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At least 541 records · Page 30

Life-cycle costing assessment of back contact doping and encapsulation alternatives for increasing the life expectancy of CdTe PV modules (Final Report)

Contribution of Research to the State-of-Knowledge This research produced comparative sustainability evaluations of back contact doping and encapsulation alternatives considered by First Solar for decreasing degradation and increasing the life of the cadmium telluride (CdTe) photovoltaic (PV) modules. Technical Effectiveness and Economic Feasibility of Methods Investigated A holistic life-cycle-assessment of the alternatives considered for longer module operational lives, showed that they add between 0.2% and 2% to environmental impact indicators at the cradle-to-gate module level, but at the cradle-to-grave system level, alternative materials offer only benefits (i.e., environmental impact indicator decreases) to the public and the environment. Parallel experimental studies at First Solar showed that the use of the considered alternative materials did not impact the effectiveness of the current module recycling separations and material recovery processes. Furthermore, the increment on the module manufacturing cost due to using alternative materials was estimated to be negligible (i.e., >1%) and longer module lives more than compensate cost increases. Specifically, increase of the current warranted module life of 30 years to 50 years, would decrease the levelized cost of electricity (LCOE) from $40/MWh to $24/MWh for utility-scale installations in the US-SW, the economic feasibility of the considered alternatives is assured. Benefit to the Public With decreasing degradation from the current ~0.3%/year of Series 6 modules to less than 0.2%/year, the public will be benefited by longer photovoltaic operational lives, and therefore. In addition, the requirement for end-of-life management is shifted from 30 years to 40 or 50 years, with profound benefits to the public and the environment.

14 SOLAR ENERGY↗

Task 12 PV Sustainability - Human Health Risk Assessment Methods for PV, Part 3: Module Disposal Risks

End-of-life management is important for addressing large future photovoltaic (PV) waste volumes and conserving raw materials for use in new PV modules. In regions without regulatory mandates for PV recycling, end-of-life PV modules can be disposed in accordance with general waste laws. Given the use of various metals as raw materials in semiconductor compounds and electrical contacts in commercial PV modules, some stakeholders have raised concerns regarding potential environmental impacts if PV modules are subject to improper disposal instead of being recycled or disposed in sanitary landfills, as is required in most world regions. To evaluate these concerns, screening-level risk assessment methods are developed herein that evaluate potential human health risks from groundwater and surface (air, soil, surface water) exposure pathways. The methods estimate potential impacts from disposal of end-of-life (EOL) PV modules in non-sanitary landfills under the following worst-case conditions: no leachate collection or groundwater monitoring, no liner for preventing leachate migration, uncovered waste, and lack of stormwater management. Examining worst-case conditions allows the exploration of maximum potential risk to attempt to ensure disposal does not increase health risk above regulatory thresholds. Specifically, this report presents an analysis of potential human health risks associated with non-sanitary landfill disposal for three PV technologies, focusing on release of the highest-prioritized chemical element for each: lead (Pb) in crystalline-silicon (c-Si) PV modules, cadmium (Cd) in thin film cadmium telluride (CdTe) PV modules, and selenium (Se) in thin film copper indium selenide (CIS) PV modules. The prioritization of these chemical elements for analysis is based on stakeholder interest. Because the methodology is chemical-specific, the risk assessment results for these chemicals cannot be directly generalized to other chemicals, although the risk assessment methodology can be applied to other chemicals. If the chemicals chosen are indeed the ones presenting greatest risk, then the results herein should represent the upper bound of health risk from exposure to a single constituent.

14 SOLAR ENERGY↗

Development of POTATO for 2S Module Grading for the CMS Phase-2 Outer Tracker Upgrade

Due to the High Luminosity-Large Hadron Collider (HL-LHC) upgrade, several detectors of the Compact Muon Solenoid (CMS) will need to be replaced, specifically the new Outer Tracker (OT) that will be assembled with 13,200 silicon modules. The OT is composed of two types of modules; the PS (pixel-strip) and the 2S (strip-strip) modules. With a large influx of production of modules, extensive testing is required to ensure quality of the modules. This research introduces POTATO (Phase-II Outer Tracker Analyzer of Test Outputs), a specialized software developed in C++ to analyze, grade, and store results in a centralized database. Module data will be collected from various international production facilities. The implementation of POTATO will facilitate with selecting the best performing modules for the Outer Tracker upgrade. This research is focused on the implementation of the analysis of 2S Module results within POTATO.

Klupshas, Anna↗

POTATO: A Unified Assessment System for HL-LHC Outer Tracker Module Productions

The CMS detector s silicon tracker will be replaced in preparation for the upcoming High-Luminosity LHC (HL LHC) upgrade. The inner tracker will include a new pixel detector while the outer tracker (OT) will feature 5,592 pixel strip (PS) and 7,608 strip strip (2S) sensor modules with production distributed across 7 sites worldwide, requiring standardized grading and testing. One testing apparatus the burn-in box replicates the temperature cycling conditions that successful modules must withstand. The Phase-II Outer Tracker Analyzer of Test Outputs (POTATO) standardizes module evaluation and grading among testing sites. Given burn-in box test output, POTATO analyzes the results and assigns a letter grade to a module and its sub-components. POTATO's grading process must adapt to evolving standards for module evaluation; hence, we detail work on POTATO's database and grading functionality that will facilitate the unified assessment of Phase-II OT module assembly and testing worldwide. Once completed, POTATO will allow technicians to interact with a database of all graded modules and efficiently assess the global module assembly effort.

Clark, Olivia J. [U. Tennessee, Knoxville]↗

A Solid-State Nanosecond Beam Kicker Modulator Based on the DSRD Switch

A fast solid-state beam kicker modulator is under development at the SLAC National Accelerator Laboratory. The program goal is to develop a modulator that will deliver 4 ns, {+-}5 kV pulses to the ATF2 damping ring beam extraction kicker. The kicker is a 50 {Omega}, bipolar strip line, 60 cm long, fed at the downstream end and terminated at the upstream end. The bunch spacing in the ring is 5.6 ns, bunches are removed from the back end of the train, and there is a gap of 103.6 ns before the next train. The modulator design is based on an opening switch topology that uses Drift Step Recovery Diodes as the opening switches. The design and results of the modulator development are discussed. There are many applications that benefit from very fast high power switching. However, at MW power levels and nanosecond time scales, solid state options are limited. One option, the Drift Step Recovery Diode (DSRD) has been demonstrated as capable of blocking thousands of volts and switching in nanosecond to sub-nanosecond ranges. When used as an opening switch, the DSRD exhibits a very fast turn off transient. The process is described in detail by its pioneers in [5,6]. In essence, charge is pumped into and then extracted from the DSRD under pulsed conditions. The turn off transient occurs precisely when the pumped charge is equal to the extracted charge and the DSRD is switched off. At the SLAC National Accelerator Laboratory, a DSRD is being used as an opening switch in the development of a fast kicker modulator. The modulator is designed to create {+-}5kV pulses with <1ns rise and fall time on a 50{Omega} strip line kicker. As is common in beam optics, the absence of power in the kicker before and after the pulse is very important. The entire {+-}5kV kicker modulator is composed of two identical 5kV pulsing circuits, each with its own DSRD component. This paper describes the modulator topology and the status of tests on one of the two 5kV pulse circuits.

43 PARTICLE ACCELERATORS↗

Testing Protocol for Module Encapsulant Creep (Presentation)

Recently there has been an interest in the use of thermoplastic encapsulant materials in photovoltaic modules to replace chemically crosslinked materials, e.g., ethylene-vinyl acetate. The related motivations include the desire to: reduce lamination time or temperature; use less moisture-permeable materials; or use materials with better corrosion characteristics. However, the use of anythermoplastic material in a high-temperature environment raises safety and performance concerns, as the standardized tests currently do not expose the modules to temperatures in excess of 85C, yet modules may experience temperatures above 100C in operation. Here we constructed eight pairs of crystalline-silicon modules and eight pairs of glass/encapsulation/glass mock modules using differentencapsulation materials of which only two were designed to chemically crosslink. One module set was exposed outdoors with insulation on the back side in Arizona in the summer, and an identical set was exposed in environmental chambers. High precision creep measurements and performance measurements indicate that despite many of these polymeric materials being in the melt state at some of thehighest outdoor temperatures achievable, very little creep was seen because of their high viscosity, temperature heterogeneity across the modules, and in the case of the crystalline-silicon modules, the physical restraint of the backsheet. These findings have very important implications for the development of IEC and UL qualification and safety standards, and in regards to the necessary level ofcure during the processing of crosslinking encapsulants.

14 SOLAR ENERGY↗

Standards for PV Modules and Components -- Recent Developments and Challenges: Preprint

International standards play an important role in the Photovoltaic industry. Since PV is such a global industry it is critical that PV products be measured and qualified the same way everywhere in the world. IEC TC82 has developed and published a number of module and component measurement and qualification standards. These are continually being updated to take advantage of new techniques and equipment as well as better understanding of test requirements. Standards presently being updated include the third edition of IEC 61215, Crystalline Silicon Qualification and the second edition of IEC 61730, PV Module Safety Requirements. New standards under development include qualification of junction boxes, connectors, PV cables, and module integrated electronics as well as for testing the packaging used during transport of modules. After many years of effort, a draft standard on Module Energy Rating should be circulated for review soon. New activities have been undertaken to develop standards for the materials within a module and to develop tests that evaluate modules for wear-out in the field (International PV Module QA Task Force). This paper will discuss these efforts and indicate how the audience can participate in development of international standards.

14 SOLAR ENERGY↗

PV module mounting method and mounting assembly

A method for mounting PV modules to a deck includes selecting PV module layout pattern so that adjacent PV module edges are spaced apart. PV mounting and support assemblies are secured to the deck according to the layout pattern using fasteners extending into the deck. The PV modules are placed on the PV mounting and support assemblies. Retaining elements are located over and secured against the upper peripheral edge surfaces of the PV modules so to secure them to the deck with the peripheral edges of the PV modules spaced apart from the deck. In some examples a PV module mounting assembly, for use on a shingled deck, comprises flashing, a base mountable on the flashing, a deck-penetrating fastener engageable with the base and securable to the deck so to secure the flashing and the base to the shingled deck, and PV module mounting hardware securable to the base.

42 ENGINEERING↗

Electroabsorption optical modulator

An electroabsorption modulator incorporates waveguiding regions along the length of the modulator that include quantum wells where at least two of the regions have quantum wells with different bandgaps. In one embodiment of the invention, the regions are arranged such that the quantum wells have bandgaps with decreasing bandgap energy along the length of the modulator from the modulator's input to its output. The bandgap energy of the quantum wells may be decreased in discrete steps or continuously. Advantageously, such an arrangement better distributes the optical absorption as well as the carrier density along the length of the modulator. Further advantageously, the modulator may handle increased optical power as compared with prior art modulators of similar dimensions, which allows for improved link gain when the optical modulator is used in an analog optical communication link.

42 ENGINEERING↗

Predicting Future Solar Modulation and Implementation in MCNP6

The application of detecting low level radiation in the field requires quantification of the natural radiation background specific to that location. This background is made up two primary components: naturally decaying radionuclides in the soil and atmosphere known as terrestrial background, and the particle cascades caused by high energy cosmic radiation interacting within the earth's atmosphere known as cosmic background. The terrestrial component dominates the background spectrum below approximately 2 MeV, however, the cosmic component comprises the entirety of the high-energy spectrum. Furthermore, the terrestrial component is relatively constant for a given location while the cosmic component is heavily dependent on solar activity, an effect known as solar modulation. Annual values of the solar modulation parameter, φ, have been determined since 1936, and their fluctuations are seen to be roughly sinusoidal over time. If one wished to predict or simulate the outcome of an experiment in the future, a prediction for the solar modulation would be necessary to accurately determine the cosmic background contribution. The previous version 6.1.1 of MCNP contained solar modulation data for 46 years between 1960 and 2005. This data was updated with newer solar modulation data, from I. G. Usoskin et al., which reports solar modulation data for an additional 33 years between 1936 and 2014. In order to use past solar modulation data to predict cosmic background radiation fluctuations for dates beyond 2014 an algorithm was developed to forecast future solar modulation data based on the sinusoidal behavior exhibited in recorded data. This algorithm was implemented into MCNP 6.1.2 to be used for cosmic background simulations and tested against benchmark data to assess its accuracy. (authors)

54 ENVIRONMENTAL SCIENCES↗

Irisin reverses platelet derived growth factor-BB-induced vascular smooth muscle cells phenotype modulation through STAT3 signaling pathway

Vascular smooth muscle cells (VSMCs) phenotype modulation toward a synthetic phenotype is the main cause of cardiovascular disease. As a newly discovered myokine, Irisin is thought to be a promising candidate for the treatment of metabolic disturbances, as well as cardiovascular disease. However, no evidence has been shown for the direct effect of Irisin on VSMCs phenotype modulation and its underling mechanisms. The aim of this study was to explore the effect of Irisin on VSMCs phenotype modulation and the mechanisms involved. In the present study, it was found that Irisin restored the PDGF-BB-induced VSMCs phenotype modulation which exhibited down-regulation of smooth muscle cells (SMC) expression and up-regulation of matrix synthesis related marker expression, as well as proliferative phenotype. Moreover, our research demonstrated that Irisin further activated STAT3 signaling pathways. Finally, by applying an STAT3 inhibitor, WP1066, we revealed the roles of STAT3 in the PDGF-BB-induced VSMCs phenotype modulation when they were treated with Irisin. Taken together, these results demonstrated that Irisin may play a crucial role in regulating VSMCs phenotype modulation via the STAT3 signaling pathway. - Highlights: • Irisin prevents PDGF-BB-stimulated VSMCs dedifferentiation. • Irisin inhibits VSMCs towards a proliferative synthetic phenotype induced by PDGF-BB stimulation. • Irisin treatment further activates STAT3 in VSMCs. • The effect of Irisin on VSMCs phenotype modulation might be STAT3-dependent.

60 APPLIED LIFE SCIENCES↗

A computational investigation of high-flux, plate-and-frame membrane modules for industrial carbon capture

In this work, we study the application of membrane-based separation systems for carbon capture, considering plate-and-frame membrane modules. The successful deployment of membrane CO 2 capture system relies on high-performing membranes as well as effective membrane modules that can fully exploit the developed membranes. A plate-and-frame membrane module is especially attractive for CO 2 capture from industrial flue gas due to its lower pressure drop compared to its counterparts such as spiral wound modules and hollow fiber modules. To design better plate-and-frame modules, we investigate their basic unit - a single membrane stack through a combination of computational modeling and experimental investigations. The modeling approach is based on Computational Fluid Dynamics (CFD) to represent a multiphysics problem, including the fluid flow and diffusion processes within a membrane module. We use experimental data collected under different operating conditions to validate the CFD model. Numerical results suggest a good agreement between experiments and model outputs for the CO 2 recovery, CO 2 mole fraction in the retentate and permeate, and stage-cut. The CFD model is able to predict accurately the flow behavior, providing valuable insights on the effects of fluid dynamics on mass transfer of CO 2 . We also carry out a sensitivity analysis to identify the effect of key parameters on the CO 2 recovery and the CO 2 purity of the outlet streams.

CFD simulation↗

Highly efficient terahertz wave modulators by photo-excitation of organics/silicon bilayers

Using hybrid bilayer systems comprising a molecular organic semiconductor and silicon, we achieve optically controllable active terahertz (THz) modulators that exhibit extremely high modulation efficiencies. A modulation efficiency of 98% is achieved from thermally annealed C{sub 60}/silicon bilayers, due to the rapid photo-induced electron transfer from the excited states of the silicon onto the C{sub 60} layer. Furthermore, we demonstrate the broadband modulation of THz waves. The cut-off condition of the system that is determined by the formation of efficient charge separation by the photo-excitation is highly variable, changing the system from insulating to metallic. The phenomenon enables an extremely high modulation bandwidth and rates of electromagnetic waves of interest. The realization of near-perfect modulation efficiency in THz frequencies opens up the possibilities of utilizing active modulators for THz spectroscopy and communications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The effects of control field detuning on the modulation instability in a three-level quantum well system

The paper presents a theoretical study of the modulation instability of a continuous or quasi-continuous optical probe in a three level quantum well system under electromagnetically induced transparency. The modulation instability is affected by the control field detuning, as well as even-order dispersion and by the strength of Kerr (third-order) and quintic (fifth-order) nonlinearities. The fourth-order dispersion reduces the bandwidth over which modulation instability occurs, whereas the quintic nonlinearity saturates the growth of the modulation instability. Detuning the control field from resonance can significantly reduce the growth of the modulation instability at both low and high power levels. At low powers, the system becomes stable against modulation instability for small detuning of the control field and at high powers modulation instability disappears for larger detuning.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Wavelength-independent constant period spin-echo modulated small angle neutron scattering

Spin-Echo Modulated Small Angle Neutron Scattering (SEMSANS) in Time-of-Flight (ToF) mode has been shown to be a promising technique for measuring (very) small angle neutron scattering (SANS) signals and performing quantitative Dark-Field Imaging (DFI), i.e., SANS with 2D spatial resolution. However, the wavelength dependence of the modulation period in the ToF spin-echo mode has so far limited the useful modulation periods to those resolvable with the limited spatial resolution of the detectors available. Here we present our results of an approach to keep the period of the induced modulation constant for the wavelengths utilised in ToF. This is achieved by ramping the magnetic fields in the coils responsible for creating the spatially modulated beam in synchronisation with the neutron pulse, thus keeping the modulation period constant for all wavelengths. Such a setup enables the decoupling of the spatial detector resolution from the resolution of the modulation period by the use of slits or gratings in analogy to the approach in grating-based neutron DFI.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Role of density modulation in the spatially resolved dynamics of strongly confined liquids

Confinement by walls usually produces a strong modulation in the density of dense liquids near the walls. Using molecular dynamics simulations, we examine the effects of the density modulation on the spatially resolved dynamics of a liquid confined between two parallel walls, using a resolution of a fraction of the interparticle distance in the liquid. The local dynamics is quantified by the relaxation time associated with the temporal autocorrelation function of the local density. We find that this local relaxation time varies in phase with the density modulation. The amplitude of the spatial modulation of the relaxation time can be quite large, depending on the characteristics of the wall and thermodynamic parameters of the liquid. To disentangle the effects of confinement and density modulation on the spatially resolved dynamics, we compare the dynamics of a confined liquid with that of an unconfined one in which a similar density modulation is induced by an external potential. We find several differences indicating that density modulation alone cannot account for all the features seen in the spatially resolved dynamics of confined liquids. We also examine how the dynamics near a wall depends on the separation between the two walls and show that the features seen in our simulations persist in the limit of large wall separation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Inelastic dark matter with spin-dependent couplings to protons and large modulation fractions in DAMA

We discuss a scenario where the DAMA modulation effect is explained by a Weakly Interacting Massive Particle (WIMP) which upscatters inelastically to a heavier state and predominantly couples to the spin of protons. In this scenario constraints from xenon and germanium targets are evaded dynamically, due to the suppression of the WIMP coupling to neutrons, while those from fluorine targets are evaded kinematically, because the minimal WIMP incoming speed required to trigger upscatters off fluorine exceeds the maximal WIMP velocity in the Galaxy, or is very close to it. In this scenario WIMP scatterings off sodium are usually sensitive to the large-speed tail of the WIMP velocity distribution and modulated fractions of the signal close to unity arise in a natural way. On the other hand, a halo-independent analysis with more conservative assumptions about the WIMP velocity distribution allows to extend the viable parameter space to configurations where large modulated fractions are not strictly necessary. We discuss large modulated fractions in the Maxwellian case showing that they imply a departure from the usual cosine time dependence of the expected signal in DAMA. However we explicitly show that the DAMA data is not sensitive to this distortion, both in time and frequency space, even in the extreme case of a 100 % modulated fraction. Moreover the same scenario provides an explanation of the maximum in the energy spectrum of the modulation amplitude detected by DAMA in terms of WIMPs whose minimal incoming speed matches the kinematic threshold for inelastic upscatters. For the elastic case the detection of such maximum suggests an inversion of the modulation phase below the present DAMA energy threshold, while this is not expected for inelastic scattering. This may allow to discriminate between the two scenarios in a future low-threshold analysis of the DAMA data.

79 ASTRONOMY AND ASTROPHYSICS↗

ON THE MODULATION OF RR LYRAE STARS IN THE GLOBULAR CLUSTER M3

New, extended time-series photometry of M3 RR Lyrae stars has revealed that 4 of the 10 double-mode stars show large-amplitude Blazhko modulation of both radial modes. The first, detailed analysis of the peculiar behavior of the unique, Blazhko RRd stars is given. While the P1/P0 period ratio is normal, and the overtone mode is dominant in the other RRd stars of the cluster, the period ratio is anomalous and the fundamental mode has a larger (or similar) mean amplitude than the overtone has in Blazhko RRd stars. The modulations of the fundamental and overtone modes are synchronized only in one of the Blazhko RRd stars. No evidence of any connection between the modulations of the modes in the other three stars is found. The Blazhko modulation accounts, at least partly, for the previously reported amplitude and period changes of these stars. Contrary to the ∼50% Blazhko statistics of RRab and RRd stars, Blazhko modulation occurs only in 10% of the overtone variables in M3. Four of the five Blazhko RRc stars are bright, evolved objects, and one has a period and brightness similar to those of Blazhko RRd stars. The regions of the instability strip with high and low occurrence rates of the Blazhko modulation overlap with the regions populated by first- and second-generation stars according to theoretical and observational studies, raising up the possibility that the Blazhko modulation occurs preferentially in first-generation RR Lyrae stars.

79 ASTRONOMY AND ASTROPHYSICS↗