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At least 73 records · Page 4

Investigation of Thermocapillary Convection of High Prandtl Number Fluid Under Microgravity

Thermocapillary convection in a liquid bridge, which is suspended between two coaxial disks under zero gravity, has been investigated numerically. The Navier-Stokes equations coupled with the energy conservation equation are solved on a staggered grid, and the level set approach is used to capture the free surface deformation of the liquid bridge. The velocity and temperature distributions inside the liquid bridge are analyzed. It is shown from this work that as the development of the thermocapillary convection, the center of the vortex inside the liquid bridge moves down and reaches an equilibrium position gradually. The temperature gradients in the regions near the upper center axis and the bottom cold corner are higher than those in the other regions.

Liang, Ruquan↗

Approaching the Radiative Efficiency Limit in Perovskite Solar Cells with Scalable Defect Passivation and Selective Contacts

This award aimed to enable perovskite solar cells to approach the radiative efficiency limit in scalable manufacturing environments by controlling recombination losses, especially surface recombination losses at electrodes and interfaces. The project combined organic molecular synthesis, perovskite film processing and characterization, and spectroscopic tool development for probing recombination centers. The project ultimately achieved record-low surface recombination velocity (SRV) in mixed cation methylammonium-free perovskite thin films, demonstrated photoluminescence as an effective process metrology tool to optimizing processing of device stacks, and showed that the aminopropyltrimethoxysilane (APTMS) is suitable for passivating the exposed perovskite interface in p-i-n stack devices. The project used combinations of phosphonic acids to modify the transparent conducting oxide and APTMS to passivate the perovskite/electron transport layer interface, thereby demonstrating reduction of SRVs in both partial and full device stacks. The project showed concomitant improvements in device performance, and demonstrated that APTMS passivation was compatible with large area coating of external stakeholder perovskite films using both scalable solution and vapor methods. Notably, the project also supplied surface passivating materials to a number of other US based and SETO-funded teams.

14 SOLAR ENERGY↗

Numerical simulation of fluid flow and heat transfer in a thin liquid film over a stationary and rotating disk and comparison with experimental data

In the first section, improvements in the theoretical model and computational procedure for the prediction of film height and heat-transfer coefficient of the free surface flow of a radially-spreading thin liquid film adjacent to a flat horizontal surface of finite extent are presented. Flows in the presence and absence of gravity are considered. Theoretical results are compared to available experimental data with good agreement. In the presence of gravity, a hydraulic jump is present, isolating the flow into two regimes: supercritical upstream from the jump and subcritical downstream of it. In this situation, the effects of surface tension are important near the outer edge of the disk where the fluid experiences a free fall. A region of flow separation is present just downstream of the jump. In the absence of gravity, no hydraulic jump or separated flow region is present. The variation of the heat-transfer coefficient for flows in the presence and absence of gravity are also presented. In the second section, the results of a numerical simulation of the flow field and associated heat transfer coefficients are presented for the free surface flow of a thin liquid film adjacent to a horizontal rotating disk. The computation was performed for different flow rates and rotational velocities using a 3-D boundary-fitted coordinate system. Since the geometry of the free surface is unknown and dependent on flow rate, rate of rotation, and other parameters, an iterative procedure had to be used to ascertain its location. The computed film height agreed well with existing experimental measurements. The flow is found to be dominated by inertia near the entrance and close to the free surface and dominated by centrifugal force at larger radii and adjacent to the disk. The rotation enhances the heat transfer coefficient by a significant amount.

Faghri, Amir↗

On the thermal stability of coronal loop plasma

The stability to thermal perturbation of static models of coronal loops is considered including the effects of cool, radiatively stable material at the loop base. The linear stability turns out to be sensitive only to the boundary conditions assumed on the velocity at the loop base. The question of the appropriate boundary conditions is discussed, and it is concluded that the free surface condition (the pressure perturbation vanishes), rather than the rigid wall (the velocity vanishes), is relevant to the solar case. The static models are found to be thermally unstable, with a growth time of the order of the coronal cooking time. The physical implications of these results for the solar corona and transition region are examined.

Antiochos, S. K.↗

Numerical simulation of fluid flow and heat transfer in a thin liquid film over a rotating disk

The results of a numerical simulation of the flow field and associated heat transfer coefficient are presented for the free surface flow of a thin liquid film adjacent to a horizontal rotating disk. The computation has been performed for different flow rates and rotational velocities using a three-dimensional boundary-fitted coordinate system. Since the geometry of the free surface is unknown and dependent on flow rate, rate of rotation, and other parameters, an interative procedure had to be used to ascertain its location. The computed film height agreed well with existing experimental measurements. The flow was dominated by inertia near the entrance and close to the free surface, and dominated by centrifugal force at larger radii and adjacent to the disk. The rotation enhanced the heat transfer coefficient by a significant amount.

Rahman, M. M.↗

Correlations of velocity and temperature fluctuations in the stagnation-point flow of circular cylinder in turbulent flow

Boundary layer flow and turbulence transport analyses to study the influence of the free-stream turbulence on the surface heat transfer rate and the skin friction around the stagnation point of a circular cylinder in a turbulent flow are presented. The analyses are formulated with the turbulent boundary layer equations, the Reynolds stress transport equations and the k - epsilon two-equation turbulence modeling. The analyses are used to calculate the time-averaged turbulence double correlations, the mean flow properties, the surface heat transfer rate and the skin friction with an isotropic turbulence in the freestream. The analytical results are described and compared with the existing experimental measurements. Depending on the free-stream turbulence properties, the turbulence kinetic energy can increase or decrease as the flow moves toward the surface. However, the turbulence kinetic energy induces large Reynolds normal stresses at the boundary layer edge. The Reynolds normal stresses change the boundary layer profiles of the time-averaged double correlations of the velocity and temperature fluctuations, the surface heat transfer rate and the skin friction. The free-stream turbulence dissipation rate can affect the stagnation-point heat transfer rate but the influence of the free-stream temperature fluctuation on the heat transfer rate is insignificant.

Wang, Chi R.↗

Verification and transfer of thermal pollution model. Volume 4: User's manual for three-dimensional rigid-lid model

The theory of a three dimensional (3-D) mathematical thermal discharge model and a related one dimensional (1-D) model are described. Model verification at two sites, a separate user's manual for each model are included. The 3-D model has two forms: free surface and rigid lid. The former allows a free air/water interface and is suited for significant surface wave heights compared to mean water depth, estuaries and coastal regions. The latter is suited for small surface wave heights compared to depth because surface elevation was removed as a parameter. These models allow computation of time dependent velocity and temperature fields for given initial conditions and time-varying boundary conditions. The free surface model also provides surface height variations with time.

Lee, S. S.↗

High Density Two-Component Glasses of Organic Semiconductors Prepared by Physical Vapor Deposition

Physical Vapor Deposition (PVD) is widely utilized for the production of organic semiconductor devices due to its ability to form thin layers with exceptional properties. Although the layers in the device usually consist of two or more components, there is limited understanding about the fundamental characteristics of such multi-component vapor-deposited glasses. Here, spectroscopic ellipsometry was employed to characterize the densities, thermal stabilities and optical properties of co-vapor deposited NPD and TPD glasses across the entire range of composition. We find that co-deposited NPD and TPD form high density glasses with enhanced thermal stability. The dependences of density and stability upon substrate temperature are correlated, and the birefringence of the co-deposited glasses is determined by the reduced substrate temperature of mixtures. Additionally, we observe that the transformation of a highly stable and dense two-component glass into its supercooled liquid initiates from the free surface and propagates into the bulk at constant velocity, like single component PVD glasses. As a result, all these features are consistent with the surface equilibration mechanism.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Gravity and geoid anomalies of the Philippine Sea: Evidence on the depth of compensation for the negative residual water depth anomaly

A negative free-air gravity anomaly which occurs in the central part of the Philippine Sea was examined to determine the distribution and nature of possible regional mass excesses or deficiencies. Geoid anomalies from GEOS-3 observation were positive. A negative residual geoid anomaly consistent with the area of negative free-air gravity anomalies were found. Theoretical gravity-topography and geoid-topography admittance functions indicated that high density mantle at about 60 km dept could account for the magnitudes of the gravity and residual geoid anomaly and the 1 km residual water depth anomaly in the Philippine Sea. The negative residual depth anomaly may be compensated for by excess density in the uppermost mantle, but the residual geoid and regional free-air gravity anomalies and a slow surface wave velocity structure might result from low-density warm upper mantle material lying beneath the zone of high-density uppermost mantle. From a horizontal disk approximation, the depth of the low-density warm mantle was estimated to be on the order of 200 km.

Bowin, C.↗

Suppression of Marangoni Convection in Float Zones

The basic purpose of this program is to demonstrate by means of an Earth-based 1-g experiment that the undesirable Marangoni (surface tension) convection can be suppressed or significantly reduced by means of gas jets directed tangentially to the free surface of the liquid in a float zone. These jets will establish the tangential shear stress field over the surface which must be adjusted to equal the counter-stress resultant of the Marangoni shear stress which causes the convection. For proposed materials processing in space (o-g), particularly of important, highly reactive semiconductor materials, e.g., silicon, microgravity will virtually eliminate the unwanted thermal-buoyancy convection in the liquid silicon, but will have no effect in reducing the Marangoni convection. Unless this can be sufficiently suppressed by other means, there may be no significant advantages to the proposed space processing of reactive semiconductors. Although some inert gas such as argon must be used for the corrosive liquid silicon, the Earth-based experiment uses air jets and various transparent oils, since the basic principle involved is the same. The first float zone is enclosed in a very small rectangular box with a quasi-planar free surface. Stable Marangoni convection has been achieved and velocities measured photographically. The air jet system with variable velocity and temperature is under construction. Three independent parameters must be optimized to attain maximum suppression: the gas velocity, angle of attack, and gas temperature.

Dressler, R. F.↗

Thermocapillary convection in floating zones under simulated reduced-gravity conditions

The present study demonstrated that calculated thermocapillary convection in a non-cylindrical floating zone can now be compared with measured one, by considering the lens effect of the floating zone. Flow visualization and computer simulation of thermocapillary convection in a silicone oil zone and a molten zone in an NaNO3 rod were conducted. The calculated results agree very well with the measured ones, including the free surface shapes, the solid/melt interface shapes and the velocity fields.

Tao, Y.↗

Assimilation of SeaWinds Scatterometer Data in the GEOS Data Assimilation System

The first SeaWinds scatterometer was launched in to space aboard the Quikscat satellite on June 19, 1999 at 7:15 p.m. PDT. Flying in a near polar orbit 800 km above the earth's surface, SeaWinds uses an advanced scatterometer design to measure surface wind velocity over 90 percent of the ice free oceans ever 24 hours. This first SeaWinds mission is designed to replace the NASA Scatterometer (NSCAT) which ceased providing wind velocity data when the ADEOS I satellite failed. A second SeaWinds is scheduled to be launched late in 2000 aboard ADEOS II. Previous scatterometer assimilation experiments conducted by the NASA Data Assimilation Office, using both ERS and NSCAT wind observations, have demonstrated considerable potential for this type of data to improve both atmospheric analyses and forecasts, however much of the smaller scale information content of the scatterometer data could not be taken into account in the early coarse resolution versions of the Goddard (GEOS) Data Assimilation System (DAS) or in operational data assimilation systems. In this paper, we will describe data assimilation experiments in which the new higher resolution versions of the GOES DAS are used to assimilate SeaWinds scatterometer winds. Following a brief discussion of the SeaWinds design and the methodology used to assimilate scatterometer data in the GOES DAS, the quality of the SeaWinds data and the impact of SeaWinds on GOES analyses and forecasts at different resolutions will be presented.

Atlas, Robert↗

Isolation and phase-space energization analysis of the instabilities in collisionless shocks

We analyse the generation of kinetic instabilities and their effect on the energization of ions in non-relativistic, oblique collisionless shocks using a 3D-3V (three spatial with three velocity components) simulation by dHybridR, a hybrid particle-in-cell code. At sufficiently high Mach number, quasi-perpendicular and oblique shocks can experience rippling of the shock surface caused by kinetic instabilities arising from free energy in the ion velocity distribution due to the combination of the incoming ion beam and the population of ions reflected at the shock front. To understand the role of the ripple on particle energization, we devise a new instability isolation method to identify the unstable modes underlying the ripple and interpret the results in terms of the governing kinetic instability. We generate velocity-space signatures using the field–particle correlation technique to look at energy transfer in phase space from the isolated instability driving the shock ripple, providing a viewpoint on the different dynamics of distinct populations of ions in phase space. Together, the field–particle correlation technique and our new instability isolation method provide a unique viewpoint on the different dynamics of distinct populations of ions in phase space and allow us to completely characterize the energetics of the collisionless shock under investigation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Passivated Interfaces and Surface Recombination Velocities in Halide Perovskites

Surfaces and charge-extracting contacts remain major sources of non-radiative recombination loss; limiting the performance of perovskite PV compared to theoretical limits. We investigate mixed-cation mixed-halide perovskites and demonstrate that, with chemical surface passivation, they can achieve >4 μs minority carrier lifetimes, and >20% external PL quantum yields (PLQY), and nearly single-exponential decay kinetics. This high PLQY observed corresponds to ~97% of the Shockley-Queisser theoretical quasi-fermi level splitting, a first for MA-free mixed-cation mixed-halide compositions. The high PLQY and long PL lifetimes allow us to measure average surface recombination velocities (SRV) <10cm/s, with a champion low of ~1cm/s (a conservative estimate). We show how such improvements in SRV should lead to an absolute improvement in PCE of >4% even with the best of contact alignments. We investigate different MA-free high bandgap compositions, including bandgaps relevant for tandem applications (1.7-1.8eV), and demonstrate performance improvements across all these compositions with our surface passivation strategy. Lastly, using a combination of surface characterization techniques, we show Lewis base interactions of the passivating agent with the perovskite surfaces.

passivation↗

Effects of a ground vortex on the aerodynamics of an airfoil

An experimental investigation was carried out to study the aerodynamics of an airfoil with a rectangular jet exiting from its lower surface at fifty percent of the chord. The airfoil was tested with and without the influence of a ground plane. Surface static pressures were measured on the airfoil at jet to free stream velocity ratios ranging from 0 to 9. From these pressures, the variation of C sub L with velocity ratio was easily determined. The measurements indicated significant positive and negative pressure regions on the lower surface of the airfoil ahead of and after the nozzle exit respectively. The presence of a ground plane enhanced these pressure regions at low velocity ratios, but at a particular ratio for each plane location, a recirculation zone or vortex formed ahead of the jet resulting in decreased pressures and a drop in C sub L.

Krothapalli, A.↗

Vapor condensation on liquid surface due to laminar jet-induced mixing: The effects of system parameters

The effects of system parameters on the interface condensation rate in a laminar jet induced mixing tank are numerically studied. The physical system consists of a partially filled cylindrical tank with a slightly subcooled jet discharged from the center of the tank bottom toward the liquid-vapor interface which is at a saturation temperature corresponding to the constant tank pressure. Liquid is also withdrawn from the outer part of the tank bottom to maintain the constant liquid level. The jet velocity is selected to be low enough such that the free surface is approximately flat. The effect of vapor superheat is assumed to be negligible. Therefore, the interface condensation rate can be determined from the resulting temperature field in the liquid region alone. The nondimensional form of the steady state conservation equations are solved by a finite difference method for various system parameters including liquid height to tank diameter ratio, tank to jet diameter ratio, liquid inflow to outflow area ratio, and a heat leak parameter which characterizes the uniform wall heat flux. Detailed analyses based on the numerical solutions are performed and simplified equations are suggested for the prediction of condensation rate.

Lin, Chin-Shun↗

Vapor condensation on liquid surface due to laminar jet-induced mixing - The effects of system parameters

The effects of system parameters on the interface condensation rate in a laminar jet induced mixing tank are numerically studied. The physical system consists of a partially filled cylindrical tank with a slightly subcooled jet discharged from the center of the tank bottom toward the liquid-vapor interface which is at a saturation temperature corresponding to the constant tank pressure. Liquid is also withdrawn from the outer part of the tank bottom to maintain the constant liquid level. The jet velocity is selected to be low enough such that the free surface is approximately flat. The effect of vapor superheat is assumed to be negligible. Therefore, the interface condensation rate can be determined from the resulting temperature field in the liquid region alone. The nondimensional form of the steady state conservation equations are solved by a finite difference method for various system parameters including liquid height to tank diameter ratio, tank to jet diameter ratio, liquid inflow to outflow area ratio, and a heat leak parameter which characterizes the uniform wall heat flux. Detailed analyses based on the numerical solutions are performed and simplified equations are suggested for the prediction of condensation rate.

Lin, Chin-Shun↗