement (e.g. flux tower footprints and other field sampling), enabling us to explore causes of SIF variation and validate satellite-based SIF products. However, harmonizing SIF across sensors and platforms (correcting for systematic errors to yield a consistent, comparable SIF product) is challenging because SIF can be retrieved in different absorption windows, with different instruments and methods complicating the comparison between different observational levels (i.e., ground, airborne, satellites) and between sites equipped with different instruments with varying optical properties (spectral resolution and sampling intervals, spatial resolution). Additionally, the spatial and temporal variability of atmospheric properties can influence the retrieval of the weak SIF signal. Because of these complications, direct comparisons of airborne and ground SIF across scales are rarely attempted. Here, in this study, we combined airborne SIF data with simultaneous ‘ground truth’ data collected by stationary and mobile platforms in a soybean field in Nebraska, USA. In this effort, we tested several SIF extraction methods, including Fraunhofer Line Discrimination (FLD), improved Fraunhofer Line Discrimination (iFLD), Spectral Fitting Method (SFM), SpecFit, and a Singular Vector Decomposition (SVD) method. The SpecFit method was sensitive to the 715–740 nm water bands and removing the water bands in the fitting process yielded better agreement between the airborne and ground SIF spectra. Accurate estimation of the ground level downwelling irradiance obtained by ground measurements over a calibration target improved agreement between airborne and ground SIF retrievals at the O 2 A band, and allowed us to derive a SIF dataset with improved agreement across platforms and sampling scales. This experimental approach provided a method for generating comparable SIF signals across instruments, methods and platforms, which is critical to understanding the SIF-GPP relationship at different scales and to cross-validate the diversity of platforms used for satellite products calibration and validation.

54 ENVIRONMENTAL SCIENCES↗

Comparative analysis of nutrient concentrations in generalist and specialist tree species and soils, Manaus, Brazil

This dataset was collected near Manaus, Brazil, at ZF-2 site, inside the North-South transect plots from 20221011 to 20221020. Measurements were made on specialists and generalist tree species along topographic gradient (in upland high-clay content soils of plateaus and high sandy content and partially flooded soils of valleys). We selected nine species (with four replicates each, totaling 35 individuals) occurring in different topographic positions: three plateau specialists, three valley specialists, and three generalists, where leaf and trunk samples were collected from each individual, and soil samples for carbon and nutrient analysis and quantification. Three soil pits were opened around each sample tree, about one meter apart (total of 105 soil pits each 60-cm deep), where soil samples were collected at four depths: 0-5, 5-10, 10-30 and 30-50 cm. In each of the three pits around each tree, one single sample was taken at each depth and combined to obtain a composite sample per depth per individual tree (35 trees × 4 depths = 140 soil samples). The files “Plant_Nutrient_Concentrations_NS_Transect_Manaus.csv” and “Soil_Nutrient_Concentrations_NS_Transect_Manaus.csv” contain the nutrient concentration data from plant and soil material, respectively. Additionally, the file “Sample_Info.csv” contains details about each variable including units and data type. The file “Species_Info.csv” includes information about each sampled individual, such as species, family, diameter at the breast height (DBH), and more. The dataset is ready to be used in any programming language like python or R. This dataset was originally published on the NGEE Tropics Archive and is being mirrored on ESS-DIVE for long-term archival Acknowledgement: Funding for NGEE-Tropics data resources was provided by the U.S. Department of Energy Office of Science, Office of Biological and Environmental Research.

54 ENVIRONMENTAL SCIENCES↗

Particle integrity, sampling, and application of a DNA-tagged tracer for aerosol transport studies

Aerosols are an ever-present part of our daily environment and have extensive effects on both human and environmental health. Particles in the inhalable range (1-10 μm diameter) are of particular concern because their deposition in the lung can lead to a variety of illnesses including allergic reactions, viral or bacterial infections, and cancer. Understanding the transport of inhalable aerosols across both short and long distances is necessary to predict human exposures to aerosols. To assess the transport of hazardous aerosols, surrogate tracer particles are required to measure their transport through occupied spaces. These tracer particles must not only possess similar transport characteristics to those of interest but also be easily distinguished from the background at low levels and survive the environmental conditions of the testing environment. A previously-developed DNA-tagged particle (DNATrax), composed of food-grade sugar and a DNA oligonucleotide as a “barcode” label, shows promise as a new aerosol tracer. Herein, the use of DNATrax material is validated for use in both indoor and outdoor environments. Utilizing passive samplers made of materials commonly found in indoor environments followed by quantitative polymerase chain reaction (qPCR) assay for endpoint particle detection, particles detection was achieved up to 90 m from the aerosolization location and across shorter distances with high spatial resolution. The unique DNA label and PCR assay specificity were leveraged to perform multiple simultaneous experiments. This allowed the assessment of experimental reproducibility, a rare occurrence among aerosol field tests. To transition to outdoor testing, the solid material provides some protection of the DNA label when exposed to ultraviolet (UV) radiation, with 60% of the DNA remaining intact after 60 minutes under a germicidal lamp and the rate of degradation declining with irradiation time. Additionally, exposure of the DNATrax material using formulations of two different food-grade sugars (maltodextrin and erythritol) to humidity as high as 66% had no significant effect on the DNA label’s degradation or the particle’s aerodynamic diameter, confirming particle stability under such conditions. In summary, confirmation of the DNATrax particles’ size and label integrity under variable conditions combined with experiment multiplexing and high resolution sampling provides a powerful experimental design for modeling aerosol transport through occupied indoor and outdoor locations.

54 ENVIRONMENTAL SCIENCES↗

STITCHES: creating new scenarios of climate model output by stitching together pieces of existing simulations

Abstract. Climate model output emulation has long been attempted to support impact research, mainly to fill in gaps in the scenario space. Given the computational cost of running coupled earth system models (ESMs), which are usually the domain of supercomputers and require on the order of days to weeks to complete a century-long simulation, only a handful of different scenarios are usually chosen to externally force ESM simulations. An effective emulator, able to run on standard computers in times of the order of minutes rather than days could therefore be used to derive climate information under scenarios that were not run by ESMs. Lately, the necessity of accounting for internal variability has also made the availability of initial-condition ensembles, under a specific scenario, important, further increasing the computational demand. At least so far, emulators have been limited to simplified ESM-like output, either seasonal, annual, or decadal averages of basic quantities, like temperature and precipitation, often emulated independently of one another. With this work, we propose a more comprehensive solution to ESM output emulation. Our emulator, STITCHES, uses existing archives of earth system models' (ESMs) scenario experiments to construct ESM-like output under new scenarios or enrich existing initial-condition ensembles, which is what other emulators also aim to do. Importantly, however, STITCHES' output has the same characteristics of the ESM output it sets out to emulate: multivariate, spatially resolved, and high frequency, representing both the forced component and the internal variability around it. STITCHES extends the idea of time sampling – according to which climate outcomes are stratified by the global warming level at which they manifest themselves, irrespective of the scenario and time at which they occur – to the construction of a continuous history of ESM-like output over the whole 21st century, consistent with a 21st-century trajectory of global surface air temperature (GSAT) derived from the scenario that has been chosen as the target of the emulation. STITCHES does so by first splitting the target GSAT trajectory into decade-long windows, then matching each window in turn to a decade-long window within an existing model simulation from the available scenario runs according to its proximity to the target in absolute size of the temperature anomaly and its rate of change. A look-up table is therefore created of a sequence of existing experiment–time-window combinations that, when stitched together, create a GSAT trajectory “similar” to the target. Importantly, we can then stitch together much more than GSAT from these windows, i.e., any output that the ESM has saved for these existing experiment–time-window combinations, at any frequency and spatial scale available in its archive. We show that the stitching does not introduce artifacts in the great majority of cases (we look at temperature and precipitation at monthly frequency and on the native grid of the ESM and at an index of ENSO activity, the Southern Oscillation Index). This is true even if the criteria for the identification of the decades to be stitched together are chosen to work for a smoothed time series of annual GSAT, a result we expect given the larger amount of noise affecting most other variables at finer spatial scales and higher frequencies, which therefore are more “forgiving” of the stitching. We successfully test the method's performance over many ESMs and scenarios. Only a few exceptions surface, but these less-than-optimal outcomes are always associated with a scarcity of the archived simulations from which we can gather the decade-long windows that form the building blocks of the emulated time series. In the great majority of cases, STITCHES' performance is satisfactory according to metrics that reward consistency in trends, interannual and inter-ensemble variance, and autocorrelation structure of the time series stitched together. The method therefore can be used to create ESM-like output according to new scenarios, on the basis of a trajectory of GSAT produced according to that scenario, which could be easily obtained by a simple climate model. It can also be used to increase the size of existing initial-condition ensembles. There are aspects of our emulator that will immediately disqualify it for specific applications, like when climate information is needed whose characteristics result from accumulated quantities over windows of times longer than those used as pieces by STITCHES, droughts longer than a decade for example. But for many applications, we argue that a stitched product can satisfy the climate information needs of impact researchers. STITCHES cannot emulate ESM output from scenarios that result in GSAT trajectories outside of the envelope available in the archive, nor can it emulate trajectories with shapes different from existing ones (overshoots with negative derivative, for example). Therefore, the size and characteristics of the available archives of ESM output are the principal limitations for STITCHES' deployment. Thus, we argue for the possibility of designing scenario experiments within, for example, the next phase of the Coupled Model Intercomparison Project according to new principles, relieved of the need to produce a number of similar trajectories that vary only in radiative forcing strength but more strategically covering the space of temperature anomalies and rates of change.

54 ENVIRONMENTAL SCIENCES↗

Advanced Laboratory and Field Arrays: Evaluating Sampling Techniques for MHK Biological Monitoring (Task 6)

The overall goal of the task was to identify cost effective biological sampling techniques for MHK environmental monitoring. Protected, demersal, and pelagic fish and selected nektonic invertebrates were surveyed using capture and remote sensing techniques at the PacWave sites. The performance of capture and remote sensing monitoring techniques were evaluated and generic nekton monitoring indices were developed for MHK technologies and sites. In parallel to data collections at the PacWave site, the ability of regression models to characterize, detect, and predict change in acoustic data was evaluated using acoustic data collected in Admiralty Inlet, WA, during a biological monitoring study of the proposed SnoPud tidal turbine project site. Expected outcomes of these efforts included an evaluation of instrumentation and techniques used to monitor biological variability; identification of data streams that can be used to detect and quantify change; and sampling requirements to ensure detection of change in monitored variables.

13 HYDRO ENERGY↗