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Results for “bulk photovoltaic”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Impact of dipolar molecules on the reliability of organic photovoltaic cells

Blending two non-fullerene acceptors (NFAs) to form bulk heterojunctions (BHJs) in ternary organic photovoltaics (OPVs) has been shown to lead to an end-capping exchange reaction that results in the generation of several new dipolar species whose impact on OPV operational stability remains uncertain. Here, we investigate the reliability of a ternary OPV system intentionally blended with dipolar NFA molecules. We reveal that an intrinsic contribution to OPV degradation is the reorganization and reorientation of the dipolar molecules during operation, which leads to an increased dielectric constant (ε r ) of the BHJ. Consequently, the electric field across the BHJ with dipolar molecules decreases compared with that of a non-dipolar BHJ under the same applied voltage, leading to a larger reduction in charge collection efficiency over time. This result has implications on the stability of a range of organic electronic devices containing dipolar molecules.

14 SOLAR ENERGY↗
NASA NTRS1984

Diffused junction p(+)-n solar cells in bulk GaAs. II - Device characterization and modelling

The photovoltaic characteristics of p(+)-n junction solar cells fabricated on bulk GaAs by an open tube diffusion technique are presented in detail. Quantum efficiency measurements were analyzed and compared to computer simulations of the cell structure in order to determine material parameters such as diffusion length, surface recombination velocity and junction depth. From the results obtained it is projected that proper optimization of the cell parameters can increase the efficiency of the cells to close to 20 percent.

Keeney, R.↗
DOE OSTI2021

Highly Efficient Ternary Solar Cells with Efficient Förster Resonance Energy Transfer for Simultaneously Enhanced Photovoltaic Parameters

Introducing a third component into organic bulk heterojunction solar cells has become an effective strategy to improve photovoltaic performance. Meanwhile, the rapid development of non-fullerene acceptors (NFAs) has pushed the power conversion efficiency (PCE) of organic solar cells (OSCs) to a higher standard. In this study, a series of fullerene-free ternary solar cells are fabricated based on a wide bandgap acceptor, IDTT-M, together with a wide bandgap donor polymer PM6 and a narrow bandgap NFA Y6. Insights from the morphological and electronic characterizations reveal that IDTT-M has been incorporated into Y6 domains without disrupting its molecular packing and sacrificing its electron mobility and work synergistically with Y6 to regulate the packing pattern of PM6, leading to enhanced hole mobility and suppressed recombination. IDTT-M further functions as an energy-level mediator that increases open-circuit voltage ( V OC ) in ternary devices. In addition, efficient Förster resonance energy transfer (FRET) between IDTT-M and Y6 provides a non-radiative pathway for facilitating exciton dissociation and charge collection. As a result, the optimized ternary device features a significantly improved PCE up to 16.63% with simultaneously enhanced short-circuit current ( J SC ), V OC , and fill factor (FF).

36 MATERIALS SCIENCE↗
NASA NTRS1987

Characterization and modelling of open tube diffused n+p bulk InP solar cells

The authors describe the photovoltaic characteristics of an n+p junction solar cell fabricated on bulk InP by an open-tube-diffusion technique. Analysis of the forward characteristics shows that the forward current is dominated by recombination in the quasineutral regions, indicating that the fabrication technique produces a clean junction. Spectral response measurements are analyzed and more realistic boundary conditions are used to model the solar cell to determine important material and device parameters.

Bothra, S.↗
DOE OSTI2021

Evaluating Utility-Scale PV-Battery Hybrids in an Operational Model for the Bulk Power System

Systems that combine solar photovoltaic and battery energy storage technologies (PV-BES) are increasingly being proposed and deployed on the bulk power system. The operations and value of PV-BES systems have been extensively studied from the project developer's perspective through analyses that maximize plant-level revenue. However, PV-BES hybrids' operational characteristics are seldom studied from the perspective of bulk power system operators, who seek to optimize the performance of a suite of generation and storage assets that are connected via the transmission network. This work presents modeling approaches for representing and evaluating PV-BES hybrids in a model that optimizes operations across the bulk power system. Its novel contributions include demonstrating a technique to modify a unit commitment and dispatch model to represent the operational synergies of PV-BES hybrids. In particular, we describe the challenges and an approach for representing so-called DC-coupled PV-BES - which utilize a single bi-directional inverter - as a dispatchable resource in a commercial, production cost model (PCM), PLEXOS. We demonstrate this technique in a PCM study of the Los Angeles Department of Water and Power (LADWP) test system, by replacing existing PV and battery generators on the test system with our PV-BES hybrids. We then pursue scenario analysis that is designed to isolate the various drivers of operational strategies for DC-coupled PV-BES hybrids, including the nature of coupling, PV penetration on the system, and varying inverter loading ratios (or degrees of over-sizing of the PV field). Results from the analysis include utilization profiles for the PV DC energy across available pathways, dispatch profiles for the battery component, and the hybrid technologies' impacts on system-wide production costs. The approach presented in this paper can be used in any PCM that is looking to study PV-BES hybrids as a resource in different power system configurations and services.

14 SOLAR ENERGY↗
DOE OSTI2022

Revealing aggregation of non-fullerene acceptors in intermixed phase by ultraviolet-visible absorption spectroscopy

Non-fullerene acceptor (NFA) aggregation is crucial in determining bulk-heterojunction (BHJ) organic photovoltaic (OPV) performance. However, it is still a big challenge to characterize the nanostructure of NFAs in the disordered donor-acceptor intermixed phase. Here, we demonstrate a method to characterize NFA aggregation and composition in the intermixed phase by measuring NFA concentration-dependent ultraviolet-visible (UV-vis) absorption spectroscopy of BHJ films. In various polymer:NFA films, an absorption shift as a function of increasing molecular concentration (ASIMC) phenomenon is observed, and different NFA aggregation behaviors can be distinguished. The ASIMC method was then applied to study the influence of processing conditions on the NFA concentration in the intermixed phase of devices to establish a correlation with device efficiency. The current work provides a feasible tool to study the nanostructure of NFAs in the complex polymer matrix and to understand the variations in the NFA concentration in the intermixed phase under non-equilibrium conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Mitigation of the internal p-n junction in CoS 2 -contacted FeS 2 single crystals: Accessing bulk semiconducting transport

Pyrite FeS 2 is an outstanding candidate for a low-cost, nontoxic, sustainable photovoltaic material, but efficient pyrite-based solar cells are yet to materialize. Recent studies of single crystals have shed much light on this by uncovering a p-type surface inversion layer on n-type (S-vacancy doped) crystals, and the resulting internal p-n junction. This leaky internal junction likely plays a key role in limiting efficiency in pyrite-based photovoltaic devices, also obscuring the true bulk semiconducting transport properties of pyrite crystals. Here, we demonstrate complete mitigation of the internal p-n junction in FeS 2 crystals by fabricating metallic CoS 2 contacts via a process that simultaneously diffuses Co (a shallow donor) into the crystal, the resulting heavy n doping yielding direct Ohmic contact to the interior. Low-temperature bulk transport studies of controllably Co- and S-vacancy doped semiconducting crystals then enable a host of previously inaccessible observations and measurements, including determination of donor activation energies (which are as low as 5 meV for Co), observation of an unexpected second activated transport regime, realization of electron mobility up to 2100 cm 2 V –1 s –1 , elucidation of very different mobilities in Co- and S-vacancy-doped cases, and observation of an abrupt temperaturedependent crossover to bulk Efros-Shklovskii variable-range hopping, accompanied by an unusual form of nonlinear Hall effect. Aspects of the results are interpreted with the aid of first-principles electronic structure calculations on both Co- and S-vacancy-doped FeS 2 . Furthermore, this work thus demonstrates unequivocal mitigation of the internal p-n junction in pyrite single crystals, with important implications for both future fundamental studies and photovoltaic devices

36 MATERIALS SCIENCE↗
DOE OSTI2021

Stabilizing the Power System in 2035 and Beyond: Evolving from Grid-Following to Grid-Forming Distributed Inverter Controllers (Final Technical Report)

Under existing grid operations, large synchronous generators provide sufficient rotational inertia to form a rigid backbone for the bulk power system. With photovoltaics (PV) forecasted to provide more than 600 GW of generation by 2050 under the U.S. Department of Energy’s SunShot Initiative objectives, however, it is clear that power electronic inverters will play a dominant role in future systems, and low-inertia stability must be ensured to maintain system reliability. Today, the risks to system stability can be observed on geographically small islands, such as Hawaii, which contain a relatively large amount of installed PV. These risks stem from a fundamental shortcoming of contemporary control strategies—existing inverter controllers cannot guarantee grid stability. Given that future power systems driven by sustainable resources will be characterized by low inertia, locations such as Hawaii provide a glimpse into the obstacles facing future power systems. Considering these challenges, the aim of this project was to develop and demonstrate distributed inverter controllers that enable the reliable control of low-inertia power systems with hundreds of gigawatts of integrated PV.

14 SOLAR ENERGY↗
DOE OSTI2020

Enhancing Photocarrier Bulk Lifetime with Defect Engineering of Polycrystalline Passivated-Contact n-Cz Photovoltaic Devices

We study the photocarrier lifetime evolution of n-Cz Si material throughout the processing sequence for polycrystalline passivated contact devices. We show that a high temperature annealing pretreatment (known as Tabula Rasa) has a clear effect on enhancing bulk lifetimes of n-Cz Si. We further this development by integrating such defect engineering into the lower-temperature annealing of passivated contact. By applying oxidizing ambient gases during these anneals we report a photocarrier lifetime enhancement over an N 2 environment. This enhancement is exhibited in a 1-sun iV OC of 735 mV when annealed in O 2 rather than 708 mV in N 2.

14 SOLAR ENERGY↗
NASA NTRS1978

Thermal and other tests of photovoltaic modules performed in natural sunlight

The bulk of the testing was the characterization of twenty-nine modules according to their nominal operating cell temperature (NOCT) and the effect on NOCT of changes in module design, various residential roof mounting configurations, and dirt accumulation. Other tests, often performed parallel with the NOCT measurements, evaluated the improvement in electrical performance by cooling the modules with water and by channeling the waste heat into a phase change material (wax). Electrical degradation resulting from the natural marriage of photovoltaic and solar water heating modules was also demonstrated. Cost effectiveness of each of these techniques are evaluated in light of the LSA cost goal of $0.50 per watt.

Stultz, J. W.↗
DOE OSTI2020

Light-Induced Currents at Domain Walls in Multiferroic BiFeO3.

Multiferroic BiFeO3 (BFO) films with spontaneously formed periodic stripe domains can generate above-gap open circuit voltages under visible light illumination; nevertheless the underlying mechanism behind this intriguing optoelectronic response has not been understood to date. Here, we make contact-free measurements of light-induced currents in epitaxial BFO films via detecting terahertz radiation emanated by these currents, enabling a direct probe of the intrinsic charge separation mechanisms along with quantitative measurements of the current amplitudes and their directions. In the periodic stripe samples, we find that the net photocurrent is dominated by the charge separation across the domain walls, whereas in the monodomain samples the photovoltaic response arises from a bulk shift current associated with the non-centrosymmetry of the crystal. The peak current amplitude driven by the charge separation at the domain walls is found to be 2 orders of magnitude higher than the bulk shift current response, indicating the prominent role of domain walls acting as nanoscale junctions to efficiently separate photogenerated charges in the stripe domain BFO films. These findings show that domain-wall-engineered BFO thin films offer exciting prospects for ferroelectric-based optoelectronics, as well as bias-free strong terahertz emitters.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Single crystal purification reduces trace impurities in halide perovskite precursors, alters perovskite thin film performance, and improves phase stability

Impurities present in commercially available halide perovskite precursors are known to affect photovoltaic performance. Here, we employ bulk single crystal growth of FAPbI 3 using solvent orthogonality induced crystallization (SONIC) to remove a broad set of extrinsic impurities from commercially available halide perovskite precursors, as verified by detailed chemical analysis. Following SONIC purification, FAPbI 3 films made from PbI 2 of originally low purity (99%) and high purity (99.99%) show improved phase purity and stability under light and heat relative to films made from raw precursors or precursors purified via retrograde powder crystallization (RPC) in 2-methoxyethanol, a method commonly utilized in recent reports of the highest-efficiency perovskite solar cells. In conclusion, single-crystal purification of precursors improves film stability under operational stressors, and the large enhancements in material purity provide a cleaner slate for improved isolation of compositional and additive effects on perovskite phase stability.

14 SOLAR ENERGY↗
DOE OSTI2021

Chapter 9: Impact of Variable Renewable Energy Sources on Bulk Power System Planning and Operations

Wind and solar photovoltaics (PV) have experienced remarkable growth in recent years, with many consequent benefits within and outside of power systems. At the same time, wind and solar PV have unique characteristics relative to the historically dominant dispatchable technologies like coal, gas, and nuclear power plants that have required and will continue to require changes in power system planning and operations. This chapter discusses planning and operational challenges of integrating wind and solar PV into bulk power systems. We first present the key characteristics of wind and solar PV that differentiate it from conventional technologies, such as variable and uncertain electricity generation, asynchronous interconnection to the power system, and near-zero marginal costs. We then link these characteristics to power system planning and operational challenges at low through high wind and solar penetrations. Finally, we discuss near- and long-term solutions to those challenges, such as diversifying the generation mix and wind and solar fleets, improving system flexibility, diversifying ancillary service products, and integrating generation and transmission planning.

bulk power system↗
NASA NTRS2008

Progress Towards III-V Photovoltaics on Flexible Substrates

Presented here is the recent progress of the NASA Glenn Research Center OMVPE group's efforts in the development of high efficiency thin-film polycrystalline III-V photovoltaics on optimum substrates. By using bulk polycrystalline germanium (Ge) films, devices of high efficiency and low mass will be developed and incorporated onto low-cost flexible substrates. Our progress towards the integration of high efficiency polycrystalline III-V devices and recrystallized Ge films on thin metal foils is discussed.

McNatt, Jeremiah S.↗
DOE OSTI2021

Root Cause Analysis of AC Overcurrent in July 2020 San Fernando Disturbance

On July 7 2020, approximately 1,000 MW reduction in solar photovoltaic (PV) output was experienced by the bulk power system in Southern California after a three-phase fault. Disturbance analysis indicates that instantaneous AC current caused inverter tripping. The projection of the root cause of AC overcurrent from the NERC report is that inverter current control is not tight. This letter provides a quantitative analysis on ac overcurrent and addresses the following questions: (i) what type of current controls may lead to ac overcurrent; and (ii) how controller parameters and grid strength influence ac overcurrent. Here, the letter provides frequency-domain analysis and time-domain simulation results of a grid-integrated inverter to illustrate the effect of control parameters and grid strength on ac overcurrent.

14 SOLAR ENERGY↗