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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2014

Zephyr: A Landsailing Rover for Venus

With an average temperature of 450C and a corrosive atmosphere at a pressure of 90 bars, the surface of Venus is the most hostile environment of any planetary surface in the solar system. Exploring the surface of Venus would be an exciting goal, since Venus is a planet with significant scientific mysteries, and interesting geology and geophysics. Technology to operate at the environmental conditions of Venus is under development. A rover on the surface of Venus with capability comparable to the rovers that have been sent to Mars would push the limits of technology in high-temperature electronics, robotics, and robust systems. Such a rover would require the ability to traverse the landscape on extremely low power levels. We have analyzed an innovative concept for a planetary rover: a sail-propelled rover to explore the surface of Venus. Such a rover can be implemented with only two moving parts; the sail, and the steering. Although the surface wind speeds are low (under 1 m/s), at Venus atmospheric density even low wind speeds develop significant force. Under funding by the NASA Innovative Advanced Concepts office, a conceptual design for such a rover has been done. Total landed mass of the system is 265 kg, somewhat less than that of the MER rovers, with a 12 square meter rigid sail. The rover folds into a 3.6 meter aeroshell for entry into the Venus atmosphere and subsequent parachute landing on the surface. Conceptual designs for a set of hightemperature scientific instruments and a UHF communication system were done. The mission design lifetime is 50 days, allowing operation during the sunlit portion of one Venus day. Although some technology development is needed to bring the high-temperature electronics to operational readiness, the study showed that such a mobility approach is feasible, and no major difficulties are seen.

rover↗
NASA NTRS2014

Launch Load Resistant Spacecraft Mechanism Bearings Made From NiTi Superelastic Intermetallic Materials

Compared to conventional bearing materials (tool steel and ceramics), emerging Superelastic Intermetallic Materials (SIMs), such as 60NiTi, have significantly lower elastic modulus and enhanced strain capability. They are also immune to atmospheric corrosion (rusting). This offers the potential for increased resilience and superior ability to withstand static indentation load without damage. In this paper, the static load capacity of hardened 60NiTi 50-mm-bore ball bearing races are measured to correlate existing flat-plate indentation load capacity data to an actual bearing geometry through the Hertz stress relations. The results confirmed the validity of using the Hertz stress relations to model 60NiTi contacts; 60NiTi exhibits a static stress capability (approximately 3.1 GPa) between that of 440C (2.4 GPa) and REX20 (3.8 GPa) tool steel. When the reduced modulus and extended strain capability are taken into account, 60NiTi is shown to withstand higher loads than other bearing materials. To quantify this effect, a notional space mechanism, a 5-kg mass reaction wheel, was modeled with respect to launch load capability when supported on standard (catalogue geometry) design 440C; 60NiTi and REX20 tool steel bearings. For this application, the use of REX20 bearings increased the static load capability of the mechanism by a factor of three while the use of 60NiTi bearings resulted in an order of magnitude improvement compared to the baseline 440C stainless steel bearings

DellaCorte, Christopher↗
NASA NTRS2024

Land Use Control Implementation Plan

This Land Use Control Implementation Plan (LUCIP) has been prepared to inform current and potential future users of the Corrosion Atmospheric Exposure Facility (CAEF) of institutional controls that have been implemented at the site. 1 Although most areas at CAEF do not pose current unacceptable risks to human health or the environment, areas of arsenic-impacted soil exceeding the Florida Department of Environmental Protection (Florida DEP) residential soil cleanup target levels (SCTLs) have been identified. Institutional land use controls (LUCs) are necessary to prevent contact with surface and subsurface soils at the site. Controls will include periodic inspection, condition certification, and agency notification.

soil↗
NASA NTRS2012

Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing - Part 2

Evaluation of metals to predict service life of metal-based structures in corrosive environments has long relied on atmospheric exposure test sites. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions similar to those of the corrosive environment. Their reliability to correlate to atmospheric exposure test results is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated corrosion testing has yet to be universally accepted as a useful tool in predicting the long-term service life of a metal, despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard, and their use is crucial, a method that correlates timescales from accelerated testing to atmospheric exposure would be very valuable. This paper presents work that began with the characterization of the atmospheric environment at the Kennedy Space Center (KSC) Beachside Corrosion Test Site. The chemical changes that occur on low carbon steel, during atmospheric and accelerated corrosion conditions, were investigated using surface chemistry analytical methods. The corrosion rates and behaviors of panels subjected to long-term and accelerated corrosion conditions, involving neutral salt fog and alternating seawater spray, were compared to identify possible timescale correlations between accelerated and long-term corrosion performance. The results, as well as preliminary findings on the correlation investigation, are presented.

Montgomery, Eliza L.↗
NASA NTRS2011

Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing

Evaluation of metal-based structures has long relied on atmospheric exposure test sites to determine corrosion resistance in marine environments. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions of the corrosive environment. Their success for correlation to atmospheric exposure is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated laboratory testing, which often focuses on the electrochemical reactions that occur during corrosion conditions, has yet to be universally accepted as a useful tool in predicting the long term service life of a metal despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard and their use is imperative, a method that correlates timescales from atmospheric exposure to accelerated testing would be very valuable. This work uses surface chemistry to interpret the chemical changes occurring on low carbon steel during atmospheric and accelerated corrosion conditions with the objective of finding a correlation between its accelerated and long-term corrosion performance. The current results of correlating data from marine atmospheric exposure conditions at the Kennedy Space Center beachside corrosion test site, alternating seawater spray, and immersion in typical electrochemical laboratory conditions, will be presented. Key words: atmospheric exposure, accelerated corrosion testing, alternating seawater spray, marine, correlation, seawater, carbon steel, long-term corrosion performance prediction, X-ray photoelectron spectroscopy.

Montgomery, Eliza L.↗
NASA NTRS1976

Flaw growth of 7075, 7475, 7050 and 7049 aluminum alloy plate in stress corrosion environments

Marine atmosphere and laboratory stress corrosion test results on smooth and precracked specimens from 7075, 7475, 7050, and 7049 alloy plates (1.25 and 3.0-in. thick) are presented. It is shown that for a given strength level, alloys 7050-T7X and 7049-T7X have superior short-transverse stress corrosion resistance (SCR) to 7X75-T7X. At typical strength levels above the minimum, for example, SCR of these alloys is considerably better than that of 7075-T76, and approaches that of 7075-T73. Alloy 7475 maintains an advantage in the area of fracture toughness, however, because it can be thermally processed to give particularly clean microstructures. Results from precracked specimens are in good qualitative agreement with those obtained from smooth specimens. Although both specimen types are capable of distinguishing between -T6, -T76 and -T73 tempers in relatively short time periods the precracked specimen provides more information about crack growth rates.

Dorward, R. C.↗
NASA NTRS1978

Flat growth of 7075, 7475, 7050 and 7049 aluminum alloy plate in stress corrosion environments: 2-year marine atmosphere results

Marine atmospheric exposure of smooth and precracked specimens from 7075, 7475, 7050 and 7049 plates support the conclusion that for a given strength level, the short transverse stress corrosion resistance of 7050-T7X and 7049-T7X is superior to that of 7075-T7X. The threshold stress intensity (K sub Iscc) for these alloys is about 25 MPa square root m at a yield strength of about 460 MPa; the corresponding yield strength level for 7075-T7X at this SCR level is about 425 MPa. Additional tests on two lots of high-toughness 7475 plate indicate that this alloy is capable of achieving K sub Iscc values of about 35 MPa square root m at yield strengths of 400-450 MPa. Precracked specimens from all these 7XXX-series alloys are subject to self loading from corrosion product wedging. This effect causes stress corrosion cracks to continue growing at very low apparent stress intensities, and should therefore be considered a potential driving force for stress corrosion in design and materials selection.

Dorward, R. C.↗
NASA NTRS1981

Flaw growth of 7075, 7475, 7050 and 7049 aluminum alloy plate in stress corrosion environments: 4-year marine atmosphere results

After nearly 53 months of exposure to marine atmosphere, crack growth in SL DCB specimens from 7075, 7475, 7050, and 7049-T7X plate has slowed to the arbitrary 10 to the -10 power m/sec used to define threshold stress intensity. Because some specimens appear to be approaching crack arrest, the importance of self-loading from corrosion product wedging as a significant driving force for crack propagation in overaged materials is questioned. Crack length-time data were analyzed using a computer curve fitting program which minimized the effects of normal data scatter, and provided a clearer picture of material performance. Precracked specimen data are supported by the results of smooth specimen tests. Transgranular stress corrosion cracking was observed in TL DCB specimens from all four alloys. This process is extremely slow and is characterized by a striated surface morphology.

Hasse, K. R.↗
NASA NTRS1976

Five meter diameter conical furlable antenna

An investigation was made to demonstrate that a 5-meter-diameter, furlable, conical reflector antenna utilizing a line source feed can be fabricated utilizing composite materials and to prove that the antenna can function mechanically and electrically as prototype flight hardware. The design, analysis, and testing of the antenna are described. An RF efficiency of 55% at 8.5 GHz and a surface error of 0.64 mm rms were chosen as basic design requirements. Actual test measurements yielded an efficiency of 53% (49.77 dB gain) and a surface error of 0.61 mm rms. Atmospherically induced corrosion of the reflector mesh resulted in the RF performance degradation. An assessment of the antenna as compared to the current state of the art technology was made. This assessment included cost, surface accuracy and RF performance, structural and mechanical characteristics, and possible applications.

Fortenberry, J. W.↗
NASA NTRS1977

Flame and acid resistant polymide fibers

Economical process improves flame resistance and resistance to acids of polyamide fibers, without modifying colors of mechanical properties. Process improves general safety of garments and other items made from polyamide fibers and makes them suitable for applications requiring exposure to oxygen-rich atmosphere or corrosive acids. Halo-olefins are added to surface of fibers by photoadditon in sealed chamber. Process could be used with films and other forms of polyamide.

Stringham, R. S.↗
NASA NTRS1984

Thin metal film and multilayers experiment (A0138-3)

The sources of degradation of in state of the art and newly developed components and testing the usefulness of the concept of storing experiment samples in dry nitrogen under launch and space vacuum conditions during reentry mission phase were investigated. Ultraviolet (UV) and extreme ultraviolet (EUV) experiments suffer degradations during space missions of even 1 month duration. It is suggested that the degradation is due to condensation of outgassing products, followed by solar induced polymerization, however, penetrating charged particles are also known to produce volume effects. Degradation may also start immediately after manufacturing of the component due to oxidation, moisture, or chemical corrosion by atmospheric constituents such as CO2 and SO2. When the filters are used as windows for gas absorption cells or gas filters, or when they define the instrumental bandwidth by themselves. The effects of mechanical degradation by thermal cycling and/or dust may cause a dramatic impact.

Delaboudiniere, J. P.↗
NASA NTRS1951

Relation of Engine Turbine-blade Life to Stress-rupture Properties of the Alloys, Stellite 21, Hastelloy B, Cast S-816, Forged S-816, X-40, Nimonic 80, Refractaloy 26, N-155, and Inconel X

An investigation was conducted to relate the engine performance of the heat-resistant alloys, Stellite 21, Hastelloy B, cast S-816, forged S-816, X-40, Nimonic 80, Refractory 26, N-155, and Iconel X to their stress-rupture properties. The engine test consisted of the repetition of a 20-minute cycle, 15 minutes at rated speed and approximately 5 minutes at idle. The results of the investigation indicated a direct correlation between stress-rupture life and blade life for the relatively low-strength alloys. The stress-rupture life and blade life for the relatively high-strength alloys did not correlate because of the effects of the vibratory stresses and the corrosive-gas atmosphere.

ALLOYS, HEAT-RESISTING↗
NASA NTRS2002

Candidate Coatings and Dry Traction Drives for Planetary Vehicles

Robert Fusaro and Fred Oswald of the Mechanical Components Branch discussed 'Candidate Coatings and Dry Traction Drives for Planetary Vehicles'. Vehicles to be designed for exploration of planets and moons of the solar system will require reliable mechanical drives to operate efficiently. Long-term operation of these drives will be challenging because of extreme operating conditions. These extreme conditions include: very high and/or very cold temperatures, wide temperature ranges, dust, vacuum or low-pressure atmospheres, and corrosive environments. Most drives used on Earth involve oil-lubricated gears. However, due to the extreme conditions on planetary surfaces, it may not be advisable or even possible to use oil lubrication. Unfortunately, solid lubricants do not work well when applied to gears because of the high contact stress conditions and large sliding motion between the teeth, which cause wear and limit life. We believe traction drives will provide an attractive alternative to gear drives. Traction drives are composed of rollers that provide geometry more conducive to solid lubrication. Minimal slip occurs in this contact geometry and thus there is very low wear to the solid lubricant. The challenge for these solid-lubricated drives is finding materials or coatings that provide the required long-life while also providing high traction. We seek materials that provide low wear with high friction.

Fusaro, Robert↗
NASA NTRS2010

SSME - Materials and Methods for Addressing High-Pressure Hydrogen Embrittlement

From the humid, corrosion-friendly atmosphere of KSC, to the extreme heat of ascent, to the cold vacuum of space, the Space Shuttle faced one hostile environment after another. One of those harsh environments the hydrogen environment existed within the shuttle itself. Liquid hydrogen was the fuel that powered the shuttle s complex, powerful, and reusable main engine. Hydrogen provided the high specific impulse the bang per pound of fuel needed to perform the shuttle s heavy lifting duties. Hydrogen, however, was also a potential threat to the very metal of the propulsion system that used it. The diffusion of hydrogen atoms into a metal can make it more brittle and prone to cracking a process called hydrogen embrittlement. This effect can reduce the toughness of carefully selected and prepared materials. A concern that exposure to hydrogen might encourage crack growth was present from the beginning of the Space Shuttle Program, but the rationale for using hydrogen was compelling. This paper outlines the material characterization, anomaly resolution, and path to understanding of hydrogen embrittlement on superalloys through the course of the SSME program. Specific examples of nickel alloy turbine housings and single crystal turbine blades are addressed. The evolution of fracture mechanics analytical methods is also addressed.

Matejczk, Daniel↗
NASA NTRS1986

Role of molybdenum in the Na sub 2SO sub 4 induced corrosion of superalloys at high temperatures

Sodium sulfate induced corrosion of a molybdenum containing nickel-base superalloy, Udimet 700, was studied in laboratory furnace tests and in a high velocity (Mach 0.3) burner rig. The effect of SO2 content in the atmosphere on the corrosion behavior in the laboratory furnace tests was determined. Catastrophic corrosion occurs only when the melt contains MoO3 in addition to Na2SO4 and Na2MoO4. The conditions under which catastrophic corrosion occurs are identified and a mechanism is described to explain the catastrophic corrosion.

Misra, A. K.↗
NASA NTRS1987

Role of molybdenum in the Na2SO4 induced corrosion of superalloys at high temperature

Sodium sulfate induced corrosion of a molybdenum containing nickel-base superalloy, Udimet 700, was studied in laboratory furnace test and in a high velocity (Mach 0.3) burner rig. Tlhe effect of SO2 content in the atmosphere on the corrosion behavior in the laboratory furnace tests was determined. catastrophic corrosion occursonly when the melt contains MoO3 in addition to Na2SO4 and Na2MoO4. The conditions under which catastrophic corrosion occurs are identified and a mechanism is described to explain the catastrophic corrosion.

Misra, A. K.↗
NASA NTRS1989

Oxidation Of Reflectors Through Pinholes In Coatings

Impacts of particles create paths for corrosion by monatomic oxygen. Report describes experiments to determine effects of monatomic oxygen on reflectors damaged by hard particles. Applies to reflectors for solar dynamic power systems in low orbit around Earth, where neutral monatomic oxygen major constituent of atmosphere. Species highly corrosive and attacks variety of materials.

Gulino, Daniel A.↗