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At least 631 records · Page 35

Analytical method for nitroaromatic explosives in radiologically contaminated soil for ISO/IEC 17025 accreditation

Here, unique hazards are presented in the analysis of radiologically contaminated samples. Strenuous safety and security precautions must be in place to protect the analyst, laboratory, and instrumentation used to perform analyses. A validated method has been optimized for the analysis of select nitroaromatic explosives and degradative products using gas chromatography/mass spectrometry via sonication extraction of radiologically contaminated soils, for samples requiring ISO/IEC 17025 laboratory conformance. Target analytes included 2-nitrotoluene, 4-nitrotoluene, 2,6-dinitrotoluene, and 2,4,6-trinitrotoluene, as well as the degradative product 4-amino-2,6-dinitrotoluene. Analytes were extracted from soil in methylene chloride by sonication. Administrative and engineering controls, as well as instrument automation and quality control measures, were utilized to minimize potential human exposure to radiation at all times and at all stages of analysis, from receiving through disposition. Though thermal instability increased uncertainties of these selected compounds, a mean lower quantitative limit of 2.37 µg/mL and mean accuracy of 2.3% relative error and 3.1% relative standard deviation were achieved. Quadratic regression was found to be optimal for calibration of all analytes, with compounds of lower hydrophobicity displaying greater parabolic curve. Blind proficiency testing (PT) of spiked soil samples demonstrated a mean relative error of 9.8%. Matrix spiked analyses of PT samples demonstrated that 99% recovery of target analytes was achieved. To the knowledge of the authors, this represents the first safe, accurate, and reproducible quantitative method for nitroaromatic explosives in soil for specific use on radiologically contaminated samples within the constraints of a nuclear analytical lab.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Design and optimization of arrays of neodymium iron boron-based magnets for magnetic tweezers applications

We present the design methodology for arrays of neodymium iron boron (NdFeB)-based magnets for use in magnetic tweezers devices. Using finite element analysis (FEA), we optimized the geometry of the NdFeB magnet as well as the geometry of iron yokes designed to focus the magnetic fields toward the sample plane. Together, the magnets and yokes form a magnetic array which is the basis of the magnetic tweezers device. By systematically varying 15 distinct shape parameters, we determined those features that maximize the magnitude of the magnetic field gradient as well as the length scale over which the magnetic force operates. Additionally, we demonstrated that magnetic saturation of the yoke material leads to intrinsic limitations in any geometric design. Using this approach, we generated a compact and light-weight magnetic tweezers device that produces a high field gradient at the image plane in order to apply large forces to magnetic beads. We then fabricated the optimized yoke and validated the FEA by experimentally mapping the magnetic field of the device. The optimization data and iterative FEA approach outlined here will enable the streamlined design and construction of specialized instrumentation for force-sensitive microscopy.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Contingency contractor optimization.

The goal of Phase 3 the OSD ATL Contingency Contractor Optimization (CCO) project is to create an engineering prototype of a tool for the contingency contractor element of total force planning during the Support for Strategic Analysis (SSA). An optimization model was developed to determine the optimal mix of military, Department of Defense (DoD) civilians, and contractors that accomplishes a set of user defined mission requirements at the lowest possible cost while honoring resource limitations and manpower use rules. An additional feature allows the model to understand the variability of the Total Force Mix when there is uncertainty in mission requirements.

Gearhart, Jared Lee↗

Genomics and Transcriptomics Analyses of the Oil-Accumulating Basidiomycete Yeast Trichosporon oleaginosus : Insights into Substrate Utilization and Alternative Evolutionary Trajectories of Fungal Mating Systems

Microbial fermentation of agro-industrial waste holds great potential for reducing the environmental impact associated with the production of lipids for industrial purposes from plant biomass. However, the chemical complexity of many residues currently prevents efficient conversion into lipids, creating a high demand for strains with the ability to utilize all energy-rich components of agricultural residues. Here, we present results of genome and transcriptome analyses of Trichosporon oleaginosus. This oil-accumulating yeast is able to grow on a wide variety of substrates, including pentoses and N-acetylglucosamine, making it an interesting candidate for biotechnological applications. Transcriptomics shows specific changes in gene expression patterns under lipid-accumulating conditions. Furthermore, gene content and expression analyses indicate that T. oleaginosus is well-adapted for the utilization of chitin-rich biomass. We also focused on the T. oleaginosus mating type, because this species is a member of the Tremellomycetes, a group that has been intensively analyzed as a model for the evolution of sexual development, the best-studied member being Cryptococcus neoformans. The structure of the T. oleaginosus mating-type regions differs significantly from that of other Tremellomycetes and reveals a new evolutionary trajectory paradigm. Comparative analysis shows that recruitment of developmental genes to the ancestral tetrapolar mating-type loci occurred independently in the Trichosporon and Cryptococcus lineages, supporting the hypothesis of a trend toward larger mating-type regions in fungi. IMPORTANCE: Finite fossil fuel resources pose sustainability challenges to society and industry. Microbial oils are a sustainable feedstock for biofuel and chemical production that does not compete with food production. We describe genome and transcriptome analyses of the oleaginous yeast Trichosporon oleaginosus, which can accumulate up to 70% of its dry weight as lipids. In contrast to conventional yeasts, this organism not only shows an absence of diauxic effect while fermenting hexoses and pentoses but also effectively utilizes xylose and N-acetylglucosamine, which are building blocks of lignocellulose and chitin, respectively. Transcriptome analysis revealed metabolic networks that govern conversion of xylose or N-acetylglucosamine as well as lipid accumulation. These data form the basis for a targeted strain optimization strategy. Furthermore, analysis of the mating type of T. oleaginosus supports the hypothesis of a trend toward larger mating-type regions in fungi, similar to the evolution of sex chromosomes in animals and plants.

10 SYNTHETIC FUELS↗

RECOVERY ACT - Robust Optimization for Connectivity and Flows in Dynamic Complex Networks

The goal of this project was to study robust connectivity and flow patterns of complex multi-scale systems modeled as networks. Networks provide effective ways to study global, system level properties, as well as local, multi-scale interactions at a component level. Numerous applications from power systems, telecommunication, transportation, biology, social science, and other areas have benefited from novel network-based models and their analysis. Modeling and optimization techniques that employ appropriate measures of risk for identifying robust clusters and resilient network designs in networks subject to uncertain failures were investigated in this collaborative multi-university project. In many practical situations one has to deal with uncertainties associated with possible failures of network components, thereby affecting the overall efficiency and performance of the system (e.g., every node/connection has a probability of partial or complete failure). Some extreme examples include power grid component failures, airline hub failures due to weather, or freeway closures due to emergencies. These are also situations in which people, materials, or other resources need to be managed efficiently. Important practical examples include rerouting flow through power grids, adjusting flight plans, and identifying routes for emergency services and supplies, in the event network elements fail unexpectedly. Solutions that are robust under uncertainty, in addition to being economically efficient, are needed. This project has led to the development of novel models and methodologies that can tackle the optimization problems arising in such situations. A number of new concepts, which have not been previously applied in this setting, were investigated in the framework of the project. The results can potentially help decision-makers to better control and identify robust or risk-averse decisions in such situations. Formulations and optimal solutions of the considered problems need to capture uncertainty and risk using appropriate probabilistic, statistical and optimization concepts. The main difficulty arising in addressing these issues is the dramatic increase in the computational complexity of the resulting optimization problems. This project studied novel models and methodologies for risk-averse network optimization- specifically, network design, network flows and cluster detection problems under uncertainty. The approach taken was to incorporate a quantitative risk measure known as conditional value-at-risk that is widely used in financial applications. This approach presents a viable alternate modeling and optimization framework to chance-constrained optimization and mean-variance optimization, one that also facilitates the detection of risk-averse solutions.

97 MATHEMATICS AND COMPUTING↗

Westinghouse waste simulation and optimization software tool

Applications for dynamic simulation can be found in virtually all areas of process engineering. The tangible benefits of using dynamic simulation can be seen in tighter design, smoother start-ups and optimized operation. Thus, proper implementation of dynamic simulation can deliver substantial benefits. These benefits are typically derived from improved process understanding. Simulation gives confidence in evidence based decisions and enables users to try out lots of 'what if' scenarios until one is sure that a decision is the right one. In radioactive waste treatment tasks different kinds of waste with different volumes and properties have to be treated, e.g. from NPP operation or D and D activities. Finding a commercially and technically optimized waste treatment concept is a time consuming and difficult task. The Westinghouse Waste Simulation and Optimization Software Tool will enable the user to quickly generate reliable simulation models of various process applications based on equipment modules. These modules can be built with ease and be integrated into the simulation model. This capability ensures that this tool is applicable to typical waste treatment tasks. The identified waste streams and the selected treatment methods are the basis of the simulation and optimization software. After implementing suitable equipment data into the model, process requirements and waste treatment data are fed into the simulation to finally generate primary simulation results. A sensitivity analysis of automated optimization features of the software generates the lowest possible lifecycle cost for the simulated waste stream. In combination with proven waste management equipments and integrated waste management solutions, this tool provides reliable qualitative results that lead to an effective planning and minimizes the total project planning risk of any waste management activity. It is thus the ideal tool for designing a waste treatment facility in an optimum manner, taking account of the detailed waste stream and specific requirements. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Searching for Low-Mass Dark Matter with SuperCDMS Soudan Detectors

SuperCDMS is a direct-detection dark matter (DM) experiment that uses cryogenically cooled germanium and silicon detectors to search for interac- tions between DM particles and detector nuclei, and in this thesis I describe my contributions to the experiment. I start with a brief review of DM and motivate the possibility of its de- tection in underground laboratories with sensitive detectors, and I review the SuperCDMS detector fundamentals. Then I focus on detector develop- ment for the future generation of the experiment, which will deploy an array of detectors at SNOLAB in Sudbury, Canada. Specifically I describe char- acterization of prototype detectors from surface facility testing, and discuss measurements of critical values that determine the detectors’ sensitivity to DM particles, such as the baseline resolution and the phonon collection ef- ficiency. I also describe analysis techniques developed to measure intrinsic detector noise in a high radiation environment such as a surface test facility. In the final chapters I describe a DM search analysis using four months of data from operation of SuperCDMS detectors in the Soudan Mine in northern Minnesota. I discuss how a particular detector operating mode, called CDMSlite, lowers the energy threshold of the detectors in order to improve the sensitivity to low-mass DM particles. I also present new analysis techniques that optimize the sensitivity to low-mass DM particles, including noise discrimination with multivariate classifiers, instrumental background modeling, and a profile likelihood signal and background fitting approach. In this analysis we set an upper limit on the DM-nucleon scattering cross section in germanium that is a factor of 2.5 improvement over the previous CDMSlite result for a DM mass that is five times the proton rest mass.

79 ASTRONOMY AND ASTROPHYSICS↗

STREAM: A technology planning and capacity expansion model for the industrial sector

The Strategic Technology Roadmapping and Energy, Environmental, and Economic Analysis Model—STREAM—is an optimization-based modeling tool and analysis framework to assist with strategic planning and technology investments of the industrial sector. This open-source framework is written in Julia using the JuMP package, which enables users to model future “pathways” for incumbent and future production technologies, costs, fuels and energy carriers, and energy and non-energy environmental impacts from industries as they transform in pursuit of a robust and competitive manufacturing sector. The model starts with an initial stock of industrial production technologies and assets at a facility level and then determines pathways that minimize cost, subject to an array of possible constraints on demand, market shares, environmental flows, and other exogenously specified operational considerations such as capacity utilization rates or regional energy costs. Key features of the framework include flexibility to model a wide range of industries and industrial technologies/processes at varying levels of granularity, ability to perform parametric sensitivity analyses, and ability to visualize model results using visualization objects.

capacity expansion↗

Performance Improvements to the Prototype Design of the AGU

The existing design for the Magnet Structure of the prototype multi-segment AGU (Adaptive- Gap Undulator) has undergone analysis (see TN #298). To optimize performance, after review of said analysis, certain design modifications are proposed herein. A primary constraint of this proposed design is to use the existing fabricated parts from initial assembly SR-ID-SAGU-4300 with three pairs of feed-throughs spaced along the platen length of a single segment, but with foresight for the eventual multi-segment prototype. Measurements of the center segment are to be conducted on the frame and gap-drive system of the NSLS X9 MGU with its single driven axis. The eventual multi-segment prototype will also use the sister devices (X13, X27) for simultaneous measurement of both central and outboard segments at various segment gaps. Criteria effecting IVU performance like Gap Tolerance, Taper Error, and the critical Planarity of pole plane as in Figure 1 are used to evaluate the design. The error in planarity to be minimized is the deviation of vertical displacement (Y direction) with Platen length (beam Z direction).

36 MATERIALS SCIENCE↗

Frequency Analysis of Solar PV Power to Enable Optimal Building Load Control

In this paper, we present a flexibility estimation mechanism for buildings’ thermostatically controlled loads (TCLs) to enable the distribution level consumption of the majority of solar photovoltaic (PV) generation by local building TCLs. The local consumption of PV generation provides several advantages to the grid operation as well as the consumers, such as reducing the stress on the distribution network, minimizing voltage fluctuations and two-way power flows in the distribution network, and reducing the required battery storage capacity for PV integration. This would result in increasing the solar PV generation penetration levels. The aims of this study are twofold. First, spectral (frequency) analyses of solar PV power generation together with the power consumption of multiple building TCLs (such as heating, ventilation, and air conditioning (HVAC) systems, water heaters, and refrigerators) are performed. These analyses define the bandwidth over which these TCLs can operate and also describe the PV generation frequency bandwidth. Such spectral analyses, in frequency domain, can help identify the flexible components of PV generation that can be consumed by the various TCLs through optimal building load utilization. Second, a quadratic optimization problem based on model predictive control is formulated to allow consuming most of the low and medium frequency content of the PV power locally by building TCLs, while maintaining occupants’ comfort and TCLs’ physical constraints. The solution to the proposed optimization problem is achieved using optimal control strategies. Numerical results show that most of the low and medium frequency content of the PV generation can be consumed locally by building TCLs. The remaining high-frequency content of the PV generation can then be stored/offset using energy storage systems.

14 SOLAR ENERGY↗

High-Throughput Method for Strontium Isotope Analysis by Multi-Collector-Inductively Coupled Plasma-Mass Spectrometer

This technical report presents the details of the Sr column configuration and the high-throughput Sr separation protocol. Data showing the performance of the method as well as the best practices for optimizing Sr isotope analysis by MC-ICP-MS is presented. Lastly, this report offers tools for data handling and data reduction of Sr isotope results from the Thermo Scientific Neptune software to assist in data quality assurance, which help avoid issues of data glut associated with high sample throughput rapid analysis.

47 OTHER INSTRUMENTATION↗

High-Throughput Method for Strontium Isotope Analysis by Multi-Collector-Inductively Coupled Plasma-Mass Spectrometer

This technical report presents the details of the Sr column configuration and the high-throughput Sr separation protocol. Data showing the performance of the method as well as the best practices for optimizing Sr isotope analysis by MC-ICP-MS is presented. Lastly, this report offers tools for data handling and data reduction of Sr isotope results from the Thermo Scientific Neptune software to assist in data quality assurance, which help avoid issues of data glut associated with high sample throughput rapid analysis.

47 OTHER INSTRUMENTATION↗

Rapid Automated Dissolution and Analysis Techniques for Radionuclides in Recycle Process Streams

The analysis of process samples for radionuclide content is an important part of current procedures for material balance and accountancy in the different process streams of a recycling plant. The destructive sample analysis techniques currently available necessitate a significant amount of time. It is therefore desirable to develop new sample analysis procedures that allow for a quick turnaround time and increased sample throughput with a minimum of deviation between samples. In particular, new capabilities for rapid sample dissolution and radiochemical separation are required. Most of the radioanalytical techniques currently employed for sample analysis are based on manual laboratory procedures. Such procedures are time- and labor-intensive, and not well suited for situations in which a rapid sample analysis is required and/or large number of samples need to be analyzed. To address this issue we are currently investigating radiochemical separation methods based on extraction chromatography that have been specifically optimized for the analysis of process stream samples. The influence of potential interferences present in the process samples as well as mass loading, flow rate and resin performance is being studied. In addition, the potential to automate these procedures utilizing a robotic platform is evaluated. Initial studies have been carried out using the commercially available DGA resin. This resin shows an affinity for Am, Pu, U, and Th and is also exhibiting signs of a possible synergistic effects in the presence of iron.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A comparison of price-taker and production cost models for determining system value, revenue, and scheduling of concentrating solar power plants

Concentrating solar power (CSP) plants convert solar energy into electricity and can be coupled with low-cost thermal energy storage to provide a dispatchable renewable resource. Maximizing the economic benefits of CSP systems requires deliberate selection of the timing of thermal energy dispatch to coincide with high-price or high-value periods. The performance and value of CSP systems have traditionally been evaluated using two distinct approaches: (1) production cost models (PCMs), which optimize commitment and dispatch schedules for an entire fleet of generators to minimize the cost of satisfying electricity demand; and (2) price-taker (PT) models, which optimize dispatch of the CSP system against historical or forecasted electricity prices to maximize revenue available to the CSP operator. The PCM approach is, in principle, superior because of the ability to capture system-level details such as transmission pathways and associated constraints, and feedback between CSP dispatch schedules and operation of other generators. The computationally simpler PT technique cannot explicitly address these concerns, but the comparative reduction in solution time is attractive for sensitivity analysis and rigorous optimization of CSP plant design and operation. In this work, we directly compare the dispatch profiles, net revenue, and operational value of CSP systems using implementations of each technique to assess how closely the solutions from the PT technique can approach those from the PCM for a specific market scenario. The PT implementation produced characteristically similar dispatch profiles as the PCM for both a large solar-multiple configuration and a small solar-multiple peaking configuration, while requiring only 1% of the computational time of the PCM. In addition, dispatching the CSP plant according to the self-scheduled PT solution - as opposed to the system-optimized PCM solution - only reduced the total CSP operational value by 1-5%, with consistent trends across CSP configurations and locations. This analysis validates the ability of the PT approach to substantially capture the economic benefits of CSP systems when pricing profiles are available, and indicates that the PT approach is suitable for initial design and optimization of CSP technologies.

14 SOLAR ENERGY↗

Acceleration of tensor-product operations for high-order finite element methods

This article is devoted to graphics processing unit (GPU) kernel optimization and performance analysis of three tensor-product operations arising in finite element methods. We provide a mathematical background to these operations and implementation details. Achieving close to peak performance for these operators requires extensive optimization because of the operators’ properties: low arithmetic intensity, tiered structure, and the need to store intermediate results during the kernel execution. We give a guided overview of optimization strategies and we present a performance model that allows us to compare the efficacy of these optimizations against an empirically calibrated roofline.

Świrydowicz, Kasia↗

Porting the Nonlinear Optimization Library HiOp to Accelerator-Based Hardware Architectures

While interior point method has been the centerpiece of nonlinear programming tools used in science and engineering, its reliance on linear solvers that can tackle sparse symmetric indefinite and highly ill-conditioned problems made it difficult to implement it effectively on hardware accelerators. HiOp optimization package attempts to provide an implementation of the interior point method suitable for hardware accelerators by compressing the original sparse problem to produce an underlying linear problem that is dense and of manageable size. Implementations of dense linear solvers are more mature and utilize hardware accelerators better than their sparse counterparts. There is a number of important domain problems, such as optimal power flow analysis for power grids, where the sparse problem can be effectively compressed and deploying dense linear solver within the interior point method can improve performance. Here we describe a portable implementation of HiOp optimization engine, which uses a linear solver from Magma library and runs entirely on hardware accelerators. To compress the problem, HiOp uses customized mixed dense-sparse linear algebra. All HiOp kernels are implemented using Umpire and RAJA portability libraries. We describe details of the implementation and discuss trade-offs between performance, portability and development cost.

97 MATHEMATICS AND COMPUTING↗

{sup 6}LiF:ZnS(Ag) Neutrons Scintillator Detector Configuration for Optimal Readout

A Chromatic Analysis Neutron Diffractometer Or Reflectometer (CANDOR) is under development at the NIST Center for Neutron Research (NCNR). The CANDOR neutron sensor will rely on scintillator material for detecting the neutrons scattered by the sample under test. It consists of {sup 6}LiF:ZnS(Ag) scintillator material into which wavelength shifting (WLS) fibers have been embedded. Solid state photo-sensors (silicon photomultipliers) coupled to the WLS fibers are used to detect the light produced by the neutron capture event ({sup 6}Li (n,α) {sup 3}H reaction) and ionization of the ZnS(Ag). This detector configuration has the potential to accomplish the CANDOR performance requirements for efficiency of 90% for 5 A (3.35 meV) neutrons with high gamma rejection (10{sup 7}) along with compact design, affordable cost and materials availability. However this novel design includes challenges for precise neutron detection. The recognizing of the neutron signature versus the noise event produce by gamma event cannot be easy overcome by pulse height discrimination obstacle as can be achieved with {sup 3}He gas tube. Furthermore the selection of silicon photomultipliers (SiPM) as the light sensor maintains the obstacle of dark noise that does not exist when a photomultiplier tube is coupled to the scintillator. A proper selection of SiPM should focus on increasing the output signal and reducing the dark noise in order to optimize the detection sensitivity and to provide a clean signal pulse shape discrimination. The main parameters for evaluation are: - Quantum Efficiency (QE) - matching the SiPM peak QE with the peak transmission wavelength emission of the WLS. - Recovery time - a short recovery time is preferred to minimize the pulse width beyond the intrinsic decay time of the scintillator crystal (improves the gamma rejection based output pulse shape (time)). - Diode dimensions -The dark noise is proportional to the diode active area while the signal is provided by the WLS fibers; therefore the diode area should ideally be only minimally larger than fiber bundle area. - Low dark noise - it is desirable to minimize the dark noise during the pulse integration period so as to minimize the background for pulse shape discrimination. - Photon Detection Efficiency - it is desirable to increase the SiPM PDE in order to enhance light collection. This will increase the likelihood of detecting neutron events with lower light production and will present a cleaner raw signal for pulse shape discrimination. We will present the SiPM optimization process and studies of dark noise and gamma and neutron sensitivity as a function of bias voltage and operating temperature that have enabled us to optimize the detector sensitivity and gamma rejection. The gamma rejection performance goal requires to overcome the challenge of discriminating between the light signature accepted by neutron event to the one received by the noise. In addition there is a huge variation between the number of light photons that reaching the WLS fibers for different neutron events caused by the heavy ions energy losses prior to ionizing the ZnS(Ag) and the high light attenuation of the scintillation mixture. This variation in the light signal along with the long decay time of the ZnS(Ag) (tens of microseconds) can cause double counting of the same neutron event in the case of high light output signature or preventing the detection of low sequential light output signature neutron event. We will presents the algorithm developed for {sup 6}LiF:ZnS(Ag) sensor readout and the results achieved by an off-line analysis by Matlab software code that successfully achieved both the high gamma rejection with a sensitive and accurate neutron event detection. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Comprehensive geoneutrino analysis with Borexino

This paper presents a comprehensive geoneutrino measurement using the Borexino detector, located at Laboratori Nazionali del Gran Sasso (LNGS) in Italy. The analysis is the result of 3262.74 days of data between December 2007 and April 2019. The paper describes improved analysis techniques and optimized data selection, which includes enlarged fiducial volume and sophisticated cosmogenic veto. The reported exposure of ( 1.29 ± 0.05 ) × 10 32 protons × year represents an increase by a factor of two over a previous Borexino analysis reported in 2015. By observing 52.6 - 8.6 + 9.4 ( stat ) - 2.1 + 2.7 ( sys ) geoneutrinos (68% interval) from U 238 and Th 232 , a geoneutrino signal of 47.0 - 7.7 + 8.4 ( stat ) - 1.9 + 2.4 ( sys ) TNU with - 17.2 + 18.3 % total precision was obtained. This result assumes the same Th/U mass ratio as found in chondritic CI meteorites but compatible results were found when contributions from U 238 and Th 232 were both fit as free parameters. Antineutrino background from reactors is fit unconstrained and found compatible with the expectations. The null-hypothesis of observing a geoneutrino signal from the mantle is excluded at a 99.0% C.L. when exploiting detailed knowledge of the local crust near the experimental site. Measured mantle signal of 21.2 - 9.0 + 9.5 ( stat ) - 0.9 + 1.1 ( sys ) TNU corresponds to the production of a radiogenic heat of 24.6 - 10.4 + 11.1 TW (68% interval) from U 238 and Th 232 in the mantle. Assuming 18% contribution of K 40 in the mantle and 8.1 - 1.4 + 1.9 TW of total radiogenic heat of the lithosphere, the Borexino estimate of the total radiogenic heat of the Earth is 38.2 - 12.7 + 13.6 TW , which corresponds to the convective Urey ratio of 0.78 - 0.28 + 0.41 . These values are compatible with different geological predictions, however there is a ~ 2.4 σ tension with those Earth models which predict the lowest concentration of heat-producing elements in the mantle. In addition, by constraining the number of expected reactor antineutrino events, the existence of a hypothetical georeactor at the center of the Earth having power greater than 2.4 TW is excluded at 95% C.L. Particular attention is given to the description of all analysis details which should be of interest for the next generation of geoneutrino measurements using liquid scintillator detectors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗