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At least 649 records · Page 36

Removal of High Specific Activity Fission Products from Uranyl Sulfate Waste Solutions

The Savannah River National Laboratory (SRNL) is currently providing support to SHINE Medical Technologies (SHINE) which plans to deploy a low energy, accelerator-based neutron source to fission low enriched U in a uranyl sulfate target solution for 99 Mo production. The 99 Mo is initially separated from the fission products and target solution by an extraction column. Subsequent washing of the column will generate waste solutions containing residual U and fission product activity. A small number of high specific activity fission products (e.g., 90 Sr, 137 Cs, and 144 Ce) in these streams will likely control the classification of the low level waste (LLW). If a sufficient amount of the high specific activity isotopes are separated from the SHINE waste streams and concentrated into a waste form, it would be possible to treat a majority of the wash solutions from the column operations as a lower class of LLW (Class A versus Class B or C or Class B versus Class C). The high specific activity fission product elements could then be dispositioned as a much smaller volume of waste rather than requiring the disposal of the entire waste stream at the higher waste classification. The Savannah River Site (SRS) has experience with using monosodium titanate (MST) and crystalline silicotitanate (CST) to remove Cs and Sr from high salt content waste solutions generated during the reprocessing of nuclear fuels and targets. Both of these materials have worked very well for their intended purposes at the SRS where the fission product elements are removed from highly alkaline waste. On the other hand, SHINE waste streams from the extraction column contain H 2 SO 4 which makes the solution acidic. Additionally, the SRS waste streams do not contain other fission product elements such as transition metals or lanthanides because they precipitate upon neutralization of the SRS waste and are not present in the supernate which is dispositioned as LLW following treatment. As such, there are inherent differences between SHINE and SRS waste treatment strategies. Savannah River National Laboratory was tasked with performing scoping studies to see if MST and CST would remove Sr, Cs, and Ce from an acidic mixed metal simulant solution. Batch contact experiments were performed using MST and two CST type materials. The MST material is a 15 wt % powder in 0.15 M NaOH slurry. The MST showed low adsorption for elements of interest from acidic solution. Furthermore, the powder size makes MST non-ideal for column operations. A CST IE-911 ion exchange material had high Cs adsorption, moderate Sr, and marginal Ce adsorption. Based on adsorption of all species, the ion exchange capacity was found to be 0.032 meq/mL. A bench-top column experiment to measure elemental breakthrough curves was performed using CST IE-911 where chromatographic separations of the mixed simulant were expected to occur. While most elements behaved as expected, the lanthanide series, containing Ce, broke though the column earlier than expected. The second CST material, CST R9120, displayed high adsorption for all elements in the acidic mixed simulant solutions in a batch contact study, and had a calculated loading capacity of 0.091 meq/mL. Future studies to develop a waste treatment flowsheet should focus on CST R9120 to treat SHINE waste solutions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Implications of a regional resource adequacy program on utility integrated resource planning: Study for the Western United States

LBNL collaborated with the Western Interstate Energy Board and the University of Texas, Austin to investigate the implications of a regional resource adequacy (RA) program on utility integrated resource planning. This report is focused on an active policy discussion to develop a novel voluntary program to share capacity resource and improve RA in the Western Interconnection. This report identifies two RA components of IRP that will be highly impacted by a regional RA program: resource capacity accreditation and RA targets. There are at least four resources that will require specific attention for their capacity credit calculation: (1) variable renewable resources, (2) demand-side resources, (3) hydropower, and (4) contracts. It will then be necessary to decide on a RA target reliability metric (e.g., a planning reserve margin) that is at least the minimum requirement in IRPs to ensure consistency in RA requirement calculations. The report finds that load forecasting and transmission expansion analyses will be moderately impacted, but that most of IRP components will not be significantly impacted. The report includes (i) a review of traditional resource adequacy practices in IRP; (ii) a case study of an existing regional RA program that interacts with IRP (Southwest Power Pool) and (iii) an overview of the NWPP regional resource adequacy proposal that is the object of this work. This paper does not (1) advocate for or against a regional RA program for the NWPP, (2) make detailed design recommendations for this program, or (3) assess its benefits and costs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Calibrating the SPECTACULAR constitutive model using legacy Sandia data for two filled epoxy systems: 828/CTBN/DEA/GMB and 828/DEA/GMB

The SPECTACULAR model is a development extension of the Simplified Potential Energy Clock (SPEC) model. Both models are nonlinear viscoelastic constitutive models used to predict a wide range of time-dependent behaviors in epoxies and other glass-forming materials. This report documents the procedures used to generate SPECTACULAR calibrations for two particulate-filled epoxy systems, 828/CTBN/DEA/GMB and 828/DEA/GMB. No previous SPECTACULAR or SPEC calibration exists for 828/CTBN/DEA/GMB, while a legacy SPEC calibration exists for 828/DEA/GMB. To generate the SPECTACULAR calibrations, a step-by-step procedure was executed to determine parameters in groups with minimal coupling between parameter groups. This procedure has often been deployed to calibrate SPEC, therefore the resulting SPECTACULAR calibration is backwards compatible with SPEC (i.e. none of the extensions specific to SPECTACULAR are used). The calibration procedure used legacy Sandia experimental data stored on the Polymer Properties Database website. The experiments used for calibration included shear master curves, isofrequency temperature sweeps under oscillatory shear, the bulk modulus at room temperature, the thermal strain during a temperature sweep, and compression through yield at multiple temperatures below the glass transition temperature. Overall, the calibrated models fit the experimental data remarkably well. However, the glassy shear modulus varies depending on the experiment used to calibrate it. For instance, the shear master curve, isofrequency temperature sweep under oscillatory shear, and the Young's modulus in glassy compression yield values for the glassy shear modulus at the reference temperature that vary by as much as 15 %. Also, for 828/CTBN/DEA/GMB, the temperature dependence of the glassy shear modulus when fit to the Young's modulus at different temperatures is approximately four times larger than when it is determined from the isofrequency temperature sweep under oscillatory shear. For 828/DEA/GMB, the temperature dependence of the shear modulus determined from the isofrequency temperature sweep under oscillatory shear accurately predicts the Young's modulus at different temperatures. When choosing values for the shear modulus, fitting the glassy compression data was prioritized. The new and legacy calibrations for 828/DEA/GMB are similar and appear to have been calibrated from the same data. However, the new calibration improves the fit to the thermal strain data. In addition to the standard calibrations, development calibrations were produced that take advantage of development features of SPECTACULAR , including an updated equilibrium Helmholtz free energy that eliminates undesirable behavior found in previous work. In addition to the previously mentioned experimental data, the development calibrations require data for the heat capacity during a stress-free temperature sweep to calibrate thermal terms.

36 MATERIALS SCIENCE↗

Aligning Ukrainian Building Energy Codes with the EPBD

The aim of this report is to support Ukraine in revising its building energy codes in line with regulations laid out by the Energy Performance in Buildings Directive (EPBD). The main objectives are to i) provide valuable information to help Ukraine align its building energy codes with EPBD requirements, ii) advance the capacity of key stakeholders in Ukraine to develop new regulations based on robust technical methodologies and analysis, iii) summarize building energy codes best practices using examples from the EU and elsewhere, and iv) recommend steps Ukraine can take to improve its building energy code regulations and implementation. This report summarizes EPBD requirements for new buildings, and buildings undergoing major renovations, related to cost-optimal and Nearly Zero Energy Building (NZEB) requirements. This report highlights Ukraine’s progress in aligning it’s building energy codes with the aforementioned requirements and best practices regarding those requirements from the EU and internationally. Based on best practices and Ukraine’s current progress on requirements, recommendations are presented. A brief overview of the EPBD and building energy codes in Ukraine is also provided. Implementation related to building energy codes is touched upon as well. Potential next steps for Ukraine are outlined based on provided recommendations.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Updated Baseline Cost Model for Hydropower (2023)

The "Updated Baseline Cost Model (BCM) for Hydropower" is an empirical model for estimating the costs of US hydropower projects in six categories (Non-Powered Dam (NPD), New Stream Development (NSD), Canal/Conduit, Pumped Storage Hydro (PSH), Capacity Expansion, Generator Rewind). The model equations have been estimated with data on existing or planned projects obtained from various sources. NOTE: This is a macro-enabled workbook, so Excel may block it on the first opening. In that case: 1. Save the workbook to a local directory 2. Right-click on the workbook in the local directory and select “Properties” 3. Then check “Unblock” at the bottom of the “General” tab.

13 HYDRO ENERGY↗

Interpreting Morphological Adaptations Associated with Viviparity in the Tsetse Fly Glossina morsitans (Westwood) by Three-Dimensional Analysis

Tsetse flies (genus Glossina), the sole vectors of African trypanosomiasis, are distinct from most other insects, due to dramatic morphological and physiological adaptations required to support their unique biology. These adaptations are driven by demands associated with obligate hematophagy and viviparous reproduction. Obligate viviparity entails intrauterine larval development and the provision of maternal nutrients for the developing larvae. The reduced reproductive capacity/rate associated with this biology results in increased inter- and intra-sexual competition. Here, we use phase contrast microcomputed tomography (pcMicroCT) to analyze morphological adaptations associated with viviparous biology. These include (1) modifications facilitating abdominal distention required during blood feeding and pregnancy, (2) abdominal and uterine musculature adaptations for gestation and parturition of developed larvae, (3) reduced ovarian structure and capacity, (4) structural features of the male-derived spermatophore optimizing semen/sperm delivery and inhibition of insemination by competing males and (5) structural features of the milk gland facilitating nutrient incorporation and transfer into the uterus. Three-dimensional analysis of these features provides unprecedented opportunities for examination and discovery of internal morphological features not possible with traditional microscopy techniques and provides new opportunities for comparative morphological analyses over time and between species.

59 BASIC BIOLOGICAL SCIENCES↗

SAMICS Validation. SAMICS Support Study, Phase 3

SAMICS provides a consistent basis for estimating array costs and compares production technology costs. A review and a validation of the SAMICS model are reported. The review had the following purposes: (1) to test the computational validity of the computer model by comparison with preliminary hand calculations based on conventional cost estimating techniques; (2) to review and improve the accuracy of the cost relationships being used by the model: and (3) to provide an independent verification to users of the model's value in decision making for allocation of research and developement funds and for investment in manufacturing capacity. It is concluded that the SAMICS model is a flexible, accurate, and useful tool for managerial decision making.

Source record↗

Implication of a color multibeam communications satellite in the 30/20 GHz bands

In order to meet the need for increased communications capacity, NASA is conducting a program to develop technology and systems for a 30/20 GHz multibeam domestic U.S. satellite. One way to provide the required national interconnectivity is to permute and time share connections among the involved areas by means of a satellite-borne multiport microwave switch with a Time-Division Multiple Access (TDMA) system. In this connection, the question was analyzed whether a practical satellite message routing system can be developed using FDMA techniques. The total traffic (model A) was derived and used as an input specification for the satellite-routed FDMA study. Attention is given to beam isolations, color and regional systems, the level of service, and the color FDMA satellite. It is concluded that the FDMA system considered can handle substantially all the Customer Premises Service (CPS) and Trunking (TR) traffic in Model A. The (color) scheme completely satisfies the CPS and TR requirements of 23 cities.

Hoffman, M.↗

The HCMM system: Development and performance

The structure and history of the heat capacity mapping mission program is reviewed and the spacecraft is described including engineering specifications, instrument design, data handling, and image characteristics.

Stuart, L. M., Jr.↗

The share flight experiment - An advanced heat pipe radiator for Space Station

This paper reports on the design and thermal vacuum certification testing of the Space Station Heat Pipe Advanced Radiator Element (SHARE) Shuttle flight experiment, with primary emphasis on the heat pipe radiator system. The main objective of the SHARE experiment is to demonstrate suitable 0 g heat transfer performance of a 50 ft-long high-capacity monogroove heat pipe radiator element being developed for possible Space Station application. All of the flight certification tests were achieved, including a maximum heat rejection of 2 kW and thawing of a frozen heat pipe; and uninterrupted operation under cycling environmental and evaporator heat loads.

Alario, J. P.↗

NASA spaceborne optical disk recorder development

Spaceflight application of a high performance (high rate, high capacity) erasable optical disk recorder is discussed. An expandable modular system concept is proposed consisting of multiple drive modules and a modular system controller. A drive contains two 14-inch magneto-optic disks and four electro-optic heads, each containing a nine-diode solid state laser array (eight data tracks, one pilot track). The performance goals of the drive module are 20 gigabyte capacity, 300 megabit per second transfer rate, 10x(Exp-10) corrected BER, and 100 millisecond access time. The system goals are 120 gigabyte capacity at up to 1.8 gigabits per second rate, concurrent 1/0, varying data rates, reconfigurable architecture, and 2 to 5 year operating life in orbit. The system environment and operational scenarios are presented.

Shull, Thomas A.↗

NASA launch vehicles - The next twenty years

Future space activities call for robust, reliable, cost-effective access to space, together with greater launch capacity. Attention is presently given to prospective developments in the field of cargo launch vehicle design, whose near-term goal for NASA is the Shuttle-C Space Shuttle-development unmanned vehicle. In the longer term, the Advanced Launch System will be developed jointly by NASA and the DOD for LEO placement of payloads of as much as 200,000 lb. NASA is studying ways of developing the current manned Space Shuttle Orbiter through incorporation of emerging technologies; eventually, a 'Shuttle-II' vehicle will be developed.

Branscome, Darrell R.↗

Power electronics for low power arcjets

In anticipation of the needs of future light-weight, low-power spacecraft, arcjet power electronics in the 100 to 400 W operating range were developed. Limited spacecraft power and thermal control capacity of these small spacecraft emphasized the need for high efficiency. Power topologies similar to those in the higher 2 kW and 5 to 30 kW power range were implemented, including a four transistor bridge switching circuit, current mode pulse-width modulated control, and an output current averaging inductor with an integral pulse generation winding. Reduction of switching transients was accomplished using a low inductance power distribution network, and no passive snubber circuits were necessary for power switch protection. Phase shift control of the power bridge was accomplished using an improved pulse width modulation to phase shift converter circuit. These features, along with conservative magnetics designs allowed power conversion efficiencies of greater than 92.5 percent to be achieved into resistive loads over the entire operating range of the converter. Electromagnetic compatibility requirements were not considered in this work, and control power for the converter was derived from AC mains. Addition of input filters and control power converters would result in an efficiency of on the order of 90 percent for a flight unit. Due to the developmental nature of arcjet systems at this power level, the exact nature of the thruster/power processor interface was not quantified. Output regulation and current ripple requirements of 1 and 20 percent respectively, as well as starting techniques, were derived from the characteristics of the 2 kW system but an open circuit voltage in excess of 175 V was specified. Arcjet integration tests were performed, resulting in successful starts and stable arcjet operation at power levels as low as 240 W with simulated hydrazine propellants.

Hamley, John A.↗

Lightning protection of full authority digital electronic systems

Modern electronic systems are vulnerable to transient and they now provide safety critical functions such as full authority digital electronic control (FADEC) units for fly by wire aircraft. Of the traditional suppression technologies available diodes have gained the wider acceptance, however, they lack the current handling capacity to meet existing threat levels. The development of high speed fold back devices where, at a specified voltage, the off state resistance switches to a very low on state one has provided the equivalent to a semiconductor spark gap. The size of the technology enables it to be integrated into connectors of interconnection cables. To illustrate the performance the technology was developed to meet the Lightning Protection requirements for FADEC units within aeroengines. Work was also carried out to study switching behavior with the waveform 5, the 500 us, 10 kA pulse applied to cable assemblies. This test enabled all the switches in a connector to be fired simultaneously.

Crofts, David↗

Life sciences research using a lunar laboratory

The necessity for life sciences research on the lunar surface in order to determine the consequences of returning from extended missions in various low gravity environments and of transiting through high multiple gravity forces during decelerations is discussed. The functions of a lunar gravitational biology laboratory are outlined. Lunar science objectives include investigations in developmental biology including the evaluation of the capacity of diverse organisms to undergo normal development and the evaluation of the use of the lunar environment to study specific developmental phenomena in ways that cannot be accomplished by earth-based research. The need for musculoskeletal studies to examine the dynamics of osteoclast and osteoblast formation and breakdown and to address bone and demineralization problems is discussed. Biological adaptation to hypogravic environments and the effects of radiation and electromagnetic environmental factors are also considered.

Cipriano, Leonard F.↗

Spaceflight optical disk recorder development

A NASA program to develop a high performance (high rate, high capacity) rewriteable optical disk recorder for spaceflight applications is presented. An expandable, adaptable system concept is proposed based on disk drive modules and a modular controller. Drive performance goals are 10 Gbyte capacity, 300 Mb transfer rate, 10 to the -12th corrected bit-error rate, and 150 msec access time. The preliminary design for an expandable controller is presented. System goals are up to 160 Gbyte capacity at up to 1.8 Gb/sec rate with concurrent I/O, asynchronous data transfer, and 2-5-year operating life in orbit. Projected system environment and operational scenarios based on Polar Orbiting Platform applications are discussed.

Shull, Thomas A.↗

Control-structure-thermal interactions in analysis of lunar telescopes

The lunar telescope project was an excellent model for the CSTI study because a telescope is a very sensitive instrument, and thermal expansion or mechanical vibration of the mirror assemblies will rapidly degrade the resolution of the device. Consequently, the interactions are strongly coupled. The lunar surface experiences very large temperature variations that range from approximately -180 C to over 100 C. Although the optical assemblies of the telescopes will be well insulated, the temperature of the mirrors will inevitably fluctuate in a similar cycle, but of much smaller magnitude. In order to obtain images of high quality and clarity, allowable thermal deformations of any point on a mirror must be less than 1 micron. Initial estimates indicate that this corresponds to a temperature variation of much less than 1 deg through the thickness of the mirror. Therefore, a lunar telescope design will most probably include active thermal control, a means of controlling the shape of the mirrors, or a combination of both systems. Historically, the design of a complex vehicle was primarily a sequential process in which the basic structure was defined without concurrent detailed analyses or other subsystems. The basic configuration was then passed to the different teams responsible for each subsystem, and their task was to produce a workable solution without requiring major alterations to any principal components or subsystems. Consequently, the final design of the vehicle was not always the most efficient, owing to the fact that each subsystem design was partially constrained by the previous work. This procedure was necessary at the time because the analysis process was extremely time-consuming and had to be started over with each significant alteration of the vehicle. With recent advances in the power and capacity of small computers, and the parallel development of powerful software in structural, thermal, and control system analysis, it is now possible to produce very detailed analyses of intermediate designs in a much shorter period of time. The subsystems can thus be designed concurrently, and alterations in the overall design can be quickly adopted into each analysis; the design becomes an iterative process in which it is much easier to experiment with new ideas, configurations, and components. Concurrent engineering has the potential to produce efficient, highly capable designs because the effect of one subystem on another can be assessed in much more detail at a very early point in the program. The research program consisted of several tasks: scale a prototype telescope assembly to a 1 m aperture, develop a model of the telescope assembly by using finite element (FEM) codes that are available on site, determine structural deflections of the mirror surfaces due to the temperature variations, develop a prototype control system to maintain the proper shape of the optical elements, and most important of all, demonstrate the concurrent engineering approach with this example. In addition, the software used for the finite element models and thermal analysis was relatively new within the Program Development Office and had yet to be applied to systems this large or complex; understanding the software and modifying it for use with this project was also required. The I-DEAS software by Structural Dynamics Research Corporation (SDRC) was used to build the finite element models, and TMG developed by Maya Heat Transfer Technologies, Ltd. (which runs as an I-DEAS module) was used for the thermal model calculations. All control system development was accomplished with MATRIX(sub X) by Integrated Systems, Inc.

Thompson, Roger C.↗