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At least 55 records · Page 3

Direct measurement of fluorocarbon radicals in the thermal destruction of perfluorohexanoic acid using photoionization mass spectrometry

Thermal destruction is a critical cornerstone of addressing the rampant contamination of natural resources with per- and polyfluoroalkyl substances (PFAS). However, grave concerns associated with stack emissions from incineration exist because mechanistic studies have thus far relied on ex situ analyses of end products and theoretical calculations. Here, we used synchrotron-based vacuum ultraviolet photoionization mass spectrometry to study the pyrolysis of a representative PFAS-perfluorohexanoic acid-and provide direct evidence of fluorocarbon radicals and intermediates. A key reaction pathway from perfluorocarboxylic acids to ketenes via acyl fluorides is proposed. We furthermore propose CF2/CF3 radical-centered pyrolysis mechanisms and explain their roles in the formation of other products that may form in full-scale incinerators. These results have not only unveiled the role of radicals and intermediates in thermal PFAS decomposition and recombination mechanisms but also provide unique insight into improving the safety and viability of industrial PFAS incineration.

Xu, Ming-Gao↗

Near-infrared spectra and molar absorption coefficients of trivalent lanthanides dissolved in molten LiCl–KCl eutectic

Determining the concentration of the dissolved lanthanide species in LiCl–KCl eutectic salt is important to the development of pyrochemical reprocessing of used nuclear fuel. In this process, lanthanide fission products are found dissolved in the electrorefiner electrolyte in their trivalent oxidation state. The presence of dissolved trivalent lanthanides increases the liquidus temperature of the electrolyte mixture and can lead to the formation of insoluble oxide or oxychloride phases and must therefore be continuously monitored and controlled during the operation. Absorbance spectroscopy is a promising method for continuous measurement of the concentration of lanthanides and other elements dissolved in the electrolyte. The absorption of light by elements is linearly proportional to the concentration of the element for relatively dilute solutions according to the Beer-Lambert law. Although measurement of the absorption of ultraviolet and visible range light by lanthanides in LiCl–KCl eutectic molten salt have been explored previously, near infrared (NIR) absorption spectroscopy has received far less attention. It may, however, provide a better analytical signal when insoluble phases are present due to less Raleigh scattering compared to shorter wavelength radiation. Additionally, it may allow for concentration determination for certain elements using NIR absorption features where UV and visible range features are overlapping with features from other species. In this study, we report the UV–Vis–NIR spectra of the trivalent lanthanide chlorides of neodymium, samarium, and dysprosium in LiCl–KCl eutectic. Molar absorption coefficients are reported for analytically useful absorption maxima, with a focus on the molar absorption coefficients for NIR absorption maxima which have not been reported previously. Additionally, we observe a NIR-range absorption band of Nd3+ which was previously predicted but never experimentally observed. Here, we compare the calculated crystal field levels to the newly observed absorbance band and find them to be in good agreement with previous predictions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A solvable quantum field theory with asymptotic freedom in (3+1) dimensions

Recently, Ai, Bender and Sarkar gave a prescription on how to obtain [Formula: see text]-symmetric field theory results from an analytic continuation of Hermitian field theories. We perform this analytic continuation for the massless (critical) [Formula: see text] model with quartic interaction in (3+1) dimensions. In the large-[Formula: see text] limit, this theory is exactly solvable, and has negative [Formula: see text]-function in the ultraviolet, and a stable bound state in the infrared. The coupling diverges at a scale [Formula: see text], but can be continued into the far infrared. At finite temperature, the theory exhibits two phases separated by a second-order phase transition near [Formula: see text].

Physics↗

Physical and Visual Evaluation of Filters for Direct Observation of the Sun and the International Standard ISO 12312-2:2015

We investigated the compliance of 43 commercially available solar filters (eclipse glasses) with the ISO 12312-2:2015 standard by measuring their spectral transmittances (280–2000 nm) and calculating their luminous, solar ultraviolet A, ultraviolet B, and infrared (IR) transmittances. We also evaluated the filters for usability by observing the full midday Sun and rating the view on a seven-point balanced scale, from “far too dark, details seen only with great difficulty” to “far too light, uncomfortable to view the Sun.” The mean ratings of two observers, one experienced and one inexperienced in solar observing, differed by 0.28 (95% confidence interval of the mean = 0.26). The inexperienced observer tended to be less accepting of high transmittances. All 43 solar filters complied with the UV and IR requirements. Eighteen filters passed the luminous transmittance requirements, and 24 were borderline too light or too dark. Seven of the 15 solar filters with a luminous transmittance darker than the requirement were rated as acceptable. One filter that passed and another that was borderline too light were rated as too light or far too light. The ISO 12312-2 limits derive from welding filter standards and do not represent an appropriate evidence base for direct solar viewing. This work provides the evidence base for a maximum 0.0012% and a minimum 0.00004% luminous transmittance for solar filters. The results of this study also support the use of welding filters between shades 12 and 16. Lighter welding filters are more acceptable than solar filters of the same luminous transmittance.

79 ASTRONOMY AND ASTROPHYSICS↗

BOSS quasar outflows traced by C iv

ABSTRACT We investigate possible factors that drive fast quasar outflows using a sample of 39 249 quasars at median redshift 〈z〉 ≈ 2.17. Unique to this study, the quasar redshifts are re-measured based on the Mg ii emission line, and explore unprecedented outflow velocities (>6000 km s−1), while maintaining statistical significance. We measure reliable C iv blueshifts for 1178 quasars with velocities >2500 km s−1. From those, 255(13) quasars have blueshifts above 4000(6000) km s−1, with the highest C iv velocity ≈7000 km s−1. Several correlations are observed, where higher C iv blueshifts in general are in quasars with broader, weaker C iv emission profiles, weak He ii emission, larger Eddington ratios, and bluer ultraviolet (UV) continuum slope across the rest-frame UV to near-infrared. Analysis reveals two primary factors contributing to faster outflows: higher Eddington ratios, and softer far-UV continuum (hν >24.6 eV). We find supporting evidence that radiative line driving may generate extreme outflow velocities, influenced by multiple factors as suggested by the aforementioned correlations. This evidence highlights the importance of considering a multidimensional parameter space in future studies when analyzing large C iv blueshifts to determine the fundamental causes of outflows.

Gillette, Jarred (ORCID:0000000185284839)↗

A Statistical Search for Star–Planet Interaction in the Ultraviolet Using GALEX

Most (∼82%) of the over 4000 confirmed exoplanets known today orbit very close to their host stars, within 0.5 au. Planets at such small orbital distances can result in significant interactions with their host stars, which can induce increased activity levels in them. In this work, we have searched for statistical evidence for star–planet interactions in the ultraviolet (UV) using the largest sample of 1355 Galaxy Evolution Explorer (GALEX) detected host stars with confirmed exoplanets and making use of the improved host-star parameters from Gaia DR2. From our analysis, we do not find any significant correlation between the UV activity of the host stars and their planetary properties. We further compared the UV properties of planet host stars to that of chromospherically active stars from the RAdial Velocity Experiment (RAVE) survey. Our results indicate that the enhancement in chromospheric activity of host stars due to star–planet interactions may not be significant enough to reflect in their near- and far-UV broadband flux.

79 ASTRONOMY AND ASTROPHYSICS↗

Phase-matching analysis in high-order harmonic generation with nonzero orbital angular momentum Laguerre-Gaussian beams

Through high-order harmonic generation driven by intense ultrashort vortex infrared or midinfrared lasers, a nonzero orbital angular momentum can be imprinted onto extreme ultraviolet (XUV) or soft-x-ray (SXR) light pulses. Here we simulate the generation of vortex XUV harmonics in the gas medium as well as their propagation in vacuum till reaching the far field. In this work, we find that the intensity and phase of generated high harmonics are very sensitive to the position of gas jet with respect to the laser focus. The topological charge of the $\textit{q}$th harmonic is found to be $\textit{q}$ times that of the driving Laguerre-Gaussian beam. Each harmonic in the far field appears as a single ring in the transverse plane with an invariant diameter which is scalable with the fundamental topological charge only when the gas jet is placed after the laser focus. The underlying phase-matching mechanism is analyzed by examining the spatial map of the coherence length and by calculating the evolution of harmonic emission in the medium. We anticipate this work to stimulate interest in generating intense vortex XUV or SXR attosecond pulses for probing dynamics of molecules where special molecular features are difficult to be detected with linear or circular XUV or SXR pulses.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Femtosecond Core-Level Spectroscopy Reveals Involvement of Triplet States in the Gas-Phase Photodissociation of Fe(CO) 5

Excitation of iron pentacarbonyl [Fe(CO) 5 ], a prototypical photocatalyst, at 266 nm causes the sequential loss of two CO ligands in the gas phase, creating catalytically active, unsaturated iron carbonyls. Despite numerous studies, major aspects of its ultrafast photochemistry remain unresolved because the early excited-state dynamics have so far eluded spectroscopic observation. This has led to the long-held assumption that ultrafast dissociation of gas-phase Fe(CO) 5 proceeds exclusively on the singlet manifold. Herein, we present a combined experimental–theoretical study employing ultrafast extreme ultraviolet transient absorption spectroscopy near the Fe M 2,3 -edge, which features spectral evolution on 100 fs and 3 ps time scales, alongside high-level electronic structure theory, which enables characterization of the molecular geometries and electronic states involved in the ultrafast photodissociation of Fe(CO) 5 . We assign the 100 fs evolution to spectroscopic signatures associated with intertwined structural and electronic dynamics on the singlet metal-centered states during the first CO loss and the 3 ps evolution to the competing dissociation of Fe(CO) 4 along the lowest singlet and triplet surfaces to form Fe(CO) 3 . Calculations of transient spectra in both singlet and triplet states as well as spin–orbit coupling constants along key structural pathways provide evidence for intersystem crossing to the triplet ground state of Fe(CO) 4 . Finally, our work presents the first spectroscopic detection of transient excited states during ultrafast photodissociation of gas-phase Fe(CO) 5 and challenges the long-standing assumption that triplet states do not play a role in the ultrafast dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Melt-grown semi-insulating Mn:β-Ga 2 O 3 single crystals exhibiting unique visible absorptions and luminescence

In this study, several acceptor dopants have been explored in β-Ga 2 O 3 to produce semi-insulating substrates and epitaxial films. Fe and Mg make up the majority of research thus far; however, other transition metals provide potential alternatives for optimized performance. β-Ga 2 O 3 bulk single crystals were grown by the Czochralski and vertical gradient freeze methods with a nominal dopant concentration of 0.25 at. % Mn. Ultraviolet-visible-near infrared spectroscopy and photoluminescence revealed polarization- and orientation-dependent optical absorptions (pleochroism) coupled with an orange luminescence. All samples were electrically insulating, on the order of 10 9 –10 11 ohm cm at room temperature, indicative of acceptor doping. Actual dopant concentrations of the intentionally doped transition metal and background impurities were determined via glow discharge mass spectrometry, indicating the macroscale segregation behavior. High-temperature resistivity measurements indicated an experimental acceptor level of 1.7 ± 0.2 eV. Hydrogenation of samples resulted in an increase in the orange luminescence and O–H stretching modes observable in the infrared spectrum. Density functional theory calculations were performed to determine the likely site-occupancy and acceptor level of Mn in the bandgap.

36 MATERIALS SCIENCE↗

Effective Selective Area Doping for GaN Vertical Power Transistors Enabled by Innovative Materials Engineering

GaN vertical power transistors have emerged as promising candidates for future high efficiency high power electronic applications, with the potential to outperform conventional GaN lateral power devices in terms of power, breakdown, and avalanche characteristics. However, the development of current GaN vertical power transistors is seriously hindered by the poor materials performance of selective area doped p-n junctions. A mechanistic understanding of these fundamental materials issues is essential in order to achieve high performance selective area doped p-n junctions and consequently to advance the GaN vertical power transistor technology. To address this challenge, we carried out a comprehensive research program that advance fundamental knowledge in the selective area doping for GaN materials, and which will lead to the development of high performance GaN vertical power transistors. First, we developed innovative fabrication processes, including novel surface etching, surface passivation, and metalorganic chemical vapor deposition (MOCVD) growth, which provided enhanced opportunities for solving the unique challenges of selective area doping in GaN materials. Second, we performed a fundamental materials study using powerful characterization methods including transmission electron microscopy (TEM), ultraviolet (UV-), x-ray and angle-resolved photoelectron spectroscopy (UPS/XPS/ARPES), electron holography, and cathodoluminescence (CL); Third, we investigated several related issues, including Mg incorporation, polarization effects in carrier transport, and non-ideal material effects, which have rarely been explored so far. At the end of this project, we successfully demonstrated (1) fundamental understanding of selective area etching, regrowth, and doping of GaN, and associated knowledge on defects, interface, and breakdown properties. (2) Effective etch and regrowth processing recipes to achieve etch/regrowth GaN p-n diodes with very low leakage of 3.5 nA at 600 V, which meets the ARPA-E target. (2) High performance vertical GaN p-n didoes and vertical junction termination extension (JTE) devices with breakdown voltage of ~ 2 kV, and breakdown electric field of ~ 3.5 MV/cm, which are close to the performance limit of GaN. The successful outcome has resulted in new fundamental understandings in the selective area doping and regrowth process for GaN, which will lead to groundbreaking GaN vertical transistors for high performance next generation power electronics.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Hubble Space Telescope UV and Hα Measurements of the Accretion Excess Emission from the Young Giant Planet PDS 70 b

Recent discoveries of young exoplanets within their natal disks offer exciting opportunities to study ongoing planet formation. In particular, a planet’s mass accretion rate can be constrained by observing the accretion-induced excess emission. So far, planetary accretion is only probed by the Hα line, which is then converted to a total accretion luminosity using correlations derived for stars. However, the majority of the accretion luminosity is expected to emerge from hydrogen continuum emission, and is best measured in the ultraviolet (UV). In this paper, we present HST/WFC3/UVIS F336W (UV) and F656N (Hα) high-contrast imaging observations of PDS 70. Applying a suite of novel observational techniques, we detect the planet PDS 70 b with signal-to-noise ratios of 5.3 and 7.8 in the F336W and F656N bands, respectively. This is the first time that an exoplanet has been directly imaged in the UV. Our observed Hα flux of PDS 70 b is higher by 3.5σ than the most recent published result. However, the light curve retrieved from our observations does not support greater than 30% variability in the planet’s Hα emission in six epochs over a five month timescale. We estimate a mass accretion rate of 1.4±0.2×10{sup −8}M{sub Jup} yr{sup −1}. Hα accounts for 36% of the total accretion luminosity. Such a high proportion of energy released in line emission suggests efficient production of Hα emission in planetary accretion, and motivates using the Hα band for searches of accreting planets. These results demonstrate HST/WFC3/UVIS’s excellent high-contrast imaging performance and highlight its potential for planet formation studies.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The electronic set-up for the scintillation light detection system of ICARUS-SBN at Fermilab

The ICARUS-T600 Liquid Argon (LAr) Time Projection Chamber (TPC) is presently used as the far detector of the Short Baseline Neutrino (SBN) program at Fermilab (USA) to search for a possible sterile neutrino signal with the Booster Neutrino Beam (BNB). We discuss a light detection system, based on 360 Hamamatsu R5912-MOD Photo-Multiplier Tubes (PMTs), which has been realized to detect vacuum ultraviolet (VUV) photons produced after the passage of ionizing particles in LAr. High performance electronics allows recording of the PMT signals and provides a fast discrimination for the exploitation of the scintillation light for trigger purposes. This system is fundamental for the TPC operation, contributing to the trigger system and for the 3D reconstruction of events.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Non-fullerene acceptor organic photovoltaics with intrinsic operational lifetimes over 30 years

Abstract Organic photovoltaic cells (OPVs) have the potential of becoming a productive renewable energy technology if the requirements of low cost, high efficiency and prolonged lifetime are simultaneously fulfilled. So far, the remaining unfulfilled promise of this technology is its inadequate operational lifetime. Here, we demonstrate that the instability of NFA solar cells arises primarily from chemical changes at organic/inorganic interfaces bounding the bulk heterojunction active region. Encapsulated devices stabilized by additional protective buffer layers as well as the integration of a simple solution processed ultraviolet filtering layer, maintain 94% of their initial efficiency under simulated, 1 sun intensity, AM1.5 G irradiation for 1900 hours at 55 °C. Accelerated aging is also induced by exposure of light illumination intensities up to 27 suns, and operation temperatures as high as 65 °C. An extrapolated intrinsic lifetime of > 5.6 × 10 4 h is obtained, which is equivalent to 30 years outdoor exposure.

14 SOLAR ENERGY↗

Attosecond photoionization delays in the vicinity of molecular Feshbach resonances

Temporal delays extracted from photoionization phases are currently determined with attosecond resolution by using interferometric methods. Such methods require special care when photoionization occurs near Feshbach resonances due to the interference between direct ionization and autoionization. Although theory can accurately handle these interferences in atoms, in molecules, it has to face an additional, so far insurmountable problem: Autoionization is slow, and nuclei move substantially while it happens, i.e., electronic and nuclear motions are coupled. Here, we present a theoretical framework to account for this effect and apply it to evaluate time-resolved and vibrationally resolved photoelectron spectra and photoionization phases of N 2 irradiated by a combination of an extreme ultraviolet (XUV) attosecond pulse train and an infrared pulse. We show that Feshbach resonances lead to unusual non–Franck-Condon vibrational progressions and to ionization phases that strongly vary with photoelectron energy irrespective of the vibrational state of the remaining molecular cation.

74 ATOMIC AND MOLECULAR PHYSICS↗

Pre-Ionization Controlled Laser Plasma Formation for Ignition Applications (Final Scientific/Technical Report)

This report consists of three grand funded papers. Abstracts for each follow. 1) In this work, we present experimental and modeling studies of air pre-ionization using ultraviolet (UV) laser pulses and its effect on laser breakdown of an overlapped near-infrared (NIR) pulse. Experimental studies are conducted with a 266 nm beam (fourth harmonic of Nd:YAG) for UV pre-ionization and an overlapped 1064 nm NIR beam (fundamental of Nd:YAG), both having pulse duration of 10 ns. Results show that the UV beam produces a pre-ionized volume which assists in breakdown of the NIR beam, leading to reduction in NIR breakdown threshold by factor of >2. Numerical modeling is performed to examine the ionization and breakdown of both beams. The modeled breakdown threshold of the NIR, including assist by pre-ionization, is in reasonable agreement with the experimental results. 2) The present contribution compares the energy absorption, optical emission, temperature, and fluid dynamics of ultraviolet (UV) λ = 266 nm and near infrared (NIR) λ = 1064 nm nanosecond laser induced plasmas in ambient air. For UV pulses at the conditions studied, energy absorption by the plasmas increases relatively gradually with laser pulse energy starting at delivered energy of E~8 mJ. Corresponding measurements of plasma luminosity show that the absorption of UV radiation does not necessarily result in visible plasma emission. For the NIR induced plasmas, the energy absorption profile is far more abrupt and begins at ~55 mJ. In contrast with UV, the absorption of NIR radiation is always accompanied by intense optical emission. The temperatures of both types of plasma have been measured with Rayleigh scattering thermometry (at times after the Thomson signal sufficiently diminishes). The UV plasmas can attain a wider range of temperatures, including lower temperatures, depending on the pulse energy (e.g., T ~400–2000K for E ~7–35 mJ at Δt = 10 μs after the pulse) while the NIR plasmas show only hotter temperatures (e.g., T ~ 12 000 K for E = 75 mJ at Δt = 10 μs after the pulse) as is consistent with the literature. Differences in the fluid dynamics for UV versus NIR pulses are shown with Schlieren imaging. In this work, the contrast in the UV and NIR plasma threshold behavior is attributed to differing roles of avalanche ionization and multiphoton ionization as is also illustrated by a simple numerical model. 3) The present contribution examines the impact of plasma dynamics and plasma-driven fluid dynamics on the flame growth of laser ignited mixtures and shows that a new dual-pulse scheme can be used to control the kernel formation process in ways that extend the lean ignition limit. We perform a comparative study between (conventional) single-pulse laser ignition (λ = 1064 nm) and a novel dual-pulse method based on combining an ultraviolet (UV) pre-ionization pulse (λ = 266 nm) with an overlapped near-infrared (NIR) energy addition pulse (λ = 1064 nm). We employ OH* chemiluminescence to visualize the evolution of the early flame kernel. For single-pulse laser ignition at lean conditions, the flame kernel separates through third lobe detachment, corresponding to high strain rates that extinguish the flame. In this work, we investigate the capabilities of the dual-pulse to control the plasma-driven fluid dynamics by adjusting the axial offset of the two focal points. In particular, we find there exists a beam waist offset whereby the resulting vorticity suppresses formation of the third lobe, consequently reducing flame stretch. With this approach, we demonstrate that the dual-pulse method enables reduced flame speeds (at early times), an extended lean limit, increased combustion efficiency, and decreased laser energy requirements.

Mechanical engineering↗

Advanced Photon Acceleration Schemes for Tunable XUV/Soft X-Ray Sources

We report on the advances made under the purview of DOE award number DE-SC0019135 that was active during the period: 09/01/2018–08/31/2021. The grant investigated the application of a “flying focus” to the problem of photon acceleration—in which a dynamic refractive index gradient is used to continuously upshift a probe beam’s frequency. Codes were written to describe the creation of ionization waves of arbitrary velocity (IWAVs) for use as a photon-accelerating medium, as well as the behavior of a witness pulse residing in said medium. Experiments first verified the spatiotemporal control over laser intensity provided by a chromatic flying focus, then used that ability to produce small-diameter IWAVs in the far-field with the expected dynamics, and finally demonstrated even further flexibility by producing large-diameter IWAVs in the laser quasi-far-field that maintained the beneficial dynamics. Multiple innovative diagnostics—spectrally resolved Schlieren and spectrally resolved interferometry—were pioneered in order to diagnose the IWAVs. For IWAV production in the laboratory, however, beam quality was identified as a key limitation in the quasi-far-field. Since the original chromatic flying focus was found to result in relatively long (ps duration) intensity peaks, which could limit some applications including photon acceleration, additional techniques were invented to provide similar spatiotemporal control while also retaining ultrashort intensity peaks. While simulations have identified several interesting regimes for photon acceleration—first predicting the upshift of a counterpropagating witness pulse from the optical to the extreme ultraviolet in less than 1 cm, and later obtaining similar shifts in less than 100 μm in a simpler self-seeded configuration—experimental demonstration is left for future work.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Design of a Nanophotonic Hybrid Coupler

This project aims to design and simulate a nanophotonic hybrid coupler for detecting vacuum ultraviolet (VUV) light with higher efficiency. VUV light is of significant interest because of its applications ranging from high energy physics to space science and electronic industry. However, current VUV photodetectors have very low efficiencies because most materials absorb in the VUV region (100-200 nm). To address this challenge, I have designed a plasmonic-dielectric coupler with wavelength shifting properties, enabling high Purcell enhancement and far-field confinement. The coupler consists of a cylindrical cSi resonator on top of a thin ZnO layer, and Ag and SiO2 are used as substrates. Simulations are done using the finite-difference time domain method to solve Maxwell’s equations, and specifically with Meep and Lumerical. The effectiveness of the coupler is characterized by the Purcell factor and far-field radiation. The Purcell factor reaches a maximum near 390 nm and is in the o rder of 10^4. Furthermore, the coupler also allows partial control of the directionality of the far-field radiation. With the presence of the resonator, the radiation is directed towards the coupled metalens. Overall, our design combines the advantages of plasmonic and dielectric couplers, along with the intrinsic wavelength shifting properties of materials to enhance VUV detection significantly, and such a device can be used in, for example, the DUNE project.

Zhou, Jiayang↗

Estimating the Ultraviolet Emission of M Dwarfs with Exoplanets from Ca ii and Hα

M dwarf stars are excellent candidates around which to search for exoplanets, including temperate, Earth-sized planets. To evaluate the photochemistry of the planetary atmosphere, it is essential to characterize the UV spectral energy distribution of the planet’s host star. This wavelength regime is important because molecules in the planetary atmosphere such as oxygen and ozone have highly wavelength-dependent absorption cross sections that peak in the UV (900–3200 Å). We seek to provide a broadly applicable method of estimating the UV emission of an M dwarf, without direct UV data, by identifying a relationship between noncontemporaneous optical and UV observations. Our work uses the largest sample of M dwarf star far- and near-UV observations yet assembled. We evaluate three commonly observed optical chromospheric activity indices—Hα equivalent widths and log{sub 10} L Hα /L bol , and the Mount Wilson Ca ii H&K S and R HK ' indices—using optical spectra from the HARPS, UVES, and HIRES archives and new HIRES spectra. Archival and new Hubble Space Telescope COS and STIS spectra are used to measure line fluxes for the brightest chromospheric and transition region emission lines between 1200 and 2800 Å. Our results show a correlation between UV emission-line luminosity normalized to the stellar bolometric luminosity and Ca ii R HK ' with standard deviations of 0.31–0.61 dex (factors of ~2–4) about the best-fit lines. We also find correlations between normalized UV line luminosity and Hα log 10 L Hα /L bol and the S index. These relationships allow one to estimate the average UV emission from M0 to M9 dwarfs when UV data are not available.

79 ASTRONOMY AND ASTROPHYSICS↗