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At least 73 records · Page 4

Assessing CLUBB PDF Closure Assumptions for a Continental Shallow-to-Deep Convective Transition Case Over Multiple Spatial Scales

Assumed-PDF (probability density function) higher-order turbulence closures (APHOCs) are now widely used for parameterizing boundary layer turbulence and shallow convection in Earth system models (ESMs). A better understanding of the resolution-dependent behavior of APHOCs is essential for improving the performance of next-generation ESMs with intended horizontal resolutions finer than 10 km. In this study, we evaluate the PDF family of Analytic double-Gaussian 1 implemented in Cloud Layers Unified By Binormals (CLUBB) over a range of spatial scales (Dx) from 2 to 100 km. A 120-km-wide large eddy simulation (LES) for a continental convection case during 2016 Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) field campaign serves as benchmark to evaluate the PDF closure using an off-line approach. We find during the shallow convection period, the CLUBB PDF closure tends to produce positive biases of cloud properties and liquid water flux near cloud base for all scales of analysis. It produces negative biases for these variables near cloud top that are more severe for Dx larger than 25 km. Results show that replacing the CLUBB-parameterized moisture and temperature skewnesses with LES-derived ones can fix most of the biases if clipping of input moments is allowed to prevent the occurrence of unrealizable solutions. Overall, the performance of the PDF closure is better for smaller Dx = 2–5 km than for larger Dx = 50–100 km; for a given grid spacing, it is better when the convective clouds become deeper in the late afternoon. Likely causes for the resolution dependence and implications for improving the PDF closure are discussed.

54 ENVIRONMENTAL SCIENCES↗

High-shade dryland agrivoltaic conditions enhanced carbon uptake and water-use efficiency in zucchini ( Cucurbita pepo )

Introduction: The increasing global demand for food and energy is intensifying land-use competition. Agrivoltaic systems are a multifunctional land-use approach that vertically integrates the production of agricultural crops and solar power on the same land area. Most food crops are adapted to full-sun conditions, and the physiological responses of these crops to the novel microclimate under solar panels remain poorly understood. We hypothesized that the microclimate beneath the high-density photovoltaic system would influence carbon uptake, water use, and yield outcomes of zucchini summer squash.Methods: We conducted a field experiment in a hot, semi-arid climate on zucchini (Cucurbita pepo). Plants were grown under an agrivoltaic system with a 75% ground cover ratio (GCR) and in a full-sun control plot, each with two irrigation regimes (100 and 50%). We measured leaf-level photosynthesis, microclimate variables, and fruit yield at plant maturity and throughout the growing season.Results: The agrivoltaic array reduced photosynthetically active radiation (PAR) by ~79%, resulting in a cooler (−1.1 °C), more humid environment with higher soil moisture. These microclimatic conditions enhanced midday photosynthesis and daily cumulative carbon uptake. However, fruit yield was consistently lower under the panels, indicating a shift in carbon allocation toward vegetative growth. Photosynthesis was primarily driven by PAR across treatments, while soil moisture significantly influenced photosynthesis only in the control plots, suggesting water limitation was alleviated under the panels.Discussion: These findings highlight a trade-off between improved physiological performance and reduced yield under high-density agrivoltaics. While the system buffered heat and drought stress and improved overall plant function, excessive shade reduced reproductive output. Optimizing panel density or selecting crops cultivated for non-fruit yields will be essential for balancing food production and energy generation in dryland agrivoltaic settings.

14 SOLAR ENERGY↗

Panta Rhei benchmark dataset: socio-hydrological data of paired events of floods and droughts

As the adverse impacts of hydrological extremes increase in many regions of the world, a better understanding of the drivers of changes in risk and impacts is essential for effective flood and drought risk management and climate adaptation. However, there is currently a lack of comprehensive, empirical data about the processes, interactions, and feedbacks in complex human–water systems leading to flood and drought impacts. Here we present a benchmark dataset containing socio-hydrological data of paired events, i.e. two floods or two droughts that occurred in the same area. The 45 paired events occurred in 42 different study areas and cover a wide range of socio-economic and hydro-climatic conditions. The dataset is unique in covering both floods and droughts, in the number of cases assessed and in the quantity of socio-hydrological data. The benchmark dataset comprises (1) detailed review-style reports about the events and key processes between the two events of a pair; (2) the key data table containing variables that assess the indicators which characterize management shortcomings, hazard, exposure, vulnerability, and impacts of all events; and (3) a table of the indicators of change that indicate the differences between the first and second event of a pair. The advantages of the dataset are that it enables comparative analyses across all the paired events based on the indicators of change and allows for detailed context- and location-specific assessments based on the extensive data and reports of the individual study areas. The dataset can be used by the scientific community for exploratory data analyses, e.g. focused on causal links between risk management; changes in hazard, exposure and vulnerability; and flood or drought impacts. The data can also be used for the development, calibration, and validation of socio-hydrological models. The dataset is available to the public through the GFZ Data Services (Kreibich et al., 2023, https://doi.org/10.5880/GFZ.4.4.2023.001).

54 ENVIRONMENTAL SCIENCES↗

Unified 0.25-degree gridded infrastructure-critical extreme weather for the United States from 1979 to 2100

Extreme weather events can severely disrupt critical infrastructure, triggering cascading effects on power, transportation, and essential services. However, standard weather and climate datasets often lack specialized variables necessary for hazard assessments. We present a unified dataset of infrastructure-critical weather and climate variables across the United States at 0.25° resolution, covering daily or sub-daily intervals from 1979 to 2100. The dataset includes temperature, dew point, wind gusts, precipitation partitioned by rain, snow, and freezing rain or ice pellets, lightning, and wildfire metrics. Historical conditions (1979-2023) are synthesized from observations and reanalysis products, while future projections are derived from 14 CMIP6 global climate models (historical, SSP245, and SSP585 experiments). Physically based and data-driven methods are used to estimate variables not directly provided by existing models. By integrating these variables into a single unified dataset, we enable consistent, high-resolution assessments of weather-related infrastructure risks across past and future periods, supporting wide-ranging applications in energy, transportation, water resources, emergency management, and beyond.

Climate and Earth system modelling↗

The Fall and Rise of the Global Climate Model

Abstract Global models are an essential tool for climate projections, but conventional coarse‐resolution atmospheric general circulation models suffer from errors both in their parameterized cloud physics and in their representation of climatically important circulation features. A notable recent study by Terai et al. (2020, https://doi.org/10.1029/2020ms002274) documents a global model capable of reproducing the regime‐based effect of aerosols on cloud liquid water path expected from observational evidence. This may represent a significant advance in cloud process fidelity in global models. Such models can be expected to give a better estimate of the effective radiative forcing of the climate. If this advance in cloud process representation can be matched by advances in the representation of circulation features such as monsoons, then such models may also be able to navigate the complex tangle between spatially heterogeneous aerosol–cloud interactions and regional circulation patterns. This tight link between aerosol and circulation results in anthropogenic perturbations of climate variables of societal importance, such as regional rainfall distributions. Upcoming global models with km‐scale resolution may improve the regional circulation and be able to take advantage of the Terai et al. (2020, https://doi.org/10.1029/2020ms002274) improvement in cloud physics. If so, an era of significantly improved regional climate projection capabilities may soon dawn. If not, then the improvement in cloud physics might spur intensified efforts on problems in model dynamics. Either way, based on the rapid changes in aerosol emissions in the near future, learning to make reliable projections based on biased models is a skill that will not go out of style.

54 ENVIRONMENTAL SCIENCES↗

Dryness controls temperature-optimized gross primary productivity across vegetation types

Temperature response of gross primary productivity (GPP) is a well-known property of ecosystem, but GPP at the optimum temperature (GPP_T opt ) has not been fully discussed. Our understanding of how GPP_T opt responds to warming and water availability is highly limited. Here, in this study, we analyzed data at 326 globally distributed eddy covariance sites (79°N-37°S), to identify controlling factors of GPP_T opt . Although GPP_T opt was significantly influenced by soil moisture, global solar radiation, mean annual temperature, and vapor pressure deficit in a non-linear pattern (R 2 = 0.47), the direction and magnitude of these climate variables’ effects on GPP_T opt depend on the dryness index (DI), a ratio of potential evapotranspiration to precipitation. The spatial pattern showed that soil moisture did not affect GPP_T opt across energy-limited sites with DI < 1 while dominated GPP_T opt across water-limited sites with DI >1. The temporal pattern showed that GPP_T opt was lowered by warming or low precipitation in water-limited sites while energy-limited sites tended to maintain a stable GPP_T opt regardless of changes in air temperature. Vegetation types in humid climates tended to have higher GPP_T opt and were more likely to benefit from a warmer climate since it was not restricted by water conditions. This study highlights that the response of GPP_T opt to global warming depends on the dryness conditions, which explains the nonlinear control of water and temperature over GPP_T opt . Our finding is essential to realistic prediction of terrestrial carbon uptake under future climate and vegetation conditions.

54 ENVIRONMENTAL SCIENCES↗

Impacts of Topography‐Driven Water Redistribution on Terrestrial Water Storage Change in California Through Ecosystem Responses

Abstract Lateral subsurface flow plays an essential role in sustaining the terrestrial ecosystem, but it is not explicitly represented in most Earth System Models. In this study, we implemented an explicit lateral saturated flow model into the E3SM land model (ELM). The model explicitly describes lateral flow in the saturated zone by representing, for each model grid, an idealized hillslope consisting of five hydrologically connected soil columns. We conducted three model experiments driven by 0.125° atmospheric forcing data during 1980–2015 over California using models of the default ELM, a modified version of ELM to enhance infiltration, and the model with the lateral saturated flow model. The simulated runoff, evapotranspiration, and terrestrial water storage anomaly (TWSA) from the three simulations were evaluated against available observations, and the model explicitly representing lateral flow performs best. The new model produces greater gridcell‐averaged evapotranspiration especially over the mountainous regions with moderate relief and seasonally dry climates. Most importantly, it improves the modeled seasonal variations, interannual variabilities, and the recent decadal decline of TWSA. Many of these improvements can be attributed to the enhanced ecosystem resilience to droughts as demonstrated by transpiration increases caused by lateral flow. Model sensitivity experiments suggest that subsurface runoff is most sensitive to the ratio between horizontal and vertical saturated hydraulic conductivity, followed by hillslope planforms (convergent, divergent, and uniform), number of columns, and lower boundary conditions. Future work should effectively characterize hillslopes in global models and explore the long‐term influences of lateral water movement on modeled biogeochemical cycle.

54 ENVIRONMENTAL SCIENCES↗

Light Water Reactor Sustainability Program: Use of Time Distributions to Predict Operator Procedure Performance in Dynamic Human Reliability Analysis

The Human Unimodel for Nuclear Technology to Enhance Reliability (HUNTER) framework affords software capable of conducting human reliability analysis (HRA) using a dynamic approach built around operating procedures (OPs) from nuclear power plants (NPPs). Previous HUNTER reports document the development of this software tool, the coupling of HUNTER to the simulator code, the collection of operator performance data by using simulators to calibrate HUNTER models, and linking HUNTER to probabilistic risk assessment (PRA) software. The present report largely addresses two topics. The first is a new function in HUNTER called the HUNTER Procedure Performance Predictor (P3). HUNTER P3 uses HUNTER’s built in Monte Carlo tools featuring human performance variability to identify potential error traps in procedures. The second topic is time distribution analysis to generate time inputs for dynamic HRA. The current analysis was performed to investigate time distributions for task primitives, which are the minimum task unit of analysis used in dynamic HRA modeling. Using the time distribution data, the elapsed time for human actions in an extended loss of AC power (ELAP) scenario is then investigated. Time data and prediction are essential for modeling procedure performance.

99 GENERAL AND MISCELLANEOUS↗

Application of a temporal multiscale method for efficient simulation of degradation in PEM Water Electrolysis under dynamic operating conditions

Hydrogen is emerging as a vital energy carrier, driven by the need to reduce carbon emissions. Proton Electrolyte Membrane Water Electrolysis (PEMWE) enables hydrogen production under fluctuating renewable power conditions but requires improved understanding and stability of the anode catalyst layer under dynamic operating conditions, especially with low noble metal loadings. Long-term degradation experiments are both time-consuming and costly; therefore, a systematic, model-aided approach is essential. In the present work, a temporal multiscale method is applied to reduce the computational effort of simulating long-term degradation processes in PEMWE, with an exemplary focus on catalyst dissolution. A mechanistic model incorporating the oxygen evolution reaction, catalyst dissolution, and hydrogen permeation from the cathode to the anode was hypothesized and implemented. In this way, the local periodicity of transport and reaction processes in dynamic PEMWE operation, which influence the gradual degradation of the catalyst layer, is captured. The temporal multiscale method significantly reduces the computational effort of simulation, decreasing processing time from hours to mere minutes. This efficiency gain is attributed to the limited evolution of Slow-Scale variables during each period of time P of the Fast-Scale variables. Consequently, simulation is required only until local periodicity is achieved within each Slow-Scale time step. Hence, the fully resolved dynamic problem is decoupled into these two scales, employing a heterogeneous multiscale technique. The developed approach effectively accelerates parameter estimation and predictive simulations, supporting systematic modeling of PEMWE degradation under dynamic conditions.

08 HYDROGEN↗

Dynamic in vivo monitoring of granum structural changes of Ctenanthe setosa (Roscoe) Eichler during drought stress and subsequent recovery

Investigating the effects of drought stress and subsequent recovery on the structure and function of chloroplasts is essential to understanding how plants adapt to environmental stressors. We investigated Ctenanthe setosa (Roscoe) Eichler, an ornamental plant that can tolerate prolonged drought periods (40 and 49 days of water withdrawal). Conventional biochemical, biophysical, physiological and (ultra)structural methods combined for the first time in a higher plant with in vivo small-angle neutron scattering (SANS) were used to characterize the alterations induced by drought stress and subsequent recovery. Upon drought stress, no significant changes occurred in the chloroplast ultrastructure, chlorophyll content, 77K fluorescence emission spectra and maximal quantum efficiency of PSII (Qy dark), but the actual quantum efficiency of PSII (Qy light) decreased, the amounts of PSI-LHCII complexes and PSII monomers declined, and that of PSII supercomplexes increased. Thickness of the leaf and of the adaxial hypodermis, chloroplast length and granum repeat distance (RD) values decreased upon drought stress, as shown by light microscopy and SANS, respectively. Because of the very slight (nm-range) changes in RD values, the large biological variability (significant differences in RD values among the leaves and studied leaf regions) and the invasive sampling required for this method, transmission electron microscopy (TEM) hardly showed significant differences. On the other side, in situ SANS analyses provided a unique insight in vivo into the fast structural recovery of the granum structure of drought-stressed leaves, which happened already 18 h after re-watering, while functional and biochemical recovery took place on a longer time scale.

59 BASIC BIOLOGICAL SCIENCES↗

Modeling State Transition and Head-Dependent Efficiency Curve for Pumped Storage Hydro in Look-Ahead Dispatch

As one of the most widely installed utility-scale storage facilities, pumped storage hydro (PSH) plays an essential role in providing flexibility for power systems worldwide. Thus, to accurately quantify the flexibility of PSH units in operational optimization problems is important. The conventional PSH models in the literature rarely consider detailed state transitions due to their hourly-based settings. However, it becomes imperative for operational optimization on short-term intervals, especially with increasing shares of renewable energy in power systems. To this end, this paper presents a novel deterministic PSH model that considers the transition time and trajectory between three states of PSH units in look-ahead dispatch. Moreover, to better characterize the varying efficiency of PSH units with water head and flow rate, this paper proposes to model detailed headdependent efficiency curves (hereafter called input-output curves) in look-ahead dispatch, which encounters heavy computational burdens when short time intervals are applied. In this work, a zig-zag piece-wise linear approximation method is used for input-output curve modeling. This can enable an accurate quantification for variable efficiency and head dependence in a computationally effective manner. Here, numerical results are presented to show performances of the proposed PSH model in both flexibility quantification and computation time.

13 HYDRO ENERGY↗

Multimodel simulation of vertical gas transfer in a temperate lake

In recent decades, several lake models of varying complexity have been developed and incorporated in numerical weather prediction systems and climate models. To foster enhanced forecasting ability and verification, improvement of these lake models remains essential. This especially applies to the limited simulation capabilities of biogeochemical processes in lakes and greenhouse gas exchanges with the atmosphere. Here we present multi-model simulations of physical variables and dissolved gas dynamics in a temperate lake (Harp Lake, Canada). The five models (ALBM, FLake, LAKE, LAKEoneD, MTCR-1) considered within this most recent round of the Lake Model Intercomparison Project (LakeMIP) all captured the seasonal temperature variability well. In contrast, none of the models is able to reproduce the exact dates of ice-cover and ice-off, leading to considerable errors in the simulation of eddy diffusivity around those dates.We then conducted an additional modeling experiment with a diffusing passive tracer to isolate the effect of the eddy diffusivity on gas concentration. Remarkably, sophisticated k -" models do not demonstrate a significant difference in the vertical diffusion of a passive tracer compared to models with much simpler turbulence closures. All models simulate less intensive spring overturn compared to autumn. Reduced mixing in the models consequently leads to the accumulation of the passive tracer distribution in the water column. The lake models with a comprehensive biogeochemical module, such as ALBM and LAKE, predict dissolved oxygen dynamics adequate to the observed data. However, for the surface carbon dioxide concentration the correlation between modeled (ALBM, LAKE) and observed data is weak (~0.3). Overall our results indicate the need to improve the representation of physical and biogeochemical processes in lake models, thereby contributing to enhanced weather prediction and climate projection capabilities.

Guseva, Sofya↗

IrrigationViz: A Geospatial Visualization Application to Facilitate Irrigation Modernization

Irrigation water delivery infrastructure, such as canals and pipelines, are essential to agriculture in the Western U.S., yet many of these systems are reaching the end of their useful lives. Reinvestment can achieve a wide variety of benefits, from water conservation to energy savings or renewable energy generation. Modernization requires significant planning, design, and implementation funding which can be a challenge for many irrigation districts. Here, this paper introduces IrrigationViz, a web-based mapping application designed to help irrigation districts visualize and generate high-level cost and benefit estimates for infrastructure modernization projects. These estimates can help water managers identify projects that benefit from additional engineering resources and ultimately obtain funding. IrrigationViz includes map interactions, graphs, and visualization components to facilitate planning and communication to stakeholders and funders. IrrigationViz combines user-provided information about a water-delivery system with public datasets and basic engineering formulas to generate estimates of the benefits of reinvestment. Estimates include the amount of water seepage in earthen canals, potential hydropower generation associated with replacing a canal with a pressurized pipe, and pipe size recommendations. We found that hydropower generation estimates compared favorably with real world projects, but seepage loss estimates showed high variability relative to on-the-ground measurements

99 - GENERAL AND MISCELLANEOUS↗

Intersection of Hydrologic Change and Hydropower in the United States: Needs for Future Research and Practice

Hydropower is crucial for electric‐grid stability in the context of variable renewables but faces threats from changing hydrology. Here, we summarize the state of the science at the intersection of hydropower operations and planning, hydrologic science, and climate. We focus on the United States, outlining research, development, and training needs. Key knowledge gaps include the risk that intensification of compound extreme events poses to future generation, as well as uncertainties surrounding greenhouse gas emissions from hydropower reservoirs with relevance to hydropower's role in energy decarbonization. Quantifying such impacts and reducing uncertainty are critical where possible, but remaining irreducible or deep uncertainty will require new approaches. Future monitoring and modeling methods must provide a better understanding of the complexity inherent in large watersheds that is critical to managing both hydropower and watersheds in the context of hydrologic change. Yet, research and development will have little impact if they do not inform practice. Standardization and consolidation of platforms are essential for data, modeling, and tool translation to local scales and small operators. An enhanced industry‐academia dialog is pivotal for fostering a robust pipeline of hydropower professionals. Collaboration among researchers, policymakers, authorities, and industry stakeholders emerges as a recurring theme, highlighting the imperative for collective efforts.

13 HYDRO ENERGY↗

Thermodynamics of Minerals Stable near Earth's Surface

Project “Thermodynamics of Minerals Stable Near the Earth’s Surface” uses specialized calorimetric techniques to obtain new thermochemical data for solid phases of interest in the Earth’s “critical zone”, the near surface regions of the planet most directly affecting and affected by human activity. Major activity was in three areas: manganese oxide materials, aluminum clusters which are precursors to aluminum oxyhydroxide precipitates, and zeolites. All these classes of minerals are potential carriers of heavy metals and radionuclides in the environment, both within their crystal structures and as adsorbed layers or colloids. Their thermodynamic stability, as well as the sequence of stability of competing phases, governs the aqueous solubility of contaminants (and nutrients) in soil, groundwater, and sediments. The thermodynamics of these phases is strongly affected by particle size and crystallinity, since they often occur as very fine particles which do not coarsen in the near-surface environment. Many of these materials exhibit extensive polymorphism, multicomponent solid solution, and variable hydration states. Thus, one must define and systematize important thermodynamic variables, since one cannot make measurements on each and every possible phase, particle size, and composition. A major finding of the work on manganese oxides was labile water-induced oxidation-reduction reactions. These will be studied further by a combination of thermodynamic and synchrotron-based spectroscopic methods, the latter in collaboration with Peggy O’Day at UC Merced. The adsorption of other species, including simple organics, on such redox-active surfaces will also be investigated by a combination of thermochemical and spectroscopic studies. Studies of the energetics of water adsorption on mineral surfaces will be expanded to emphasize the adsorption of CO2 and small organic molecules, relevant to soil, groundwater, and the subsurface environment. Gas adsorption calorimetry, immersion calorimetry, and solution calorimetry will be combined with appropriate analytical and spectroscopic techniques to obtain a comprehensive picture of the interactions and their energetics. The evolution of aqueous aluminum clusters to form aluminum oxyhydroxide precipitates will be studied in detail by a combination of calorimetric and structural methods applied to aqueous samples aged at room temperature. The energetics of new classes of clusters will be explored. The project addresses several common themes relevant to the broad mission of the Department of Energy. Thermochemical data for minerals stable near the Earth’s surface, though still incomplete, are essential for understanding both natural and anthropogenic processes that affect our very existence on this planet. Such data contribute to the fundamental underpinning for mitigation and management strategies for the extraction and use of energy. Fundamental thermodynamic and mechanistic understanding is required to model processes ranging from heavy metal pollution to nuclear waste disposal to climate change.

58 GEOSCIENCES↗

Using Machine Learning to Predict Cloud Turbulent Entrainment–Mixing Processes

Different turbulent entrainment–mixing mechanisms between clouds and environment are essential to cloud–related processes; however, accurate representation of entrainment–mixing in weather/climate models still poses a challenge. This study exploits the use of machine learning (ML) to address this challenge. Four ML (Light Gradient Boosting Machine [LGB], eXtreme Gradient Boosting, Random Forest, and Support Vector Regression) are examined and compared. It is found that LGB performs best, and thus is selected to understand the impact of entrainment–mixing on microphysics using simulation data from Explicit Mixing Parcel Model. Compared with traditional parameterizations, the trained LGB provides more accurate microphysical properties (number concentration and cloud droplet spectral dispersion). The partial dependences of predicted microphysics on features exhibit a strong alignment with physical mechanisms and expectations, as determined by the interpreting method, thus overcoming the limitations of the “black box” scheme. The underlying mechanisms are that the smaller number concentration and larger spectral dispersion correspond to more inhomogeneous entrainment–mixing. Specifically, number concentration after entrainment–mixing is positively correlated with adiabatic number concentration and liquid water content affected by entrainment–mixing, and inversely correlated with adiabatic volume mean radius. Spectral dispersion after entrainment–mixing is negatively correlated with liquid water content affected by entrainment–mixing, turbulent dissipation rate and relative humidity of entrained air. Sensitivity analysis further suggests that number concentration is mainly determined by cloud microphysical properties whereas spectral dispersion is influenced by both cloud microphysical properties and environmental variables. The results indicate that the LGB scheme has the potential to enhance the representation of entrainment–mixing in weather/climate models.

54 ENVIRONMENTAL SCIENCES↗

Competition response of cloud supersaturation explains diminished Twomey effect for smoky aerosol in the tropical Atlantic

The Twomey effect brightens clouds by increasing aerosol concentrations, which activates more droplets and decreases cloud supersaturation in response to more competition for water vapor. To quantify this competition response, we used marine low cloud observations in clean and smoky conditions at Ascension Island in the tropical South Atlantic during the Layered Aerosol Smoke Interactions with Cloud (LASIC) campaign. These observations show similar increases in droplet number for increased accumulation-mode particles from surface-based and satellite cloud retrievals, demonstrating the importance of below-cloud aerosol measurements for retrieving aerosol–cloud interactions (ACI) in clean and smoky aerosol conditions. Four methods for estimating cloud supersaturation from aerosol–cloud measurements were compared, with cloud scene-based and parcel-based methods showing sufficient variability for a strong dependence on both aerosol accumulation number concentration and cloud-base updraft velocities. Decomposing aerosol-related changes in cloud albedo and optical depth shows the calculated competition response accounts for dampening the activation response by 12 to 35%, explaining the diminished Twomey effect at high aerosol concentrations observed for smoky conditions at LASIC and previously around the world. This result was consistent for independent supersaturation retrievals by cloud scene-based droplet number and cloud condensation nuclei and parcel-based multimode size-resolving Lagrangian methods. Translating aerosol effects to local radiative forcing with clean conditions as a proxy for preindustrial and smoky conditions for present-day showed that the competition response reduces cooling from the Twomey radiative forcing by 12 to 35%, providing an essential process-specific constraint for improving the representation of aerosol competition in climate model simulation of indirect aerosol forcing.

54 ENVIRONMENTAL SCIENCES↗

Pumped Storage Hydropower Augmented with Pressurized Air: The Ground-Level Integrated Diverse Energy Storage (GLIDES) System — GLIDES System Configurations and Use Cases

Energy storage is essential for cost-effective integration of variable renewable energy sources to support a low-carbon grid. It is also a key enabler of a modern grid infrastructure for demand management. However, several main challenges remain for different kind of energy storage technologies in grid scale deployment. Currently, the largest source of utility-scale storage and long-duration storage in the US is pumped storage hydropower (PSH). Prospect of growth in conventional PSH faces challenges that have limited its deployment over the last three decades, including high capital costs and long deployment timelines. Batteries have high energy densities and are the primary technology of choice for small-scale energy storage. Compressed air energy storage (CAES) is another large-scale energy storage technology, but there are few plants deployed worldwide. They suffer from their low round trip efficiency (RTE) due to the use of high-pressure air compressors. To address some of the challenges associated with these various storage technologies, the Ground-Level Integrated Diverse Energy Storage (GLIDES) is a modular PSH technology that was invented in 2015 at Oak Ridge National Laboratory. It utilizes gas compression to store electric energy. GLIDES stores energy by compressing gas using a liquid piston in high-pressure vessels. In doing so the vessels act as the upper reservoir in conventional PSH. Initially, the vessels are filled with gas to a prescribed pressure. To store energy, GLIDES uses a hydraulic piston pump to pump water into the pressurized vessels. As the water volume increases inside the vessels, water acts as a hydraulic piston compressing the gas on top of it. This process can be thought of as pumping water from the lower reservoir to the higher reservoir in PSH, increasing the water head. To dispatch the stored energy, the high-head water in the vessel is discharge through a high head Pelton hydraulic turbine that is connected to an electric generator. Employing high-pressure vessels enables GLIDES to reach water heads ~10-80 times higher than conventional PSH, achieving ~40 times higher energy densities, and overcomes the geographic limitation of conventional PSH. Although its energy density is much lower than that of batteries, GLIDES holds the potential advantages of having long service life, ease of system integration and being less hazardous over batteries. GLIDES prospective scalability could make it suitable for wide range of applications from behind the meter storage in buildings to grid-scale storage. It also makes it suitable for installations in densely populated urban areas where energy storage is most needed and real estate is limited. Over the last 5 years, work has focused on increasing GLIDES’ energy density, decreasing its initial capital cost of the system, and increasing its revenue potential. Several designs were developed and prototyped to verify and demonstrate the improvement in energy density. The latest prototype achieved energy density of 1.21 kWh/m 3 . Our analysis showed that it could achieve up to 1.7 kWh/m 3 with a mixture of air and carbon dioxide as the gas being compressed.

13 HYDRO ENERGY↗