Solar Thermochemical Water Splitting (STCH)
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This project was motivated primarily by the opportunity of turning photocatalysis into a cost efficient hydrogen generation method for domestic energy and chemical production, and by the need to provide detailed mechanisms of photocatalytic reactions of broad scientific and technological interest. Specifically, we focused on the development of a new technique for analysis of (photo)catalytic reaction mechanisms to guide photocatalyst design. Our approach was based on applying velocity map imaging (VMI) to surface catalyzed reactions in order to identify photocatalytic reaction products, intermediates, and relate these to photocatalyst composition, dimensions, size and other characteristics. By coupling VMI with other spectroscopic and microstructural characterization, we aimed to reveal the features that limit performance of photocatalysis. As a first step to achieve this goal, we constructed a custom VMI microscope specifically designed for investigation of surface photocatalytic reactions and validated it’s design using a photodissociatinon of MnBr(CO) 5 adsorbed on a metallic surface. Using both 230 nm and 266 nm pulsed laser excitations, we observed that there are likely three main pathways for photodissociation of Mn(CO)5Br: from the gas phase, the surface, and ejected Mn complex from the surface increasing the gas phase concentration.
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This project advances the understanding of how roof solar PV systems and battery energy storage systems (BESS) can be effectively deployed in multifamily residential buildings, a sector that has historically faced barriers due to misaligned incentives between landlords and tenants. By leveraging high-resolution building stock data and simulation tools, the research demonstrates how energy consumption patterns vary across building types, climates, and occupant characteristics, and how these variations influence the optimal sizing and operation of distributed energy resources. A key contribution is the development of a publicly accessible, web-based tool named RESIDE (Residential Energy Systems & Infrastructure Data Evaluation) that allows users to explore building energy use and evaluate solar and battery configurations without requiring specialized expertise. This significantly lowers the barrier to entry for stakeholders such as property owners, utilities, and policymakers. From a technical perspective, the project shows that integrating rooftop solar PV with battery energy storage can substantially reduce electricity costs and peak demand through strategies such as energy arbitrage and peak shaving. The modeling framework incorporates real-world constraints, including time-of-use electricity pricing and battery degradation, providing realistic and actionable insights. Economically, the results indicate that properly sized systems can deliver meaningful cost savings, improving the feasibility of energy investments in multifamily housing. More broadly, the project benefits the public by supporting the transition to affordable and reliable energy, particularly in rental multifamily housing where adoption has traditionally lagged.
Abstract not provided.
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Raw data for all figures and panels in the paper. Data is contained in Igor files. Trial version of Igor can be obtained free for 30 days from https://www.wavemetrics.com/order/order_igordownloads.htm
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Apparatus and method for analyzing an electron beam including a circular sensor disk adapted to receive the electron beam, an inner semi-circular slit in the circular sensor disk; an outer semi-circular slit in the circular sensor disk wherein the outer semi-circular slit is spaced from the first semi-circular slit by a fixed distance; a system for sweeping the electron beam radially outward from the central axis to the inner semi-circular slit and outer second semi-circular slit; a sensor structure operatively connected to the circular sensor disk wherein the sensor structure receives the electron beam when it passes over the inner semi-circular slit and the outer semi-circular slit; and a device for measuring the electron beam that is intercepted by the inner semi-circular slit and the outer semi-circular slit.
The present disclosure relates to air conditioning systems and methods. An aspect of the present disclosure is a device that includes a housing having an external surface and defining an interior volume, a heat exchanger positioned within the interior volume, a fluid line partially positioned within the interior volume, a sleeve extending from the external surface and terminating at a distal end of the sleeve, and a fluid connector. The sleeve has an outside wall spanning a length of the sleeve and defining an internal cavity, the fluid connector is positioned at or near the distal end, a portion of the fluid line is positioned within the internal cavity, and the fluid line provides a fluid connection between the heat exchanger and the fluid connector.
Manuscript to submit to Review of Scientific Instruments.
Abstract not provided.
A particle accelerator can include a first waveguide portion and a second waveguide portion. The first waveguide portion can include a first plurality of cell portions and a first iris portion that is disposed between two of the first plurality of cell portions. The first iris portion can include a first portion of an aperture such that the aperture is configured to be disposed about a beam axis. The first waveguide portion can further include a first bonding surface. The second waveguide portion can include a second plurality of cell portions and a second iris portion that is disposed between two of the second plurality of cell portions. The second iris portion can include a second portion of the aperture. The second waveguide portion can include a second bonding surface.
Conventional refrigerants, e.g. R-410A have high global warming potentials (GWP) > 1800. They are being phased out to protect the environment. The candidates to replace R-410A include R-32, R-452B, R-454B and R-466A for heat pump applications. These candidates are intended for drop-in replacement, i.e. having minimum modifications on existing systems. The paper investigates the low GWP refrigerants drop-in application via system simulations using a well-regarded, hardware-based heat pump model. A baseline heat pump having all fin-and-tube heat exchangers and a two-speed compressor was used. Cross-comparisons were made under rated conditions of ambient temperatures, compressor speeds, indoor air flow rates, respectively for cooling and heating operations. The seasonal performance indices, i.e. SEER and HSPF are presented.
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An organic light emitting diode (OLED) device includes an emissive layer having a first sublayer with a first emitter as a dopant, a second sublayer with a second emitter as a dopant, and a third sublayer with a third emitter as a dopant. The second sublayer is between the first sublayer and the third sublayer. A concentration of the first emitter in the first sublayer exceeds a concentration of the third emitter in the third sublayer, and the concentration of the third emitter in the third sublayer exceeds a concentration of the second emitter in the second sublayer.
Abstract not provided.