The contraction of molecular hydrogen protostars
Molecular hydrogen protostar contraction - stellar evolution
CONTRACTION↗
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Stellar evolution. ii. the hydrogen-burning phase of a star of 7.0 solar masses <sternentwicklung. ii. die wasserstoff- brennende phase eines sterns von 7.0 sonnenmassen<
With the computer program by Hofmeister, Kippenhahn, Weigert (1964, from now on referred to as ''I") the evolution of a population I star of 7.0 solar masses has been followed. The results presented here are based on a sequence of 119 models, the first of which represents the homogeneous main sequence state and has a convective core containing 26% of the mass. The following models describe the phase of depletion of hydrogen in the core, which is shrinking in mass until the convection around the centre disappears. After this the gradual development of a hydrogen burning shell source is shown. The models show the evolution into the red giant region, while the helium core is contracting until helium burning starts at the centre and a new convective core is built up. The luminousity is increased about 1 magnitude compared with the main sequence state. At the same time the outer convective region grows in mass and covers at the maximum 71% of the total mass of the star. During the evolution to the red giant state, the evolutionary track crosses the region of the cepheids. Some aspects of the corresponding models are discussed.
STELLAR EVOLUTION↗
THE EVOLUTION OF MASSIVE STARS. III. HYDROGEN EXHAUSTION THROUGH THE ONSET OF CARBON-BURNING
Evolution of massive stars - hydrogen exhaustion through carbon burning
STELLAR EVOLUTION↗
Determination of hydrogen in milligram quantities of titanium and its alloys
An accurate, versatile, and sensitive method for the determination of hydrogen in milligram-size titanium samples is presented. It involves extraction of hydrogen at 1070 K while a mercury diffusion pump transfers the evolved gases into the inlet of a mass spectrometer. All the evolved gases may then be positively identified and determined. This method can be readily adapted for use with other metals and for the study of the slow evolution of hydrogen. Reduction of interferences due to the evolution of hydrogen by reactions involving vapors such as those of water, acetone, and vacuum grease is discussed.
Otterson, D. A.↗
Evolution of o stars. ii - hydrogen exhaustion and gravitational contraction.
O stars from early phase of hydrogen burning to hydrogen exhaustion and gravitational attraction preceding helium burning
HYDROGEN↗
The semiconvective zone in very massive stars
Semiconvective zone and convective core as function of stellar mass and evolution during hydrogen burning
CONVECTION↗
Hot hydrogen atoms reactions of interest in molecular evolution and interstellar chemistry
Hot hydrogen atoms which are photochemically generated initiate reactions among mixtures of methane, ethane, water and ammonia, to produce ethanol, organic amines, organic acids, and amino acids. Both ethanol and ethyl amine can also act as substrates for formation of amino acids. The one carbon substrate methane is sufficient as a carbon source to produce amino acids. Typical quantum yields for formation of amino acids are approximately 0.00002 to 0.00004. In one experiment, 6 protein amino acids were identified and 8 nonprotein amino acids verified utilizing gas chromatography-mass spectroscopy. We propose that hot atoms, especially hydrogen, initiate reactions in the thermodynamic nonequilibrium environment of interstellar space as well as in the atmospheres of planets.
Becker, R. S.↗
Theoretical evolution of a hydrogen-helium star of 3 solar-mass units from the pre-main sequence to the core helium-exhaustion phase.
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Ezer, D.↗
Chemical evolution. XXIX - Pyrimidines from hydrogen cyanide
Compounds obtained by hydrolysis of HCN oligomers formed by allowing pH 9.2, 0.1 M cyanide to stand at room temperature for 4 to 12 months were analyzed. Hydrolysis of HCN oligomers yielded 4,5-dihydroxypyrimidine and 5-hydroxyuracil; orotic acid was detected after hydrolysis at pH 8.5. A unified pathway from diaminofumaronitrile to the pyrimidines observed is suggested. As purines, pyrimidines and amino acids are released by hydrolysis of HCN oligomers in either acidic or mildly basic aqueous solutions, they could have been formed on the primitive earth in spite of fluctuations in pH. 4,5-dihydroxypyrimidines appear to be likely candidates for incorporation into primitive nucleic acids, as they should undergo Watson-Crick hydrogen bonding with adenine.
Ferris, J. P.↗
Hydrogen peroxide and the evolution of oxygenic photosynthesis
Possible pathways for the evolution of oxygenic photosynthesis in the early reducing atmosphere of the earth are discussed. It is suggested that the abiotic production of atmospheric oxidants could have provided a mechanism by which locally oxidizing conditions were sustained within spatially confined habitats thus removing the available reductants and forcing photosynthetic organisms to utilize water (rather than ferrous or sulfide ions) as the electron donor. It is argued that atmospheric H2O2 played the key role in inducing oxygenic photosynthesis, because, as peroxide concentrations local environments increased, primitive organisms would not only be faced with a loss of a reductant, but would be also forced to develop a biochemical apparatus (such as catalase) that would protect them against the products of oxygenic photosynthesis. This scenario allows for the early evolution of oxygenic photosynthesis at the time when global conditions were still anaerobic.
Mckay, C. P.↗
A novel unitized regenerative proton exchange membrane fuel cell
A difficulty encountered in designing a unitized regenerative proton exchange membrane (PEM) fuel cell lies in the incompatibility of electrode structures and electrocatalyst materials optimized for either of the two functions (fuel cell or electrolyzer) with the needs of the other function. This difficulty is compounded in previous regenerative fuel cell designs by the fact that water, which is needed for proton conduction in the PEM during both modes of operation, is the reactant supplied to the anode in the electrolyzer mode of operation and the product formed at the cathode in the fuel cell mode. Drawbacks associated with existing regenerative fuel cells have been addressed in work performed at Lynntech. In a first innovation, electrodes function either as oxidation electrodes (hydrogen ionization or oxygen evolution) or as reduction electrodes (oxygen reduction or hydrogen evolution) in the fuel cell and electrolyzer modes, respectively. Control of liquid water within the regenerative fuel cell has been brought about by a second innovation. A novel PEM has been developed with internal channels that permit the direct access of water along the length of the membrane. Lateral diffusion of water along the polymer chains of the PEM provides the water needed at electrode/PEM interfaces. Fabrication of the novel unitized regenerative fuel cell and results obtained on testing it will be presented.
Murphy, O. J.↗
A Novel Unitized Regenerative Proton Exchange Membrane Fuel Cell
A difficulty encountered in designing a unitized regenerative proton exchange membrane (PEM) fuel cell lies in the incompatibility of electrode structures and electrocatalyst materials optimized for either of the two functions (fuel cell or electrolyzer) with the needs of the other function. This difficulty is compounded in previous regenerative fuel cell designs by the fact that water, which is needed for proton conduction in the PEM during both modes of operation, is the reactant supplied to the anode in the electrolyzer mode of operation and the product formed at the cathode in the fuel cell mode. Drawbacks associated with existing regenerative fuel cells have been addressed. In a first innovation, electrodes function either as oxidation electrodes (hydrogen ionization or oxygen evolution) or as reduction electrodes (oxygen reduction or hydrogen evolution) in the fuel cell and electrolyzer modes, respectively. Control of liquid water within the regenerative fuel cell has been brought about by a second innovation. A novel PEM has been developed with internal channels that permit the direct access of water along the length of the membrane. Lateral diffusion of water along the polymer chains of the PEM provides the water needed at electrode/PEM interfaces. Fabrication of the novel single cell unitized regenerative fuel cell and results obtained on testing it are presented.
Murphy, O. J.↗
Relative Importance of Various Sources of Defect-Producing Hydrogen Introduced into Steel During Application of Vitreous Coatings
When porcelain enamels or vitreous-type ceramic coatings are applied to ferrous metals, there is believed to be an evolution of hydrogen gas both during and after the firing operation. At elevated temperatures rapid evolution may result in blistering while if hydrogen becomes trapped in the steel during the rapid cooling following the firing operation gas pressures may be generated at the coating-metal interface and flakes of the coating literally blown off the metal. To determine experimentally the relative importance of the principal sources of the hydrogen causing the defects, a procedure was devised in which heavy hydrogen (deuterium) was substituted in turn for regular hydrogen in each of five possible hydrogen-producing operations in the coating process. The findings of the study were as follows: (1) the principal source of the defect-producing hydrogen was the dissolved water present in the enamel frit that was incorporated into the coating. (2) the acid pickling, the milling water, the chemically combined water in the clay, and the quenching water were all minor sources of defect-producing hydrogen under the test conditions used. Confirming experiments showed that fishscaling could be eliminated by using a water-free coating.
Moore, Dwight G↗
Hydrogen Isotopic Constraints on the Evolution of Surface and Subsurface Water on Mars
The geology and geomorphology of Mars provide clear evidence for the presence of liquid water on its surface during the Noachian and Hesperien eras (i.e., >3 Ga). In contrast to the ancient watery environment, today the surface of Mars is relatively dry. The current desert-like surface conditions, however, do not necessarily indicate a lack of surface or near-surface water/ice. In fact, massive deposits of ground ice and/or icy sediments have been proposed based on subsurface radar sounder observations. Hence, accurate knowledge of both the evolution of the distribution of water and of the global water inventory is crucial to our understanding of the evolution of the climate and near-surface environments and the potential habitability of Mars. This study presents insights from hydrogen isotopes for the interactive evolution of Martian water reservoirs. In particular, based on our new measurement of the D/H ratio of 4 Ga-old Noachian water, we constrain the atmospheric loss and possible exchange of surface and subsurface water through time.
Usui, T.↗
Trapping of hydrogen atoms in X-irradiated salts at room temperature and the decay kinetics
The salts (hypophosphites, formates, a phosphite, a phosphate, and an oxalate) were X-irradiated, whereby hydrogen formed chemically by a radiolytic process becomes trapped in the solid. By room temperature vacuum extraction, the kinetics for the evolution of this trapped hydrogen was studied mass spectrometrically. All salts except two exhibited second-order kinetics. The two exceptions (NaH2PO2(H2O) and K2HPO4) showed first-order kinetics. Based on experimental results, the escape of hydrogen involves three steps: the diffusion of hydrogen atoms from the bulk to the surface, association of these atoms on the surface (rate controlling step for second-order hydrogen evolution), and the desorption of molecular hydrogen from the surface. The hydrogen does not escape if the irradiated salt is stored in air, apparently because adsorbed air molecules occupy surface sites required in the escape mechanism.
May, C. E.↗
Plated nickel wire mesh makes superior catalyst bed
Porous nickel mesh screen catalyst bed produces gas evolution in hydrogen peroxide thrust chambers used for attitude control of space vehicles. The nickel wire mesh disks in the catalyst bed are plated in rugose form with a silver-gold coating.
Sill, M.↗
Metal-poor stars. I - Evolution from the main sequence to the giant branch
Metal-poor stars evolution during hydrogen and helium burning from main sequence to giant branch, estimating relative cluster ages
Iben, I., Jr.↗
Platinum electrodes for electrochemical detection of bacteria
Bacteria is detected electro-chemically by measuring evolution of hydrogen in test system with platinum and reference electrode. Using system, electrodes of platinum are used to detect and enumerate varieties of gram-positive and gram-negative organisms compared in different media.
Wilkins, J. R.↗