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At least 649 records · Page 36

Equivalent equilibrium ion distributions in ion sources and beams

Ion sources and ion beams often contain ions of more than one charge-to-mass ratio, due to the presence of multiple ionization states and/or multiple atomic and molecular ion species in the source. We show that, under certain conditions, analysis of these systems can be simplified using the notion of “equivalent equilibrium ion distributions” (EEIDs). These distributions have identical ion trajectories, space-charge distributions, and electric-field distributions, but can be composed of ion species with arbitrary charge-to-mass ratios. We use this result to obtain multi-species generalizations for the perveance of an ion diode, which relates the diode voltage to the extracted beam current, and for the perveance of a drifting ion beam, which determines the axial length-scale for beam expansion due to the self-electric field. Applied to a quasi-neutral plasma ion source containing cold ions and hot electrons, we find that the location of the beam-plasma interface (meniscus), where ions are extracted from the plasma, depends on the electron density and ion energy per unit charge at the interface, independent of the ion composition. For certain types of numerical simulations, EEIDs allow one to calculate the beam optics of an intense multi-species ion source by doing a simulation for a single ion species with an artificial charge-to-mass ratio chosen to minimize computation time. We illustrate these results using the 3D particle-in-cell, finite-element code Aleph. The simulations show how ions in a plasma source self-consistently accelerate to the supersonic speed needed for steady, radially expanding flow. Multi-species equilibria are subject to streaming instabilities because, while the different species have the same kinetic energy per unit charge, their velocities scale with the square root of the charge-to-mass ratio. The simulations show that a strong ion streaming instability can occur in a multi-species plasma ion source.

74 ATOMIC AND MOLECULAR PHYSICS↗

Development and characterization of an aerosol-generated multi-method analytical particle test material

Ceria (CeO 2 ) particles with low to ultra-low loading of nickel dopant were produced using an aerosol-based, droplet-to-particle synthesis via an in-line calcination technique. This aerosol-based synthesis method enables the production of particles with a monodisperse size distribution. These produced and well-characterized, multi-element, ceria-based particles demonstrate a material exemplar for multi-method analytical testing. They were prepared from a cerium nitrate feedstock where low loading nickel dopant was added at target Ni/(Ni + Ce) atomic percents of 1 %, 0.1 %, and 0.01 %, using a nickel nitrate spike. This methodology proved to produce ceria particles doped with a dynamic range of low to ultra-low loadings of nickel over a 24-h period, with consistent size distribution, morphology, and composition. The successful incorporation of nickel was demonstrated with bulk and single particle inductively coupled plasma mass spectroscopy and revealed notable particle-to-particle elemental homogeneity. X-ray photoelectron spectroscopy demonstrated the presence of a high concentration of nickel dopant incorporated preferentially toward the surface of the particles, and that this dopant aided oxidation of surface Ce(III) atoms to Ce(IV). These particle test materials were then validated through X-ray absorption near edge spectroscopy, comparing the ultra-low 0.01 % Ni and low 1 % Ni-doped ceria samples. This revealed a more-reduced oxidation state of the nickel with an increase in dopant concentration. Finally, this work demonstrates a synthesis and systematic characterization scheme to produce multi-method analytical test particulates.

36 MATERIALS SCIENCE↗

Dynamical behavior of the polar topside ionosphere.

A review is given of magnetospheric interactions with the polar ionosphere using recent experimental and theoretical results. The effect of the polar wind is discussed with reference to the observational data of J. Hoffman. These and the results of other experiments support the concept of polar wind ion flows as a general feature of the topside ionosphere for all regions outside the plasmasphere. It is shown that most of the semi-permanent topside density features result from changes in plasma temperature and F2-region effects rather than being associated with changes in ion composition. Finally, the polar peak density enhancement is discussed in terms of recent observations of the polar cusp.

Banks, P. M.↗

A satellite-borne ion mass spectrometer for the energy range 0 to 16 keV

The Ion Composition Experiment (ICE) on GEOS represents the first comprehensive attempt to measure the positive ion composition at high altitudes in the magnetosphere. Due to the heterogeneous nature of the magnetospheric plasma a novel mass spectrometer has been developed to cover the mass per charge range from H-1(+) to beyond Ba-138(+) and the energy per charge range from 0 to 16 keV/e. The ICE consists primarily of a cylindrical electrostatic analyzer followed by a curved analyzer incorporating crossed magnetic and electric fields. This combination has limited angular and energy focusing properties, but it maintains a mass resolution of about 4 over a wide range in energy and mass, sufficient for the objectives of measuring plasmas of both solar and terrestrial origin. High sensitivity and low background should allow measurements of rarer ion constituents down to flux levels of 0.01 ions/sq cm sec ster eV. A sophisticated electronics combined with powerful ground computer and telecommand systems allow for very efficient scanning of the mass-energy space.

Balsiger, H.↗

Effect of long-term hypokinesia on the electrolytic composition of the blood in patients with osteoarticular tuberculosis

Seventy-six patients with osteoarticular tuberculosis were divided into two groups, one of which was required to maintain strict bed rest and the other of which was allowed unrestricted motor activity. A study of blood electrolyte composition in the two groups revealed that bed rest for these patients results in decreased plasma potassium calcium, and magnesium content, but that these indices improved after the patients were allowed to move freely. The study suggests that patients with osteoarticular tuberculosis who are on bed rest be carefully observed for alterations in blood electrolytes and that proper electrolyte balance be maintained.

Zakutaeva, V. P.↗

Spacelab mission 2: Experimental descriptions

The second Spacelab Mission and the 12 multidisciplinary experiments selected to fly on board are described. These experiments include the following: vitamin D metabolities and bone demineralization; interaction of oxygen and gravity influenced lignification; ejectable plasma diagnostics package; plasma depletion experiments for ionospheric and radio astronomical studies; small helium cooled IR telescope; elemental composition and energy spectra of cosmic ray nuclei; hard X-ray imaging of clusters of galaxies and other extended X-ray sources; solar magnetic and velocity field measurement system; solar coronal helium abundance Spacelab experiment; solar UV high resolution telescope and spectroraph; solar UV spectral irradiance monitor; and properties of superfluid helium in zero-G.

Clifton, K. S.↗

The organic aerosols of Titan

The optical properties and chemical composition of thiolin, an organic solid synthesized by high-energy-electron irradiation in a plasma discharge (Sagan et al., 1984) to simulate the high-altitude aerosols of Titan, are investigated experimentally using monochromators, ellipsometers, and spectrometers (on thin films deposited by continuous dc discharge) and sequential and nonsequential pyrolytic gas chromatography/mass spectrometry (of the volatile component), respectively. The results are presented in tables and graphs and characterized. The real and imaginary elements of the complex refractive index in the visible are estimated as 1.65 and 0.004-0.08, respectively, in agreement with observations of Titan, and the IR absorption features include the nitrile band at 4.6 microns. The molecules identified in the volatile part of thiolin include complex species considered important in theoretical models of the origin of life on earth.

Khare, B. N.↗

Hypersonic aerodynamic coefficients and convection flow estimation in a HERMES type project

An analysis of all the experimental and computation requirements of the HERMES project is presented. The discussion includes the influence of the upper atmosphere composition and possible chemical reactions, the information collected in Orbiter experiments, the possibility of utilizing plasma generators and CF4 in wind tunnel tests, the development of parabolized Navier-Stokes models and solutions, and the computing capacity requirements.

Pollak, C.↗

Experimental evaluation of chromium-carbide-based solid lubricant coatings for use to 760 C

A research program is described which further developed and investigated chromium carbide based self-lubricating coatings for use to 760 C. A bonded chromium carbide was used as the base stock because of the known excellent wear resistance and the chemical stability of chromium carbide. Additives were silver and barium fluoride/calcium fluoride eutectic. The three coating components were blended in powder form, applied to stainless steel substrates by plasma spraying and then diamond ground to the desired coating thickness. A variety of coating compositions was tested to determine the coating composition which gave optimum tribological results. Coatings were tested in air, helium, and hydrogen at temperatures from 25 to 760 C. Several counterface materials were evaluated with the objective of discovering a satisfactory metal/coating sliding combination for potential applications, such as piston ring/cylinder liner couples for Stirling engines. In general, silver and fluoride additions to chromium carbide reduced the friction coefficient and increased the wear resistance relative to the unmodified coating. The lubricant additives acted synergistically in reducing friction and wear.

Dellacorte, Christopher↗

Preliminary Results from a Laboratory Study of Charging Mechanisms in a Dusty Plasma

A laboratory investigation has been developed to experimentally study the interaction of micron sized particles with plasmas and electromagnetic radiation. The intent is to investigate under what conditions particles of various compositions and sizes become charged, or discharged, while exposed to an electron beam and ultraviolet radiation. Primary emphasis is on two charging mechanisms: secondary emission of electrons and the photoelectric effect. Preliminary results are presented.

Venturini, Catherine C.↗

Recent Results from a Laboratory Study of Charging Mechanisms in a Dusty Plasma

A laboratory investigation has been developed to experimentally study the interaction of micron sized particles with plasmas and electromagnetic radiation. The intent is to investigate under what conditions particles of various compositions and sizes become charged, or discharged, while exposed to an electron beam and UV radiation. This investigation uses a unique laboratory technique known as electrodynamic suspension of particles. Here, a single charged micron size particle is suspended in a quadrupole trap and then subjected to a controlled environment. In this paper, we will discuss recent results from this experiment in which different materials including polystyrene and aluminum oxide, and sizes ranging from 10 microns to 1 micron have been used to determine charge to mass ratios and then subjected to an electron beam and /or UV radiation. In each instance, the particle's charge as well as beam current flux and radiation intensity flux is measured. These results will be compared with initial results using salt crystals. It was found that a negatively charged salt crystal exposed for 30 minutes to a 500 eV electron beam with primary electron beam current of -3.06 x 10(exp -5) picoamps yielded a secondary electron current of 3.23 x 10(exp -5) picoamps. Additionally, the particle was observed to be steadily losing charge over this time interval. By studying the microphysics of one particle, a better understanding of theoretical models and other laboratory results associated with particle charging mechanisms can be achieved.

Venturini, Catherine C.↗

Preliminary Results from a Laboratory Study of the Charging Mechanisms of Particles in a Dusty Plasma

A laboratory study has been developed to experimentally study the interaction of micron sized particles with plasmas and electromagnetic radiation. The intent is to investigate under what conditions particles of various compositions and sizes become charged, or discharged, while exposed to an electron beam and ultraviolet radiation. Primary emphasis is on two charging mechanisms: secondary emission of electrons and the photoelectric effect. Preliminary results are presented.

Venturini, Catherine C.↗

Modelling the Neutral Atmosphere and Plasma Environment of Saturn

The first year of this contract has resulted in two publications with the P.I. and co-I Jurac as lead authors and two publications where these team members are co-authors. These papers discuss modeling work undertaken in preparation for Cassini; the goal was to summarize our current best knowledge of the ion and neutrals sources and distributions. One of the major goals of this project is to improve models of the plasma and neutral environment near Saturn. The paper "A self-consistent model of plasma and neutrals at Saturn: Neutral cloud morphology" [Jurac and Richardson, 20051 presents results on the neutral clouds near Saturn using a model which for the first times treats the ions and neutrals self-consistently. We also for the first time include a directly sputtered H source. The Voyager and HST observations are used as model constraints. The neutral source is adjusted to give a good match to the HST observations of OH. For this initial run the ion parameters from Richardson et al. are used; charge exchange with ions is a major neutral loss process. The neutral profile derived from the model is then used in a model of plasma transport and chemistry (with the plasma diffusion rate the only free parameter). This model gives new values of the ion composition which are then fed back into the neutral model. This iteration continues until the values converge.

Richardson, John D.↗

Rosetta Radio Science Investigations

The Rosetta Radio Science Investigations (RSI) experiment was selected by the European Space Agency to be included in the International Rosetta Mission to comet P/Wirtanen (launch in 2003, arrival and operational phase at the comet 2011-2013). The RSI science objectives address fundamental aspects of cometary physics such as the mass and bulk density of the nucleus, the gravity field, non-gravitational forces, the size and shape, the internal structure, the composition and roughness of the nucleus surface, the abundance of large dust grains and the plasma content in the coma and the combined dust and gas mass flux on the orbiter. RSI will make use of the radio system of the Rosetta spacecraft.

P/Wirtanen radio science cometary physics cometary↗

Characterization of NUW-LHT-5m, A Lunar Highland Simulant

A new simulant of the lunar highlands regolith, NUW-LHT-5M, was designed by NASA and manufactured by Washington Mills. The simulant was based on Apollo 16 data and is a member of the NU-LHT-series. NASA’s Marshall Space Flight Center and Johnson Space Center have already purchased 3 metric tons of the simulant for advanced engineering work. In support of engineering uses of the simulant, we provided measurements of the simulant including: mineral abundance and composition, liberation, X-ray fluorescence (XRF), ferrous iron, carbon, sulfur, 60 element inductively coupled plasma (ICP), loss on ignition, particle size, both 2D and 3D particle shape, specific surface area, shear, cohesion, internal friction, helium pycnometry, minimum index density, tap density, magnetic susceptibility, cryogenic and high temperature permittivity, visible and near-infrared (VNIR) and middle infra-red spectroscopy (MIR), differential scanning calorimetry (DSC), viscosity, thermal diffusivity, thermal conductivity, thermal gravimetric analysis (TGA), evolved gas analysis (EGA), and spark sintering. For the crystalline components the design of the simulant called for two rocks from the Stillwater Complex, Montana: 17.6 wt% norite, 37.7% anorthosite, and 4.7 wt% olivine from an unspecified commercial source. The other 40% of the simulant was a high calcium (An100), vesicular glass that Washington Mills made specifically for the simulant. Fabrication and quality control processes for both the glass and the simulant are described. Importantly, most of the graphs and tables presented herein provide values for both the new simulant and data for the older NASA mare simulant, JSC-1A. Finally, we discussed the current limitations of NUW-LT-5M and most other lunar regolith simulants to replicate the lunar material.

lunar regolith simulant↗

Laser Surface Preparation of Epoxy Composites for Secondary Bonding: Optimization of Ablation Depth

Surface preparation has been identified as one of the most critical aspects of attaining predictable and reliable adhesive bonds. Energetic processes such as laser ablation or plasma treatment are amenable to automation and are easily monitored and adjusted for controlled surface preparation. A laser ablation process was developed to accurately remove a targeted depth of resin, approximately 0.1 to 20 micrometers, from a carbon fiber reinforced epoxy composite surface while simultaneously changing surface chemistry and creating micro-roughness. This work demonstrates the application of this process to prepare composite surfaces for bonding without exposing or damaging fibers on the surface. Composite panels were prepared in an autoclave and had a resin layer approximately 10 micrometers thick above the fiber reinforcement. These composite panels were laser surface treated using several conditions, fabricated into bonded panels and hygrothermally aged. Bond performance of aged, experimental specimens was compared with grit blast surface treated specimens using a modified double cantilever beam test that enabled accelerated saturation of the specimen with water. Comparison of bonded specimens will be used to determine how ablation depth may affect average fracture energies and failure modes.

Palmieri, Frank L.↗

New class of tritium breeders for fusion applications: Metal-reinforced composite breeders

Commercial fusion reactors operating on a D-T fuel cycle will require a steady supply of tritium to maintain the burning plasma required for continuous power generation. Since tritium has a short half-life, there is negligible natural abundance which necessitates fusion reactors to produce their own source of tritium. Tritium is most easily produced by surrounding a fusion reactor core with lithium (Li), which reacts under the intense neutron flux leaving the reactor core to form tritium and helium. Due to the hazards and technical challenges associated with surrounding a fusion reactor core with many tons of molten Li, other Li-bearing tritium breeder materials have been pursued. Unfortunately, most of the liquid breeders historically examined are exceedingly corrosive to reactor structural materials while many solid breeders in the form of ceramics are forced to make tradeoffs between Li content and mechanical integrity. In this work, to break the historic limit between Li-density and mechanical integrity of traditional solid breeders, a new class of solid tritium breeders is developed: metal-reinforced composite (MERC) breeders. Specifically, the high Li-density of lithium oxide (Li 2 O) is exploited through the addition of a metal reinforcing phase, producing a composite breeder material exhibiting high splitting tensile strength and quasi-ductility with a Li-density greater than other leading solid breeder candidates, including lithium orthosilicate (Li 4 SiO 4 ) and lithium metatitanate (Li 2 TiO 3 ). Mechanical testing, microstructural characterization, and neutronic simulation results are presented and discussed in light of fusion reactor design considerations.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗