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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Stratospheric minor constituent distributions from far-infrared thermal emission spectra

We retrieve mixing ratio profiles of O3, H2(O-16), H2(O-17), H2(O-18), HF, and HCl from far-infrared thermal emission observations of the limb in the 80-220 cm/sec spectral region. The observations were made with a balloon-borne Fourier transform spectrometer as a part of the 1983 Balloon Intercomparison Campaign (BIC-2). A subset of the data was analyzed previously using the method in the work of Traub et al. (1982, 1991); in the present paper we use an alternative method of calibration and analysis, given by Abbas et al. (1985). The retrieved constituent profiles are compared with the measurements made with other instruments on the BIC-2 flights. The results for the concentrations of H2(O-17) and H2(O-18) obtained in this study indicate no isotopic enhancement or depletion with a standard deviation of about 20 percent.

Abbas, Mian M.↗
NASA NTRS1981

Stratospheric constituent measurements using UV solar occultation technique

The photochemistry of the stratospheric ozone layer was studied as the result of predictions that trace amounts of pollutants can significantly affect the layer. One of the key species in the determination of the effects of these pollutants is the OH radical. A balloon flight was made to determine whether data on atmospheric OH could be obtained from lower resolution solar spectra obtained from high altitude during sunset.

Murcray, D. G.↗
NASA NTRS1981

High latitude stratospheric electrical measurements in fair and foul weather under various solar conditions

Stratospheric electric field and conductivity measurements are presented for sites of latitude greater than 50 deg N GG, during the months of either April or August, in a variety of weather and solar conditions. Vertical electric field data from balloon flights with an average duration of 18 hours at ceiling, in fair weather, are shown to be appropriately modeled by a simple, exponential, altitude-dependent equation. Data collected over electrified clouds and thunderstorms are presented, along with a discussion of the thunderstorm-related electric currents. Current surges in the atmosphere due to DC currents as well as the spheric are calculated, and it is found that in over 1000 hours of balloon data, no direct solar influence is identified except during major flares.

Holzworth, R. H.↗
NASA NTRS1989

Measurement of stratospheric HOCl - Concentration profiles, including diurnal variation

Determinations have been made of concentration profiles of HOCl in the earth's stratosphere, including the diurnal variation. Measurements of the rotational Q2 branch at 99.5/cm and of five RR(J3) transitions between 143 and 159/cm were made using far-infrared thermal emission spectroscopy. The spectra were obtained during a balloon flight of the FIRS 2 far-infrared Fourier-transform spectrometer and telescope from Palestine, Texas on May 12-13, 1988. From these measurements, altitude profiles of HOCl from 23 to 42 km are obtained. Daytime and nighttime average profiles of HOCl, as well as measurements on a 30-min time scale through the sunset transition at a single (35 km) altitude are presented. The measured profiles are lower than the current predictions from several modeling groups by a factor of approximately 0.6.

Chance, K. V.↗
NASA NTRS1994

Harvard ER-2 OH laser-induced fluorescence instrument

The Harvard ER-2 OH instrument is scheduled to be integrated into the NASA ER-2 high altitude aircraft ozone payload in August 1992. Design and fabrication is presently underway. This experiment is a descendant of a balloon borne instrument designed and built in the mid-1980s. The ER-2 instrument is being designed to measure OH and HO2 as part of the NASA ozone payload for the investigation of processes controlling the concentration of stratospheric ozone. Although not specifically designed to do so, it is hoped that valid measurements of OH and HO2 can be made in the remote free troposphere with this instrument.

Wennberg, Paul O.↗
NASA NTRS1995

Chlorine Partitioning in the Arctic Vortex During Winter 1995 Derived From Submillimeterwave Remote Sensing and in Situ Constituent Measurements

High altitude balloon flights of a combined payload of the Submillimeterwave Limb Sounder and the whole air sampler instruments were performed on 27 January 1995 and 08 March 1995. Both flights were launched from sweden as part of the Second European Stratospheric Arctic and Mid-latitude Experiment (SESAME). Results of the first flight suggest that most of the available chlorine had been converted to CLOx in the observed air parcel, while warmer air in the second flight had much more HCl than CLOx.

Arctic vortex stratosphere chlorine remote sensing↗
NASA NTRS1976

Measures of the solar spectral irradiance between 1200 and 3000 A

Tabulated data on solar flux measurements are presented. The measurements, taken from balloons, rockets and satellites, are not new data, but have been critically re-evaluated. The eleven year sunspot cycle is discussed. Also discussed is the brightness temperature. The effect of solar radiation at various wavelengths, on the photochemistry of stratospheric ozone is briefly discussed.

Heath, D. F.↗
NASA NTRS1982

Forward scattering and backscattering of solar radiation by the stratospheric limb after Mount St. Helens eruption

Stratospheric limb radiance profiles versus altitude of closest approach of the line of sight to the Earth's surface have been measured before and after the Mount St. Helens eruptions by means of photographs taken from a Sun-oriented balloon gondola floating above 35 km altitude over France. Preliminary data were reported for flights in October 1979 and in May and June 1980. The radiance integrated along the line of sight as in-situ radiance (R) can be derived taking into account absorption by ozone and air. The onion peeling inversion method was used to derive the vertical radiance (R) profiles respectively. The values of R were determined in the solar azimuth. The solar elevation angles are chosen larger for the backscattering observation than for the forward scattering observation to deal with as similar illumination conditions as possible despite the Earth's sphericity.

Ackerman, M.↗
NASA NTRS1983

Lidar- and balloon-borne particle counter comparisons following recent volcanic eruptions

Balloon-borne particle counter measurements at Laramie, Wyoming (41 deg N) are used to calculate the expected lidar backscatter at 0.694 micron wavelength from July 1979 to February 1982, a period which included at least four detectable perturbations of the stratospheric aerosol layer due to volcanic eruptions. These calculations are compared with lidar measurements conducted at Garmisch-Partenkirchen (47.5 deg N) during the same period. While the agreement is generally good using only the main mode in the particle size distribution (radius about 0.07 micron) during approximately the first 6 months following a major volcanic eruption, a measured secondary mode near 1 micron radius, when included, improves the agreement. Calculations of the expected backscatter at 25-30 km reveal that substantial number of particles diffuse into this high altitude region about 7 months after a major eruption, and these particles should be taken into account when normalizing lidar at these altitudes.

Hofmann, D. J.↗
NASA NTRS1984

The Ponape ST radar

In May, 1984, a 50-MHz ST radar was installed on the island of Ponape in the western equatorial Pacific (7 deg N, 158 deg E) by the Aeronomy Laboratory of NOAA. The radar consists of a 100 m x 100 m array with a single, vertically directed, beam and is initially transmitting micro sec. (2.25 km) pulses. The radar is operating continuously, with Doppler spectra being recorded at approximately 1 1/2 minute intervals and sent to Boulder for later analysis. One of the principal goals of the radar is to measure vertical motions in the troposphere and lower stratosphere at a location which is within the intertropical convergence zone during part of the year. First results, during generally fair weather conditions, show detectable echoes up to about 21 km with the tropopause at 17-18 km. Once daily balloon soundings are available locally from a NOAA Weather Service Office on the island, it is planned that this radar will be joined in the coming year by two others with oblique as well as vertical beams on two yet-to-be-selected equatorial islands as part of the TOGA (Tropical Oceans Global Atmosphere) program.

Carter, D. A.↗
NASA NTRS1989

Stratospheric temperature-ozone relationships 1978-1986

Global stratospheric temperature and geopotential height at eight pressure levels (70, 50, 30, 10, 5, 2, 1, and 0.4 hPa) were derived at NMC daily since October 1978. These fields are based on NOAA operational satellite sounder information. Comparable daily global fields of stratospheric ozone (30 to 0.4 hPa and total ozone) were derived from the SBUV instrument on Nimbus 7 and are now derived from the operational NOAA SBUV/2 instrument. The ozone and meteorological fields are verified against ground based measurements (Umkehr, balloon, rocket, lidar) to determine fields of temperature and ozone was assembled. Some of the interesting features of correlation between the synoptic patterns of the two data sets as well as their change with time are discussed. Seasonal as well as interannual variations in the patterns of correlation are compared in the Northern and Southern Hemisphere polar regions. Other outstanding features in both the temperature and ozone fields are highlighted.

Gelman, M. E.↗
NASA NTRS1991

Ozone climatology at Natal, Brazil, from in situ ozonesonde data

A large ozone-profile data set has been obtained through balloon ozonesonde soundings at Natal, Brazil, during 1978-1988. Maximum ozone concentrations occur during local spring (September-October), and minimum concentrations during late autumn (April-May); the seasonal variation is much larger in the troposphere than in the stratosphere. If there were no seasonal variation in the stratosphere, the seasonal variation observed in the troposphere alone would be sufficient to drive a total ozone column variation of about 5 percent. This is about half the size of the variation observed in the Natal Dobson spectrophotometer data.

Kirchhoff, V. W. J. H.↗
NASA NTRS1993

Data processing and calibration for tunable diode laser harmonic absorption spectrometers

Data processing and calibration methods are described for tunable diode laser absorption spectrometers which produce harmonic absorption spectra as raw data for measuring gas mixing ratios down to parts-per-trillion levels at a variety of pressures. The methods, which take advantage of modern computer speed, memory, and data storage capabilities, are applicable to the detection of weakly absorbing gases in quantitative industrial monitoring, in addition to aircraft and balloon atmospheric measurements for which they were designed. Algorithms for calibration and data analysis, including rejection of erroneous spectra, variation of effective integration time, spectral alignment prior to averaging, and plotting and archiving of results, have been tested on actual stratospheric laser spectra recorded by the Aircraft Laser Infrared Absorption Spectrometer (ALIAS) spectrometer in numerous flights of NASA's ER-2 aircraft.

May, Randy D.↗
NASA NTRS2000

High Resolution Spectroscopy to Support Atmospheric Measurements

The major research activities performed during the cooperative agreement enhanced our spectroscopic knowledge of molecules of atmospheric interest such as carbon dioxide, water vapor, ozone, methane, and carbon monoxide, to name a few. Measurements were made using the NASA Langley Tunable Diode Laser Spectrometer System (TDL) and several Fourier Transform Spectrometer Systems (FTS) around the globe. The results from these studies made remarkable improvements in the line positions and intensities for several molecules, particularly ozone and carbon dioxide in the 2 to 17-micrometer spectral region. Measurements of pressure broadening and pressure induced line shift coefficients and the temperature dependence of pressure broadening and pressure induced line shift coefficients for infrared transitions of ozone, methane, and water vapor were also performed. Results from these studies have been used for retrievals of stratospheric gas concentration profiles from data collected by several Upper Atmospheric Research satellite (UARS) infrared instruments as well as in the analysis of high resolution atmospheric spectra such as those acquired by space-based, ground-based, and various balloon- and aircraft-borne experiments. Our results made significant contributions in several updates of the HITRAN (HIgh resolution TRANsmission) spectral line parameters database. This database enjoys worldwide recognition in research involving diversified scientific fields.

Benner, D. Chris↗
NASA NTRS2006

High Resolution Spectroscopy to Support Atmospheric Measurements

The major research activities performed during the cooperative agreement enhanced our spectroscopic knowledge of molecules of atmospheric interest such as H2O (water vapor), O3 (ozone), HCN (hydrogen cyanide), CH4 (methane), NO2 (nitrogen dioxide) and CO (carbon monoxide). The data required for the analyses were obtained from two different Fourier Transform Spectrometers (FTS); one of which is located at the National Solar Observatory (NSO) on Kitt Peak, Arizona and the other instrument is located at the Pacific Northwest National Laboratories (PNNL) at Richland, Washington. The data were analyzed using a modified multispectrum nonlinear least squares fitting algorithm developed by Dr. D. Chris Benner of the College of William and Mary. The results from these studies made significant improvements in the line positons and intensities for these molecules. The measurements of pressure broadening and pressure induced line shift coefficients and the temperature dependence of pressure broadening and pressure induced shift coefficients for hundreds of infrared transitions of HCN, CO3 CH4 and H2O were also performed during this period. Results from these studies have been used for retrievals of stratospheric gas concentration profiles from data collected by several Upper Atmospheric Research Satellite (UARS) infrared instruments as well as in the analysis of high resolution atmospheric spectra such as those acquired by space-based, ground-based, and various balloon- and aircraft-borne experiments. Our results made significant contributions in several updates of the HITRAN (HIgh resolution TRANsmission) spectral line parameters database. This database enjoys worldwide recognition in research involving diversified scientific fields. The research conducted during the period 2003-2006 has resulted in publications given in this paper. In addition to Journal publications, several oral and poster presentations were given at various Scientific conferences within the United States and abroad.

Venkataraman, Malathy Devi↗
NASA NTRS1990

Upper Atmosphere Data Program (UADP)

Rapid, effective access to the increasing volume of information on stratospheric trace gases, both from measurements and model calculations, is important in advancing our knowledge of the Earth's atmosphere. The data have their origins in a variety of sources, ranging from satellite experiments and 2-D model predictions to individual balloon measurements, and are found in a variety of locations and formats. This task focuses on development and operation of an electronic data base for such trace gas data. The objectives are to provide effective access to these diverse data sets; to foster electronic data access, manipulation, and display; and to support periodic assessment and intercomparison activities.

Seals, R. K., Jr.↗
NASA NTRS2000

High Resolution Spectroscopy to Support Atmospheric Measurements

The major research activities performed during the cooperative agreement enhanced our spectroscopic knowledge of molecules of atmospheric interest such as carbon dioxide, water vapor, ozone, methane, and carbon monoxide, to name a few. Measurements were made using the NASA Langley Tunable Diode Laser Spectrometer System (TDL) and several Fourier Transform Spectrometer Systems (FTS) around the globe. The results from these studies made remarkable improvements in the line positions and intensities for several molecules, particularly ozone and carbon dioxide in the 2 to 17-micrometer spectral region. Measurements of pressure broadening and pressure induced line shift coefficients and the temperature dependence of pressure broadening and pressure induced line shift coefficients for infrared transitions of ozone, methane, and water vapor were also performed. Results from these studies have been used for retrievals of stratospheric gas concentration profiles from data collected by several Upper Atmospheric Research satellite (UARS) infrared instruments as well as in the analysis of high resolution atmospheric spectra such as those acquired by space-based, ground-based, and various balloon-and aircraft-borne experiments. Our results made significant contributions in several updates of the HITRAN (HIgh resolution TRANsmission) spectral line parameters database. This database enjoys worldwide recognition in research involving diversified scientific fields.

Benner, D. Chris↗
NASA NTRS2023

M2-SCREAM: A Stratospheric Composition Reanalysis of Aura MLS Data With MERRA-2 Transport

MERRA-2 Stratospheric Composition Reanalysis of Aura Microwave Limb Sounder (M2-SCREAM) is a new reanalysis of stratospheric ozone, water vapor, hydrogen chloride (HCl), nitric acid (HNO 3 ) and nitrous oxide (N 2 O) between 2004 and the present (with a latency of several months). The assimilated fields are provided at a 50-km horizontal resolution and at a three-hourly frequency. M2-SCREAM assimilates version 4.2 Microwave Limb Sounder (MLS) profiles of the five constituents alongside total ozone column from the Ozone Monitoring Instrument. Dynamics and tropospheric water vapor are constrained by the MERRA-2 reanalysis. The assimilated species are in excellent agreement with the MLS observations, except for HNO 3 in polar night, where data are not assimilated. Comparisons against independent observations show that the reanalysis realistically captures the spatial and temporal variability of all the assimilated constituents. In particular, the standard deviations of the differences between M2-SCREAM and constituent mixing ratio data from The Atmospheric Chemistry Experiment Fourier Transform Spectrometer are much smaller than the standard deviations of the measured constituents. Evaluation of the reanalysis against aircraft data and balloon-borne frost point hygrometers indicates a faithful representation of small-scale structures in the assimilated water vapor, HNO 3 and ozone fields near the tropopause. Comparisons with independent observations and a process-based analysis of the consistency of the assimilated constituent fields with the MERRA-2 dynamics and with large-scale stratospheric processes demonstrate the utility of M2-SCREAM for scientific studies of chemical and transport variability on time scales ranging from hours to decades. Analysis uncertainties and guidelines for data usage are provided.

MERRA-2↗