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At least 55 records · Page 3

Fast Charging of Li-Ion Cells: Part V. Design and Demonstration of Protocols to Avoid Li-Plating

Fast charging of Li-ion batteries would make “fueling” of electric vehicles comparable in time to fueling of gasoline-powered cars, increasing consumer appeal of the new technology. Taking the US Department of Energy goal of safe 6 C charging to 80% capacity as a guide, we describe approaches that can mitigate Li plating on the graphite anode. To make this possible, a variable-rate anode potential charging protocol has been implemented by using a microprobe reference electrode to continuously monitor and adjust the current, in this way avoiding low anode potentials that favor Li deposition. Various implementations of the anode potential control are considered using electrochemical modeling and compared with the experimental data. For charge to 80% capacity at 30 °C, an average C-rate of 4.97 C was obtained for an NCM523/graphite cell with 70 μ m thick graphite electrode and 7.40 C for a cell with 47 μ m thick graphite electrode. Our electrochemical model accounts for these observations and provides a means to extrapolate the approach to other cell designs and operation regimes, drawing the maximum average fast charging rates that can still avoid Li plating.

25 ENERGY STORAGE↗

Disrupting EV Charging Sessions and Gaining Remote Code Execution with DoS, MITM, and Code Injection Exploits using OCPP 1.6

Open Charge Point Protocol (OCPP) 1.6 is widely used in the electric vehicle (EV) charging industry to communicate between Charging System Management Services (CSMSs) and Electric Vehicle Supply Equipment (EVSE). Unlike OCPP 2.0.1, OCPP 1.6 uses unencrypted websocket communications to exchange information between EVSE devices and an onpremise or cloud-based CSMS. In this work, we demonstrate two machine-in-the-middle (MITM) attacks on OCPP sessions to terminate charging sessions and gain root access to the EVSE equipment via remote code execution (RCE). Second, we demonstrate a malicious firmware update with a code injection payload to compromise an EVSE. Lastly, we demonstrate two methods to prevent availability of the EVSE or CSMS. One of these, originally reported by SaiFlow, prevents traffic to legitimate EVSE equipment using a DoS-like attack on CSMSs by repeatedly connecting and authenticating several CPs with the same identities as the legitimate CP. These vulnerabilities were demonstrated with proof-of-concept exploits in a virtualized Cyber Range at Wright State University and/or with a 350 kW Direct Current Fast Charger (DCFC) at Idaho National Laboratory. The team found that OCPP 1.6 could be protected from these attacks by adding secure shell (SSH) tunnels to the protocol, if upgrading to OCPP 2.0.1 was not an option. Index Terms—Electric vehicle charging, cybersecurity, OCPP, cyberattack, cyber-resilience. INSPEC Accession Number: 23981565

99 GENERAL AND MISCELLANEOUS↗

Implementation Guide for Minimum Required Error Codes in Electric Vehicle Charging Infrastructure

With the growing adoption of Electric Vehicles (EVs), there is an increasing need for a reliable EV charging infrastructure. To help meet this need, the report “Recommendations for Minimum Required Error Codes for Electric Vehicle Charging Infrastructure,” recommends a set of minimum required error codes (MRECs) and their functional and responsibility classification. Charger manufacturers, charging station operators, EV manufacturers, and other stakeholders in the North American market are encouraged to uniformly adopt the MRECs to enhance EV charging error reporting, interpretation, and diagnostics. This document serves as a guide to enable uniform implementation of the MRECs using the Open Charge Point Protocol (OCPP).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

V2XConnect: Harmonizing the Landscape of Bidirectional Charging Codes, Standards, and Communication Protocols

The utility grid is constantly evolving with new generation sources and diverse loads from backup generators, backup batteries, rooftop photovoltaics (PV), and flexible charging loads. Each of these technologies presents consumers with an opportunity to work with their local utility to promote grid stability, reliability, and affordability. Through a wide range of programs, utilities are incentivizing the use of these resources to benefit the grid. However, especially for devices with inverters that supply power back to the grid, it is important that these assets comply with local grid codes to ensure human safety, power quality, and grid reliability. One of the most promising of these new technologies is the bidirectional electric vehicle (EV) coupled with bidirectional electric vehicle supply equipment (EVSE). This report introduces the technologies that enable bidirectional charging and how these systems operate. It then outlines the necessary interconnection codes and industry standards that govern the operations of grid-tied inverters, including those in bidirectional charging. A key challenge is then outlined from the complex landscape of communication protocols and proprietary systems designed to coordinate these grid assets. Finally, a single gateway solution is proposed to harmonize communications between all assets across an entire site for a cohesive response to grid codes and utility programs that is flexible enough to support a range of market options.

33 ADVANCED PROPULSION SYSTEMS↗

Recommendations for Minimum Required Error Codes for Electric Vehicle Charging Infrastructure

OCPP protocol manages the interaction between the EVSE and its respective back-end communication network. It plays a pivotal role in both error reporting and troubleshooting, carried out primarily through the CSMS. OCPP defines both standard error codes and a flexible framework for creating and communicating custom error codes. The OCPI protocol orchestrates the communication between different backhaul communication networks, incorporating the exchange of error codes. These error codes are instrumental in pinpointing and rectifying issues that can surface prior to, during, or after charging operations, fortifying the reliability and resilience of the EV charging infrastructure. The flexibility offered by the OCPP and OCPI frameworks through the introduction of custom error codes also creates its own set of challenges. While the integration of custom error codes allows for enhanced granularity, it also introduces inconsistencies and fragmentation within the overarching diagnostic reporting system. To address the challenges with custom error codes this report proposes a set of Minimum Required Error Codes (MRECs) for streamlined error reporting, interpretability, and diagnostics. Recommendations in this report are based on independent analysis of custom error codes from multiple stakeholders within the EV charging ecosystem. For better error resolution, this report also assigns one or more entities responsible for the resolution of every mentioned error code. Finally, a functional classification for each mentioned error code is also identified to describe the nature of the error. In summary, the purpose of this document is to simplify the troubleshooting process and increase charging reliability for all EV users. This report serves as a recommendation for industry stakeholders, encouraging a unified methodology to define, transmit, and interpret common error codes.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Recommendations for Minimum Required Diagnostics Information

The rapid growth of electrified transportation, including light- and medium-duty electric vehicles (EVs) as a mobility solution requires a reliable EV-charging infrastructure. To advance charging reliability, the ChargeX Consortium reports “Recommendations for Minimum Required Error Codes for Electric Vehicle Charging Infrastructure” and “Implementation Guide for Minimum Required Error Codes in Electric Vehicle Charging Infrastructure” provided recommendations for a set of minimum required error codes (MRECs), their functional and responsibility classifications, and a guide for their implementation, using Open Charge Point Protocol (OCPP) versions 1.6J4 and 2.0.1.5 These reports outline a recommended practice for consistent error reporting and interpretation, which is essential for communicating issues uniformly across the complex and diverse EV-charging ecosystem. However, MRECs are just one part of diagnosing issues; another critical part is obtaining enough information about the current state and performance of the various charging components to identify root causes for each of the error codes. This additional diagnostics data can be used by technicians or automated systems to understand the context around an issue, allowing for timely resolution, decreased maintenance costs, and increased charging reliability. During everyday operations, data are regularly collected and analyzed across the ecosystem. Although sharing of all that available data would be great for diagnostics, concerns on data ownership, privacy, and original equipment manufacturer (OEM) intellectual property pose a challenge. To overcome this obstacle, this report proposes a set of minimum required diagnostic information (MRDI) and recommends that the industry implement these uniformly across the North American EV charging ecosystem. MRDI provides a means to exchange only data deemed necessary for root cause determination.

33 ADVANCED PROPULSION SYSTEMS↗

A Blockchain and PKI-Based Secure Vehicle-to-Vehicle Energy-Trading Protocol

With the increasing awareness for sustainable future and green energy, the demand for electric vehicles (EVs) is growing rapidly, thus placing immense pressure on the energy grid. To alleviate this, local trading between EVs should be encouraged. In this paper, we propose a blockchain and public key infrastructure (PKI)-based secure vehicle-to-vehicle (V2V) energy-trading protocol. A permissioned blockchain utilizing the proof of authority (PoA) consensus and smart contracts is used to securely store data. Encrypted communication is ensured through transport layer security (TLS), with PKI managing the necessary digital certificates and keys. A multi-leader, multi-follower Stackelberg game-based trade algorithm is formulated to determine the optimal energy demands, supplies, and prices. Finally, we propose a detailed communication protocol that ties all the components together, enabling smooth interaction between them. Key findings, such as system behavior and performance, scalability of the trade algorithm and the blockchain, smart contract execution costs, etc., are presented through numerical results by implementing and simulating the protocol in various scenarios. This work not only enhances local energy trading among EVs, encouraging efficient energy usage and reducing burden on the power grid, but also paves a way for future research in sustainable energy management.

Stackelberg game↗

Determining Partial Atomic Charges for Liquid Water: Assessing Electronic Structure and Charge Models

Partial atomic charges provide an intuitive and efficient way to describe the charge distribution and the resulting intermolecular electrostatic interactions in liquid water. Many charge models exist and it is unclear which model provides the best assignment of partial atomic charges in response to the local molecular environment. In this work, we systematically scrutinize various electronic structure methods and charge models (Mulliken, natural population analysis, CHelpG, RESP, Hirshfeld, Iterative Hirshfeld, and Bader) by evaluating their performance in predicting the dipole moments of isolated water, water clusters, and liquid water as well as charge transfer in the water dimer and liquid water. Although none of the seven charge models is capable of fully capturing the dipole moment increase from isolated water (1.85 D) to liquid water (about 2.9 D), the Iterative Hirshfeld method performs best for liquid water, reproducing its experimental average molecular dipole moment, yielding a reasonable amount of intermolecular charge transfer, and showing modest sensitivity to the local water environment. The performance of the charge model is dependent on the choice of the density functional and the quantum treatment of the environment. The computed molecular dipole moment of water generally increases with the percentage of the exact Hartree–Fock exchange in the functional, whereas the amount of charge transfer between molecules decreases. For liquid water, including two full solvation shells of surrounding water molecules (within about 5.5 Å of the central water) in the quantum chemical calculation converges the charges of the central water molecule. Furthermore, our final pragmatic quantum chemical charge-assigning protocol for liquid water is the Iterative Hirshfeld method with M06-HF/aug-cc-pVDZ and a quantum region cutoff radius of 5.5 Å.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

node-red-contrib-ocpp2

Open source Node-Red "nodes" to support the Open Charge Point Protocol (OCPP) 2.0.1 protocol.

Nystrom, Bryan↗

High-efficiency, high-fidelity charge initialization of shallow nitrogen-vacancy centers in diamond

Nitrogen-vacancy (N-𝑉) centers in diamond exhibit long spin-coherence times, optical initialization, and optical-spin readout under ambient conditions, making them excellent quantum sensors. However, the conventional scheme for charge-state initialization based on off-resonant green excitation results in significant state-preparation errors, typically around 30%. One method for improving charge-state initialization fidelity is to use multicolor excitation, which has been demonstrated to achieve a near-unity preparation fidelity for bulk N-𝑉 centers by using a few milliseconds of near-infrared (NIR) (5-mW) and green (10-μ⁢W) excitation. The translation of such schemes to N-𝑉 centers near the diamond surface with higher-efficiency optical pumping would enable new applications in nanoscale sensing. Here, we demonstrate a protocol for efficient charge initialization of shallow N-𝑉 centers between 5 nm and 15 nm from the diamond surface. By carefully studying the charge dynamics of shallow N-𝑉 centers, we identify a region of parameter space that allows for near-unity (95%) charge initialization within 300 μ⁢s of NIR (905-nm, 1-mW) and green (520-nm, 10-μ⁢W) excitation. The time to 90% charge initialization can be as fast as 10 μ⁢s for 4 mW of NIR and 39 μ⁢W of green illumination. This fast, efficient charge initialization protocol will especially benefit nanoscale sensing applications in which state-preparation errors currently prohibit scaling, such as measuring higher-order multipoint correlators.

infrared techniques↗

Post-Marcus Theory and Simulation of Interfacial Charge Transfer Dynamics in Organic Semiconducting Materials (Final Report)

The research program developed, validated and applies predictive computational protocols for calculating charge transfer (CT) rates in complex molecular systems, including molecular dyads and triads in liquid solution and solid-state organic semiconducting (OSC) materials. We have established a transformative computational scheme that goes beyond widely used simplifications, to achieve realistic descriptions of CT processes. The approach properly addresses the contribution of molecular environment at ambient conditions to CT processes. Our approach achieves unique insight on investigated CT processes in relevant experimental efforts. The collaborative team included three principal investigators (PIs), with complimentary expertise in classical molecular dynamics simulations and data science (Cheung), state-of-the-art electronic structure calculations (Dunietz), and cutting-edge theory and simulation techniques for modeling energy, charge and coherence transfer dynamics in molecular systems (Geva).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Motivation and Design of the OCPP Security Service

Pacific Northwest National Laboratory is conducting in-depth research aimed at exploring how zero trust security principles can be effectively applied to electric vehicle charging infrastructure. This investigation seeks to enhance the resilience and reliability of these systems against cyber threats, ensuring secure and uninterrupted access to charging services for electric vehicle users and electric supply. Zero trust is a security concept centered on the belief that system operators should not automatically trust users or systems based on their location, whether inside or outside the organization, but instead must verify everything trying to connect to their systems before granting access. A key aspect of the project is to demonstrate and validate zero trust approaches targeted to electric vehicle (EV) charging infrastructure. It has been observed that both open-source and commercial solutions often overlook the specific protocols employed in managing EV charging stations and proceeded with a general, protocol-agnostic approach. While these strategies effectively block non-authorized routes to the charging infrastructure, they do not tackle the situations where attackers may exploit legitimate access channels, such as the inattentive operator model posited by the Idaho National Laboratory. To address this gap, this paper proposes and discusses a new security service targeted to the Open Charge Point Protocol (OCPP), which is the de facto protocol for the management of charging stations and serves a critical role in the broader adoption of electric vehicles. The design and architecture of the proposed OCPP security service are discussed in detail, outlining how it aims to safeguard charging station management system (CSMS) functions. The service is particularly important in scenarios where the charging station operator (CSO), responsible for the maintenance and operation of charging stations, and the charging network provider (CNP), which manages the charging network's accessibility and billing, are separate entities. This distinction is crucial because CSOs and CNPs often have different priorities, objectives, and operational responsibilities, which may not always align perfectly. For instance, a CSO might prioritize uptime and customer satisfaction, while a CNP might focus on maximizing revenue and network utilization. Such misalignment can create security vulnerabilities, as each entity might implement different policies and standards, potentially leaving gaps in the overall security posture.

33 ADVANCED PROPULSION SYSTEMS↗

Robust quantification of the diamond nitrogen-vacancy center charge state via photoluminescence spectroscopy

Nitrogen vacancy (NV) centers in diamond are at the heart of many emerging quantum technologies, all of which require control over the NV charge state. Hence, methods for quantification of the relative photoluminescence intensities of the NV 0 and NV − charge states, i.e., a charge state ratio, are vital. Several approaches to quantify NV charge state ratios have been reported but are either limited to bulk-like NV diamond samples or yield qualitative results. We propose an NV charge state quantification protocol based on the determination of sample- and experimental setup-specific NV 0 and NV − reference spectra. The approach employs blue (400–470 nm) and green (480–570 nm) excitation to infer pure NV 0 and NV − spectra, which are then used to quantify NV charge state ratios in subsequent experiments via least squares fitting. We test our dual excitation protocol (DEP) for a bulk diamond NV sample and 20 and 100 nm nanodiamond particles and compare results with those obtained via other commonly used techniques such as zero-phonon line fitting and non-negative matrix factorization. We find that DEP can be employed across different samples and experimental setups and yields consistent and quantitative results for NV charge state ratios that are in agreement with our understanding of NV photophysics. By providing robust NV charge state quantification across sample types and measurement platforms, DEP will support the development of NV-based quantum technologies.

Color center laser spectroscopy↗

ChargeX OCPI Recommendations

The Open Charge Point Interface (OCPI) is an open protocol that enables electric vehicle (EV) charging systems to work together across networks. It supports communication and data sharing between Charge Point Operators (CPOs), who manage charging stations, and e-Mobility Service Providers (eMSPs), who provide charging services to EV drivers. OCPI facilitates functions like user authorization, remote charge point control, charging session data exchange, and billing through Charge Detail Records (CDRs). This allows EV roaming, so drivers can charge at different networks without multiple accounts. As the EV market grows due to increased adoption and technological advancements, OCPI faces higher demands. This has revealed issues with CDR format consistency, timestamp standardization across regions, transmission of EV-side error codes for troubleshooting, and support for new use cases. These challenges can affect operations and user experience, particularly as the industry starts considering Vehicle-to-Grid (V2G) systems, where EVs supply energy to the grid, and Vehicle-to-Everything (V2X) technologies for broader energy interactions. Using feedback from the ChargeX Diagnostics taskforce discussions, industry 1-on-1 meetings, technical standards, and OCPI’s evolution through versions (e.g., OCPI 2.1.1, 2.2, and 2.2.1), this report identifies these issues and suggests practical recommendations. These aim to improve interoperability, streamline operations, and prepare OCPI for future trends in the EV charging ecosystem.

32 - ENERGY CONSERVATION, CONSUMPTION, AND UTILIZA↗

Neural network potentials with effective charge separation for non-equilibrium dynamics of ionic solids: a ZnO case study

Developing neural network potentials (NNPs) accurate under non-equilibrium dynamics is challenging, as such systems require extensive sampling beyond equilibrium phases. Here we construct high-fidelity NNPs for zinc oxide (ZnO), a polymorphic ionic solid, using density functional theory (DFT) reference data. To efficiently capture transitional configurations, we combine enhanced-sampling molecular dynamics with empirical potentials, data distillation, and pretraining on short-range atomic energies (A-Train), followed by transfer learning with DFT-relabeled datasets. This hierarchical approach improves transferability across polymorphs and stress states. We further introduce effective charge separation, treating long-range Coulombic terms analytically while short-range residual interactions are learned by the NNP. The optimal effective charges fall in the range 0.5–1.0 q e , consistent with dielectric-screened values derived from formal charges but distinct from Bader estimates. Motivated by this observation, we propose a simple data-driven protocol in which effective charges are optimized by comparing DFT reference energies with explicit Coulomb calculations, without additional NNP training. This strategy improves accuracy and transferability in DFT-level predictions of energies, forces, and stress. Together, these results provide a practical charge-selection framework for robust NNP development in ionic solids, enabling reliable simulation of polymorphic phase transformations and non-equilibrium dynamics.

Chemistry↗

Cybersecurity for Electric Vehicle Fast-Charging Infrastructure

The integration of electric vehicles (EVs) into electric grid operations can potentially leave the grid vulnerable to cyberattacks from both legacy and new equipment and protocols, including extreme fast-charging infrastructure. This paper introduces a co-simulation platform to perform cyber vulnerability analysis of EV charging infrastructure and its dependencies on communications and control systems. Grid impact scenarios through linkages to power system simulation tools such as OpenDSS and vehicle infrastructure-specific attack paths are discussed. An adaptive platform that assists with predicting and solving evolving cybersecurity challenges is demonstrated with a cyber-energy emulation that accelerates the analysis of cyberattacks and system behavior.

47 OTHER INSTRUMENTATION↗

EV Charging Infrastructure Energization An Overview of Approaches for Simplifying and Accelerating Timelines to Processing EV Charging Load Service Requests

The United States has seen significant growth in electric vehicle (EV) adoption, leading to increased demand for EV charging infrastructure. Over the past decade, EV charging infrastructure site developers, site hosts, and electric distribution utilities have navigated the process to integrate chargers onto the electric grid. Site developers and site hosts have raised the alarm that the integration process for high-powered EV charging projects does not meet the needs of the EV market for timeliness or cost. High-powered charging stations typically require a load service request or an agreement with the local utility to connect to the grid. The process of energizing a new high-powered charging site can be complex and time-consuming, often taking up to 2 years. This timeline is the result of current utility energization processes having been designed for construction projects that take longer to build (i.e., buildings). The specific challenges stem from various factors, including compartmentalization in application processes, the integration of EV charging process approvals with other distributed energy resources (DERs), and the need to ensure grid reliability. The energization process needs to evolve to meet the growing demand for high-powered EV charging. This white paper compiles information gathered through various conversations with key stakeholders, including utilities, utility regulators, EV charging operators, site developers, and authorities having jurisdiction (AHJ) as well as through an extensive literature review. This document identifies the challenges and provides potential solutions to streamline the process of connecting EV charging infrastructure to the power grid in the United States, serving as a starting point for future conversations around these solutions. The solutions noted in this white paper require collaborative efforts among utilities, regulators, and EV charging infrastructure developers to streamline the grid connection process for EV charging infrastructure. They are broadly organized into four areas: 1. Increase data access and transparency: Develop automated load service request tools, integrate hosting capacity and load service request analyses, incorporate EV adoption forecasts, and provide transparency on the processing queue. 2. Improve energization processes and timing: Create fast-track options based on prescreening criteria, provide flexibility or phased approvals in the load service request/interconnection process, build internal knowledge within utilities about EV charging technologies, and provide standardized workforce training. 3. Promote economic efficiency: Right size distribution components to accurately reflect the load requirements of EV charging infrastructure, make proactive investments in grid infrastructure based on EV adoption forecasts and growth projections, and consider energy equity and environmental justice factors such as equitable access to EV charging when planning infrastructure. 4. Improve grid reliability and resilience: Use load management/power control systems (PCS) at EV charging stations, adopt and implement harmonized standards for communication protocols and information models between the EV charging and grid control infrastructure, and address cybersecurity considerations by implementing robust security measures and standards for EV charging infrastructure—with particular emphasis on clarifying the security requirements for the interface to the grid. The objective of the solutions proposed in this white paper is to accelerate the timeline and decrease costs associated with connecting EV charging infrastructure to the grid. Electric utilities, utility regulators, EV charging infrastructure developers, and site hosts will first need to understand which solutions are available in their service territory, and if warranted, which combination of solutions would support their specific needs. Through the successful implementations of solutions at scale detailed here, industry will demonstrate a new and innovative ecosystem where timely deployment and energization of EV charging infrastructure with greater grid resiliency and reliability is a reality.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Cybersecurity for Electric Vehicle Fast-Charging Infrastructure: Preprint

The integration of electric vehicles (EVs) into electric grid operations can potentially leave the grid vulnerable to cyberattacks from both legacy and new equipment and protocols, including extreme fast-charging infrastructure. This paper introduces a co-simulation platform to perform cyber vulnerability analysis of EV charging infrastructure and its dependencies on communications and control systems. Grid impact scenarios through linkages to power system simulation tools such as OpenDSS and vehicle infrastructure-specific attack paths are discussed. An adaptive platform that assists with predicting and solving evolving cybersecurity challenges is demonstrated with a cyber-energy emulation that accelerates the analysis of cyberattacks and system behavior.

47 OTHER INSTRUMENTATION↗