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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Statistical mechanics of negative temperature states

The dynamics of two-dimensional interacting line vortices is identical to that of the two-dimensional electrostatic guiding center plasma. Both are Hamiltonian systems and are therefore susceptible to statistical mechanical treatments. The predictions of the microcanonical ensemble are explored for this system. Interest focuses primarily on the regime of total positive interaction energy, which should be above the Onsager negative temperature threshold. Calculations of the probability distribution for a component by means of the central limit theorem are carried out in the manner of Khinchin. The probability distribution of a component reduced to the usual Gibbs distribution in the regime of positive temperatures, and is still explicitly calculable for negative temperatures. The negative temperature states are neither quiescent nor spatially uniform. Expressions for the temperature are explicitly provided in terms of the total particle energy and particle number. A BBGKY hierarchy can be derived for both temperature regimes. Numerical simulations involving solutions of the equations of motion of 4008 particles are presented.

Montgomery, D. C.↗
NASA NTRS1980

The Pioneer Venus Orbiter plasma analyzer experiment

The plasma analyzer experiment on the Pioneer Venus Orbiter was designed to determine the basic characteristics of the plasma environment of Venus and the nature of the solar wind interaction at Venus. The plasma analyzer experiment is an electrostatic energy-per-unit charge (E/Q) spectrometer which measures ions and electrons. There is a curved plate electrostatic analyzer system with multiple collectors. The experiment obtains the three dimensional plasma distribution function. Some of the scientific objectives of the instrument are briefly discussed, the general characteristics of the experiment are summarized, and some of the analyses based on the data are presented.

Intriligator, D. S.↗
NASA NTRS1990

Properties of large scale plasma flow during the early stage of the plasmaspheric refilling

The objective is to better characterize the macroscopic properties of the interhemisphere plasma flow by solving a more complete set of hydrodynamic equations than that solved previously. Specifically, the ion continuity, momentum and energy equations were solved for the plasma flow along the closed magnetic field lines. During the initial stage of the supersonic outflow in the equatorial region, the ions cool substantially. Using the hydrodynamic model for the large-scale plasma flow, the dynamics of shocks was examined which form in the geomagnetic flux tubes during the early stages of refilling. These shocks are more like those forming in neutral gases than the electrostatic shocks driven by microinstabilities involving ion-ion interaction. Therefore, the shocks seen in the hydrodynamic model are termed as hydrodynamic shocks. Such shocks are generally unsteady and therefore the usual shock jump conditions given by Rankine-Hugoniot relations are not strictly applicable to them. The density, flow velocity and temperature structures associated with the shocks are examined for both asymmetrical and symmetrical flows. In the asymmetrical flow the outflow from one of two conjugate ionospheres is dominant. On the other hand, in the symmetrical case outflows from the two ionospheric sources are identical. Both cases are treated by a two-stream model. In the late type of flow, the early-time refilling shows a relaxation type of oscillation, which is driven by the large-scale interactions between the two identical streams. After this early stage, the resulting temperature structure shows some interesting features. In the equatorial region the streams are isothermal, but in the off-equatorial regions the streams have quite different temperatures, and also densities and flow velocities. The dense and slow stream is found to be warmer than the low-density fast stream. In the late stage of refilling, the temperature is found to steadily increase from the conjugate ionospheres towards the equator; the equatorial temperature is found to be as high as about 8000 K compared to the ionospheric temperature of 3600 K.

Singh, Nagendra↗
NASA NTRS2005

A Dynamic Fountain Model for Lunar Dust

During the Apollo era of exploration it was discovered that sunlight was scattered at the terminators giving rise to horizon glow and streamers above the lunar surface. This was observed from the dark side of the Moon during sunset and sunrise by both surface landers and astronauts in orbit. These observations were quite unexpected, as the Moon was thought to be a pristine environment with a negligible atmosphere or exosphere. Subsequent investigations have shown that the sunlight was most likely scattered by electrostatically charged dust grains originating from the surface. It has since been demonstrated that this dust population could have serious implications for astronomical observations from the lunar surface. The lunar surface is electrostatically charged by the Moon s large-scale interaction with the local plasma environment and the photoemission of electrons due to solar ultra-violet (UV) light and X-rays. The like-charged surface and dust grains then act to repel each other, such that under certain conditions the dust grains are lifted above the surface. We present a dynamic fountain model which can explain how sub-micron dust is able to reach altitudes of up to approximately 100 km above the lunar surface. Previous static dust levitation models are most applicable to the heavier micron-sized grains in close proximity proximity to the surface, but they cannot explain the presence of extremely light grains at high altitudes. If we relax the static constraint applied to previous models, and instead assume that the grains are in constant motion (under the action of dynamic forces), a new picture emerges for the behavior of sub-micron lunar dust.

Stubbs, T. J.↗
DOE OSTI2019

Controlling the stability of Pickering emulsions by pH-responsive nanoparticles

Electrostatic dissipative particle dynamics simulations were conducted to model the interactions between emulsion droplets stabilized by pH-sensitive polyelectrolyte-grafted nanoparticles. Using a steered molecular dynamics approach, a mechanistic study of forced coalescence was performed to probe the resistance between two particle-covered droplets. The degree of ionization of the grafted polyelectrolytes was adjusted to capture the pH responsiveness. The maximal resistance forces were measured to quantitatively discriminate the efficacy of particles in stabilizing emulsions at different degrees of ionization. Through analyzing droplet dynamics, resistance force variation, and electric field, we discovered that the resistance is attributed to direct electrostatic repulsion, the image charge effect near the water–oil interface, and steric hindrance among extended polymers. When the particle density on the droplet surface is relatively low, the increasing resistance forces at higher degrees of ionization can effectively prevent droplet coalescence. Oppositely, the ionization compromises emulsion stability when the particle surface coverage is high. Substantial desorption of particles from the interface was triggered as the degree of ionization increases. Finally, this in turn reduces resistance force and facilitates coalescence. Moreover, the nanoparticles prevent coalescence at high surface coverages by forming dense layers at individual interfaces, while the particle bridges straddling two interfaces were found at low surface coverages, which can also keep the droplets apart.

42 ENGINEERING↗
DOE OSTI2019

Experimental and Theoretical Investigation of Optical Spectra of Methylene Green in Solutions

The hybrid multilevel approach based on molecular dynamics, quantum mechanics, and statistical theory has been applied to profiles of electronic absorption bands of a number of thiazine dyes (phenothiazine, methylene blue, and methylene green), whose photochemical and biological properties depend on the external medium. The effect of single fragments of the methylene green (MG) molecule on its spectral-luminescent properties is studied. The most preferred geometry for the MG molecule is identified, and its relations with the spectral properties and the solvent nature are established. The energies of the electron states are calculated, and their nature is revealed. The electrostatic potential is analyzed, and the places of the most probable interaction of the molecule with the medium are found. Conclusions on the mechanism of forming the MG absorption spectrum are made based on the observations and calculations performed within the framework of the present work. It is established that the formation of the N–H bonds leads to the formation of an inactive lower excited singlet state and delocalization of the electron charge upon excitation. The position of the maximum of the long-wavelength absorption band of the MG correlates with the donor number of solvents in the series acetonitrile < water < ethanol < isopropanol < dimethyl sulfoxide. The position of the MG electron transition in the region of 630 nm is determined by the interaction of nitrogen and sulfur atoms of the central ring rather than by the increased number of substituents in the structure of the molecule.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1976

Magnetospheric dynamics and wave-particle interactions

It has been demonstrated that two general classes of wave-particle interactions are of great importance for magnetospheric dynamics. Electromagnetic and electrostatic plasma instabilities give rise to relatively narrow-banded spontaneous emissions (e.g., ELF hiss, chorus, three-halves noise, ion cyclotron and ion-plasma-frequency turbulence) that can scatter trapped particles into the loss cone, leading to modified pitch-angle distributions, stable trapping limits, diffuse aurora, proton precipitation events, etc. The current-driven plasma instabilities give rise to impulsive ion acoustic or Buneman mode turbulence that provides very effective energy transfer (via the anomalous conductivity mechanism) at the bow shock and in regions where strong field-aligned currents are observed. We review these interactions and identify significant open questions that must be investigated during the IMS.

Scarf, F. L.↗
NASA NTRS1979

Electrostatic protection of the Solar Power Satellite and rectenna

Several features of the interactions of the solar power satellite (SPS) with its space environment were examined theoretically. The voltages produced at various surfaces due to space plasmas and the plasma leakage currents through the kapton and sapphire solar cell blankets were calculated. At geosynchronous orbit, this parasitic power loss is only 0.7%, and is easily compensated by oversizing. At low-Earth orbit, the power loss is potentially much larger (3%), and anomalous arcing is expected for the EOTV high voltage negative surfaces. Preliminary results of a three dimensional self-consistent plasma and electric field computer program are presented, confirming the validity of the predictions made from the one dimensional models. Magnetic shielding of the satellite, to reduce the power drain and to protect the solar cells from energetic electron and plasma ion bombardment is considered. It is concluded that minor modifications can allow the SPS to operate safely and efficiently in its space environment. The SPS design employed in this study is the 1978 MSFC baseline design utilizing GaAs solar cells at CR-2 and an aluminum structure.

Freeman, J. W.↗
DOE OSTI2020

Visualizing biomolecular electrostatics in virtual reality with UnityMol-APBS

The APBS software was developed to solve the equations of continuum electrostatics for large biomolecular assemblages. APBS has enjoyed widespread adoption throughout the biomedical community and is used in numerous applications involving biomolecular structures. However, visualization of complex biomolecular electrostatic properties can be challenging for two-dimensional graphics systems. Therefore, advanced visualization and manipulation capabilities have been incorporated. In particular, APBS tools have been integrated with the UnityMolX virtual reality platform to provide an immersive experience for preparing biomolecular systems for calculations as well as visualizing and comparing calculated results.

electrostatics, molecular visualization, solvation↗
DOE OSTI2019

On the Contribution of the Long-Range Scattering Potential in the Process of Multiphoton Above-Threshold Ionization of Atoms in the Laser Field

Using the quantum mechanical analysis of stimulated bremsstrahlung of an electron on an electrostatic potential in the field of a strong electromagnetic wave in the generalized eikonal approximation, the simplified formula for the probability of multiphoton above-threshold ionization of a hydrogen-like atom in the laser field is obtained, taking into account the interaction of the photoelectron with the long-range Coulomb field of the residual ion.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

Ultra-sensitive radon assay using an electrostatic chamber in a recirculating system

Rare event searches such as neutrinoless double beta decay and Weakly Interacting Massive Particle detection require ultra-low background detectors. Radon contamination is a significant challenge for these experiments, which employ highly sensitive radon assay techniques to identify and select low-emission materials. This work presents the development of ultra-sensitive electrostatic chamber (ESC) instruments designed to measure radon emanation in a recirculating gas loop, for future lower background experiments. Unlike traditional methods that separate emanation and detection steps, this system allows continuous radon transport and detection. This is made possible with a custom-built recirculation pump. A Python-based analysis framework, PyDAn, was developed to process and fit time-dependent radon decay data. Radon emanation rates are given for various materials measured with this instrument. A radon source of known activity provides an absolute calibration, enabling statistically-limited minimal detectable activities of 20 µBq. These devices are powerful tools for screening materials in the development of low-background particle physics experiments.

47 OTHER INSTRUMENTATION↗
DOE OSTI2025

Ultra-sensitive radon assay using an electrostatic chamber in a recirculating system

Rare event searches such as neutrinoless double beta decay and Weakly Interacting Massive Particle detection require ultra-low background detectors. Radon contamination is a significant challenge for these experiments, which employ highly sensitive radon assay techniques to identify and select low-emission materials. This work presents the development of ultra-sensitive electrostatic chamber (ESC) instruments designed to measure radon emanation in a recirculating gas loop, for future lower background experiments. Unlike traditional methods that separate emanation and detection steps, this system allows continuous radon transport and detection. This is made possible with a custom-built recirculation pump. A Python-based analysis framework, PyDAn, was developed to process and fit time-dependent radon decay data. Radon emanation rates are given for various materials measured with this instrument. A radon source of known activity provides an absolute calibration, enabling statistically-limited minimal detectable activities of 20 uBq. These devices are powerful tools for screening materials in the development of low-background particle physics experiments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRSDate not supplied

As Seen by Parker Solar Probe: In-Situ Signatures of Wave-Particle Interactions Driven by Solar Ejecta

Parker Solar Probe (PSP) is sampling regions of the inner heliosphere never seen before to address where and why energy flows between the Sun and earth. With the onset of solar maximum, recent encounters have witnessed the increase in solar activity. We present in-situ signatures of coronal mass ejections and other smaller transients of coronal origin. Using simultaneous measurements from the SWEAP and FIELDS instrument suite, both ion and electron-scale dynamics are investigated in coincidence with both lower frequency electromagnetic and higher frequency electrostatic waves. We present an overview of these wave-particle interaction observations and hypothesize on their role in plasma energization and subsequent solar wind heating.

J. L. Verniero↗
NASA NTRS1988

Wave-particle interactions in the magnetosphere of Uranus

The Voyager 2 encounter of Uranus has provided observations of plasma waves in and near the magnetosphere. These data, while the first from Uranus, will also be the only direct information on wave-particle interactions at this planet for many years to come. The observations include electrostatic waves upstream of the bow shock, turbulence in the shock, Bernstein emissions and whistler mode waves in the magnetosphere, broadband electrostatic noise in the magnetotail, and a number of the other types of plasma waves which have yet to be clearly identified. Each of these types of waves exist in a plasma environment which both supports the growth of the waves and is modified by interactions with the waves. Wave-particle interactions provide the channels through which the waves can accelerate, scatter, or thermalize the plasmas. The most spectacular example in the case of Uranus is the extremely intense whistler mode activity in the inner magnetosphere which is the source of strong pitch angle diffusion. The resulting electron precipitation is sufficient to produce the auroral emissions observed by Voyager. The strong diffusion, however, presents the problem of supplying electrons in the range of 5 to 40 keV in order to support the losses to the atmosphere.

Kurth, W. S.↗
NASA NTRS1991

Wave-particle interactions in the magnetosphere of Uranus

The Voyager 2 encounter of Uranus has provided observations of plasma waves in and near the magnetosphere. These data, while the first from Uranus, will also be the only direct information on wave-particle interactions at this planet for many years to come. The observations include electrostatic waves upstream of the bow shock, turbulence in the shock Bernstein emissions and whistler mode waves in the magnetosphere, broadband electrostatic noise in the magnetotail, and a number of the other types of plasma waves which have yet to be clearly identified. Each of these types of waves exist in a plasma environment which both supports the growth of the waves and is modified by interactions with the waves. Wave-particle interactions provide the channels through which the waves can accelerate, scatter, or thermalize the plasmas. The most spectacular example in the case of Uranus is the extremely intense whistler mode activity in the inner magnetosphere which is the source of strong pitch angle diffusion. The resulting electron precipitation is sufficient to produce the auroral emissions observed by Voyager. The strong diffusion, however, presents the problem of supplying electrons in the range of 5 to 40 keV in order to support the losses to the atmosphere.

Kurth, W. S.↗
DOE OSTI2020

Assembly of Building Blocks by Double-End-Anchored Polymers in the Dilute Regime Mediated by Hydrophobic Interactions at Controlled Distances

Hierarchical assembly of building blocks via competing, orthogonal interactions is a hallmark of many of nature’s composite materials that do not require highly specific ligand-receptor interactions. To mimic this assembly mechanism requires the development of building blocks capable of tunable interactions. In the present work, we explored the interplay between repulsive (steric and electrostatic) and attractive hydrophobic forces. The designed building blocks allow hydrophobic forces to effectively act at controlled, large distances, to create and tune the assembly of membrane-based building blocks under dilute conditions and affect their interactions with cellular membranes via physical cross-bridges. Specifically, we employed double-end-anchored poly(ethylene glycol)s (DEA-PEGs)—hydrophilic PEG tethers with hydrophobic tails on both ends. Using differential-interference-contrast optical microscopy, synchrotron small angle X-ray scattering (SAXS), and cryogenic electron microscopy, we investigated the ability of DEA-PEGs to mediate assembly in the dilute regime on multiple length scales and on practical time scales. The PEG length, anchor hydrophobicity, and molar fraction of DEA-PEG molecules within a membrane strongly affect the assembly properties. Additional tuning of the intermembrane interactions can be achieved by adding repulsive interactions via PEG-lipids (steric) or cationic lipids to the DEA-PEG-mediated attractions. Further, while the optical and electron microscope imaging methods provided qualitative evidence of the ability of DEA-PEGs to assemble liposomes, the SAXS measurements and quantitative line-shape analysis in dilute preparations demonstrated that the ensemble average of loosely organized liposomal assemblies maintains DEA-PEG concentration-dependent tethering on defined nanometer length scales. For cationic liposome–DNA nanoparticles (CL–DNA NPs), aggregation induced by DEA-PEGs decreased internalization of NPs by cells, but tuning the DEA-PEG-induced attractions by adding repulsive steric interactions via PEG-lipids limited aggregation and increased NP uptake. However, confocal microscopy imaging together with colocalization studies with Rab11 and LysoTracker as markers of intracellular pathways showed that modifying CL–DNA NPs with DEA-PEGs alters their interactions with the plasma and endosomal membranes.

- x-ray scattering↗
DOE OSTI2026

Atomic-Scale Imaging Reveals Polar-π Interactions in Two-Dimensional Molecular Superlattices

Controlling coassembly of synthetic oligomers into binary superlattices at the atomic level is challenging. Here, we report a strategy for programming polar-π interactions in oligomeric peptoids, a class of sequence-defined peptidomimetics, facilitating the formation of homogeneous two-dimensional (2D) superlattices. N-2-phenylethyl and N-(2-perfluorophenyl)ethyl side chains, similar in size, but with contrasting electrostatic characteristics, were introduced at defined sequence positions to generate favorable dipolar aromatic interactions. The resulting nanosheets exhibit different crystal motifs depending on the side chain interactions: systems containing only one type of aromatic side chain form a parallel V-shaped motif driven by π-π interactions, whereas a combination of both types of aromatic side chains, either within one backbone or through the coassembly of two distinct peptoids, adopt an antiparallel V-shaped superlattice with higher thermal stability, driven by polar-π interactions. Cryogenic transmission electron microscopy directly resolved the packing arrangement of perfluorophenyl and phenyl rings in individual nanosheet superlattices, confirming that intermolecular polar-π interaction dominates the superlattice motifs and increases lattice stability. Molecular dynamics simulations and density functional theory calculations further substantiate the energetic favorability of polar-π interactions over π-π interactions, rationalizing the formation of homogeneous superlattices with enhanced thermal stability. Our discoveries establish a design principle for binary coassembly using sequence-defined oligomers, which enables control over unit cell geometry, lattice stability, and molecular registration through aromatic side chain polarization and sequence control. This ability to program atomic-scale binary superlattices opens new avenues for designing functional 2D soft materials.

Lee, Yen Jea [Lawrence Berkeley National Laborator↗
DOE OSTI2025

Steric Modulation of Protein‐Mediated Nanoparticle Assembly: Controlling Cluster Size, Polydispersity, and FRET Responses by Rebalancing Short‐ and Long‐Range Interactions

Understanding and manipulating protein-nanoparticle interactions is of broad interest to fields ranging from nanomedicine to the biological fabrication of functional hierarchical materials. This study investigates how steric forces introduced by a pegylated derivative of superfolder green fluorescent protein (sfGFP) that is monofunctional for silica binding modulate the delicate interplay of long-range (electrostatic and van der Waals) and short-range (protein-mediated) interactions in pH-responsive silica nanoparticle (SiNP) assembly by bifunctional silica-binding sfGFP. Increasing the length of the PEG segment and pre-incubating SiNPs with increasing concentrations of pegylated proteins enables precise control over cluster size within the 800–1450 nm range with a sixfold decrease in polydispersity index to a remarkable 0.1 endpoint. Weakening short-range attractive interactions via mutagenesis extends this control to clusters in the 50–250 nm range and reveals that the Förster resonance energy transfer (FRET) efficiency of clusters scales linearly with cluster diameter below 230 nm but increases only by 15% as clusters grow to 1450 nm. Furthermore, these findings enable the development of a system that provides an optical readout to dynamic changes in solution conditions enacted by a combination of pH adjustment and ion charge screening.

77 NANOSCIENCE AND NANOTECHNOLOGY↗