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Results for “coherent precipitation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Stress field and interaction forces between dislocations and precipitate distributions

A computational method is developed for calculation of the stress field and interaction forces between dislocations and precipitates of arbitrary shape and distribution. The internal stress generated by precipitates due to coherency strain is implemented within the discrete dislocation dynamics (DDD) framework. The s-version finite element method (s-FEM), which models a precipitate of arbitrary shape using a local mesh is used to calculate coherency stress fields. The method facilitates meshing precipitate volumes of arbitrary geometry, and multiple local meshes can be superimposed at various positions of the global mesh. Accuracy and convergence conditions of the method are established. For a single precipiate, the method is shown to be 3.5 times faster than a standard FEM calculation for the same accuracy, and the gain in speed increases with the number of precipitates. The CRSS of spherical precipitates is found to be higher than disk-shaped precipitates of the same volume fraction.

42 ENGINEERING↗
DOE OSTI2020

Extensive nanoprecipitate morphology transformation in a nanostructured ferritic alloy due to extreme thermomechanical processing

Nano-oxide precipitates in a modern nanostructured ferritic alloy were investigated after extreme thermomechanical processing into a thin-walled tube geometry. It was found that the morphology of the precipitates changed from spherical to rod-shaped, with some increasing to aspect ratios of up to 9, despite the precipitate volume fraction (0.3%) and number density (> 10 23 m -3 ) of precipitates remaining unchanged. High-resolution electron microscopy showed that the precipitates likely remained coherent with the Fe-matrix, while atom probe tomography confirmed that the precipitate compositions remained unaffected by the transformation. The morphological change was attributed to the shearable nature of the (Y,Ti,O)-rich precipitates, indicating they should be considered as “soft” obstacles to dislocation motion. The elongation was most pronounced in larger (>5 nm) precipitates, which may be caused by preferential dissolution of the smallest (1–3 nm) precipitates followed by the competition between re-precipitation and solute diffusion to larger precipitates during recovery heat treatments.

36 MATERIALS SCIENCE↗
NASA NTRS2002

The Evolution of El Nino-Precipitation Relationships from Satellites and Gauges

This study uses a twenty-three year (1979-2001) satellite-gauge merged community data set to further describe the relationship between El Nino Southern Oscillation (ENSO) and precipitation. The globally complete precipitation fields reveal coherent bands of anomalies that extend from the tropics to the polar regions. Also, ENSO-precipitation relationships were analyzed during the six strongest El Ninos from 1979 to 2001. Seasons of evolution, Pre-onset, Onset, Peak, Decay, and Post-decay, were identified based on the strength of the El Nino. Then two simple and independent models, first order harmonic and linear, were fit to the monthly time series of normalized precipitation anomalies for each grid block. The sinusoidal model represents a three-phase evolution of precipitation, either dry-wet-dry or wet-dry-wet. This model is also highly correlated with the evolution of sea surface temperatures in the equatorial Pacific. The linear model represents a two-phase evolution of precipitation, either dry-wet or wet-dry. These models combine to account for over 50% of the precipitation variability for over half the globe during El Nino. Most regions, especially away from the Equator, favor the linear model. Areas that show the largest trend from dry to wet are southeastern Australia, eastern Indian Ocean, southern Japan, and off the coast of Peru. The northern tropical Pacific and Southeast Asia show the opposite trend.

Curtis, Scott↗
DOE OSTI2024

Microstructural and Hall–Petch Analysis of Additively Manufactured Ferritic Alloy Using 2507 Duplex Stainless Steel Powder

The powder bed fusion–laser beam (PBF-LB) process, a method of additive manufacturing (AM), was used to print duplex stainless steel (DSS) using commercial-grade 2507 powders. While conventionally processed DSS has a two-phase microstructure consisting of 50% austenite and 50% ferrite, the PBF-LB-printed 2507 alloy was nearly 100% ferrite. Optimal processing conditions that minimized porosity were determined to be 290 W laser power and 1000 mm/s scan speed, and grain size, texture, and phases were characterized as a function of laser power and scan speed. Grain size increased with increasing laser power but decreased with increasing scan speed. A <100> texture diminished with increasing scan speed from 1000 mm/s to 1400 mm/s. No austenite phase was detected. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) characterization revealed nanoscale chromium nitride precipitates in the ferritic matrix (incoherent hexagonal close-packed (HCP) precipitates at grain boundaries and coherent body-centered cubic (BCC) precipitates within the grains) and a high density of tangled dislocations. Tensile tests of as-printed alloys showed a yield strength of 570 MPa, an ultimate tensile strength of 756 MPa, and an elongation to failure of 10%. The tensile properties were analyzed based on the observed microstructure considering grain size, nanoscale precipitates, and the high density of dislocations.

Crystallography↗
DOE OSTI2025

Local chemical ordering of a neutron-irradiated CrFeMnNi compositionally complex alloy

While ion-irradiation studies are a critical first step in studying compositionally complex alloys (CCAs) for nuclear applications, they do not capture all the microstructural changes occurring under the low irradiation dose rates and different particles’ scattering patterns experienced in a nuclear reactor setting. To explore these phenomena in reactor-relevant conditions for the first time in CCA, the single-phase solid-solution Cr 10 Fe 30 Mn 30 Ni 30 was neutron irradiated up to 6.61 displacements per atom at 395 and 579 °C. Irradiation-enhanced local chemical ordering (LCO) well beyond the range of short range ordering was observed, and is predicted to be the precursor to the precipitation of a coherent Ni-Mn L1 0 phase and a Cr-rich α’ phase, though TEM analysis did not indicate the presence of either in any irradiation condition. The line density of faulted dislocation loops decreased from 6.47 to 1.69 ∙ 10 15 m -2 from 3.43 to 6.61 dpa at 579 °C despite no appreciable faulted loop content in the unirradiated material. LCO is expected to increase the complexity of the energy landscape within this alloy, restricting interstitial point defect mobility and creating local regions of greater stacking fault energy. These contribute to the negative correlation between irradiation dose and faulted dislocation loop density in this study, as well as the lack of void swelling observed.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Superalloy composition modeling

Development of a predictive method for determination of the gamma/gamma prime phase fields, i.e., gamma prime volume fraction as a function of the multicomponent composition, is described. The cluster variation method used for binary alloys in which the precipitated phase is coherent with the matrix phase is extended for application to the multicomponent coherent gamma/gamma prime nickel-based superalloys. It is shown that the cluster variation method can accurately describe the equilibrium (incoherent) gamma/gamma prime phase fields in the binary Ni-Al phase diagram. The gamma/gamma prime phase field for the Ni-Cr-Al ternary phase diagram is computed as a function of temperature. A reasonable fit results between the calculated and the experimental diagrams. The modeling of the six-component Ni-Cr-Al-Co-Mo-Ti base superalloy and the effect of Ni substitution of Co are discussed.

Barefoot, J.↗
NASA NTRS1982

Role of cobalt in nickel base superalloys

The effect of cobalt or substituting for cobalt on the mechanical properties of nickel-based superalloys is discussed. Waspaloy, UDIMET 700, and NIMONIC 115, which are representative of Ni-Cr-Co-Al-Ti-Mo superalloys having different gamma prime contents which are strengthened by a heavily alloyed matrix, coherent gamma prime precipitates, and carbides at the grain boundaries. Microstructure and in situ and extracted phase STEM micro-analysis were used to evaluate the three alloys.

Jarrett, R.↗
NASA NTRS1984

Development of powder metallurgy 2XXX series Al alloys for high temperature aircraft structural applications

The objective of the present investigation was to improve the strength and fracture toughness combination of P/M 2124 Al alloys in accordance with NASA program goals for damage tolerance and fatigue resistance. Two (2) P/M compositions based on Al-3.70 Cu-1.85 Mg-0.20 Mn with 0.12 and 0.60 wt. pct. Zr were selected for investigation. The rapid solidification rates produced by atomization were observed to prohibit the precipitation of coarse, primary Al3Zr in both alloys. A major portion of the Zr precipitated as finely distributed, coherent Al3Zr phases during vacuum preheating and solution heat treatment. The proper balance between Cu and Mg contents eliminated undissolved, soluble constituents such as Al2CuMg and Al2Cu during atomization. The resultant extruded microstructures produced a unique combination of strength and fracture toughness. An increase in the volume fraction of coherent Al3Zr, unlike incoherent Al20Cu2Mn3 dispersoids, strengthened the P/M Al base alloy either directly by dislocation-precipitate interactions, indirectly by a retardation of recrystallization, or a combination of both mechanisms. Furthermore, coherent Al3Zr does not appear to degrade toughness to the extent that incoherent Al20Cu2Mn3 does. Consequently, the addition of 0.60 wt. pct. Zr to the base alloy, incorporated with a 774K (935 F) solution heat treatment temperature, produces an alloy which exceeds all tensile property and fracture toughness goals for damage tolerant and fatigue resistant applications in the naturally aged condition.

Chellman, D. J.↗
DOE OSTI2026

Microstructural evolution, defect mitigation, and precipitation behavior in AA6061 via laser powder bed fusion with high-temperature substrate heating

Defects, particularly solidification cracking, remain persistent challenges in the laser powder bed fusion (LPBF) processing of AA6061 aluminum alloy. This study systematically investigates defect mitigation, microstructural evolution, and mechanical properties associated with high-temperature substrate preheating at 500 °C. Comprehensive microstructural analyses, including characterization of defects, grain structures, and precipitation behavior, were performed on samples in both as-built and T6 heat-treated states. Elevated preheating substantially reduced solidification cracking across a wide processing window, while demonstrating decreased crack sensitivity to laser parameters. Columnar cracks along the build direction were observed despite substrate preheating. Lack-of-fusion and keyhole porosity were effectively eliminated, though gas-induced microporosity persisted at higher powers. In-depth characterization of two distinct laser power and speed conditions confirmed the formation of micron-sized, non-coherent Mg 2 Si precipitates under heated substrate conditions, alongside α-AlFeCrMnSi intermetallic phases indicative of in-situ thermal effects during fabrication. Subsequent T6 heat treatment revealed the formation of fine, coherent needle-shaped β″ strengthening precipitates. Despite substantial differences in processing parameters, comparable mechanical properties were measured in the as-built samples (∼52 MPa yield strength, ∼130 MPa tensile strength), primarily due to reduced strain hardening effects and consistent precipitation characteristics. Meanwhile, the T6 heat treatment led to significant improvement in properties, enhancing yield strength by over 400%, aligning closely with the performance of conventional wrought AA6061-T6. These findings underscore that high-temperature substrate preheating offers an effective means to suppress cracks, control precipitation, and enhance mechanical performance in LPBF-processed AA6061.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Effect of thermal treatments on electrochemical behavior of binder jetted 17-4 PH stainless steel

Binder jetted 17–4 PH stainless steel was post-processed to relate heat treatment, microstructure, and corrosion in 3.5 wt% NaCl. Specimens were sintered at 1380 or 1400 °C, solution-annealed at 1055 °C for 1 h, and aged at 482 °C for 1 h. Here, as-sintered parts showed α′-martensitic matrix with a δ-ferrite network and Cu-rich precipitates in ferrite; inclusions (MnS, NbC) promoted localized attack. solutionizing redistributed elements and reduced ferrite, while aging generated coherent Cu nano-precipitates. Corrosion resistance was highly sensitive to post-processing in which aged specimens exhibited the lowest corrosion current density and formed a thicker, stable Cr 2 O 3 -rich passive film, whereas sintered specimens degraded most. Pitting potential depended on sintering temperature and microstructure, with 1400 °C sintering yielding more positive pitting potentials and the best overall performance after aging. Although the 1400-solutionized condition showed a relatively noble pitting response versus 1380-solutionized, it displayed unstable corrosion kinetics attributed to an imperfect passive film linked to higher NbC density. XPS depth profiles corroborated these trends, showing thicker, more continuous Cr 2 O 3 in aged states and discontinuous/thinning oxides in less resistant conditions. Practically, high-temperature sintering (∼1400 °C) followed by solutionizing and aging is recommended, with further gains expected from reducing NbC/MnS populations and porosity via powder and process control.

36 MATERIALS SCIENCE↗
DOE OSTI2026

A theoretical index for understanding distinct land relative humidity trends in observations, reanalyses, and models

Land surface relative humidity (RH) is a key variable in the coupled land–atmosphere system that profoundly influences terrestrial hydroclimate and ecosystems. Yet historical changes in land RH are not well understood due to limited observations, biased reanalyses, and the lack of a framework for interpreting RH changes under multiple influencing factors. Here, we show that the spatiotemporal variability of land RH and its distinct historical trends among observations, reanalyses, and Earth system models are captured by a simple index based on the ratio of precipitation (P) to a modified potential evapotranspiration formulated independently of RH (PET°). The index provides a physical calibration of biased land RH in reanalyses and a quantitative framework for interpreting land RH changes. Over 1973–2024, land RH has decreased substantially, owing to the intrinsic rise in PET° with temperature and little increase in land precipitation. Reanalyses overestimate the observed RH decrease, consistent with exaggerated surface warming and precipitation decline. The index captures this coherent bias and enables a calibration using observed precipitation and temperature. Models simulate a wide range of land RH trends, but nearly all runs underrepresent the historical drying. The index captures the model spread and discrepancy and attributes them to contributions of precipitation and PET°. Weaker land RH decreases in models arise mainly from weaker subtropical precipitation declines, linked to muted intensification of subtropical highs and biased subtropical climatology. The model–observation discrepancy is unlikely explained by internal variability, implying model underestimation of forced RH decrease and a drier land future than current projections.

Earth system models↗
DOE OSTI2022

Uncovering the role of nanoscale precipitates on martensitic transformation and superelasticity

Here we characterize the role of coherent nanoscale B2 Ni 50 Al 50 precipitates on the temperature- and stress-induced martensitic phase transformation in nanocrystalline Ni 63 Al 37 shape memory alloys using multi-million-atoms molecular dynamics (MD) simulations. We studied two types of precipitates: one with single crystal precipitates (SXP) and a second where grain boundaries cut through precipitates (PXP). Simulations reveal that the presence of B2 precipitates stabilizes the cyclic flag-shaped stress-strain response, characteristic of superelasticity, and reduces remnant strain. In contrast, single-phase nanocrystalline Ni 63 Al 37 exhibits degradation of the reverse transformation during cyclic loading and, eventually, incomplete reversible transformation within a few cycles. This is consistent with previous experimental findings of ultra-low fatigue in Ni-Ti-Cu alloys with Ti 2 Cu precipitates. The simulations reveal that the presence of precipitates significantly improves the reversibility of the transformation by acting as elastic zones that partially shield the martensitic transformation and drive the reverse transformation. A detailed analysis of the MD trajectories reveals that the martensitic transformation of the matrix induces ultra-large elastic deformation in some of the B2 precipitates (approximately 12%) to the point of resulting in a martensite-like atomic structure.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Phase field modeling of shearing processes of a dual-lobed γ"|γ'|γ" coprecipitate

The Ni-based superalloy IN718 is one of the most widely used commercial alloy in the aerospace industry since its development in 1960s. The excellent mechanical properties have been attributed in a great deal to strengthening by coherent γ' and γ" precipitates. The deformation mechanisms of these two phases have been well studied individually. Recent experimental characterization has shown coprecipitates of these two phases in a variety of morphologies and it was argued that these coprecipitates may lead to improved strengthening as compared to their monolithic counterparts. However, the deformation mechanisms of these coprecipitates are still not well understood. In this study, we performed microscopic phase field simulations, with generalized-stacking-fault (GSF) energy surfaces from ab initio calculations as inputs, to systematically study the shearing processes of a periodical array of dual-lobed coprecipitates as well as monolithic precipitates. We found that the coupling between the γ' and γ" phases in the coprecipitates forces dislocations to take high energy shearing pathways in both phases that would not occur if they were in monolithic forms. The coupling also creates stacking fault configurations in the coprecipitates that require high stress to form. Thus, the presence of coprecipitates in general should increase the resistance to dislocation shearing and lead to higher strength levels. Various fault configurations observed during the shearing process are documented as a reference for future comparison with experimental observations. The link between stacking fault shearing and microtwinning is also discussed. Here, the mechanisms analyzed in this study deepens our understanding of coprecipitation effects on alloy strength and may form a cornerstone for multi-precipitate strengthened alloy design strategies.

36 MATERIALS SCIENCE↗
NASA NTRS1978

Diffuse auroral precipitation

The paper summarizes the development of a plausibly coherent view of the self-consistent coupling of convection in the plasma sheet to auroral particle precipitation and the ionosphere. Attention is given to an understanding of the plasma instabilities responsible for diffuse auroral precipitation. The electrostatic ion and electron cyclotron harmonic loss-cone instabilities seem to be the best candidates, although they depend sensitively upon the cold electron density and temperature deep in space on auroral field lines. However, there is little or no experimental or theoretical information about these parameters. For this reason, further theoretical progress on cyclotron harmonic instabilities will be limited until the cold electron temperature is known. Also necessary are a complete phenomenological understanding of ion harmonic modes and a modeling of the cold electron distribution on auroral field lines.

Ashour-Abdalla, M.↗
NASA NTRS2016

Comparison of gamma-gamma Phase Coarsening Responses of Three Powder Metal Disk Superalloys

The phase microstructures of several powder metal (PM) disk superalloys were quantitatively evaluated. Contents, chemistries, and lattice parameters of gamma and gamma strengthening phase were determined for conventionally heat treated Alloy 10, LSHR, and ME3 superalloys, after electrolytic phase extractions. Several of long term heat treatments were then performed, to allow quantification of the precipitation, content, and size distribution of gamma at a long time interval to approximate equilibrium conditions. Additional coarsening heat treatments were performed at multiple temperatures and shorter time intervals, to allow quantification of the precipitation, contents and size distributions of gamma at conditions diverging from equilibrium. Modest differences in gamma and gamma lattice parameters and their mismatch were observed among the alloys, which varied with heat treatment. Yet, gamma coarsening rates were very similar for all three alloys in the heat treatment conditions examined. Alloy 10 had higher gamma dissolution and formation temperatures than LSHR and ME3, but a lower lattice mismatch, which was slightly positive for all three alloys at room temperature. The gamma precipitates of Alloy 10 appeared to remain coherent at higher temperatures than for LSHR and ME3. Higher coarsening rates were observed for gamma precipitates residing along grain boundaries than for those within grains in all three alloys, during slow-moderate quenching from supersolvus solution heat treatments, and during aging at temperatures of 843 C and higher.

Superalloys↗