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At least 469 records · Page 26

Ion temperature profiles in the horns of the plasma sheet

The plasma sheet horns are the low-altitude extensions of the plasma sheet that lie poleward of the plasmasphere and equatorward of the tail lobes. Within the horns, magnetic field lines of increasing geomagnetic latitudes map to increasing distances into the downtail plasma sheet. Plasma data from the fast plasma experiment on ISEE 2 have been analyzed for 11 outbound crossings of the horns in the premidnight sector of the magnetosphere at typical altitudes of 2-4 R(E). These crossings typically occurred on time scales of less than 1 hour, providing almost instantaneous snapshots of plasma gradients within the horns. Ion temperatures observed during these crossings generally decreased by a factor of four to eight as magnetic field lines of increasing geomagnetic latitude were traversed. If we make the reasonable assumption that the ion temperatures are constant along the field lines within the plasma sheet, then this result implies that the ion temperatures in the downtail plasma sheet also commonly decrease by this same factor over the radial range extending from the inner edge of the plasma sheet at the plasmapause boundary to the outer edge at a neutral line in the distant tail.

Suszcynsky, D. M.↗

Non-thermal plasma-assisted steam methane reforming for electrically-driven hydrogen production

Plasma-assisted steam methane reforming (SMR) has become a promising approach for low temperature and small-scale hydrogen production. To increase H 2 yields, water-gas-shift reactions are needed to drive the formed CO to CO 2 and H 2 . In this study, bulk gas temperature, plasma power and water feed rate strongly impacted the CO and CO 2 product selectivity at high methane conversions of 60–80% in the presence of a Ni-based catalyst. CO 2 -enriched hydrogen could be formed directly with H 2 O/methane ratios > 4. To further increase the CO 2 /CO product selectivity, a “one-pot” cascade design with a Cu/ZnO/Al 2 O 3 /MgO catalyst bed placed downstream of the plasma zone achieved substantially higher CO 2 /CO selectivity (>15) in the effluent gas at 60% methane conversion and 300°C. Comparably, placing the Cu-based catalyst in the plasma zone does not alter the CO 2 /CO selectivity. Further, this study highlights the use of plasma reactor systems to directly tune the catalytic SMR performance and lead to an electrified route for hydrogen production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Low-energy X-ray observations of the Wolf 630 system

The Exosat channel multiplier array is used to resolve the septuplet of M dwarfs into three components (Wolf 630ABab, Wolf 629ab, and VB 8AB) with widely different X-ray characteristics. An isothermal plasma temperature of between 800,000 and 550,000 K (which is very low in the known range of coronal temperatures) is found for any relatively quiescent state of VB 8. It is shown from the count rate during 18,112 sec of effective exposure with Exosat that VB 8 flared once in 0.05-2 keV flux.

Johnson, Hugh M.↗

Spheroidization of Nd–Fe–B particles

Spherical powders are required for many advanced manufacturing techniques due to their inherent requirement of flowability, either within feed tubes or during powder spreading. As advanced manufacturing of magnets continues to develop, new production methods for feedstocks are also sought. Plasma spheroidization is a high-yield method to produce spherical Nd–Fe–B powders from irregularly shaped particles, with advantages including high throughput and a well-controlled size distribution. Highly spherical Nd–Fe–B powders with large scale production (i.e., kg) have been demonstrated using an inductively coupled thermal plasma system; however, the magnetic properties of the output powder display significant degradation. The coercivity was decreased from the initial 8 kOe (636 kA/m) of the as-received to 0.7 kOe (55 kA/m) for spheroidized powders. Microstructural investigation reveals 6% Nd depletion caused by the extreme temperatures of the plasma, leading to the formation of low-coercivity α-Fe and a subsequent decrease in energy product. In conclusion, post-spheroidization heat treatments with Nd can partially mitigate the coercivity degradation, increasing to 1.7 kOe (135 kA/m), potentially offering a pathway toward spherical powders for a range of applications.

36 MATERIALS SCIENCE↗

Microwave-enhanced thin-film deposition

The deposition of semiconducting and insulating thin films at low temperatures using microwave technology was explored. The method of plasma formations, selection of a power source, the design of the microwave plasma cavity, the microwave circuitry, impedance matching, plasma diagnostics, the deposition chamber and the vacuum system were studied.

Chitre, S.↗

Comparative magnetospheric/ionospheric studies using Dynamics Explorer spacecraft and ground-based radars

Coincident observations between the Dynamics Explorer 1 and 2 spacecraft with Chatanika and Arecibo ground-based radar are briefly reviewed. Ionospheric-magnetospheric coupling processes in the plasmasphere, main trough, auroral zone, and polar cap are inferred from the density, temperature, composition, and angular distributions of the low-energy plasma observed from the E-region ionosphere out into the magnetosphere to an altitude of 2.5 earth radii (Re). From the polar cap to the inner plasmasphere, parallel and perpendicular electric fields, polar wind flow, and equilibrium diffusion appear to be involved in the ionospheric-magnetospheric coupling of the low energy plasma.

Green, J. L.↗

Large amplitude, low frequency plasma fluctuations at Comet Giacobini-Zinner

Very large amplitude fluctuations in electron density, temperature, and flow velocity were a prominent aspect of the solar wind interaction with Comet Giacobini-Zinner during the ICE encounter in September 1985. These fluctuations were detected at a distance of at least 900,000 km and grew in amplitude as ICE approached the comet, peaking in amplitude 60,000 km from closest approach. A typical period associated with the fluctuations was about 2 min, which corresponds to a scale length in the solar wind frame of about 50,000 km. For the most part these fluctuations appear to be a product of one or more plasma instabilities associated with the solar wind pick up of cometary ions.

Gosling, J. T.↗

Observations of ionospheric magnetospheric coupling - DE and Chatanika coincidences

Observations from several experiments on board the Dynamics Explorer 1 and 2 (DE 1 and 2) spacecraft and ground-based radar measurements from the Chatanika radar are combined in order to examine the details of ionospheric/magnetospheric coupling in the local evening sector. DE 1 and DE 2 were in coplanar polar orbits that provided measurements almost simultaneously in time and magnetically coincident with the Chatanika radar from L = 3 to L = 17. The coupling processes are inferred from the density, temperature, composition, and angular distributions of the low-energy plasma observed from the E region of the ionosphere to magnetospheric altitudes of 2.5 earth radii. Plasma characteristics of the plasmasphere, main trough, auroral zone, and polar cap can be studied in this data set. The observations imply that as L increases, the dominant coupling mechanism between the ionosphere and magnetosphere in the measured energy range changes from equilibrium diffusion to perpendicular acceleration and finally to parallel acceleration.

Green, J. L.↗

Comparative magnetospheric/ionospheric studies using Dynamics Explorer spacecraft and ground-based radars

Coincident magnetosphere-ionosphere observations between the Dynamics Explorer 1 and 2 spacecraft with ground-based radar are reviewed. Ionospheric-magnetospheric coupling processes in the plasmasphere, main trough, auroral zone, and polar cap are inferred from the density, temperature, composition, and angular distributions of the low-energy plasma observed from the E-region ionosphere out into the magnetosphere to an altitude of 2.5 Re. From the polar cap to the inner plasmasphere, parallel and perpendicular electric fields, polar wind flow, and equilibrium diffusion appear to be involved in the ionospheric-magnetospheric coupling of the low energy plasma.

Green, J. L.↗

Strong Coulomb coupling influences ion and neutral temperatures in atmospheric pressure plasmas

Molecular dynamics simulations are used to model ion and neutral temperature evolution in partially-ionized atmospheric pressure plasma at different ionization fractions. Results show that ion–ion interactions are strongly coupled at ionization fractions as low as 10 –5 and that the temperature evolution is influenced by effects associated with the strong coupling. Specifically, disorder-induced heating is found to rapidly heat ions on a timescale of the ion plasma period (~10 s ps) after an ionization pulse. This is followed by the collisional relaxation of ions and neutrals, which cools ions and heats neutrals on a longer (~ns) timescale. Slight heating then occurs over a much longer (~100 s ns) timescale due to ion-neutral three-body recombination. An analytic model of the temperature evolution is developed that agrees with the simulation results. Finally, a conclusion is that strong coupling effects are important in atmospheric pressure plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Metal/Ceramic Bond Coatings For High Temperatures

Reduced-thermal-expansion bond coatings developed for use at high temperatures in thermal-barrier-coating systems. Bond coatings composed of low-pressure-plasma-sprayed metallic matrices dispersed with low-thermal-expansion high-bulk-modulus ceramic particles. New coatings and application lower thermal-expansion-mismatch strain while maintaining integrity at high temperatures.

Miller, Robert A.↗

Plasma technology for lignocellulosic biomass conversion toward an electrified biorefinery

Lignocellulosic biomass conversion to renewable, carbon-neutral materials, fuels, and chemicals is the cornerstone of the transition to a sustainable future bioeconomy. Green energy in the form of electricity needs to be coupled with or substitute conventional thermally driven processes to realize small-scale, economically viable and environmentally friendly biorefineries. Gas discharge plasmas enable the conversion of renewable electric energy, supplied in the form of an electric field, to chemical energy through the formation of a highly reactive environment that can induce several transformations related to agricultural waste valorization processes. Herein, we review the application of plasma technology to lignocellulosic biomass upgrade, aiming to provide the scientific background and technical challenges in this rapidly emerging research field. To bridge the gap between plasma science and biomass valorization technologies, we initially present the technical aspects of plasma reactors related to biomass processing and further discuss the advances in plasma processing for each biomass conversion technology, providing insights into the related plasma chemistry and interaction mechanisms. Here, we first focus on the low and medium-temperature biomass conversion processes, including biomass pretreatment and delignification to promote enzyme or acid-catalyzed hydrolysis to sugars and biomass liquefaction using plasma electrolysis. Then we discuss the high and very high-temperature conversion processes, such as plasma-assisted pyrolysis and gasification to syngas and plasma application to tar removal, combustion, and vitrification. Overall, this review provides knowledge at the interface of plasma science and biomass conversion technology to promote the interaction between the individual communities, which is crucial for the further advancement of the field.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Beam-plasma interactions as a heat source in the magnetosphere

Strong electron precipitation fluxes are frequently accompanied by strong downward heat conduction fluxes, deduced from simultaneous high and low altitude electron temperature measurements. It is shown that the heat input due to beam-plasma interactions is of the correct order of magnitude to sustain the observed heat flux.

Fontheim, E. G.↗

Investigation of radiated-power for low aspect ratio fusion plasmas

Investigating radiated power in fusion plasmas is of utmost importance to understand the effect of undesired impurities, such as metals, in present devices, or also desired impurities, such as noble gasses, to purposefully radiate a large fraction of power in future devices. These studies are especially important for high Z impurities which will play a crucial role in future generation fusion pilot plants. In this work, we have developed a power radiation analysis module, which is used to investigate 2D distributions of impurity densities and radiated power asymmetries caused due to both plasma rotation and the cooling rate dependence on temperature profile for the cases of experimental NSTX plasmas and designed scenarios for the spherical tokamak advanced reactor (STAR), both being low aspect ratio tokamaks. Two different atomic databases have been tested during this work to study their impact on the radiated power distribution, especially for high Z impurities. Also in PRAM, self-consistent calculations of two-dimensional electron, main ion, and impurity ion densities are carried out using one-dimensional input density, temperature, and rotation profiles. In the case of NSTX, discharges with high rotation of ∼ 170 km s, measured with charge exchange recombination spectroscopy, have been investigated. Rotation-induced charge separation, leading to an electrostatic potential, is calculated iteratively to a self-consistent solution while testing high Z impurities to observe any 2D asymmetry in the core radiated power due to centrifugal forces. The STAR design, being much larger (R = 4 m), is projected to have a much lower rotation, and is shown to have low rotation-induced asymmetries, on the order of ten percent or less, between the low field and high field sides. However, another effect not due to rotation but to the dependence of impurity cooling rates on temperature can lead to radiation peaking off-axis, near the plasma edge. This effect is noticeable for argon in NSTX, for example, but can also be enhanced for certain impurities at much higher temperatures projected for STAR (T e0 ~ 32 keV), for example for undesired tungsten or possibly desired xenon.

NSTX↗

Generation of high-frequency broadband electrostatic noise - The role of cold electrons

Broadband electrostatic noise (BEN) is commonly observed in the plasma sheet boundary layer in association with ion beams. The generation of these waves in a plasma consisting of an ion beam and a background of hot ions, hot electrons, and cold electrons is investigated. The cold electrons are of ionospheric origin. A complete, systematic study of electrostatic ion beam instabilities, including cold electrons, has been done, and it is shown that for the plasma configuration described, four instabilities can be excited: (1) ion acoustic, (2) Buneman, (3) beam resonant, and (4) electron acoustic instabilities. A low and high beam temperature division is shown to exist that separates when different instabilities can be excited. For typically observed parameters in the plasma sheet boundary layer, the ion beams lie in the high-temperature regime. In this regime, the beam resonant and electron acoustic instabilities are excited, and these instabilities can account for the high-frequency (higher than 500 Hz), low-power portion of the BEN spectrum. In the absence of cold electrons, no such wave growth occurs.

Schriver, David↗

Large-Area Permanent-Magnet ECR Plasma Source

A 40-cm-diameter plasma device has been developed as a source of ions for material-processing and ion-thruster applications. Like the device described in the immediately preceding article, this device utilizes electron cyclotron resonance (ECR) excited by microwave power in a magnetic field to generate a plasma in an electrodeless (noncontact) manner and without need for an electrically insulating, microwave-transmissive window at the source. Hence, this device offers the same advantages of electrodeless, windowless design - low contamination and long operational life. The device generates a uniform, high-density plasma capable of sustaining uniform ion-current densities at its exit plane while operating at low pressure [<10(exp -4) torr (less than about 1.3 10(exp -2) Pa)] and input power <200 W at a frequency of 2.45 GHz. Though the prototype model operates at 2.45 GHz, operation at higher frequencies can be achieved by straightforward modification to the input microwave waveguide. Higher frequency operation may be desirable in those applications that require even higher background plasma densities. In the design of this ECR plasma source, there are no cumbersome, power-hungry electromagnets. The magnetic field in this device is generated by a permanent-magnet circuit that is optimized to generate resonance surfaces. The microwave power is injected on the centerline of the device. The resulting discharge plasma jumps into a "high mode" when the input power rises above 150 W. This mode is associated with elevated plasma density and high uniformity. The large area and uniformity of the plasma and the low operating pressure are well suited for such material-processing applications as etching and deposition on large silicon wafers. The high exit-plane ion-current density makes it possible to attain a high rate of etching or deposition. The plasma potential is <3 V low enough that there is little likelihood of sputtering, which, in plasma processing, is undesired because it is associated with erosion and contamination. The electron temperature is low and does not vary appreciably with power.

Foster, John E.↗

Low-pressure inductively coupled plasmas in hydrogen: impact of gas heating on the spatial distribution of atomic hydrogen and vibrationally excited states

Non-equilibrium inductively coupled plasmas (ICPs) operating in hydrogen are of significant interest for applications including large-area materials processing. Increasing control of spatial gas heating, which drives the formation of neutral species density gradients and the rate of gas-temperature-dependent reactions, is critical. In this study, we use 2D fluid-kinetic simulations with the Hybrid Plasma Equipment Model to investigate the spatially resolved production of atomic hydrogen in a low-pressure planar ICP operating in pure hydrogen (10–20 Pa or 0.075–0.15 Torr, 300 W). The reaction set incorporates self-consistent calculation of the spatially resolved gas temperature and 14 vibrationally excited states. We find that the formation of neutral-gas density gradients, which result from spatially non-uniform electrical power deposition at constant pressure, can drive significant variations in the vibrational distribution function and density of atomic hydrogen when gas heating is spatially resolved. This highlights the significance of spatial gas heating on the production of reactive species in relatively high-power-density plasma processing sources.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗