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At least 73 records · Page 4

Data processing and calibration for tunable diode laser harmonic absorption spectrometers

Data processing and calibration methods are described for tunable diode laser absorption spectrometers which produce harmonic absorption spectra as raw data for measuring gas mixing ratios down to parts-per-trillion levels at a variety of pressures. The methods, which take advantage of modern computer speed, memory, and data storage capabilities, are applicable to the detection of weakly absorbing gases in quantitative industrial monitoring, in addition to aircraft and balloon atmospheric measurements for which they were designed. Algorithms for calibration and data analysis, including rejection of erroneous spectra, variation of effective integration time, spectral alignment prior to averaging, and plotting and archiving of results, have been tested on actual stratospheric laser spectra recorded by the Aircraft Laser Infrared Absorption Spectrometer (ALIAS) spectrometer in numerous flights of NASA's ER-2 aircraft.

May, Randy D.↗

Absolute Density Calibration Cell for Laser Induced Fluorescence Erosion Rate Measurements

Flight qualification of ion thrusters typically requires testing on the order of 10,000 hours. Extensive knowledge of wear mechanisms and rates is necessary to establish design confidence prior to long duration tests. Consequently, real-time erosion rate measurements offer the potential both to reduce development costs and to enhance knowledge of the dependency of component wear on operating conditions. Several previous studies have used laser-induced fluorescence (LIF) to measure real-time, in situ erosion rates of ion thruster accelerator grids. Those studies provided only relative measurements of the erosion rate. In the present investigation, a molybdenum tube was resistively heated such that the evaporation rate yielded densities within the tube on the order of those expected from accelerator grid erosion. This work examines the suitability of the density cell as an absolute calibration source for LIF measurements, and the intrinsic error was evaluated.

Domonkos, Matthew T.↗

Electric current heating calibration of a laser holographic nondestructive test system

Holographic NDT was used to measure small surface displacements controlled by electric heating by detecting the difference of the interference fringe patterns as viewed through the hologram on a real time basis. A perforated aluminum test plate, with the holes used to position thin metal foils, was used in the experiment. One of the foils was connected to an electric power source and small displacements of the foil were caused and controlled by Ohmic heating. An He-Ne laser was used to perform the holography.

Liu, H.-K.↗

Partial Least Squares and Neural Networks for Quantitative Calibration of Laser-induced Breakdown Spectroscopy (LIBs) of Geologic Samples

The ChemCam instrument [1] on the Mars Science Laboratory (MSL) rover will be used to obtain the chemical composition of surface targets within 7 m of the rover using Laser Induced Breakdown Spectroscopy (LIBS). ChemCam analyzes atomic emission spectra (240-800 nm) from a plasma created by a pulsed Nd:KGW 1067 nm laser. The LIBS spectra can be used in a semiquantitative way to rapidly classify targets (e.g., basalt, andesite, carbonate, sulfate, etc.) and in a quantitative way to estimate their major and minor element chemical compositions. Quantitative chemical analysis from LIBS spectra is complicated by a number of factors, including chemical matrix effects [2]. Recent work has shown promising results using multivariate techniques such as partial least squares (PLS) regression and artificial neural networks (ANN) to predict elemental abundances in samples [e.g. 2-6]. To develop, refine, and evaluate analysis schemes for LIBS spectra of geologic materials, we collected spectra of a diverse set of well-characterized natural geologic samples and are comparing the predictive abilities of PLS, cascade correlation ANN (CC-ANN) and multilayer perceptron ANN (MLP-ANN) analysis procedures.

Anderson, R. B.↗

Spectral and Radiometric Calibration Using Tunable Lasers

A tunable laser system includes a tunable laser, an adjustable laser cavity for producing one or more modes of laser light emitted from the tunable laser, a first optical parametric oscillator positioned in a light path of the adjustable laser cavity, and a controller operable to simultaneously control parameters of at least the tunable laser, the first optical parametric oscillator, and the adjustable laser cavity to produce a range of wavelengths emitted from the tunable laser system. A method of operating a tunable laser system includes using a controller to simultaneously control parameters of a tunable laser, an adjustable laser cavity for producing one or more modes of laser light emitted from the tunable laser, and a first optical parametric oscillator positioned in a light path of the adjustable laser cavity, to produce a range of wavelengths emitted from the tunable laser system.

McCorkel, Joel↗

Intermode calibration of diode-laser spectra using tandem etalons

The paper deals with an approach which can improve the accuracy of etalon calibration of tunable diode-laser (TDL) spectra in the IR and extend absolute calibration among several isolated modes. Two etalons placed in the laser beam produce a combined fringe pattern that, with the aid of a monochromator mode selector, can be used to establish the number of fringes between any two spectral points separated by a large frequency interval. This technique has been applied to several similar cases for calibration of isolated modes or verification of the identity of lines of known frequency.

Jennings, D. E.↗

Retrievals of Thick Cloud Optical Depth from the Geoscience Laser Altimeter System (GLAS) by Calibration of Solar Background Signal

Laser beams emitted from the Geoscience Laser Altimeter System (GLAS), as well as other space-borne laser instruments, can only penetrate clouds to a limit of a few optical depths. As a result, only optical depths of thinner clouds (< about 3 for GLAS) are retrieved from the reflected lidar signal. This paper presents a comprehensive study of possible retrievals of optical depth of thick clouds using solar background light and treating GLAS as a solar radiometer. To do so we first calibrate the reflected solar radiation received by the photon-counting detectors of GLAS' 532 nm channel, which is the primary channel for atmospheric products. The solar background radiation is regarded as a noise to be subtracted in the retrieval process of the lidar products. However, once calibrated, it becomes a signal that can be used in studying the properties of optically thick clouds. In this paper, three calibration methods are presented: (I) calibration with coincident airborne and GLAS observations; (2) calibration with coincident Geostationary Operational Environmental Satellite (GOES) and GLAS observations of deep convective clouds; (3) calibration from the first principles using optical depth of thin water clouds over ocean retrieved by GLAS active remote sensing. Results from the three methods agree well with each other. Cloud optical depth (COD) is retrieved from the calibrated solar background signal using a one-channel retrieval. Comparison with COD retrieved from GOES during GLAS overpasses shows that the average difference between the two retrievals is 24%. As an example, the COD values retrieved from GLAS solar background are illustrated for a marine stratocumulus cloud field that is too thick to be penetrated by the GLAS laser. Based on this study, optical depths for thick clouds will be provided as a supplementary product to the existing operational GLAS cloud products in future GLAS data releases.

Yang, Yuekui↗

Mitigation Strategies for the Impact of Low Energy Laser Pulses in CALIOP Calibration and Level 2 Retrievals

Since mid-2016, the frequency of low energy laser pulses emitted by the CALIPSO lidar has been slowly increasing due to pressure losses in the canister housing the laser. While originally confined primarily to the South Atlantic Anomaly (SAA) region, these low energy pulses now occur intermittently around the globe. Low energy pulses can cause calibration biases and degrade the science quality of level 2 retrievals. We describe a new low energy mitigation (LEM) algorithm that will be implemented incrementally in future versions of the CALIOP data processing to identify and reject affected profiles during calibration and feature detection. The LEM algorithm effectively eliminates low energy calibration biases, improves level 2 retrievals, and minimizes level 2 data loss.

Jason Tackett↗

Neptunium transition probabilities estimated through laser induced breakdown spectroscopy (LIBS) measurements

in tis report calibration free–laser induced breakdown spectroscopy (CF-LIBS) approaches are promising for the analysis of radioactive materials; however, a lack of reported fundamental properties for these materials is an obstacle to implementation. Spectra of laser induced plasmas containing Np and Sr, along with Saha–Boltzmann methods, were used to estimate the first reported transition probabilities (TPs) of Np. These TPs enabled the first attempt at CF-LIBS analysis of radioactive samples to predict Np/Sr ratios with a mean error of 3.86%. The presented methodology of TP estimation will be applied to the study of other actinides and allow broader applications of CF-15 LIBS in the nuclear field.

74 ATOMIC AND MOLECULAR PHYSICS↗

A calibration line list for 807-1167 cm -1 from high resolution Fourier spectroscopy of the 14NH3 nu sub 2 band

A calibration list of 295 lines observed over the 800 to 1170 cm to the -1 power region is presented. This list is intended for use as a calibration reference for calibrating diode laser spectra. The transition frequencies were calibrated against the well established laser frequencies of CO2. The estimated uncertainty in the corrected frequencies is + or - 1x.0001 cm to the -1 power.

Hillman, J. J.↗

Calibration of a tunable excimer laser using the optogalvanic effect

A device for the calibration of a tunable excimer laser is currently under development. The laser provides UV radiation at three principal wavelengths, 193, 248, and 308 nm and is tunable over a range of 1 nm at each of these wavelengths. The laser is used as a non-intrusive optical probe to excite electronic transitions, and thereby induce fluorescence, of the principle molecules or atoms of interest in supersonic flowfields, both reacting and nonreacting. The fluorescence resulting from the excitation is observed with an intensified camera. Over the range of tunability at the three wavelengths are a number of transitions that can be observed. The intensity of the fluorescence depends in part on the local temperature and density. The nature of this thermodynamic dependence is variable among transitions; thus, identification of the transition under observation is required. The specific transition excited corresponds directly to the wavelength of the radiation. The present technique used for transition identification consists of scanning the laser across the range of tunability and observing the fluorescence resulting from various molecular transitions.

Abbitt, John D.↗

Cryogenic radiometers and intensity-stabilized lasers for Eos radiometric calibrations

Liquid helium-cooled electrical substitution radiometers (ESRs) provide irradiance standards with demonstrated absolute accuracy at the 0.01 percent level, spectrally flat response between the UV and IR, and sensitivity down to 0.1 nW/sq cm. We describe an automated system developed for NASA - Goddard Space Flight Center, consisting of a cryogenic ESR illuminated by servocontrolled laser beams. This system is designed to provide calibration of single-element and array detectors over the spectral range between 257nm in the UV to 10.6 microns in the IR. We also describe a cryogenic ESR optimized for black body calibrations that has been installed at NIST, and another that is under construction for calibrations of the CERES scanners planned for Eos.

Foukal, P.↗

Fifteen Years of Millimeter Accuracy Lunar Laser Ranging with APOLLO: Data Reduction and Calibration

The Apache Point Lunar Laser-ranging Operation (APOLLO) has been collecting lunar range measurements for 15 yr at millimeter accuracy. The median nightly range uncertainty since 2006 is 1.7 mm. A recently added Absolute Calibration System (ACS), providing an independent assessment of APOLLO system accuracy and the capability to correct lunar range data, revealed a ∼0.4% (10 ps) systematic error in the calibration of one piece of hardware that has been present for the entire history of APOLLO. The application of ACS-based timing corrections suggests systematic errors are reduced to <1 mm, such that overall data accuracy and precision are both ∼1 mm. This paper describes the processing of APOLLO/ACS data that converts photon-by-photon range measurements into the aggregated normal points that are used for science analyses. Additionally, we present methodologies to estimate timing corrections for range data lacking contemporaneous ACS photons, including range data collected prior to installation of the ACS. We also provide access to the full 15 yr archive of APOLLO normal points (2006 April 6–2020 December 27).

LLR↗