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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 469 records · Page 26
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Electrodes for thermionic energy conversion

Problems concerning an application of thermionic energy conversion methods are related to the high heat source temperatures currently required for practical power densities and efficiencies. A description is given of advances made in the development of improved emitter and collector surfaces as a basis for the reduction of operating temperatures. The controlled addition of oxygen has resulted in a considerable improvement of emitter performance. Improvements in converter performance have been obtained by a reduction of the collector work function. Attention is given to fundamental studies, simulated converter environment tests, and variable spacing converter experiments.

Rufeh, F.↗
NASA NTRS1975

Practical aspects of plasma processes in thermionic energy converters

Over a decade of cesium vapor thermionic converter research has yielded sufficient understanding of the basic plasma processes to permit application of this understanding to improvement of converter performance. A performance index is defined which relates such converter improvements directly to increases in system performance. A prime practical objective of current research is to reduce or eliminate the arc potential drop presently required to sustain the plasma in the ignited cesium diode. This will substantially increase the energy conversion efficiency, and will permit operation at substantially lower emitter temperatures without requiring lower collector (heat rejection) temperature. Present work is concentrating on evaluating and reducing to practice the several methods employing auxiliary ion sources to eliminate the arc drop which were demonstrated over a decade ago: i.e., various ignited and unignited triode concepts, and the pulse-enhanced diode and triode. These methods are reviewed in light of present understanding and recent experimental data.

Rasor, N. S.↗
NASA NTRS1975

Comparative assessment of out-of-core nuclear thermionic power systems

The hardware selections available for fabrication of a nuclear electric propulsion stage for planetary exploration were explored. The investigation was centered around a heat-pipe-cooled, fast-spectrum nuclear reactor for an out-of-core power conversion system with sufficient detail for comparison with the in-core system studies completed previously. A survey of competing power conversion systems still indicated that the modular reliability of thermionic converters makes them the desirable choice to provide the 240-kWe end-of-life power for at least 20,000 full power hours. The electrical energy will be used to operate a number of mercury ion bombardment thrusters with a specific impulse in the range of about 4,000-5,000 seconds.

Estabrook, W. C.↗
NASA NTRS1976

Fabrication and surface characterization of composite refractory compounds suitable for thermionic converters

Procedures for fabricating high purity single crystals of LaB6 and SmB6 have been developed. Auger spectroscopy shows that a clean surface can be obtained by thermal heating at 1700 K; such a clean surface gives a value of B/La of 2.3 to 2.6 for the (100) face. The measured thermionic and FERP work functions of the (100) face of LaB6 are 2.47 and 2.28 eV, respectively. The electron reflection coefficient for LaB6(100) increases near zero primary energy to 0.5. Flash thermal desorption of an oxygen dosed surface showed that B2O3 is the desorption product at 1600 to 1700 K. A work function increase of 1.6 eV was observed on oxygen adsorption on LaB6(100). Thermal desorption of Co occurs at approximately 1300 K. A reduction of the work function to 1.39 eV was observed on adsorption of a partial monolayer of Cs on LaB6(100). The evaporation of LaB6 occurs as atomic La and B with a value of B/La of 6 to 3 in the temperature range 1700 to 2000 K. The activation energies of desorption for La and B are 6.3 + or - 0.3 and 6.8 + or - 0.3 eV, respectively.

Swanson, L. W.↗
NASA NTRS1976

NASA thermionic-conversion program

Current out-of-core emphases allow converter material and design freedoms previously prohibited by in-core nucleonic and geometric restrictions. As a result, potential improvements indicate possibilities for severalfold increases in efficiencies. The new TEC-ART program concentrated initially on low-work function collectors and interelectrode-loss reduction and revealed much in a short time. This new emission capability coupled with improved collectors that maintain performance with emitter-vapor deposit accumulations are requisites for efficient, enduring thermionic converters.

Morris, J. F.↗
NASA NTRS1974

Advanced thermionic energy conversion

Basic analytical and experimental exploration was conducted on several types of advanced thermionic energy converters, and preliminary analysis was performed on systems utilizing advanced converter performance. The Pt--Nb cylindrical diode which exhibited a suppressed arc drop, as described in the preceding report, was reassembled and the existence of the postulated hydrid mode of operation was tentatively confirmed. Initial data obtained on ignited and unignited triode operation in the demountable cesium vapor system essentially confirmed the design principles developed in earlier work, with a few exceptions. Three specific advanced converter concepts were selected as candidates for concentrated basic study and for practical evaluation in fixed-configuration converters. Test vehicles and test stands for these converters and a unique controlled-atmosphere station for converter assembly and processing were designed, and procurement was initiated.

Britt, E. J.↗
NASA NTRS1976

Diminiode thermionic conversion with 111-iridium electrodes

Preliminary data indicating thermionic-conversion potentialities for a 111-iridium emitter and collector spaced 0.2 mm apart are presented. These results comprise output densities of current and of power as functions of voltage for three sets of emitter, collector, and reservoir temperatures: 1553, 944, 561 K; 1605, 898, 533 K; and 1656, 1028, 586 K. For the 1605 K evaluation, estimates produced work-function values of 2.22 eV for the emitter and 1.63 eV for the collector with a 2.0-eV barrier index (collector work function plus interelectrode voltage drop) corresponding to the maximum output of 5.5 W/sq cm at 0.24 volt. The current, voltage curve for the 1656 K 111-iridium diminiode yields a 6.2 W/sq cm maximum at 0.25 volt and is comparable with the 1700 K envelope for a diode with an etched-rhenium emitter and a 0.025-mm electrode gap made by TECO and evaluated by NASA.

Koeger, E. W.↗
NASA NTRS1977

Nuclear thermionic converter

Efficient nuclear reactor thermionic converter units are described which can be constructed at low cost and assembled in a reactor which requires a minimum of fuel. Each converter unit utilizes an emitter rod with a fluted exterior, several fuel passages located in the bulges that are formed in the rod between the flutes, and a collector receiving passage formed through the center of the rod. An array of rods is closely packed in an interfitting arrangement, with the bulges of the rods received in the recesses formed between the bulges of other rods, thereby closely packing the nuclear fuel. The rods are constructed of a mixture of tungsten and thorium oxide to provide high power output, high efficiency, high strength, and good machinability.

Phillips, W. M.↗
NASA NTRS1977

The NASA thermionic-conversion (TEC-ART) program

The current emphasis is on out-of-core thermionic conversion (TEC). The additional degrees of freedom offer new potentialities, but high-temperature material effects determine the level and lifetime of TEC performance: New electrodes not only raise power outputs but also maintain them regardless of emitter-vapor deposition on collectors. In addition, effective electrodes serve compatibly with hot-shell alloys. Space TEC withstands external and internal high-temperature vaporization problems, and terrestrial TEC tolerates hot corrosive atmospheres outside and near-vacuum inside. Finally, reduction of losses between converter electrodes is essential even though rather demanding geometries appear to be required for some modes of enhanced operation.

Morris, J. F.↗
NASA NTRS1977

NASA thermionic-conversion program

Technological processes in out-of-core thermionic energy conversion are described. The emphasis was on high temperature electrode materials and system engineering of converter geometries to produce practical power densities.

Morris, J. F.↗
NASA NTRS1976

The plasmatron as an advanced performance thermionic converter

A study concerned with the improvement of thermionic converter performance has shown that the plasma arc drop of the conventional arc (ignited) mode converter can be suppressed by use of an auxiliary ion source as in a plasmatron converter. However, this improved performance is now limited to low current densities and narrow interelectrode spacings because of voltage losses due to plasma resistance. An examination of plasmatron performance characteristics for both argon and cesium plasma has shown that the argon plasmatron is superior.

Hansen, L. K.↗
NASA NTRS1976

Low vapor pressure braze alloys for thermionic energy converters

Preliminary results in the use of some low-vapor-pressure braze alloys are reported; these are binary alloys of refractory metals (Th, Zr, Hf, Ru, Nb, Ir, Mo, Ta, Os, Re, W) with vapor pressures below 0.1 nanotorr at 1500 K or 10 microtorr at 2000 K. The melting point minima or eutectics of the alloys range from 1510 K to above 3000 K. Melting points and surface wetting on a Ta base are given. Results are presented on brazing of Ir, LaB6, Nb, Re, W, and ZrO2 (with 22 wt % Zr) into a Ta base or a Nb-1% Zr base. The results are applicable in electrode screening programs for thermionic cesium diodes.

Bair, V. L.↗
NASA NTRS1977

NASA Thermionic-Conversion program

NASA's program for applied research and technology (ART) in Thermionic Energy Conversion (TEC) has made worthwhile contributions in a relatively short time. Materials and designs previously prohibited by in-core nucleonics and geometrics now offer new potentialities. High-temperature material effects are crucial to the level and duration of TEC performance: New electrodes must increase and maintain power output regardless of emitter-vapor deposition on collectors. They must also serve compatibly with hot-shell alloys. And while space TEC must face high-temperature vaporization problems externally as well as internally, terrestrial TEC must tolerate hot corrosive atmospheres outside and near-vacuum inside. Furthermore, some modes for decreasing interelectrode losses appear to requisite rather demanding converter geometries to produce practical power densities.

Morris, J. F.↗
NASA NTRS1977

Thermionic converter performance with oxide collectors

Thermionic converters using a variety of metal oxide collector surfaces have been fabricated and tested. Both work function and power output data are presented and evaluated. Oxides of barium, strontium, zinc, tungsten and titanium have been incorporated into a variable spacing converter. Tungsten oxide was found to give the highest converter performance and to furnish oxygen for the emitter at the same time. Oxygenated emitters operate at reduced cesium pressure with an increase in electrode spacing. Electron spectroscopy for chemical analysis (ESCA) performed on several tungsten oxide collectors showed cesium penetration of the oxide layer, possibly forming a cesium tungstate bronze. Titanium oxide showed high performance but did not furnish oxygen for the emitter; strontium oxide, in the form of a sprayed layer, appeared to dissociate in the presence of cesium. Sprayed coatings of barium and zinc oxides produced collector work functions of about 1.3 eV, but had excessive series resistance. Lanthanum hexaboride, in combination with oxygen introduced through a silver tube, and cesium produced a low work function collector and better than average performance.

Lieb, D.↗
NASA NTRS1977

High-temperature, high-power-density thermionic energy conversion for space

Theoretic converter outputs and efficiencies indicate the need to consider thermionic energy conversion (TEC) with greater power densities and higher temperatures within reasonable limits for space missions. Converter-output power density, voltage, and efficiency as functions of current density were determined for 1400-to-2000 K emitters with 725-to-1000 K collectors. The results encourage utilization of TEC with hotter-than-1650 K emitters and greater-than-6W sq cm outputs to attain better efficiencies, greater voltages, and higher waste-heat-rejection temperatures for multihundred-kilowatt space-power applications. For example, 1800 K, 30 A sq cm TEC operation for NEP compared with the 1650 K, 5 A/sq cm case should allow much lower radiation weights, substantially fewer and/or smaller emitter heat pipes, significantly reduced reactor and shield-related weights, many fewer converters and associated current-collecting bus bars, less power conditioning, and lower transmission losses. Integration of these effects should yield considerably reduced NEP specific weights.

Morris, J. F.↗
NASA NTRS1977

Optimize out-of-core thermionic energy conversion for nuclear electric propulsion

Current designs for out of core thermionic energy conversion (TEC) to power nuclear electric propulsion (NEP) were evaluated. Approaches to improve out of core TEC are emphasized and probabilities for success are indicated. TEC gains are available with higher emitter temperatures and greater power densities. Good potentialities for accommodating external high temperature, high power density TEC with heat pipe cooled reactors exist.

Morris, J. F.↗
NASA NTRS1978

Diminiode thermionic energy conversion with lanthanum-hexaboride electrodes

Thermionic conversion data obtained from a variable gap cesium diminiode with a hot pressed, sintered lanthanum hexaboride emitter and an arc melted lanthanum hexaboride collector are presented. Performance curves cover a range of temperatures: emitter 1500 to 1700 K, collector 750 to 1000 K, and cesium reservoir 370 to 510 K. Calculated values of emitter and collector work functions and barrier index are also given.

Kroeger, E. W.↗
NASA NTRS1977

ERDA-NASA advanced thermionic technology program

Research is summarized on surface studies (work functions of different LaB6 surfaces), plasma studies, converter development (tungsten emitter, nickel collector and tungsten emitter La B6 collector), and hot shell development for using thermionic converters in the topping cycle of fossil-fuel plants.

Source record↗