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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Modifying a silicone potting compound for space flight applications

RTV-615 has been devolatilized by subjecting the uncatalyzed resin to a temperature of between 125 and 150 C for 24 hours in a vacuum of about 10 to the -6th torr. The resultant resin can be catalyzed and after a room temperature cure the outgassing of the resin is sufficiently low when tested according to ASTM E-595 that it is suitable for space flight use. Tests of physical properties of the cured devolatilized resin were compared with those of the as received silicone. The devolatilized silicones are slightly harder, have a higher tear resistance and higher tensile strengths.

Park, J. J.↗
NASA NTRS1982

Cometary ephemerides for spacecraft flyby missions

The determination of cometary ephemerides is considered with reference to proposed missions to Comet Halley. It is noted that the ability of spacecraft without onboard navigation capability to fly close to target comets is limited chiefly by the comet's ephemeris uncertainty. The situation is complicated by nongravitational forces acting on a comet's nucleus and the paucity of observers currently making astrometric observations of comets. The nongravitational forces affecting Comet Halley are consistent with the rocket effect of an outgassing water ice nucleus; the nucleus is apparently rotating in a direct sense about a stable spin axis. It is emphasized that accurate Comet Halley ephemerides for close spacecraft flybys will require continued efforts to refine the existing nongravitational force model. In addition, the flyby mission to Comet Halley will require a well-organized network of astrometric observers. For this purpose, an Astrometry Network is being set up within NASA's International Halley Watch program.

Yeomans, D. K.↗
NASA NTRS1982

The derivation of Halley parameters from observations

Nominal value model parameters for the nucleus (size, mass, rotation, albedo, hydrogen production) the dust and gas for P/Halley at 0.9 AU postperihelion are derived from the light curve and spectra of Halley and by modeling the effect of the nongravitational forces, e.g., the outgassing rocket type effect of the nucleus. In those cases where Halley observations are not sufficient, the average value derived from a larger set of other comets is used, or data from comet Bennett, Halley's best analog, are taken. A flow diagram shows how the parameter values are derived and to what extent these derived values are interdependent. Previously announced in STAR as N82-23097

Newburn, R. L.↗
NASA NTRS1983

Surface characterization of Ti and Ti (6 percent, Al-4 percent, V) metal powders and interaction with primer solutions

The interaction of Ti and Ti 6-4 powders with water and primer solutions was investigated experimentally by measuring the heats of immersion. Similar comparative studies were made on anatase and rutile TiO2 powders. The surface oxide layers of Ti and Ti 6-4 cracked on heating in vacuum between 300 and 400 C as evidenced by high heats of immersion in both water and primer solutions. Polyimide and polyphenylquinoxaline interacted preferentially, compared with the solvents with both metal powders after outgassing at room temperature. The heats of immersion of Ti 6-4 in water, solvents, and primer solutions increased significantly after pretreatment of the powder by an alkaline etch and a phosphate-fluoride process. The TiO2 powders were not satisfactory models for the surface oxide layer on either Ti or Ti 6-4 powder.

Siriwardane, R. V.↗
NASA NTRS1983

Origin and evolution of the atmosphere of Venus

Implications for the origin and evolution of the terrestrial planets are drawn from a comparison of the Venus, earth and Mars atmosphere volatile inventories. Attention is given to the possible loss of an appreciable amount of water from Venus, in light of recent evidence for a 100-fold deuterium enrichment. Ar-40 and He-4 abundances suggest that outgassing has been inefficient for much of Venus's lifetime, in keeping with evidence for a lower level of tectonic activity on Venus than on the earth. Attention is also given to Venus's CO2 geochemistry. The picture now emerging is that of a Venus that began to evolve along a path similar to that of the earth, but suffered a catastrophic, runaway greenhouse effect early in its lifetime. How early the castastrophe occurred may be suggested by the presently low inventories of radiogenic argon and helium in its atmosphere.

Donahue, T. M.↗
NASA NTRS1983

Interaction of hydrogen chloride and water with oxide surfaces. III - Titanium dioxide

The adsorption of hydrogen chloride and water vapors on five TiO2 powders in both the anatase and rutile crystalline forms was studied as a function of temperature, pressure, and outgas conditions. The adsorbents were characterized utilizing X-ray powder diffraction, scanning electron microscopy, surface area analysis, indicator method, microelectrophoresis, XPS, and infrared spectroscopy. It was found that both outgas temperature and adsorption temperature influenced the adsorption of water vapor on TiO2, while water vapor adsorption on TiO2 was completely reversible. It is argued that the number of hydroxyl groups present on the surface determines the adsorption capacity of water on the different titanium dioxides. It was found that heats of immersion in water were affected significantly by outgas temperature. Hydrogen chloride adsorption isotherms at 30 C measured on TiO2 after outgassing at 100-400 C showed that a part of the total HCl adsorbed was irreversibly adsorbed. The highest HCl adsorption capacity per unit area was exhibited by anatase, while pure rutile exhibited the lowest adsorption capacity.

Siriwardane, R. V.↗
NASA NTRS1983

Shuttle measured contaminant environment and modeling for payloads. Preliminary assessment of the space telescope environment in the shuttle bay

A baseline gaseous and particulate environment of the Shuttle bay was developed based on the various measurements which were made during the first four flights of the Shuttle. The environment is described by the time dependent pressure, density, scattered molecular fluxes, the column densities and including the transient effects of water dumps, engine firings and opening and closing of the bay doors. The particulate conditions in the ambient and on surfaces were predicted as a function of the mission time based on the available data. This basic Shuttle environment when combined with the outgassing and the particulate contributions of the payloads, can provide a description of the environment of a payload in the Shuttle bay. As an example of this application, the environment of the Space Telescope in the bay, which may be representative of the environment of several payloads, was derived. Among the many findings obtained in the process of modeling the environment, one is that the payloads environment in the bay is not substantially different or more objectionable than the self-generated environment of a large payload or spacecraft. It is, however, more severe during ground facilities operations, the first 15 to 20 hours of the flight, during and for a short period after ater was dumped overboard, and the reaction control engines are being fired.

Scialdone, J. J.↗
NASA NTRS1984

Adaptive microwave reflector

As an interim step in going to the 100-meter reflector that was evaluated, a 5-meter reflector is proposed to test the electrostatic concept under space conditions. Some of the issues which require the space environment for evaluation are the following questions: Can deployment of a box ring structure with a thin film reflector attached be manually deployed? In the absence of humidity, can a 0.3-mil aluminized Kapton film reflector be formed by the electrostatic process suitable for antenna applications? Can the photogrammetric process be used to evaluate the reflector surface with pictures taken from the payload handling station? Can the space charging effect be evaluated with the 5-meter reflector attached to the Shuttle? Does the outgassing of moisture from 0.3-mil Kapton film affect its reflector capability? A box ring truss support structure and an automatic sequence deployment system are discussed.

Goslee, J. W.↗
NASA NTRS1984

Thin metal film and multilayers experiment (A0138-3)

The sources of degradation of in state of the art and newly developed components and testing the usefulness of the concept of storing experiment samples in dry nitrogen under launch and space vacuum conditions during reentry mission phase were investigated. Ultraviolet (UV) and extreme ultraviolet (EUV) experiments suffer degradations during space missions of even 1 month duration. It is suggested that the degradation is due to condensation of outgassing products, followed by solar induced polymerization, however, penetrating charged particles are also known to produce volume effects. Degradation may also start immediately after manufacturing of the component due to oxidation, moisture, or chemical corrosion by atmospheric constituents such as CO2 and SO2. When the filters are used as windows for gas absorption cells or gas filters, or when they define the instrumental bandwidth by themselves. The effects of mechanical degradation by thermal cycling and/or dust may cause a dramatic impact.

Delaboudiniere, J. P.↗
NASA NTRS1979

Heat Capacity Mapping Radiometer (HCMR) data processing algorithm, calibration, and flight performance evaluation

The rationale and procedures used in the radiometric calibration and correction of Heat Capacity Mapping Mission (HCMM) data are presented. Instrument-level testing and calibration of the Heat Capacity Mapping Radiometer (HCMR) were performed by the sensor contractor ITT Aerospace/Optical Division. The principal results are included. From the instrumental characteristics and calibration data obtained during ITT acceptance tests, an algorithm for post-launch processing was developed. Integrated spacecraft-level sensor calibration was performed at Goddard Space Flight Center (GSFC) approximately two months before launch. This calibration provided an opportunity to validate the data calibration algorithm. Instrumental parameters and results of the validation are presented and the performances of the instrument and the data system after launch are examined with respect to the radiometric results. Anomalies and their consequences are discussed. Flight data indicates a loss in sensor sensitivity with time. The loss was shown to be recoverable by an outgassing procedure performed approximately 65 days after the infrared channel was turned on. It is planned to repeat this procedure periodically.

Bohse, J. R.↗
NASA NTRS1983

Toxicological evaluation of the Columbia spacecraft

The toxicology procedures developed for the Space Shuttle program to evaluate and eliminate contaminants in the cabin atmosphere characterized, and results from STS missions 1-5 are reviewed. Shuttle maximum-allowable-concentration standards (SMAC) equal to 10-50 percent of those established for normal 40-h work weeks on the ground have been established for a broad range of substances, and outgassing data are employed in choosing spacecraft construction materials. Gases are removed by the atmospheric revitalization system (CO2-removal bed, catalytic oxidizer, and dehumidifier). Whole-gas and adsorbed-gas samples are employed in ground-based and inflight measurements of contaminants: results are presented in tables. A total of 152 substances, of which 64 were well defined, were detected in STS-1-5. Only the toluene contamination on STS-2 (17 ppm compared to the SMAC of 20 ppm) was considered serious.

Rippstein, W. J., Jr.↗
NASA NTRS1983

Evaluation of spacecraft materials and processes for optical degradation potential

A Wide Field Planetary Camera instrument with wide wavelength sensitive Charged Coupled Device detectors has been designed and built for employment in space. The contamination potential of the spacecraft hardware is determined by the outgassing characteristics of the selected materials and the effect of the performed processing procedures. An investigation was conducted to provide for more selective material screening with respect to contamination potential and to develop an optical effects data base. In the investigation, a series of thermogravimetric, residual gas, Micro-Volatile Condensible Material (VCM), and Vacuum Optical Degradation tests were performed. The results of the Micro-VCM testing of four epoxy adhesive systems are presented in tables.

Odonnell, T.↗
NASA NTRS1983

New black paint for cryogenic infrared applications

A black paint has been developed and tested for cryogenic applications involving wavelengths beyond 10 microns. The paint has been used extensively for liquid helium cooled applications in a variety of instruments operating between 10 and 120 microns. The material is applied by brush over a spray or brush applied primer coat. A final covering is applied by either brush or spray. The composition and preparation of the paint are described, as are data about its outgassing properties. Infrared reflection and scattering data obtained by other groups which compare this material to other commercially available surface preparations are presented.

Houck, J. R.↗
NASA NTRS1984

Compositional trends and cooling rates of group IVB iron meteorites

It is found, on the basis of new neutron activation data for group IVB, that log-element - log-Ni trends are best understood in terms of core formation and fractional crytstallizaion. The limited compositional range found in gorup IVB is thought to reflect the fact that, owing to the low concentrations of S, P, and C and the high concentration of Ni, the k sub x (the solid/liquid partition ratio) values are closer to unity than are those in other magmatic groups. Mean volatile abundances in group IVB are significantly lower than those found in any group of chondritic meteorites, indicating that these low abundances are not entirely the result of nebular processes and that planetary outgassing was also involved.

Rasmussen, K. L.↗
NASA NTRS1984

Absolute measurement of the extreme UV solar flux

A windowless rare-gas ionization chamber has been developed to measure the absolute value of the solar extreme UV flux in the 50-575-A region. Successful results were obtained on a solar-pointing sounding rocket. The ionization chamber, operated in total absorption, is an inherently stable absolute detector of ionizing UV radiation and was designed to be independent of effects from secondary ionization and gas effusion. The net error of the measurement is + or - 7.3 percent, which is primarily due to residual outgassing in the instrument, other errors such as multiple ionization, photoelectron collection, and extrapolation to the zero atmospheric optical depth being small in comparison. For the day of the flight, Aug. 10, 1982, the solar irradiance (50-575 A), normalized to unit solar distance, was found to be 5.71 + or - 0.42 x 10 to the 10th photons per sq cm sec.

Carlson, R. W.↗
NASA NTRS1984

Interactions between the orbiting Space Shuttle and the ionosphere

This paper presents an analysis of interactions between the Space Shuttle Orbiter and the ionosphere based on thermal plasma data obtained from a Spherical Retarding Potential Analyzer (SRPA) and a Langmuir Probe (LP) flown on the third Space Shuttle flight (STS-3) in March 1982. While previous work on spacecraft-plasma interactions has dealt with wake effects, the present work deals with effects that are seen in ram conditions that have not been previously discussed. One observation is a higher degree of plasma turbulence than has been reported from unmanned spacecraft measurements that manifests itself as a frequency component at 2.2 kHz in the SRPA signal. Also seen are unusually high number densities of what appear to be ions with a mass of at least 30 or 32 amu and a temperature in the range 2000-3000 K. Coincident with the enhanced molecular ion species, the temperature of the thermal electrons is seen elevated to above 5000 K. It is hypothesized that these measurements are evidence for a plasma instability resulting from the motion of the outgassing Orbiter through the ionosphere.

Siskind, D. E.↗
NASA NTRS1984

Maintenance of contamination sensitive surfaces on board long-term space vehicles

In the current age, highly sensitive instruments are being flown on spacecraft, and questions of contamination have become important. The present investigation is concerned with the available approaches which can provide long-term protection for contamination sensitive surfaces. Aspects and sources of spacecraft contamination are examined, taking into account materials outgassing, particulates, propulsion system interaction, overboard venting, man-made and cosmic debris, and atomic oxygen/ambient atmosphere interaction. Suitable protection approaches provided by current technology are discussed, giving attention to aperture covers, a possibility for a retractable cover design, gaseous purges, options for prolonging the lifetime of the thermal control system, and plume shields. Some new possibilities considered are related to an early warning system for excessive amounts of contamination, a molecular/wake shield, and the use of atomic oxygen.

Phillips, A.↗
NASA NTRS1985

Diffusely Reflecting Paints Containing TFE

Highly reflective, diffused coatings developed by incorporating polytetrafluoroethylene (TFE) pigment with alcohol-soluble binders. Alcohol and binder mixed together in blender before adding TFE. TFE preferably outgassed in mechanical-pump vacuum for typical interval of 4 hours before adding to liquid. Like wetting agent, vacuum treatment helps to prevent clumping of TFE and eases dispersion throughout mixture. Mixture blended for 3 to 5 minutes before used. Coatings useful on reflectance-standard surfaces for calibrating radiometric instruments in both laboratory and field. Paints washable and usable as optical reference surfaces.

Shai, M. C.↗