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Assessing high fidelity multi-component models to facilitate safeguards at Gas Centrifuge Enrichment Plants

We report that the International Atomic Energy Agency (IAEA) inspectors routinely carry out environmental sampling (ES) as a verification method. Collection of environmental swipe samples at various locations in Gas Centrifuge Enrichment Facilities (GCEPs) is an important process in detecting misuse of a declared facility and possibly the existence of undeclared nuclear material. These samples are measured for isotopic composition in uranium containing particles by Thermal Ionization Mass Spectrometry (TIMS) or Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Even though ES is highly effective in detecting the absolute value of enrichments and their deviations from the declared values, it cannot explain the cause of those changes. Several potential explanations can serve as possibilities for particles detected above or other than the declared enrichment. These include normal and non-malicious events such as the design of the enrichment cascades, unintentional failures of the machines, or overshoot during startup of a cascade. It can also be the result of deliberate misuse by the facility operators. The primary objective of this work is to understand how these factors affect the enrichments produced by a cascade and quantify anticipated multi-isotopic concentrations for each case. The following methodology is employed to determine signatures at a particular facility. 1) Utilize a new two-dimensional multi-component diffusion code to obtain centrifuge performance data and use that information to design and perform cascade analysis. Compare and contrast the results with previous 1-D radially averaged solutions from the Pancake code. 2) Design a GCEP cascade with the production goal of 19.75% 235 U for each set of machine data above. Investigate two cascade scenarios that include enrichment of natural uranium (NU) feed to 19.75% 235U in a single cascade compared to a two-step process of NU to 5% and then 5% to 19.75%. 3) Simulate the intentional vs. unintentional off-normal scenarios in the cascades to assess the differences in isotopic concentrations. A non-ideal squared-off cascade model developed at the University of Virginia is used to calculate flow rates and isotopic concentrations of the process gas. The analysis is performed using the Rome machine model operated at 600 m/s rotor speed. The upper and lower bounds of normal and abnormal enrichments in a typical facility are used in conjunction with ES results to understand the root causes of such observations.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Open database for GPD analyses

This article summarizes the main ideas behind creating an open database proposed for use in the exploration of generalized parton distributions (GPDs). This lightweight database is well suited for GPD phenomenology and is designed to store both experimental and lattice-QCD data. It can also aid in benchmarking GPD-related developments, such as GPD models. The database utilizes a new data format based on the YAML serialization language, enabling the storage of essential information for modern analyses, such as replica values. It includes interfaces for both Python and C++, allowing straightforward integration with analysis codes.

Burkert, V. D. [Thomas Jefferson National Accelera↗

The Nuclear Digital I&C System Supply Chain Cyber-Attack Surface

The nuclear supply chain attack surface is a large, complex network of interconnected stakeholders and activities. The global economy has widened and deepened the supply chain, resulting in larger numbers of geographically dispersed locations and increased difficulty ensuring the authenticity and security of digital assets. Although the nuclear industry has made significant strides in securing facilities from cyber-attacks, the supply chain remains vulnerable. This paper outlines supply chain threats and vulnerabilities and provides a Digital I&C System Supply Chain Cyber-Attack Surface diagram to illustrate the complexity of securing hardware, firmware, software, and system information throughout the entire supply chain lifecycle. The knowledge presented in this paper provides a foundation to use in cybersecurity supply chain risk analysis and to guide future supply chain research and development efforts leading to enhancement of a nuclear facility’s overall security posture.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Safety Basis Compliant Flexible Operations [Capstone Project]

Compliant nuclear operations must be weighed against the radiological risk to the worker, public, and the environment. This project set out to look at one facility at Los Alamos National Laboratory (LANL or the Laboratory) and compare the risk with the operational restrictions associated with the Technical Safety Requirements (TSRs). The hope was to identify controls that could be reduced or simplified while maintaining compliance with 10 CFR 830, Nuclear Safety Management. This would result in increasing facility operational flexibility and efficiency. Controls were identified to be simplified or eliminated based on risk. This identification was initially envisioned from the perspective of reanalysis of the accident and hazard analysis consequences. Additionally, it was envisioned that fire testing could show that the consequences of a fire are not as dramatic as analyzed. Specific facility controls were identified that cause operational inefficiencies. Based on data collection, two controls were identified for further evaluation. The first control was combustible loading within the waste storage buildings, and the second control is related to the seismic power cutoff switch. In evaluating the combustible loading control, the thought is that the fire suppression system (FSS) provides adequate protection and the combustible loading controls do not need elevation to a TSR control. The FSS, along with the Fire Protection Program, would provide protection to prevent a fire from impacting large amounts of stored waste material. The seismic switch was more of a challenge. When reviewing the facility operation, it was determined that the facility does not operate anywhere near the established material-at-risk (MAR – radioactive material) limits. By adjusting these limits, a reduced consequence could be achieved and hence, a significant risk reduction achieved. A new operating mode would be used to achieve this reduction. A reduced MAR limit was successfully used as a test case for snow removal during this project. This project expands on that trial case as related to combustible loading and the seismic power cutoff switch TSRs. This will increase the efficiency of operations with reduced TSR controls while reducing overall facility risk. This is a win-win situation for Triad National Security, LLC (Triad) and the U.S. Department of Energy (DOE). Due to schedule and budgetary constraints, not all envisioned work scope was accomplished. However, it is maintained in this report for future efforts.

61 RADIATION PROTECTION AND DOSIMETRY↗

Industry Partnerships & Their Role In Reducing Natural Gas Supply Chain Greenhouse Gas Emissions – Phase 2

This analysis is the product of collaboration between Our Nation’s Energy Future (ONE Future) and the United States (U.S.) Department of Energy (DOE) National Energy Technology Laboratory (NETL). This analysis is an update to Phase 1 of the collaboration between ONE Future and NETL. Phase 1 had three objectives: 1. Calculate a greenhouse gas (GHG) emission profile representative of ONE Future’s supply chain, including methane (CH 4 ) emission rates. 2. Compare ONE Future’s emission profile to the emission profile for the U.S. natural gas supply chain. 3. Evaluate specific emission reduction opportunities. Phase 2 has two key enhancements over Phase 1: 1. The reporting year of the data is updated from 2016 to 2017. 2. The emission profiles and the specific emission reduction opportunities are regionalized for the ONE Future supply chain. The ONE Future supply chain is based on data provided by ONE Future members for all their U.S. onshore assets. ONE Future’s data are mostly representative of their participation in the Greenhouse Gas Reporting Program (GHGRP) administered by the Environmental Protection Agency (EPA) and is supplemented by ONE Future facilities that are not required to report to GHGRP. The U.S. scenario is based on NETL’s life cycle analysis (LCA) of natural gas extraction and power generation, which also uses data from the GHGRP (but does not include non-GHGRP facilities). In addition to the data from these sources, NETL accounted for uncertainty due to data variability, data limitations, and variability in liquids unloading frequency and event duration. This report is a re-issue of the 2020 study (published on July 28, 2020). It revises the device count in the mitigation strategy “pipeline pump-down before maintenance” in the Marginal Abatement Cost (MAC) Analysis section of the report (Section 7). Please see the addendum for more details on this revision and resultant changes. This revision does not change most of our conclusions and recommendations. It only changes the total methane reduced from all the mitigation opportunities (low cost and high cost) from 6.5 Bcf CH 4 /yr to 4.8 Bcf CH 4 /yr.

03 NATURAL GAS↗

Nuclear Science User Facilities: Instrument Scientist Program

The traditional single institution User Facility model prevalent in the DOE complex funds Instrument Scientists (IS) full-time to collaborate with and guide users, disseminate results through publication, build a broad and competent user base, continuously improve instrumentation, enhance data collection methods, and improve data analysis methods. This model focuses the Instrument Scientist on ensuring that visiting researchers obtain the best and most comprehensive data. Instrument Scientists are also expected to establish personal research programs based on the use of the instrument(s) under their charge, which allows for further advances in instrumentation and science. This model ensures that the User Facility offers unique, world-leading instruments and data analysis to the user community, creates high demand among top researchers for the use of these capabilities, and as a result, positively impacts science and technology in the United States.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Manufacturing Cost Analysis of Advanced Parabolic Trough Collector

The research team performed a detailed bottom-up manufacturing cost estimate for an advanced parabolic trough design - the Solar Dynamics Sunbeam-MT (Sunbeam Mid-Term). This includes all components for manufacturing and assembly in a manufacturing facility (e.g. space frame and arms), and the purchased parts (e.g. mirrors and receiver tubes). Estimates of the construction and assembly activities have been made to then determine an estimated installed cost. Prior analysis has already undertaken detailed bottom-up manufacturing, assembly, and construction analysis for the Ultimate Trough from schlaich bergermann partner (sbp), and this work updates the solar field cost estimates based on a similar aperture area as the SunBeam-MT. For this analysis, the Ultimate Trough is considered the commercial parabolic trough and the Sunbeam-MT as the advanced parabolic trough. For similarity, both the Sunbeam-MT and the Ultimate Trough have been modelled with a solar field with approximately 800,000 square meters (m2) in aperture area - the equivalent of a large CSP plant. The analysis has found a potential installed cost estimate of the Sunbeam-MT could be $120/m2 but must be built at scale to confirm this estimate. Compared to prior analysis, the commercial Ultimate Trough using U.S. conditions, has reduced in installed cost from $178/m2 to $152/m2. Both designs could be even cheaper with Chinese steel.

cost analysis↗

Sensitivity analyses of a homogeneous model and a RZ model of the MYRRHA reactor in its critical configuration

Two homogenized models of the MYRRHA (Multi-purpose hybrid Research Reactor for High-tech Applications) reactor in its critical configuration are presented in this study. Both models will be verified by comparing the main reactor parameters (K{sub eff}, β{sub eff} and Λ) with those of the heterogeneous model and a sensitivity analysis will be performed. A sensitivity analysis of some important parameters related to reactivity, namely the vacuum coefficient, the Doppler and the power peaking factors, is also presented. The study of the vacuum coefficient has been carried out by analyzing two possible scenarios: 50% vacuum in the coolant (lead bismuth eutectic) and 100%, obtaining a list of the 10 reactions and nuclides that most affect the k{sub eff} value. With respect to the Doppler coefficient, it will be seen that a 300 degree increase in fuel temperature (starting at 800 K) results in a reduction of the total reactivity of the system by 134 pcm.. Finally, the map of the power peaking factors will be shown, as well as a sensitivity analysis. For making the sensitivity calculations Serpent-2 reactor physics Monte Carlo code has been used and JEFF-3.3 library has been chosen in order to continue with the OECD/NEA WPEC SG46 work evaluating the nuclear data of this library. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Using Simulation to Interpret LArS's Results

Scintillation light analysis in liquid argon based neutrino detectors is restrained in capability due to uncertainty in fundamental constants critical to the analysis process. One such property is the Rayleigh scattering length of liquid argon. In the fall of 2023, the TallBo cryostat, located in the Noble Liquid Testing Facility (NLTF) at Fermilab, was used to study the scattering length of liquid argon in the Liquid Argon Scattering (LArS) experiment. Due to systematic errors unknown during measurement analysis, LArS s measurements were quite uncertain. By simulating the LArS experiment, we found that the downturn in detector count rate as a function of liquid argon height at low heights was caused by a misplaced silicon photo multiplier (SiPM). With concentrated effort, we may be able to successfully correct this effect by understanding the relationship between the specified Rayleigh scattering length and the measured attenuation length. With this information and further progression in analysis, we may be able to extract corrected measurements from the LArS data and attain a tangible experimental measurement of the scattering length of liquid argon.

Breaux, Auto D. [Tulane U.]↗

Site-specific Design Case Study for Wet Waste Hydrothermal Liquefaction and Biocrude Upgrading to Hydrocarbon Fuels

Hydrothermal liquefaction (HTL) is a thermal process that converts wet biomass to renewable hydrocarbon fuel blendstocks (i.e., renewable naphtha, renewable diesel, and sustainable aviation fuel (SAF)). It can utilize a wide range of pure and blended wet feedstocks, including sewage sludge from water resource recovery facilities (WRRF), food and agriculture wastes, algae, fats, oils and greases (FOG) and blends of dry and wet wastes/feedstocks. Historically, techno-economic analysis (TEA) and annual state of technology (SOT) assessments with standard economic assumptions used by the Bioenergy Technologies Office (BETO) were conducted for the wet waste HTL pathway leveraging experimental data collected from Pacific Northwest National Laboratory’s (PNNL) continuous flow reactor systems. The objective of the SOT assessment has been to guide and track progress of BETO’s HTL research and development (R&D) toward reduced cost and greenhouse gas (GHG) emissions for the pathway. However, gaps exist between BETO’s traditional SOT updates and the needs of key external stakeholders that – if addressed – will accelerate technology adoption. This Business Case Study aims to bridge this gap by providing an updated design, TEA, and LCA based on PNNL’s FY23 R&D with added analyses and information that provide enhanced relevance for stakeholders of the HTL technology. This includes specific siting, regional wet waste resource inventory and transportation cost analyses, fuel market information, sustainable fuel policy impacts, economic metrics of net present value (NPV) and internal rate of return (IRR), greenhouse gas (GHG) emissions analysis, and statistical analysis of cost and technical uncertainties of the HTL plant design. The study focuses on the “Detroit combined statistical area (CSA)” region for siting of a wet waste HTL plant adjacent to the Great Lakes Water Authority (GLWA) facility with guidance from industry participants. Regional resource and siting analyses were conducted to identify feedstock availability, scale, and cost, as well as a beneficial site location. TEA with detailed rigorous capital cost estimation for the specific site application was conducted to evaluate the key economic metrics of most value to industrial partners. These include total capital investment, operating costs, minimum fuel selling price (MFSP) of the biocrude and fuel blendstock, and NPV and internal rate of return IRR with sustainable fuel credits. Life cycle analysis was conducted to evaluate the supply chain greenhouse gas (GHG) emissions for the wet waste HTL process as compared with petroleum derived diesel. This study is also informed by years of R&D and process de-risking learnings and was conducted with a basic engineering HTL plant design and costing that akin to a “first-of-a-kind” plant economics. This differs from our conventional “nth plant ” SOT assessments. Specifically, the HTL process model has been updated with more operationally reliable methods for feed heating and phase separations. Further, we have implemented additional spare equipment for redundancy, a more rigorous installed equipment cost estimation approach, and additional costs associated with feed formatting and delivery, building, piping and site development. An Excel-based cost sheet based on the basic engineering design is also released alongside the report that allows users to conduct customized TEA with their own feed composition and financial assumptions.

09 BIOMASS FUELS↗

Supporting data for Site-specific Design Case Study for Wet Waste Hydrothermal Liquefaction and Biocrude Upgrading to Hydrocarbon Fuels

Hydrothermal liquefaction (HTL) is a thermal process that converts wet biomass to renewable hydrocarbon fuel blendstocks (i.e., renewable naphtha, renewable diesel, and sustainable aviation fuel (SAF)). It can utilize a wide range of pure and blended wet feedstocks, including sewage sludge from water resource recovery facilities (WRRF), food and agriculture wastes, algae, fats, oils and greases (FOG) and blends of dry and wet wastes/feedstocks. Historically, techno-economic analysis (TEA) and annual state of technology (SOT) assessments with standard economic assumptions used by the Bioenergy Technologies Office (BETO) were conducted for the wet waste HTL pathway leveraging experimental data collected from Pacific Northwest National Laboratory’s (PNNL) continuous flow reactor systems. The objective of the SOT assessment has been to guide and track progress of BETO’s HTL research and development (R&D) toward reduced cost and greenhouse gas (GHG) emissions for the pathway. However, gaps exist between BETO’s traditional SOT updates and the needs of key external stakeholders that – if addressed – will accelerate technology adoption. This Business Case Study aims to bridge this gap by providing an updated design, TEA, and LCA based on PNNL’s FY23 R&D with added analyses and information that provide enhanced relevance for stakeholders of the HTL technology. This includes specific siting, regional wet waste resource inventory and transportation cost analyses, fuel market information, sustainable fuel policy impacts, economic metrics of net present value (NPV) and internal rate of return (IRR), greenhouse gas (GHG) emissions analysis, and statistical analysis of cost and technical uncertainties of the HTL plant design. The study focuses on the “Detroit combined statistical area (CSA)” region for siting of a wet waste HTL plant adjacent to the Great Lakes Water Authority (GLWA) facility with guidance from industry participants. Regional resource and siting analyses were conducted to identify feedstock availability, scale, and cost, as well as a beneficial site location. TEA with detailed rigorous capital cost estimation for the specific site application was conducted to evaluate the key economic metrics of most value to industrial partners. These include total capital investment, operating costs, minimum fuel selling price (MFSP) of the biocrude and fuel blendstock, and NPV and internal rate of return IRR with sustainable fuel credits. Life cycle analysis was conducted to evaluate the supply chain greenhouse gas (GHG) emissions for the wet waste HTL process as compared with petroleum derived diesel. This study is also informed by years of R&D and process de-risking learnings and was conducted with a basic engineering HTL plant design and costing that akin to a “first-of-a-kind” plant economics. This differs from our conventional “nth plant ” SOT assessments. Specifically, the HTL process model has been updated with more operationally reliable methods for feed heating and phase separations. Further, we have implemented additional spare equipment for redundancy, a more rigorous installed equipment cost estimation approach, and additional costs associated with feed formatting and delivery, building, piping and site development. An Excel-based cost sheet based on the basic engineering design is also released alongside the report that allows users to conduct customized TEA with their own feed composition and financial assumptions.

Li, Shuyun↗

Neutronics analysis of Full Size Plate–1 Experiment using MC21

Qualification and testing of Low Enriched Uranium fuel is desired so that it can be used in research reactors instead of High Enriched Uranium. The Full Size Plate - 1 (FSP-1) experiment involves irradiating a low enriched metallic fuel in the Advanced Test Reactor to assist in this general qualification. Prior to irradiation, an in-depth neutronics analysis is needed to ensure the safety requirements of the Advanced Test Reactor are met. To accomplish this, the MC21 software was used to analyze the FSP-1 experiment, which will allow a test run to be performed with this new fuel in the Advanced Test Reactor Critical facility. By verifying and validating the results of the MC21 software with comparisons to other codes and the preliminary irradiation in the Advanced Test Reactor Critical facility, the FSP-1 experiment will be ready to irradiate using the Advanced Test Reactor. This work is concerned with the neutronics analysis of the FSP-1 experiment using the MC21 software.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Techno-economic analysis of sugarcane bagasse and straw conversion into cellulosic ethanol via consolidated bioprocessing

Cellulosic biofuels offer a sustainable alternative to fossil fuels and a means to mitigate climate change. Consolidated bioprocessing (CBP) featuring engineered thermophilic bacteria, combined with mechanical disruption during fermentation (cotreatment), has potential to lower production costs compared to featuring thermochemical pretreatment and added cellulase. A techno-economic analysis was conducted (230 million L ethanol/year) from sugarcane bagasse and straw at stand-alone facilities generating electricity from residues. Three scenarios were evaluated: Conventional, featuring hydrothermal pretreatment, fungal cellulase, and yeast fermentation (current commercial standard); Mid-term CBP, relying on bagasse solubilization without pretreatment or cotreatment; and Mature CBP, incorporating cotreatment but no pretreatment. Results for these scenarios in this order were: fixed capital investment (CapEx) $\$$589M, $\$$658M, and $\$$472M; net annual revenue (EBITDA) $\$$56M, $\$$96M, and $\$$94M; and minimum ethanol selling price 0.73, 0.61, and 0.48 US$\$$/L. Payback periods were 10.5, 6.9, and 5.1 years, while all scenarios showed <5 years at European prices for scales >100M L/year. Sensitivity and risk analysis highlighted ethanol price as the most critical variable. It is notable that Mid-term CBP had shorter payback times and better overall economic feasibility compared to Conventional. Our results underscore opportunities for research-driven innovation on low-cost cellulosic ethanol technologies in Brazil and elsewhere.

Consolidated bioprocessing↗

Workflows Community Summit: Tightening the Integration between Computing Facilities and Scientific Workflows

Scientific workflows are used almost universally across science domains for solving complex and largescale computing and data analysis problems. The importance of workflows is highlighted by the fact that they have underpinned some of the most significant discoveries of the past decades. Many of these workflows have significant computational, storage, and communication demands, and thus must execute on a range of large-scale computer systems, from local clusters to public clouds and upcoming exascale HPC platforms. Managing these executions is often a significant undertaking, requiring a sophisticated and versatile software infrastructure. Historically, infrastructures for workflow execution consisted of complex, integrated systems, developed in-house by workflow practitioners with strong dependencies on a range of legacy technologies—even including sets of ad hoc scripts. Due to the increasing need to support workflows, dedicated workflow systems were developed to provide abstractions for creating, executing, and adapting workflows conveniently and efficiently while ensuring portability. While these efforts are all worthwhile individually, there are now hundreds of independent workflow systems. These workflow systems are created and used by thousands of researchers and developers, leading to a rapidly growing corpus of workflows research publications. The resulting workflow system technology landscape is fragmented, which may present significant barriers for future workflow users due to many seemingly comparable, yet usually mutually incompatible, systems that exist. In order to tackle some of the challenges described above, the DOE-funded ExaWorks and NSF-funded WorkflowsRI projects have organized in 2021 a series of events entitled the “Workflows Community Summit”. The third edition of the “Workflows Community Summit” explored workflows challenges and opportunities from the perspective of computing centers and facilities. This third summit builds on two prior summits (https://workflowsri.org/summits) that (i) established a high level vision for workflows research; and (ii) explored technical approaches for realizing that vision. The third summit brought together a small group of facilities representatives with the aim to understand how workflows are currently being used at each facility, how facilities would like to interact with workflow developers and users, how workflows fit with facility roadmaps, and what opportunities there are for tighter integration between facilities and workflows. This report documents and organizes the wealth of information provided by the participants before, during, and after the summit.

97 MATHEMATICS AND COMPUTING↗

A scalable transformer model for real-time decision making in neutron scattering experiments

The U.S. Department of Energy's (DOE's) neutron research facilities at Oak Ridge National Laboratory (ORNL), including the High Flux Isotope Reactor (HFIR) and the Spallation Neutron Source (SNS), are a state-of-the-art neutron scattering facility that allows researchers to study the structure and dynamics of materials at the atomic scale. At the SNS, neutrons are measured using the time-of-flight (TOF) technique as they move through a neutron beamline to interact with a sample. Large volumes of neutron scattering data are collected and recorded in neutron event mode. Optimal productivity of the TOF instrument is limited due to the lack of real-time data analysis tools. The large amount of data generated by the experiments can be challenging to process and analyze in real time, particularly for experiments that require rapid feedback and adjustment of experimental parameters. The regular computer/workstation cannot keep up with the experiment speed to provide real-time feedback to adjust experimental parameters, so connecting the supercomputers available to the neutron facility is necessary to achieve real-time data analysis and experiment steering. To address this challenge, we exploit the Frontier supercomputer at Oak Ridge Leadership Computing Facility (OLCF) to train a scalable temporal fusion transformer model for real-time decision making of TOF neutron scattering experimentation. Here, in this paper, we present the results using Frontier to provide the processing power needed to rapidly process and analyze large volumes of single-crystal diffraction data collected at TOPAZ, a neutron time-of-flight Laue single-crystal diffractometer at the SNS.

97 MATHEMATICS AND COMPUTING↗

Air Dispersion Modeling for the Idaho National Laboratory Permit to Construct P-2015.0023 Facility Emission Cap Revision Request

The U.S. Department of Energy Idaho Operations Office (DOE-ID) is seeking to modify permit to construct (PTC) P-2015.0023 issued to U S Dept. of Energy – Idaho National Laboratory (INL) on January 11, 2018 by the Idaho Department of Environmental Quality (DEQ). This PTC allowed the INL to become a synthetic minor source of air pollutants using a facility emission cap (FEC). Air dispersion modeling was performed as part of the permit revision application process to demonstrate that the modifications will comply with the National Ambient Air Quality Standards (NAAQS). This report documents the modeling methodology and complete results for the air dispersion impact analysis and is supplied as an appendix to the permit revision request, Idaho National Laboratory Permit to Construct P-2015.0023 Facility Emission Cap Revision Request (DOE-ID 2020). All CAPs regulated under Section 109 of the Clean Air Act were modeled with the exception of lead (Pb) and ozone which are not required to be modeled by DEQ. Consistent with the original permit application, modeling was not performed for toxic air pollutants (TAPs) as uncontrolled emissions did not exceed screening emission levels for carcinogenic and non-carcinogenic TAPs. Acceptable model design values (concentrations) for each CAP and averaging period were summed with average background concentrations and compared to NAAQS. The results demonstrate the impacts of requested FEC limits for CAPs are less than applicable standards and demonstrate emissions up to FEC limits will not cause a violation of ambient air quality standards.

99 GENERAL AND MISCELLANEOUS↗

Evaluation of Detritiation Strategies for Mitigating Tritium Releases

Tritium confinement is performed using different barriers to minimize releases to the environment. Primary confinement is usually performed by process piping and components, secondary confinement typically by inerted gloveboxes connected to a continuously operating tritium stripper system. Some facility designs employ tertiary tritium confinement by using process room confinement with a tritium stripper system activated after an accident to further mitigate tritium releases to the environment. Secondary confinement of some tritium systems such as radiation-hardened or shielded-cell enclosures are not easily achieved using designs for inerted glovebox. These enclosures can be challenging to seal for secondary tritium confinement due to heating, ventilation, and air conditioning (HVAC) needs for temperature control, as well as feedthroughs for equipment and instrumentation, are potential pathways for tritium leaks or loses. Additional tritium leak paths can be created in secondary confinement enclosures due to a Design Basis Accident (DBA) seismic event. These new, larger tritium leak rates from the DBA event are usually not part of the stripper system design basis so all tritium released to the secondary confinement enclosure is assumed released to the environment. Detritiation strategies for shielded enclosures and/or gloveboxes with significant leak rates are necessary to minimize off-site radiological dose consequences. To address this, the relationship between the confinement system leak rate and stripper system (recirculating) flow rate was evaluated to meet prescribed maximum allowable environmental tritium emissions from the event. The simple analysis described assumes a constant leak rate from the confinement system (i.e. shielded enclosure or glovebox) while a recirculating stripper system strips tritium from the system– a competition between tritium release and tritium recovery. At a high level, the resulting expression summarizes the relationship between system leak rate (F L ) and stripper flow rate (F S ) relative to allowable tritium release (Q A ) and initial tritium release (Q 0 ): $\frac{F_L}{F_s}$ ≈ $\frac{Q_A}{Q_0}$. This report derives the relationship between these parameters, examines the impact of finite stripping times followed by purging of the stripped volume. The analysis provides example results for up to 30 gram tritium releases: the maximum tritium inventory of a Hazard Category III (Department of Energy) Nuclear Facility. The detritiation model presented represents a high-level analysis of tritium recovery versus losses for “leaky” confinement enclosures such as shielded cells after large tritium releases. Key parameters for doing the analyses are the system leak rate, stripper flow rate, initial tritium release, and allowable tritium release values. The analyses show a proportional decrease in releases with reduction in initial tritium release but a non-linear increase in tritium recovery with increased stripper flow rate or reduced leak-rate. The analyses also apply to glovebox confinement systems which could have significant increases in leak rates after a DBA. The analysis recognizes but does not include tritium absorption followed by re-emission from the walls of the confinement volume – an analysis which could be pursued in future studies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Non-Nuclear Test Facility Development to Support Verification and Validation Needs

This study focuses on developing a non-nuclear test facility to help meet the verification and validation (V&V) requirements of a water-cooled small modular reactor (SMR) system. The scaling analysis necessary for reactor system experimentation and assessment model V&V considers various reactor system accident scenarios such as main steam line break (MSLB), steam generator tube rupture (SGTR), and containment condensation and heat transfer. The goal is to identify key physics based phenomena of interest (POI), specific figures of merit (FOMs), and the state of knowledge (SOK) by employing phenomena identification and ranking table (PIRT) studies. Important physics phenomena such as heat transfer, fluid dynamics, structural integrity, and material selection must be addressed when scaling a thermal-hydraulics system. Alongside these considerations, modifications to the facility may be needed to align the scaled system with the available footprint (height and space) of the facility. These modifications may include infrastructure upgrades, changes to the piping layout, implementation of safety measures, and installation of new instrumentation and control systems. The test facility aims to provide a scaled-down version of prototypic facilities for comprehensive V&V activities by overcoming these challenges and making the necessary modifications. This approach minimizes scaling distortion, simulates prototypic plant conditions, and accurately models accident event progressions. Thus, the facility will be capable of adequately modeling a scaled SMR system to support the design, development and licensing needs.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗