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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Molecular Insights Into the Ionic Assembly of Poly-Galacturonic Acid Oligomers - Impact of Charge, Ionic Radius, and Polymer Functionalization

Pectin, a major class of matrix polysaccharides present in plant cell walls (PCW), contains widespread anionic saccharides that cross-link in the presence of cations. It modulates important functions such as cell-cell adhesion and determines the PCW's biomechanical properties. It is known that mono-, di-, and tri-valent cations facilitate cross-linking; however, significant knowledge gaps remain in understanding the structure and mechanism of pectin cross-linking. In this study, replica-exchange molecular dynamics (REMD) simulations were employed to elucidate the role of ionic charge, ionic radii, and functional groups on the cross-linking of homogalacturonan (HG), the most abundant pectin molecule. Our enhanced sampling approach in fully solvated environments suggests more effective cross-linking with higher-valent and smaller ions, and that the "zipper" conformation is more favorable than the prevalent "egg-box" conformation. These findings advance our fundamental understanding of pectin matrix structure in PCWs and provide a solid foundation to probe structure-property relationships in pectic polysaccharides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRSDate not supplied

An Overview of Ground-Based Radar and Optical Measurements Utilized By the Nasa Orbital Debris Program Office

For over 30 years, the NASA Orbital Debris Program Office (ODPO) has led the characterization of orbital debris (OD) too small to be tracked by the U.S. Space Surveillance Network (SSN), yet which may pose the greatest threat to human spaceflight and robotic missions. Measurements from specialized sensors, including ground-based radars and telescopes capable of detecting smaller objects, provide the foundation for developing statistical models to describe the current state and future evolution of the OD environment from low Earth orbit (LEO) to geosynchronous Earth orbit (GEO). Since 1990, the ODPO has partnered with the U.S. Department of Defense and the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL) to collect data using the Haystack Ultrawideband Satellite Imaging Radar (HUSIR) – formerly Haystack – to characterize OD in LEO with a sensitivity of approximately 5 mm at 1000 km altitude. In addition, since 1993, the Goldstone Orbital Debris Radar, operated by NASA’s Jet Propulsion Laboratory, has provided data on OD as small as approximately 2-3 mm for altitudes below 1000 km, some of the most sensitive ground-based measurements achievable at these altitudes. Recently, collaborations with the 18 th Space Control Squadron of the U.S. Space Force have also provided the ODPO with special datasets from the Space Fence to extend coverage below the historical SSN limit of 10 cm and to characterize individual breakup events in LEO. For GEO altitudes, the Eugene Stansbery Meter Class Autonomous Telescope (ES-MCAT), a joint NASA-Air Force Research Laboratory project that reached full operational capability in 2021, collects data on debris smaller than 1 m and provides coverage of debris in historically under-sampled high-altitude orbital regimes. This paper summarizes the radar and optical sensors utilized by the ODPO, their unique capabilities, and recent datasets and applications for statistical sampling of the dynamic OD environment.

Alyssa Manis↗
NASA NTRSDate not supplied

An Overview of Ground-Based Radar and Optical Measurements Utilized By the Nasa Orbital Debris Program Office

For over 30 years, the NASA Orbital Debris Program Office (ODPO) has led the characterization of orbital debris (OD) too small to be tracked by the U.S. Space Surveillance Network (SSN), yet which may pose the greatest threat to human spaceflight and robotic missions. Measurements from specialized sensors, including ground-based radars and telescopes capable of detecting smaller objects, provide the foundation for developing statistical models to describe the current state and future evolution of the OD environment from low Earth orbit (LEO) to geosynchronous Earth orbit (GEO). Since 1990, the ODPO has partnered with the U.S. Department of Defense and the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL) to collect data using the Haystack Ultrawideband Satellite Imaging Radar (HUSIR) – formerly Haystack – to characterize OD in LEO with a sensitivity of approximately 5 mm at 1000 km altitude. In addition, since 1993, the Goldstone Orbital Debris Radar, operated by NASA’s Jet Propulsion Laboratory, has provided data on OD as small as approximately 2-3 mm for altitudes below 1000 km, some of the most sensitive ground-based measurements achievable at these altitudes. Recently, collaborations with the 18 th Space Control Squadron of the U.S. Space Force have also provided the ODPO with special datasets from the Space Fence to extend coverage below the historical SSN limit of 10 cm and to characterize individual breakup events in LEO. For GEO altitudes, the Eugene Stansbery Meter Class Autonomous Telescope (ES-MCAT), a joint NASA-Air Force Research Laboratory project that reached full operational capability in 2021, collects data on debris smaller than 1 m and provides coverage of debris in historically under-sampled high-altitude orbital regimes. This paper summarizes the radar and optical sensors utilized by the ODPO, their unique capabilities, and recent datasets and applications for statistical sampling of the dynamic OD environment.

Alyssa Manis↗
NASA NTRS2008

MISSE Thermal Control Materials with Comparison to Previous Flight Experiments

Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment (MISSE), including inorganic coatings, anodized aluminum, and multi-layer insulation materials. These and other material samples were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was limited for some samples. Materials flown on MISSE-1 and MISSE-2 were exposed to the space environment for nearly four years. Materials flown on MISSE-3, MISSE-4, and MISSE-5 were exposed to the space environment for one year. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. Effects of short duration versus long duration exposure on ISS are explored, as well as comparable data from previous flight experiments, such as the Passive Optical Sample Assembly (POSA), Optical Properties Monitor (OPM), and Long Duration Exposure Facility (LDEF).

Finckenor, Miria↗
NASA NTRS2011

Mass Spectrometry on Future Mars Landers

Mass spectrometry investigations on the 2011 Mars Science Laboratory (MSL) and the 2018 ExoMars missions will address core science objectives related to the potential habitability of their landing site environments and more generally the near-surface organic inventory of Mars. The analysis of complex solid samples by mass spectrometry is a well-known approach that can provide a broad and sensitive survey of organic and inorganic compounds as well as supportive data for mineralogical analysis. The science value of such compositional information is maximized when one appreciates the particular opportunities and limitations of in situ analysis with resource-constrained instrumentation in the context of a complete science payload and applied to materials found in a particular environment. The Sample Analysis at Mars (SAM) investigation on MSL and the Mars Organic Molecule Analyzer (MOMA) investigation on ExoMars will thus benefit from and inform broad-based analog field site work linked to the Mars environments where such analysis will occur.

Brinckerhoff, W. B.↗
DOE OSTI2017

Preliminary Analysis of Damage to MPFDs Caused by Reactor Pulses

The need for next-generation, accident-tolerant fuels has generated significant interest in the restart of domestic fuels testing at the Transient Reactor Test (TREAT) facility. The TREAT reactor is designed to produce large, transient fluxes that replicate the effects of a wide variety of accident conditions on an irradiated fuel sample. Peak powers generated during short pulses approach 20 GW with a neutron flux of approximately 10{sup 17} n cm{sup -2} s{sup -1}. As part of the restart effort, new vehicle designs are being explored for sample irradiation, including the Static Environment Rodlet Transient Test Apparatus (SERTTA) and variants. As part of the SERTTA designs, micro-pocket fission detectors (MPFDs) are being explored for localized flux measurements before, during, and after transient operations. These detectors are also being considered as part of future, core-wide instrumentation for the TREAT reactor. However, the high fluxes associated with the pulses in the TREAT core present certain thermodynamic concerns given their intensity and the amount of energy they will release within the MPFDs within such a short amount of time. Assuming each fission that occurs in a MPFD results in a fission fragment depositing 85 MeV of energy in the substrate on average and each MPFD has 0.5 μg of natural uranium deposited on it, a 100 ms long pulse in the TREAT reactor at 1017 n cm{sup -2} s{sup -1} flux will produce approximately 4.6 x 10{sup 6} fissions in an MPFD. This pulse deposits 6.3 x 10{sup -5} J in the substrate over a 100 ms duration. That amount of energy is sufficient to melt roughly 33% of the Pt under the UO{sub 2} deposition or a circular spot with a diameter of approximately 860 μm. Of course, the above estimate makes a number of simplifying assumptions and ignores heat transfer, but does serve to illustrate the point that this rapid heating effect could be detrimental to the integrity and life of these in-core MPFDs. To study how these layers are affected by large transient neutron fluxes, five samples were prepared, pre-analyzed, and then subjected to a pulse in the central thimble of the Kansas State University TRIGA Mark II reactor to a peak power of 1.58 GW. After being allowed to decay to safer radiation levels, the sample substrates and coatings were inspected using scanning electron microscopy (SEM) to identify any changes to their surface morphology. Indeed, certain changes were found and are discussed in greater detail in this paper.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2014

Microstructure and Macrosegregation Study of Directionally Solidified Al-7Si Samples Processed Terrestrially and Aboard the International Space Station

This talk reports research that has been carried out under the aegis of NASA as part of a collaboration between ESA and NASA for solidification experiments on the International Space Station (ISS). The focus has been on the effect of convection on the microstructural evolution and macrosegregation in hypoeutectic Al‐Si alloys during directional solidification (DS). The DS‐experiments have been carried out under 1‐g at Cleveland State University (CSU) and under low‐g on the International Space Station (ISS). The thermal processing‐history of the experiments is well defined for both the terrestrially‐processed samples and the ISS‐processed samples. We have observed that the primary dendrite arm spacings of two samples grown in the low‐g environment of the ISS show good agreement with a dendrite‐growth model based on diffusion controlled growth. The gravity‐driven convection (i.e., thermosolutal convection) in terrestrially grown samples has the effect of decreasing the primary dendrite arm spacings and causes macrosgregation. In order to process DS‐samples aboard the ISS, dendritic‐seed crystals have to partially remelted in a stationary thermal gradient before the DS is carried out. Microstructural changes and macrosegregation effects during this period are described.

Angart, Samuel↗
NASA NTRS2024

Space Exposure of Indium Tin Oxide Coatings

Indium tin oxide (ITO) coated thermal control samples were exposed to the space environment as part of the Materials International Space Station Experiment-9 (MISSE-9) mission to assess the impact of low Earth orbit (LEO) on material properties. Six samples were flown as part of the Polymers and Composites Experiment-1 (PCE-1): four samples of ITO coated silver Teflon (FEP/Ag/Inconel), and two samples of ITO coated Kapton HN (Kapton HN/Al). Samples were flown in ram, wake and zenith directions and were directly exposed to space for 0.77 years (ram) or 0.54 years (wake and zenith). Flight and corresponding control samples were tested post flight for changes in optical properties (total reflectance and solar absorptance) and film electrical resistance. In addition, the atomic oxygen erosion yield (E y ) was determined for each flight sample. This paper provides details on the flight sample materials, the mission space exposure and the postflight test results. Indium tin oxide coated samples were not significantly damaged by the LEO exposures. The atomic oxygen E y values were very low and the solar absorptance changed very little. Sheet resistance of the ITO coated Kapton HN/Al doubled after ram exposure, however its final resistance of 10,820 Ohm/square is believed to be low enough to enable dissipation of electrostatic charges. Sheet resistance measurements for the ITO coated FEP/Ag/Inconel sheets suffered from high levels of scatter, with some resistance measurements higher than 370,000 Ohms/square.

Atomic oxygen↗
DOE OSTI2018

Predicting Polymer Degradation and Mechanical Property Changes for Combined Radiation-Thermal Aging Environments

Here, a new approach is presented for conducting and extrapolating combined environment (radiation plus thermal) accelerated aging experiments. The method involves a novel way of applying the time-temperature-dose rate (t-T-R) approach derived many years ago, which assumes that by simultaneously accelerating the thermal-initiation rate (from Arrhenius T-only analysis) and the radiation dose rate R by the same factor x, the overall degradation rate will increase by the factor x. The dose rate assumption implies that equal dose yields equal damage, which is equivalent to assuming the absence of dose-rate effects (DRE). A plot of inverse absolute temperature versus the log of the dose rate is used to indicate experimental conditions consistent with the model assumptions, which can be derived along lines encompassing so-called matched accelerated conditions (MAC lines). Aging trends taken along MAC lines for several elastomers confirms the underlying model assumption and therefore indicates, contrary to many past published results, that DRE are typically not present. In addition, the MAC approach easily accommodates the observation that substantial degradation chemistry changes occur as aging conditions transition R-T space from radiation domination (high R, low T) to temperature domination (low R, high T). The MAC-line approach also suggests an avenue for gaining more confidence in extrapolations of accelerated MAC-line data to ambient aging conditions by using ultrasensitive oxygen consumption (UOC) measurements taken along the MAC line both under the accelerated conditions and at ambient. From UOC data generated under combined R-T conditions, this approach is tested and quantitatively confirmed for one of the materials. In analogy to the wear-out approach developed previously for thermo-oxidative aging, the MAC-line concept can also be used to predict the remaining lifetimes of samples extracted periodically from ambient environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Prevalence of Self-Reported Voice Concerns and Associated Risk Markers in a Nonclinical Sample of Military Service Members

Introduction: Difficult communication environments are common in military settings, and effective voice use can be critical to mission success. This study aimed to estimate the prevalence of self-reported voice disorders among U.S. military service members and to identify factors that contribute to their voice concerns. Method: A nonclinical sample of 4,123 active-duty service members was recruited across Department of Defense hearing conservation clinics. During their required annual hearing evaluation, volunteers provided responses to voice-related questions including a slightly adapted version of the Voice Handicap Index-10 (VHI-10) as part of a larger survey about communication issues. Changepoint detection was applied to age and years of service to explore cohort effects in the reporting of voice concerns. Logistic regression analyses examined multiple available factors related to communication to identify factors associated with abnormal results on the VHI-10. Results: Among the respondents, 41% reported experiencing vocal hoarseness or fatigue at least several times per year, and 8.2% ( n = 336) scored above the recommended abnormal cut-point value of 11 on the VHI-10. Factors independently associated with the greatest risk for self-reported voice concerns were sex (female), cadmium exposure, vocal demands (the need for a strong, clear voice), and auditory health measures (frequency of experiencing temporary threshold shifts; self-reported hearing difficulties). Conclusions: Based on self-reported voice concerns and false negative rates reported in the literature, the prevalence of dysphonia in a large sample of active-duty service members is estimated to be 11.7%, which is higher than that in the general population. Certain predictors for voice concerns were expected based on previous literature, like female sex and voice use, but frequency of temporary threshold shifts and exposure to cadmium were surprising. The strong link between voice and auditory problems has particular implications regarding the need for effective communication in high-noise military and other occupational environments.

Audiology & Speech-Language Pathology↗
DOE OSTI2018

Atmospheric and Long-term Aging Effects on the Electrical Properties of Variable Thickness WSe 2 Transistors

Atmospheric and long-term aging effects on electrical properties of WSe 2 transistors with various thicknesses are examined. While countless published studies report electrical properties of transition-metal dichalcogenide materials, many are not attentive to testing environment or to age of samples, which we have found significantly impacts results. Our as-fabricated exfoliated WSe 2 pristine devices are predominantly n-type, which is attributed to selenium vacancies. Transfer characteristics of as-fabricated devices measured in air then vacuum reveal physisorbed atmospheric molecules significantly reduced n-type conduction in air. First-principles calculations suggest this short-term reversible atmospheric effect can be attributed primarily to physisorbed H 2 O on pristine WSe 2 , which is easily removed from the pristine surface in vacuum due to the low adsorption energy. Devices aged in air for over 300 h demonstrate irreversibly increased p-type conduction and decreased n-type conduction. Moreover, they develop an extended time constant for recovery of the atmospheric adsorbents effect. Short-term atmospheric aging (up to approximately 900 h) is attributed to O 2 and H 2 O molecules physisorbed to selenium vacancies where electron transfer from the bulk and adsorbed binding energies are higher than the H 2 O-pristine WSe2. The residual/permanent aging component is attributed to electron trapping molecular O 2 and isoelectronic O chemisorption at selenium vacancies, which also passivates the near-conduction band gap state, p-doping the material, with very high binding energy. All effects reflected have the expected thickness dependence, namely, thinner devices are more sensitive to atmospheric and long-term aging effects.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Containerless undercooling and solidification of bulk metastable Nb3Ge alloys

Experiments using containerless undercooling and low-gravity solidification of Nb(1-x)Ge(x) alloys for x=0.13-0.27 have been carried out in a 32-m drop-tube apparatus to study the feasibility of forming metastable Nb3Ge in bulk form. It is found that bulk samples (2-3 mm diam) of Nb-Ge alloys with 18-22% Ge can be undercooled by large amounts (300-500 K) and solidified in a containerless environment. Subsequent quenching of the solidified samples in oil helps preserve the metastable A-15 phase by removing the latent heat of fusion and quickly cooling the samples to a stable temperature below 1000 C. Even at an undercooling of less than 100 K, the superconducting transition temperature of the material is enhanced over the cast material by about 1 K.

Lacy, L. L.↗
DOE OSTI2023

Diagnostic diagrams for ram pressure stripped candidates

ABSTRACT This paper presents a method for finding ram pressure stripped (RPS) galaxy candidates by performing a morphological analysis of galaxy images obtained from the Legacy survey. We consider a sample of about 600 galaxies located in different environments such as groups and clusters, tidally interacting pairs and the field. The sample includes 160 RPS previously classified in the literature into classes from J1 to J5, based on the increasing level of disturbances. Our morphological analysis was done using the astromorphlib software followed by the inspection of diagnostic diagrams involving combinations of different parameters like the asymmetry (A), concentration (C), Sérsic index (n), and bulge strength parameters $F(G,\, M_{20})$. We found that some of those diagrams display a distinct region in which galaxies classified as J3, J4, and J5 decouples from isolated galaxies. We call this region as the morphological transition zone and we also found that tidally interacting galaxies in pairs are predominant within this zone. Nevertheless, after visually inspecting the objects in the morphological transition zone to discard obvious contaminants, we ended up with 33 bona fide new RPS candidates in the studied nearby groups and clusters (Hydra, Fornax, and CLoGS sample), of which one-third show clear evidence of unwinding arms. Future works may potentially further increase significantly the samples of known RPS using such method.

Astronomy & Astrophysics↗
NASA NTRS1977

Real time reflectometer

A real time reflectometer with the particular utility of measuring fairly rapid (transient) changes in the specular reflectance of a sample which is continuously exposed to a perturbing environment is described. A fixed radiation source, a fixed detector, a uniformly rotating sample wheel, and a uniformly rotating optical wheel protect against misalignment problems. The reflectometer operates by comparing the measurings of a reflected signal with that of a reference signal made within fractions of a second of one another. Reflectance is measured in the infrared, visible, and vacuum ultraviolet regions.

Zwiener, J. M.↗
NASA NTRS2024

The Scientific Value of Collecting Samples From the Jezero Crater Rim

The Mars 2020 mission has been conducting ground-based investigation of the geology, habitability, and biosignature preservation potential and collecting samples for return to Earth in Jezero crater, Mars for nearly 3 years. Analysis of these samples will address outstanding questions in Mars science including potential habitability and how and why the climate the interior of the planet evolved through time. As of December 2023, samples of 4 igneous rocks of the Jezero crater floor and 9 sedimentary rocks of the Jezero fan and inner margin, remain on the rover. 15 tubes remain to be filled to enhance the diversity of the cache and broaden the scope of the science questions that can be addressed with returned sample studies. The next step in the mission is to explore the Jezero crater rim. It will be imperative to investigate and sample the diversity of crater rim rocks because they represent materials from Mars’ most ancient crust older than those sampled in Jezero crater, a diversity of geologic processes, and potential ancient habitable environments that have not yet been investigated or sampled. Ongoing mapping efforts are using orbiter data and long-distance images from Perseverance to identify and interpret the geologic context of the crater rim. Building on this effort and the broader geologic context for the crater rim put forward by previous studies, we identify diverse targets for in situ investigation and potential sampling by Mars 2020.

Mars sample return↗
DOE OSTI2024

Tracing back the birth environments of Type Ia supernova progenitor stars: a pilot study based on 44 early-type host galaxies

The environmental dependence of Type Ia supernova (SN Ia) luminosities is well established, and efforts are being made to find its origin. Previous studies typically use the currently observed status of the host galaxy. However, given the delay time between the birth of the progenitor star and the SN Ia explosion, the currently observed status may differ from the birth environment of the SN Ia progenitor star. In this paper, employing the chemical evolution and accurately determined stellar population properties of 44 early-type host galaxies, we, for the first time, estimate the SN Ia progenitor star birth environment, specifically [Fe/H] Birth and [α/Fe] Birth . We show that [α/Fe] Birth has a $30.4^{\text{+10.6}}_{-10.1}{{\ \rm per\ cent}}$ wider range than the currently observed [α/Fe] Current , while the range of [Fe/H] Birth is not statistically different ($17.9^{\text{+26.0}}_{-27.1}{{\ \rm per\ cent}}$) to that of [Fe/H] Current . The birth and current environments of [Fe/H] and [α/Fe] are sampled from different populations (p-values of the Kolmogorov–Smirnov test <0.01). We find that light-curve fit parameters are insensitive to [Fe/H] Birth (<0.9σ for the non-zero slope), while a linear trend is observed with Hubble residuals (HRs) at the 2.4σ significance level. With [α/Fe] Birth , no linear trends (<1.1σ) are observed. Interestingly, we find that [α/Fe] Birth clearly splits the SN Ia sample into two groups: SN Ia exploded in [α/Fe] Birth -rich or [α/Fe ]Birth -poor environments. SNe Ia exploded in different [α/Fe] Birth groups have different weighted-means of light-curve shape parameters: 0.81 ± 0.33 (2.5σ). They are thought to be drawn from different populations (p-value = 0.01). Regarding SN Ia colour and HRs, there is no difference (<1.0σ) in the weighted-means and distribution (p-value > 0.27) of each [α/Fe] Birth group.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Identification and properties of isolated field elliptical galaxies from CFHTLS-W1

We present a catalogue of isolated field elliptical (IfE) galaxies drawn from the W1 field of the Canada-France-Hawaii Telescope Legacy Survey (CFHTLS). 228 IfEs were identified from a flux-limited (r < 21.8) galaxy catalogue which corresponds to a density of 3 IfE/sq.deg. For comparison we consider a sample of elliptical galaxies living in dense environments, based on identification of the brightest cluster galaxies (BGCs) in the same survey. Using the same dataset for the comparison sample ensures a uniform selection, including in the redshift range as IfEs (i.e. 0.1 < z <0.9). A comparison of elliptical galaxies in different environments reveals that IfEs and BCGs have similar behaviours in their colours, star formation activities, and scaling relations of mass–size and size–luminosity. IfEs and BCGs have similar slopes in the scaling relations with respect to cluster ellipticals within the $ -24 \leq M_{r} \leq -22 $ magnitude and $10.2 < \textrm{log}(M_{*}/ \textrm M_\odot)\leq12.0 $ mass ranges. Three IfEs identified in this study can be associated with fossil groups found in the same survey area which gives clues for future studies.

79 ASTRONOMY AND ASTROPHYSICS↗