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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Observation of bound valence excited electronic states of deprotonated 2-hydroxytriphenylene using photoelectron, photodetachment, and resonant two-photon detachment spectroscopy of cryogenically cooled anions

Polycyclic aromatic hydrocarbons (PAHs) are common atmospheric pollutants, and they are also ubiquitous in the interstellar medium. Here, we report the study of a complex O-containing PAH anion, the deprotonated 2-hydroxytriphenylene (2-OtPh–), using high-resolution photoelectron imaging and photodetachment spectroscopy of cryogenically cooled anions. Vibrationally resolved photoelectron spectra yield the electron affinity of the 2-OtPh radical as 2.629(1) eV and several vibrational frequencies for its ground electronic state. Photodetachment spectroscopy reveals bound valence excited electronic states for the 2-OtPh– anion, with unprecedentedly rich vibronic features. Evidence is presented for a low-lying triplet state (T1) and two singlet states (S1 and S2) below the detachment threshold. Single-color resonant two-photon photoelectron spectroscopy uncovers rich photophysics for the 2-OtPh– anion, including vibrational relaxation in S1, internal conversion to the ground state of 2-OtPh–, intersystem crossing from S2 to T1, and a long-lived autodetaching shape resonance about 1.3 eV above the detachment threshold. The rich electronic structure and photophysics afforded by the current study suggest that 2-OtPh– would be an interesting system for pump–probe experiments to unravel the dynamics of the excited states of this complex PAH anion.

Chemistry↗

Characterization of Two Positional Isomers of the Cs + Gly Complex Using Two-Color, IR–IR Photobleaching of the Cryogenically Cooled Ions

Metal ion binding to amino acid residues is an important interaction motif that controls the tertiary structures of oligopeptides. Analyses of the vibrational band patterns displayed by the amino acid scaffolds are commonly used to characterize the local docking motifs. Here we carry out two-color, IR-IR photobleaching measurements to obtain isomer-selective vibrational spectra of the Cs + Gly ion-molecule complex isolated in a cryogenically cooled, radiofrequency ion trap. The distinct band patterns of two non-interconverting isomers are observed and traced to different bidentate binding motifs between Cs + and the glycine scaffold. In one isomer, the ion attaches to the oxygen atoms of the carboxyl group whereas in the other it docks to the amino nitrogen and the carbonyl oxygen. Attachment to the acid head group yields a very diffuse absorption associated the OH group engaged in a strong intramolecular H-bond that closes a 5 membered ring. Furthermore, the band assignments, rearrangement pathways and electrostatic distortion of the electron density distributions in the glycine scaffold by the proximal ion are explored with electronic structure calculations and anharmonic theory.

Infrared spectroscopy↗

Open-Mode Debonding Analysis of Curved Sandwich Panels Subjected to Heating and Cryogenic Cooling on Opposite Faces

Increasing use of curved sandwich panels as aerospace structure components makes it vital to fully understand their thermostructural behavior and identify key factors affecting the open-mode debonding failure. Open-mode debonding analysis is performed on a family of curved honeycomb-core sandwich panels with different radii of curvature. The curved sandwich panels are either simply supported or clamped, and are subjected to uniform heating on the convex side and uniform cryogenic cooling on the concave side. The finite-element method was used to study the effects of panel curvature and boundary condition on the open-mode stress (radial tensile stress) and displacement fields in the curved sandwich panels. The critical stress point, where potential debonding failure could initiate, was found to be at the midspan (or outer span) of the inner bonding interface between the sandwich core and face sheet on the concave side, depending on the boundary condition and panel curvature. Open-mode stress increases with increasing panel curvature, reaching a maximum value at certain high curvature, and then decreases slightly as the panel curvature continues to increase and approach that of quarter circle. Changing the boundary condition from simply supported to clamped reduces the magnitudes of open-mode stresses and the associated sandwich core depth stretching.

Ko, William L.↗

Feasibility of Passive Cryogenic Cooling for Solar Powered Outer Planetary Missions

Spacescience instruments with cooled detectors require innovative thermal cooling solutions to meet science objectives. Detector sensitivity increases with decreasing temperature and low optics temperatures are often needed to reduce background photon noise. As the detector spectral range coverage increases from the visible to far infrared also requires lower detector temperatures. Increasing demands on detector performance lead to larger format detectors and higher refresh rates resulting in significant increases in power dissipation. Passive coolers rely on emissive power of radiating surfaces to reject heat to space. As the operating temperature requirements of detectors and optics decreases, the ability to reject heat to space becomes increasingly more difficult. Reducing both cooler internal parasitic and external environmental heat loads and maximizing the passive cooler field of view to space will enhance performance. While instrument heat loads and passive cooler parasitic heat loads are controlled by instrument designers, the external environmental heat loads and cooler views to space are governed by spacecraft and mission designers. Solar powered planetary missions require large arrays to generate sufficient power for spacecraft subsystems and payloads. Two or more solar array wings with cell coverage of the order of 40-80 m2 are often needed to generate sufficient power at 3-6 AU. These large arrays are typically symmetrically configured and can extend tens of meters. The arrays along with spacecraft attitude requirements near the target planetary bodies pose significant challenges for passive cooling at large AU. It is very difficult to provide a clear field of view to space for the cooler with large articulating arrays while keeping solar loads from impinging the cooler and meeting the spacecraft attitude science pointing requirements. This is counter intuitive because of the decreasing solar flux and colder planetary body temperatures at large AU. This paper presents the challenges and opportunities of passive cryogenic cooling versus active cooling for solar powered planetary missions.

Rodriguez, Jose I.↗

Dielectric-loaded waveguide circulator for cryogenically cooled and cascaded maser waveguide structures

A dielectrically loaded four port waveguide circulator is used with a reflected wave maser connected to a second port between first and third ports to form one of a plurality of cascaded maser waveguide structures. The fourth port is connected to a waveguide loaded with microwave energy absorbing material. The third (output signal) port of one maser waveguide structure is connected by a waveguide loaded with dielectric material to the first (input) port of an adjacent maser waveguide structure, and the second port is connected to a reflected wave maser by a matching transformer which passes the signal to be amplified into and out of the reflected wavemaser and blocks pumping energy in the reflected wave maser from entering the circulator. A number of cascaded maser waveguide structures are thus housed in a relatively small volume of conductive material placed within a cryogenically cooled magnet assembly.

Clauss, R. C.↗

Advanced passive radiator for spaceborne cryogenic cooling

A novel design to improve the cooling capability of spaceborne cryogenic passive radiators is described. The design is based on the use of lightweight angled radiation shields, low-conductance structural supports, and a separate detachable launch-support system to reduce the parasitic heat leaks from the warm spacecraft to the cold radiator. The effectiveness of this design is demonstrated by thermal-vacuum-chamber experiments which indicate that the angled-radiation-shield assembly has an effective emittance that is an order of magnitude lower than that of the best multilayer insulation used in flight. Performance predictions based on the experiments and analytical model indicate that an advanced passive-radiator design based on this technology would be between 10 and 57% of the size and 10 and 36% of the mass of the best state-of-the-art passive radiators and would make lower temperatures (< 60 K) and larger heat loads practical. The cooling requirements of many new spaceborne instruments could be accommodated by application of this new passive-radiator design.

Steven Bard↗

On 32-GHz cryogenically cooled HEMT low-noise amplifiers

The cryogenic noise temperature performance of a two-stage and a three-stage 32 GHz High Electron Mobility Transistor (HEMT) amplifier was evaluated. The amplifiers employ 0.25 micrometer conventional AlGaAs/GaAs HEMT devices, hybrid matching input and output microstrip circuits, and a cryogenically stable dc biasing network. The noise temperature measurements were performed in the frequency range of 31 to 33 GHz over a physical temperature range of 300 K down to 12 K. Across the measurement band, the amplifiers displayed a broadband response, and the noise temperature was observed to decrease by a factor of 10 in cooling from 300 K to 15 K. The lowest noise temperature measured for the two-stage amplifier at 32 GHz was 35 K with an associated gain of 16.5 dB, while the three-stage amplifier measured 39 K with an associated gain of 26 dB. It was further observed that both amplifiers were insensitive to light.

Bautista, J. J.↗

32-GHz cryogenically cooled HEMT low-noise amplifiers

The cryogenic noise temperature performance of a two-stage and a three-stage 32 GHz high electron mobility transistor (HEMT) amplifier was evaluated. The amplifiers employ 0.25 micrometer conventional AlGaAs/GaAs HEMT devices, hybrid matching input and output microstrip circuits, and a cryogenically stable dc biasing network. The noise temperature measurements were performed in the frequency range of 31 to 33 GHz over a physical temperature range of 300 K down to 12 K. Across the measurement band, the amplifiers displayed a broadband response, and the noise temperature was observed to decrease by a factor of 10 in cooling from 300 to 15 K. The lowest noise temperature measured for the two-stage amplifier at 32 GHz was 35 K with an associated gain of 16.5 dB, while the three-stage amplifier measured 39 K with an associated gain of 26 dB. It was further observed that both amplifiers were insensitive to light.

Duh, K. H. George↗

Cryogenic cooling study for the advanced limb scanner

The cryogenic operating requirements for a VM refrigerator to be used for detector cooling of the advanced limb scanner (ALS) instrument are defined. Determination of these requirements include consideration of mission and environmental constraints. Based on the operating requirements a detailed refrigerator design and performance analysis is conducted resulting in an optimized VM refrigerator conceptual design. The cooler-instrument-spacecraft interfaces are evaluated resulting in recommendations as to the best approach and most effective concepts resulting in simple and satisfactory interfaces. A preliminary implementation plan and schedule describing the general tasks required to develop, design, manufacture, test, and deliver three VM coolers and required support equipment to support an ALS flight experiment are presented. The result of this effort shows that existing VM cooler technology is sufficient to satisfy ALS mission requirements and schedules.

Russo, S. C.↗

Preliminary design of the cryogenic cooled limb scanning interferometer radiometer (CLIR), phase 2

A cryogenic system to be utilized with a mounted pointing system is designed. The analysis indicates that the resulting design is significantly heavier than previous design due to the increased diameter of the system, resulting in greater tank and vacuum enclosure weights. Additional weight is also required in the area where the payload is attached to the pointing system in order to provide additional stiffness to the payload. The vacuum shell required to enclose the instrument is shorter and therefore an attendant reduction in instrument package weight would be expected. The primary resonance of the cooler instrument package occurs at 21 Hz, a mode in which the flexibility of the vacuum shell allows motion of the cryogen tank and instrument, and which can be increased by additional stiffening in the region of the pointing system vacuum shell connection at the cost of additional weight. The second resonance at 59 Hz is due to vibration of the helium tank on the fiberglass support tubes. The parasitic heat load can be reduced to 0.28 W by the utilization of a sandwich support tube structure in place of the monocoque structure assumed in the design.

Source record↗

A study of central cryogenic cooling system for the comet rendezvous spacecraft

Several science instruments required temperatures between 100 K and 120 K on a proposed Halley Flyby, Tempel-2 Rendezvous Mission. Significant features of the thermal environment are a large variation in heliocentric as well as comet distance, very large solar panels for a Solar Electric Propulsion stage, and the comet dust environment. The best cooling is achieved by one central radiative cooler connected by insulated cryogenic heat pipes to the instruments. The conceptual design is of a single-stage rectangular shielded radiator deployed on a boom some distance from the spacecraft bus and solar panels. Thermal modeling determined sensitivity to solar and comet distance and was used to optimize cooler geometry.

Salazar, R. P.↗

Temperature control of silica mirrors for cryogenically-cooled telescopes in space

The SIRTF (Space Infrared Telescope Facility) optical subsystem, including the primary mirror, has been modeled using lumped-parameter techniques and a thermal and cryogenic transient analysis program developed previously. Since silica mirrors have been shown to have significantly less distortion due to cryogenic cooldown, a silica primary mirror of approximately 1 m diameter is being considered. Thermal responses to variations in aperture heat load and heat sink temperature have been explored. Calculations have been made of system noise components from primary mirror spatial and temporal temperature variations. Background-limited infrared observations can be made at wavelengths out to 200 micrometers. Mirror thermal performance with and without copper wires for cooling is also considered.

Melugin, R. K.↗

Using Liquid Natural Gas Fuel to Cryogenically Cool and Enhance a Hybrid Electric Aircraft Power System

A previous system study identified significant increases in range and number of urban air mobility (UAM) missions by replacing the all battery power system of a notional UAM vehicle with an advanced diesel hybrid using conventional diesel or liquid natural gas (LNG) fuels (at constant vehicle design gross weight). Some benefits were realized using the LNG's cryogenic properties to reduce some electrical component losses and cooling requirements. Significant questions were raised concerning volume and thermal management considerations for all studied systems. The notional, baseline vehicle was a hybrid helicopter / airplane design capable of vertical take-off and landing (VTOL), balancing high cruise efficiency with reasonable hover capability. A subsequent power system assessment using the same notional vehicle and mission was performed that identified increased volume and power requirements for the active cooling required. The cooling airflow could also generate additional drag on the vehicle during operation. For the notional vehicle studied, the additional volume identified by the subsequent study would not affect vehicle mold line and therefore drag. However, the additional drag from cooling airflow and the power to circulate it as needed would impact power system and vehicle mission performance. Vehicle and mission models were updated and rerun. Updated results still indicated significant benefits in range and number of UAM missions, but reduced the benefit by 12-15%. Hold time for the hybrid systems also generally increased a few minutes because of reduced power available for charging from the power for required cooling flows. Vehicle weights, thermal loads, and cooling airflows from the updated analyses were similar to previous results.

systems analysis↗

Experimental investigation of contamination prevention techniques for a cryogenically cooled telescope in earth-orbit

A one-tenth scale model of the Shuttle Infrared Telescope Facility (SIRTF) was constructed to experimentally investigate the feasibility of a helium purge system to reduce contamination on cryogenic surfaces. The on-orbit ambient contaminant environment was simulated with ion beams of N2(+), O(+) and H2O(+). Helium was injected into the model telescope at the simulated plane of the primary optics using two techniques: a) porous plug, b) nozzle. Helium flow rates and telescope pressures were varied to determine the purge effectiveness against potential contaminants. Based on the subscale results, a 90% reduction in O, N2, and H2O at the primary optics of the SIRTF can be obtained using 20 K helium with a pressure of .00001 torr and a flow rate of less than 0.1 g/s.

Hetrick, M. A.↗

New Technique for Cryogenically Cooling Small Test Articles

Convective heat removal techniques to rapidly cool small test articles to Earth-Moon L2 temperatures of 77 K were accomplished through the use of liquid nitrogen (LN2). By maintaining a selected pressure range on the saturation curve, test articles were cooled below the LN2 boiling point at ambient pressure in less than 30 min. Difficulties in achieving test pressures while maintaining the temperature tolerance necessitated a modification to the original system to include a closed loop conductive cold plate and cryogenic shroud

Rodriquez, Karen M.↗

A cryogenically cooled photofragment fluorescence instrument for measuring stratospheric water vapor

An instrument developed for high-resolution daytime measurements of water vapor in the stratosphere using the technique of photofragment fluorescence is examined. A detailed description of all aspects of the instrument, as well as the results of its first two flights, are presented. The main areas of concern were optical baffling, cryogen transfer, water vapor measurement without contamination, and a dual path absorption measurement. Results of the second flight test indicate that the problems of instrument and gondola contamination, identified in the first flight test, were solved. A signal-to-noise ratio of about 50:1 for 10 sec of averaging throughout the stratosphere is achieved, as well as an altitude resolution of better than 100 m.

Weinstock, Elliot M.↗