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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26

Mechanistic Understanding of Interphase-driven Aging in Silicon Anodes

Conventional solid electrolyte interphases (SEIs) strongly adhere to micro-silicon (µ-Si) and crack under volume changes, causing poor cycling performance. Nano-silicon improves cycling performance but remains costly with limited calendar life. Here potentiostatic ageing tests demonstrate that both calendar and cycle ageing are governed by SEI cracking and dissolution with different relative contributions. When the system is not dominated by SEI dissolution, the relative calendar life of Si anodes could correlates positively with their cycle life. LiF-rich SEI that enables long cycle life in µ-Si is therefore expected to enhance calendar life as well. Using this framework, we screened electrolytes, SEIs and electrodes and validated them with full-cell storage. LiF-rich SEI minimizes cracking and dissolution, enabling μ-Si to achieve excellent calendar life, whereas nano-silicon suffers from SEI dissolution and needs reduced electrolyte–electrode contact for better calendar life. This work clarifies calendar-ageing behaviour and accelerates electrolytes and SEI development for long-life Si anodes.

Johnson, Christopher S.↗

What Is the Value of Alternative Methods for Estimating Ramping Needs?

Power system operators procure and deploy flexibility reserves or ramping products to address balancing needs caused by uncertainty and variability of load and generation. Existing methods estimate ramping needs using calendar information and historical forecast errors. Novel methods investigate if real-time weather information could inform ramping and other balancing requirements. This paper compares estimation methods for ramping requirements in theory and practice. The theoretical framework indicates when an alternative method could yield improved economic or reliability performance than existing methods by requiring lower or higher levels of ramping products. Preliminary simulations on a 118-bus test system for 4 days in May 2019 illustrate how system performance improves or deteriorates when ramping requirements are weather-informed (alternative) instead of calendar-based (baseline). Preliminary results suggest high variability in change of performance and underline the impact of additional factors, such as system conditions, on the realized performance change.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Introduction to a series of LiNi 0.8 Co 0.2 O 2 -based high-power lithium-ion battery positive electrodes analyzed by x-ray photoelectron spectroscopy

High-power lithium-ion batteries are rapidly replacing the nickel metal hydride batteries currently used for energy storage in hybrid electric vehicles. Widespread commercialization of these batteries for vehicular applications is, however, limited by calendar-life performance, thermal abuse characteristics, and cost. The Advanced Technology Development Program was established by the U.S. Department of Energy to address these limitations. An important objective of this program was the development and application of diagnostic tools that provide unique ways to investigate the phenomena that limit lithium-ion cell life, performance, and safety characteristics. This report introduces a set of six Surface Science Spectra xray photoelectron spectroscopy (XPS) comparison records of data collected from positive electrodes (cathode) harvested from cylindrically wound, 18650-type, 1 A h capacity cells. The cathodes included in this study are (1) fresh, (2) following three formation cycles, (3) following calendar-life test for 12 weeks at 40 C, 60% state-of-charge (SOC), (4) following calendar-life test for 8 weeks at 50 C, 60% SOC, (5) following calendar-life test for 8 weeks at 60 C, 60% SOC, and (6) following calendar-life test for 2 weeks at 70 C, 60% SOC.

XPS↗

LiNi 0.8 Co 0.2 O 2 -based high power lithium-ion battery positive electrodes analyzed by x-ray photoelectron spectroscopy: 1. Fresh electrode

High-power lithium-ion batteries are rapidly replacing the nickel metal hydride batteries currently used for energy storage in hybrid electric vehicles. Widespread commercialization of these batteries for vehicular applications is, however, limited by calendar-life performance, thermal abuse characteristics, and cost. The Advanced Technology Development Program was established by the U.S. Department of Energy to address these limitations. An important objective of this program was the development and application of diagnostic tools that provide unique ways to investigate the phenomena that limit lithium-ion cell life, performance, and safety characteristics. This report introduces a set of six Surface Science Spectra xray photoelectron spectroscopy (XPS) comparison records of data collected from positive electrodes (cathode) harvested from cylindrically wound, 18650-type, 1 A h capacity cells. The cathodes included in this study are (1) fresh, (2) following three formation cycles, (3) following calendar-life test for 12 weeks at 40 C, 60% state-of-charge (SOC), (4) following calendar-life test for 8 weeks at 50 C, 60% SOC, (5) following calendar-life test for 8 weeks at 60 C, 60% SOC, and (6) following calendar-life test for 2 weeks at 70 C, 60% SOC.

energy conversion and storage↗

LiNi 0.8 Co 0.2 O 2 -based high power lithium-ion battery positive electrodes analyzed by x-ray photoelectron spectroscopy: 2. Following 3 formation cycles

High-power lithium-ion batteries are rapidly replacing the nickel metal hydride batteries currently used for energy storage in hybrid electric vehicles. Widespread commercialization of these batteries for vehicular applications is, however, limited by calendar-life performance, thermal abuse characteristics, and cost. The Advanced Technology Development Program was established by the U.S. Department of Energy to address these limitations. An important objective of this program was the development and application of diagnostic tools that provide unique ways to investigate the phenomena that limit lithium-ion cell life, performance, and safety characteristics. This report introduces a set of six Surface Science Spectra xray photoelectron spectroscopy (XPS) comparison records of data collected from positive electrodes (cathode) harvested from cylindrically wound, 18650-type, 1 A h capacity cells. The cathodes included in this study are (1) fresh, (2) following three formation cycles, (3) following calendar-life test for 12 weeks at 40 C, 60% state-of-charge (SOC), (4) following calendar-life test for 8 weeks at 50 C, 60% SOC, (5) following calendar-life test for 8 weeks at 60 C, 60% SOC, and (6) following calendar-life test for 2 weeks at 70 C, 60% SOC.

energy conversion and storage↗

Effects of catholyte aging on high-nickel NMC cathodes in sulfide all-solid-state batteries

Sulfide solid-state electrolytes (SSEs) in all-solid-state batteries (SSBs) are recognized for their high ionic conductivity and inherent safety. The LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) cathode offers a high thermodynamic potential of approximately 3.8 V vs. Li/Li + and a theoretical specific capacity of 200 mA h g −1 . However, the practical utilization of NMC811 in sulfide SSBs faces significant interfacial challenges. The oxidation instability of sulfide solid electrolytes against NMC811 and the formation of the cathode electrolyte interphase (CEI) during cycling lead to degradation and reduced cell performance. Volumetric changes in NMC during lithiation and de-lithiation can also cause detachment from sulfide electrolytes or internal particle cracking. Despite extensive galvanostatic cycling studies to address the issues, the calendar life of sulfide SSBs remains poorly understood. Here, we systematically studied the effects of four different catholytes on the calendar aging of LiNbO 3 (LNO)-coated NMC811, including Li 6 PS 5 Cl (LPSCl), Li 3 InCl 6 –Li 6 PS 5 Cl (LIC–LPSCl), Li 3 YCl 6 –Li 6 PS 5 Cl (LYC–LPSCl), and Li 10 GeP 2 S 12 (LGPS). Our results indicate that LPSCl provides optimal capacity retention when stored at high state-of-charge (SOC) at room temperature, but the LIC–LPSCl cathode shows significant capacity degradation and chemical incompatibility. We also established an effective electrochemical calendar aging testing protocol to simulate daily usage, enabling quick inference of the calendar life of SSBs. In conclusion, this new testing approach accelerates materials selection strategies for high-nickel NMC composite cathodes in sulfide SSBs.

25 ENERGY STORAGE↗

Quantitative Microstructure Characterization of a NMC Electrode

Performance of lithium-ion batteries (LIBs) is strongly influenced by the porous microstructure of their electrodes. In this work, 3D microstructures of calendared and un-calendared positive electrode LiNi1/3Mn1/3Co1/3O2 (NMC) have been investigated in order to extract relevant properties useful for battery modeling. Transport (volume fraction, connectivity, particle size and tortuosity) and electrochemical (specific surface area) properties have been calculated for the pore and the active material. Special attention has been paid to determine the size of the so-called representative volume element (RVE) required to be statistically representative of the heterogeneous medium. Several parameters have been calculated using a panel of different numerical methods in order to compare their results. Besides, the image level of detail has been evaluated (using original criteria based upon edge detection) to assess the overall data quality available for the study.

30 DIRECT ENERGY CONVERSION↗

Research and Development on Advanced Electrochemical Energy Storage Devices Enabling a Spectrum of Electrified Vehicles

The USABC Advanced Battery development plan had the following three focus areas: 1. Existing technology validation, implementation, and cost reduction 2. Identification of the next viable technology with emphasis on the potential to meet USABC cost and energy density goals. 3. Support high-risk, high-reward battery technology R&D The primary aim of this project was focused on the barriers that most impede wider public adoption of electrification in vehicles-cost, energy density, low-temp performance, calendar life, and improvements in abuse tolerance. The specific objectives are as follows: Cost Reduction: drive to significantly reduce battery cost to be in-line with the $\$$100/kWh or less (by the end of calendar year 2020) DOE cost goals. Additionally, goals of $\$$75/KWh were set for 2023 aligned with fast charge and some offset of energy density. Energy Density Increase: focus on improving the cell-level specific energy and energy densities to >350 watt hours per kilogram (Wh/kg) and >750Wh/L. Low Temperature Performance Increase: strive toward developments that improve the discharge power and eliminate or dramatically reduce the life limiting lithium plating associated with regenerative braking at low temperatures, during the program. Calendar Life Increase: drive to achieve a 15-year calendar life. Abuse Tolerance Improvement: strive to develop improvements in Li-ion abuse tolerance and/or development of electrochemical energy storage technologies with inherently better response to abuse circumstances. Emerging Areas: initiate new programs that address emerging technologies that arise during the contract period.

25 ENERGY STORAGE↗

Preliminary evaluation of spectral, normal and meteorological crop stage estimation approaches

Several of the projects in the AgRISTARS program require crop phenology information, including classification, acreage and yield estimation, and detection of episodal events. This study evaluates several crop calendar estimation techniques for their potential use in the program. The techniques, although generic in approach, were developed and tested on spring wheat data collected in 1978. There are three basic approaches to crop stage estimation: historical averages for an area (normal crop calendars), agrometeorological modeling of known crop-weather relationships agrometeorological (agromet) crop calendars, and interpretation of spectral signatures (spectral crop calendars). In all, 10 combinations of planting and biostage estimation models were evaluated. Dates of stage occurrence are estimated with biases between -4 and +4 days while root mean square errors range from 10 to 15 days. Results are inconclusive as to the superiority of any of the models and further evaluation of the models with the 1979 data set is recommended.

Cate, R. B.↗

Surface and Bulk Stabilization of Silicon Anodes with Mixed-Multivalent Additives: Ca(TFSI) 2 and Mg(TFSI) 2

Here, silicon is drawing attention as the upcoming anode material for the next generation of lithium-ion batteries due to its higher capacity compared to commercial graphite. However, silicon anions formed during lithiation are highly reactive with binder and electrolyte components creating an unstable SEI layer and limiting the calendar life of silicon anodes. The reactivity of lithium silicide and the formation of an unstable SEI layer is mitigated by utilizing the use of a mixture of Ca and Mg multivalent cations as an electrolyte additive for Si anodes to improve their calendar life. The effect of mixed salts on the bulk and surface of silicon anodes was studied by multiple structural characterization techniques. Ca and Mg ions in the electrolyte formed relatively thermodynamically stable quaternary Li-Ca-Mg-Si Zintl phases in an in-situ fashion and more stable and denser SEI layer on the Si particles. These in turn protect silicon particles against side reactions with electrolytes in a coin cell. The full cell with the mixed cation electrolyte demonstrates enhanced calendar life performance with lower measured current and current leakage than that of the baseline electrolyte due to reduced side reactions. Electron Microscopy, HRXRD, and solid-state NMR results showed that electrodes with mixed cations tended to have less cracking on the electrode surface compared to Si electrodes with Gen2 + FEC and the presence of mixed cations enhances cation migration and formation of quaternary Zintl phases stabilizing bulk and forming a more stable SEI.

25 ENERGY STORAGE↗

The importance of cycle-by-cycle data in performing rapid battery technology development and validation

Lithium-ion battery (LiB) technology is playing a crucial role in transforming the predominantly fossil fuel-based transportation and stationary storage sectors to achieve a low-carbon economy. Rapid innovation in the LiB materials to electrode to cell design is happening to satisfy the performance, life, and safety metrics required by those myriads of applications. Lately, advanced analytics, such as machine-learning or artificial intelligence (ML/AI) techniques, are being used more frequently to aid in expedited LiB technology development, performance validation, and life prediction. The success of these techniques often relies on a large volume of well-defined and high-quality battery test data. On the other hand, most battery developers and research and development (R&D) communities are still following a classical approach to develop batteries, which is running calendar- and/or cycle-aging tests, performing reference performance tests (RPTs), and conducting post-mortem analyses periodically without paying attention to the wealth of data often not collected during the calendar or cycle life aging tests. This sparse data collection approach is time- and resource-intensive, requiring data capture and evaluation of months to years of RPT data to diagnose accurate battery state of performance, health, and safety. Even so, the underlying aging modes and mechanisms can be missed. If collected properly, battery test data during cycling or calendaring can be efficiently combined with ML/AI techniques to create powerful tools in the rapid diagnosis of battery state of performance, health, and safety along with insights into underlying aging modes and mechanisms. In this report, we discuss the importance of effective cycle-by-cycle (CBC) data collection with example case studies. Within a reasonable timeframe, RPT data are often inadequate in capturing many of the crucial battery aging dynamics, which often predominantly show up in CBC test data. Finally, we also show examples of ML/AI techniques that use CBC data in rapid diagnosis and projection of LiB state of health (SOH) to motivate the scientific community in collecting and using CBC data to facilitate expeditious technology development and validation.

25 ENERGY STORAGE↗

Resolving three-dimensional nanoscale heterogeneities in lithium metal batteries with cryoelectron tomography

Current direct observation of sensitive battery materials and interfaces primarily relies on two-dimensional (2D) imaging, leaving out their three-dimensional (3D) relationship. Here, in this study, we used cryoelectron tomography (cryo-ET) to visualize the lithium metal anode in 3D at nanometer resolution and cryoelectron microscopy (cryo-EM) to reveal atomic details in local regions. We imaged both freshly prepared and calendar-aged Li metal anodes to reveal the development of LiH in Li dendrites and the Li-LiH interface, as well as the development of the solid-electrolyte interphase (SEI). Using a convolutional neural network-based technique, the 3D arrangement of Li metal, along with nanoscale LiH and Cu heterogeneities in dendrites, was visualized and annotated. In longer-term calendar aging, we observed more substantial LiH growth accompanied by extended SEI growth. Our results show that the growth of LiH and the extended SEI during battery calendar aging are temporally and spatially separate processes.

LiH↗

Substituted thiadiazoles as energy-rich anolytes for nonaqueous redox flow cells

Understanding structure–property relationships is essential for designing energy-rich redox active organic molecules (ROMs) for all-organic redox flow batteries. In this paper we examine thiadiazole ROMs for storage of negative charge in the flow cells. These versatile molecules have excellent solubility and low redox potentials, allowing high energy density to be achieved. By systematically incorporating groups with varying electron accepting/withdrawing ability, we have examined substituent effects on their properties of interest, including redox potentials, calendar lives of charged ROMs in electrolyte, and the flow cell cycling performance. Finally, while the calendar life of energized fluids can be tuned in a predictable fashion over a wide range, the improvements in the calendar life do not automatically translate into the enhanced cycling performance, indicating that in addition to the slow reactions of charged species in the solvent bulk, there are other parasitic reactions that occur only during the electrochemical cycling of the cell and can dramatically affect the cycling lifetime.

25 ENERGY STORAGE↗

Annual Site Environmental Report: 2010 (ASER)

This report provides information about environmental programs during the calendar year of 2010 at the SLAC National Accelerator Laboratory (SLAC), Menlo Park, California. Activities that overlap the calendar year - i.e., stormwater monitoring covering the winter season of 2010/2011 (October 2010 through May 2011) are also included. SLAC is a federally-funded research and development center with Stanford University as the M&O contractor. Under Executive Order (EO) 13423, Strengthening Federal Environmental, Energy, and Transportation Management, EO 13514, Federal Leadership in Environmental, Energy, and Economic Performance, and DOE Order 450.1A, Environmental Protection Program, SLAC effectively implements and integrates the key elements of an Environmental Management System (EMS) to achieve the site's integrated safety and environmental management system goals. For normal daily activities, SLAC managers and supervisors are responsible for ensuring that policies and procedures are understood and followed so that: (1) Worker safety and health are protected; (2) The environment is protected; and (3) Compliance is ensured. Throughout 2010, SLAC continued to improve its management systems. These systems provided a structured framework for SLAC to implement 'greening of the government' initiatives such as EO 13423, EO 13514, and DOE Orders 450.1A and 430.2B. Overall, management systems at SLAC are effective, supporting compliance with all relevant statutory and regulatory requirements. During 2010, there were no reportable releases to the environment from SLAC operations. In addition, many improvements in waste minimization, recycling, stormwater management, groundwater restoration, and SLAC's chemical management system (CMS) were continued. The following are among SLAC's environmental accomplishments for 2010. To facilitate management and identification of future potential greenhouse gases (GHG) reduction opportunities, SLAC voluntarily completed GHG inventories for calendar year (CY) 2008 and CY 2009 and submitted the results to The Climate Registry. A Lead Management Plan was completed to reduce the potential of lead impacting the environment, and two large legacy tube-trailer modules, each containing 38 tubes of compressed ethane, were reused or recycled by an outside contractor, resulting in hazardous waste avoidance and cost savings of approximately $100,000 in transportation and disposal costs. SLAC continues to make progress on achieving the sustainability goals of EOs 13423 and 13514, which include, but are not limited to reductions in the use of water, energy, and fuel, building to green standards and reductions in GHG emissions. Phase I of the SLAC Advanced Metering project for electrical and natural gas systems was completed. Phase I included the design of the metering system and purchase of the enterprise software. The planning, design, and installation of an advanced water metering system for select buildings, landscape, and process systems were completed. In addition, the last major onsite chiller containing a Class I ozone-depleting substance was taken out of service, and SLAC continued to replace conventional vehicles with electric vehicles. In 2010, there were no radiological impacts to the public or the environment from SLAC operations. The potential doses to the public were negligible and far below the regulatory and SLAC administrative limits. No radiological incidents occurred that increased radiation levels to the public or released radioactivity to the environment. In addition to managing its radioactive wastes safely and responsibly, SLAC worked to reduce the amount of waste generated. SLAC shipped 2,891 cubic feet of low-level radioactive waste, half of which was legacy waste, to appropriate treatment and disposal facilities for low-level radioactive waste. SLAC also continued its efforts to reduce the inventory of materials no longer needed for its mission by permanently removing 125 sealed radioactive sources from the inventory. Ninety-seven of the sealed sources were returned to the manufacturer, and 28 were sent to Energy Solutions for processing before being sent to the Nevada Test Site for burial. In addition, 87 concrete blocks which had been stored in an area known as the Bone Yard were surveyed for potential surface contamination and volumetric activation prior to off-site release. Based on the comprehensive measurements, all 87 blocks were qualified for release and were disposed of as ordinary materials at a landfill. In 2010, the SLAC Environmental Restoration Program personnel continued work on site characterization and evaluation of remedial alternatives at four sites with volatile organic compounds in groundwater and several areas with polychlorinated biphenyls and low concentrations of lead in soil.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

2013 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 22)

This 2013 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 22) provides water use information for production and potable water wells at the Idaho National Laboratory for Calendar Year 2013. It also provides detailed information for new, modified, and decommissioned wells and holes. Two new wells were drilled and completed in Calendar Year 2013. No modifications were performed on any wells. Seven wells were decommissioned in Calendar Year 2013. Detailed construction information for the new and decommissioned wells is provided. Location maps are included, provided survey information was available. This report is being submitted in accordance with the Water Rights Agreement between the State of Idaho and the United States, for the United States Department of Energy (dated 1990) and the subsequent Partial Decree for Water Right 34-10901 issued June 20, 2003.

2013 idaho national laboratory water use report an↗

2014 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 23)

This 2014 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 23) provides water use information for production and potable water wells at the Idaho National Laboratory for Calendar Year 2014. It also provides detailed information for new, modified, and decommissioned wells and holes. One new well was drilled and completed in Calendar Year 2014. No modifications were performed on any wells. No wells were decommissioned in Calendar Year 2014. Detailed construction information and a location map for the new well is provided. This report is being submitted in accordance with the Water Rights Agreement between the State of Idaho and the United States, for the United States Department of Energy (dated 1990), the subsequent Partial Decree for Water Right 34-10901 issued June 20, 2003, and the Final Unified Decree issued August 26, 2014.

2014 Idaho National Laboratory Water Use Report an↗

2017 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 26)

This 2017 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 26) provides water use information for production and potable water wells at the Idaho National Laboratory (INL) Site for Calendar Year 2017. It also provides detailed information for new, modified, and decommissioned wells. Fourteen new wells were drilled and completed in Calendar Year 2017. No wells on the INL Site were decommissioned in Calendar Year 2017. However, an offsite area near Box Canyon that contained instrumented boreholes used for research was decommissioned. Detailed construction and decommissioning information and location maps for the wells are provided. This report is being submitted in accordance with the Water Rights Agreement between the State of Idaho and the United States, for the United States Department of Energy (dated 1990), the subsequent Partial Decree for Water Right 34-10901 issued June 20, 2003, and the Final Unified Decree issued August 26, 2014.

2017 Idaho National Laboratory Water Use Report an↗

2016 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 25)

This 2016 Idaho National Laboratory Water Use Report and Comprehensive Well Inventory (Revision 25) provides water use information for production and potable water wells at the Idaho National Laboratory Site for Calendar Year 2016. It also provides detailed information for new, modified, and decommissioned wells. Four new wells were drilled and completed in Calendar Year 2016. Five storm water injection wells were decommissioned in Calendar Year 2016. Detailed construction and decommissioning information and location maps for the wells are provided. This report is being submitted in accordance with the Water Rights Agreement between the State of Idaho and the United States, for the United States Department of Energy (dated 1990), the subsequent Partial Decree for Water Right 34-10901 issued June 20, 2003, and the Final Unified Decree issued August 26, 2014.

2016 Water Use Report and Comprehensive Well Inven↗