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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

The effect of magnetospheric ion bombardment on the reflectance of Europa's surface

Laboratory investigations have been conducted to ascertain the role of sulphur ion implantation on differences in the reflectivity of the leading and trailing atmospheres of Europa in the visible and UV ranges. Under the laboratory conditions tested, neither S-implantation nor SO2 deposition can account for the general 'reddening' of the trailing hemisphere in the UV, relative to the leading hemisphere; this feature has been shown to be producible by fast penetrating ions.

Sack, N. J.↗

Formation of Na-containing molecular ions at Io

Fast sodium atoms, which appear to be associated with the motion of the magnetic 'field lines' downstream from Io (Schneider et al. 1991), are thought to be produced by dissociation of NaX(+) in Io's plasma torus. It was suggested that these molecular ions are formed near Io's exobase by electron-impact ionization and picked up be the corotating filed lines (Wilson and Schneider 1994). Because electron cooling processes dominate electron-impact ionization in Io's corona, two reactions are suggested here as sources of NaX(+) and, hence, as the ultimate sources of the observed fast Na. First, the charge-exchange cross sections for forming NaX(+) are shown to be large for plasma torus ions (O(+), S(+), O(2+), S(3+)) colliding with NaX molecules in Io's corona. Sputtering from the surface (Chrisey et al. 1988) and rapid transport to the exobase is a potential source of NaX, where X is O,S, Na, or a molecular species such as NaS or O2. Second ions of the more abundant molecules (e.g., SO(+), SO2(+), O2(+), and S2(+)) can react efficiently with atomic Na in Io's corona to form NaX(+). Here cross sections are estimated for these two processes, as well as for charge exchange in O(+) and S(+) on Na collisions.

Johnson, R. E.↗

Sputtering from a Porous Material by Penetrating Ions

Porous materials are ubiquitous in the universe and weathering of porous surfaces plays an important role in the evolution of planetary and interstellar materials. Sputtering of porous solids in particular can influence atmosphere formation, surface reflectivity, and the production of the ambient gas around materials in space, Several previous studies and models have shown a large reduction in the sputtering of a porous solid compared to the sputtering of the non-porous solid. Using molecular dynamics simulations we study the sputtering of a nanoporous solid with 55% of the solid density. We calculate the electronic sputtering induced by a fast, penetrating ion, using a thermal spike representation of the deposited energy. We find that sputtering for this porous solid is, surprisingly, the same as that for a full-density solid, even though the sticking coefficient is high.

Rodriguez-Nieva, J. F.↗

Spacecraft observations of the interaction of active comets with the solar wind

Six spacecraft encountered two comets during 1985 and 1986, obtaining a wealth of data relative to the plasma processes at work in the interaction of an active comet with the solar wind. A review of what space plasma scientists have learned from these data and of their interpretations is presented. The interaction process begins millions of kilometers from the nucleus where the solar wind first picks up cometary ions that slow down the wind and causes the interplanetary magnetic field to pile up and drape around the comet's ionosphere. Thus the geometry of a comet's plasma tail is defined by this draped field. At Halley the Giotto spacecraft noted a well-defined boundary separating the mixture of solar wind and cometary plasmas and the interplanetary magnetic field from the free-field, almost pure cometary plasma in the inner coma. Additional unexpected features in the inner coma were a flux of fast 'granddaughter' ions and high densities of negative ions. Further details covering pickup ions and plasma waves, mass loading, bow shock, energetic particles, the cometosheath, the ionopause, the plasma tail, and the field-free region are provided.

Neugebauer, M.↗

Two Types of Transpolar Arc Development, Event Studies with Data Set of ASTRID-2, DMSP, FAST, and SuperDARN

Aurorae which appear in the polar cap are called transpolar arcs, polar cap arcs, sun-aligned arcs, or occasionally Theta-aurora because of its spatial distribution resembling Greek character 'Theta.' Morphology, IMF (Interplanetary Magnetic Field) relationship, and ionospheric convection patterns were studied in quest of mechanisms of transpolar arcs. Four events were analyzed: 1999/Jan/22/19:00 - 23/01:30 (1 event: a) 1999/Jan/24/06:00 - 10:00 (1 event: b) 1999/Feb/1 1/20:00 - 12/02:00 (2 events: c, d), with data set of ExB drift velocity data obtained by electric field measurements of ASTRID-2 and FAST, DMSP ion driftmeter data, and line-of-sight velocity data of SuperDARN. POLAR-UVI image data were used for spatial and temporal variations of transpolar arcs and ACE data set were used for investigation of IMF relationship. IMF-Bz was strongly positive (Bz from +8nT to +20 nT) during periods of all four transpolar arcs. In events (a),(b),(c), transpolar arcs appeared immediately after the direction of IMF turned northward, though IMF was fluctuating in event (b). A sudden increase of IMF-By, from +3nT to +18nT, was observed in event (d). Two different types of transpolar arc development were observed in POLAR-UVI: one which begins as a split from dawn or dusk sector of auroral oval and shifts poleward in event (a),(c),(d), and another which is initially a patch of auroral oval disturbed by substorm but develops as a transpolar arc, forming a growing finger-like shape from midnight sector (event b). Sunward flow, associated with positive IMF-Bz, were observed within newly-created polar caps in event (a),(c),(d). Not clear ionospheric convection pattern was seen across the polar cap arc in event (b) die to limitation of data set. In event (c), O+ with energy more than 1 keV were observed by FAST within a transpolar arc, suggesting that their origin be from plasma sheet. Transpolar arcs are thought to be projection of plasma sheet bifurcation into lobe regime. There can be several ways of development of transpolar arcs and two different patterns were observed through this work.

Narita, Yasuhito↗

Research for preparation of cation-conducting solids by high-pressure synthesis and other methods

It was shown that two body-centered-cubic skeleton structures, the Im3 KSbO3 phase and the defect-pyrochlore phase A(+)B2X6, do exhibit fast Na(+)-ion transport. The placement of anions at the tunnel intersection sites does not impede Na(+)-ion transport in (NaSb)3)(1/6 NaF), and may not in (Na(1+2x)Ta2 5F)(Ox). The activation energies are higher than those found in beta-alumina. There are two possible explanations for the higher activation energy: breathing of the bottleneck (site face or edge) through which the A(+) ions must pass on jumping from one site to another may be easier in a layer structure and/or A(+)-O bonding may be stronger in the cubic structures because the O(2-) ion bonds with two (instead of three) cations of the skeleton. If the former explanation is dominant, a lower activation energy may be achieved by optimizing the lattice parameter. If the latter is dominant, a new structural principle may have to be explored.

Goodenough, J. B.↗

Partition function corrections

The vibration-rotation interaction coupling in diatomic molecules is analyzed and first-order expressions for the energy levels are deduced. Corrections to the partition function to account for this coupling are derived. The effects of long-range intermolecular forces due to induced dipole-induced dipole interactions, dipole-induced dipole interactions, charge-dipole interactions, and charge-charge interactions are considered. London's quantized oscillator model of the induced dipole-induced dipole interaction is developed. The partition function including effects of such dispersion forces is derived and is shown to lead to the virial equation of state. For a model combining the hard sphere and long-range attractive type potentials, this is found to lead to the van der Waals equation of state. The equation of state near the critical point is presented in reduced form (thermodynamic variables expressed in units of critical point values). Finally, approximate corrections to the electronic partition functions are derived to account for perturbations of excited electronic states induced by neighboring neutral particles, heavy ions, and fast electron collisions.

Source record↗

Structure of medium Mach number quasi-parallel shocks - Upstream and downstream waves

The transition from steady low-Mach-number to unsteady high-Mach-number quasi-parallel shocks was investigated by performing large-scale 1D hybrid code simulations at increasing Mach numbers. It was found that only at very low Mach number shocks the steepening is limited by upstream phase-standing whistlers, as predicted by the classical theory (Tidman and Northrop, 1968). In the intermediate region of Mach numbers between 1.5 and 3.5, a very diverse behavior is observed. Backstreaming ions generate fast magnetosonic waves which dominate the upstream, with wavelengths longer than phase-standing whistlers. At increasing Mach numbers, the phase and group velocities of the dominant waves are reduced until they point back toward the shock; when there is sufficient energy flux in these waves, they lead to unsteady shock behavior and eventually to shock reformation.

Krauss-Varban, D.↗

Was Ferrocyanide a Prebiotic Reagent?

Hydrogen cyanide is the starting material for a diverse array of prebiotic syntheses, including those of amino acids and purines. Hydrogen cyanide also reacts with ferrous ions to give ferrocyanide, and so it is possible that ferrocyanide was common in the early ocean. This can only be true if the hydrogen cyanide concentration was high enough and the rate of reaction of cyanide with ferrous ions was fast enough. We show experimentally that the rate of formation of ferrocyanide is rapid even at low concentrations of hydrogen cyanide in the pH range 6-8, and therefore an equilibrium calculation is valid. The equilibrium concentrations of ferrocyanide are calculated as a function of hydrogen cyanide concentration, pH and temperature. The steady state concentration of hydrogen cyanide depends on the rate of synthesis by electric discharges and ultraviolet light and the rate of hydrolysis, which depends on pH and temperature. Our conclusions show that ferrocyanide was a major species in the prebiotic ocean only at the highest production rates of hydrogen cyanide in a strongly reducing atmosphere and at temperatures of 0 C or less, although small amounts would have been present at lower hydrogen cyanide production rates. The prebiotic application of ferrocyanide as a source of hydrated electrons, as a photochemical replication process, and in semi-permeable membranes is discussed.

Keefe, Anthony D.↗

Inverse Bremsstrahlung in Shocked Astrophysical Plasmas

There has recently been interest in the role of inverse bremsstrahlung, the emission of photons by fast suprathermal ions in collisions with ambient electrons possessing relatively low velocities, in tenuous plasmas in various astrophysical contexts. This follows a long hiatus in the application of suprathermal ion bremsstrahlung to astrophysical models since the early 1970s. The potential importance of inverse bremsstrahlung relative to normal bremsstrahlung, i.e. where ions are at rest, hinges upon the underlying velocity distributions of the interacting species. In this paper, we identify the conditions under which the inverse bremsstrahlung emissivity is significant relative to that for normal bremsstrahlung in shocked astrophysical plasmas. We determine that, since both observational and theoretical evidence favors electron temperatures almost comparable to, and certainly not very deficient relative to proton temperatures in shocked plasmas, these environments generally render inverse bremsstrahlung at best a minor contributor to the overall emission. Hence inverse bremsstrahlung can be safely neglected in most models invoking shock acceleration in discrete sources such as supernova remnants. However, on scales approximately > 100 pc distant from these sources, Coulomb collisional losses can deplete the cosmic ray electrons, rendering inverse bremsstrahlung, and perhaps bremsstrahlung from knock-on electrons, possibly detectable.

Baring, Matthew G.↗

Fabricating Ultra-Thin Silicon Carbide Diaphragms

A process for fabricating relatively thin SiC diaphragms may include fast Reactive Ion Etching (RIE) followed by Dopant Selective Reactive Ion Etching (DSRIE). The process may produce silicon carbide (SiC) diaphragms thinner than 10 microns. These thinner, more sensitive diaphragms may then be used to effectively resolve sub-psi pressures in jet engines, for example.

Okojie, Robert S.↗

X-ray and gamma-ray line production by nonthermal ions

X-ray production at about 6.8 keV by the 2p to 1s transition in fast hydrogen- and helium-like iron ions is calculated, following both electron capture to excited levels and collisional excitation. A refinement of the Oppenheimer-Brinkman-Kramers (1930) approximation is used to obtain an improved charge-exchange cross-section. This, and the corresponding ionization cross section, were used to determine equilibrium charge fractions for iron ions as functions of their energy. The effective X-ray line production cross section was found to be sharply peaked in energy at about 8 to 12 MeV per amu. Since fast ions of similar energies can also excite nuclear levels, the ratio of selected strong gamma-rays line emissivities to the X-ray line emissivity is calculated. These calculations are employed to set limits on the intensity of gamma-rays line emission from the galactic center and the radio galaxy Cen A, and it is found that these limits are generally lower than those reported in the literature.

Bussard, R. W.↗

X-ray and gamma-ray line production by nonthermal ions

X-ray production was calculated at approximately 6.8 keV by the 2p to 1s transition in fast hydrogen- and helium-like iron ions, following both electron capture to excited levels and collisional excitation. A refinement of the OBK approximation was used to obtain an improved charge exchange cross section. This, and the corresponding ionization cross section were used to determine equilibrium charge fractions for iron ions as functions of their energy. The effective X-ray line production cross section was found to be sharply peaked in energy at about 8 to 12 MeV/amu. Because fast ions of similar energies can also excite nuclear levels, the ratio of selected strong gamma ray line emissivities to the X-ray line emissivity was also calculated. Limits set by this method on the intensity of gamma ray line emission from the galactic center and the radio galaxy Centaurus A are generally lower than those reported in the literature.

Bussard, R. W.↗

Dual Ion Spectrometers and Their Calibration for the Fast Plasma Investigation on NASA's Magnetospheric Multiscale Mission

The scientific target of NASA's Magnetospheric Multiscale (MMS) mission is to study the fundamentally important phenomenon of magnetic reconnection. Theoretical models of this process predict a small size, on the order of hundred kilometers, for the ion diffusion region where ions are demagnetized at the dayside magnetopause. This region may typically sweep over the spacecraft at relatively high speeds of 50 km/s, requiring the fast plasma investigation (FPI) instrument suite to have an extremely high time resolution for measurements of the 3D particle distribution functions. As part of the FPI on MMS, the 16 dual ion spectrometers (DIS) will provide fast (150 ms) 3D ion velocity distributions, from 10 to 30,000 eV/q, by combining the measurements from four dual spectrometers on each of four MMS spacecraft. For any multispacecraft mission, the response uniformity among the spectrometer set assumes an enhanced importance. Due to these demanding instrument requirements and the effort of calibrating more than 32 sensors (16 × 2) within a tight schedule, a highly systematic and precise calibration was required for measurement repeatability. To illustrate how this challenge was met, a brief overview of the FPI DIS was presented with a detailed discussion of the calibration method of approach and implementation. Finally, a discussion of DIS performance results, their unit-to-unit variation, and the lessons learned from this calibration effort are presented.

Coffey, V. N.↗

Mars Organic Molecule Analyzer (MOMA) Laser Desorption/Ionization Source Design and Performance Characterization

The Mars Organic Molecule Analyzer (MOMA), a dual-source, ion trap-based instrument capable of both pyrolysis-gas chromatography mass spectrometry (pyr/GC-MS) and laser desorption/ionization mass spectrometry (LDI-MS), is the core astrobiology investigation on the ExoMars rover. The MOMA instrument will be the first spaceflight mass analyzer to exploit the LDI technique to detect refractory organic compounds and characterize host mineralogy; this mode of analysis will be conducted at Mars ambient conditions. In order to achieve high performance in the Martian environment while keeping the instrument compact and low power, a number of innovative designs and components have been implemented for MOMA. These include a miniaturized linear ion trap (LIT), a fast actuating aperture valve with ion inlet tube, and a Microelectromechanical System (MEMS) Pirani sensor. Advanced analytical capabilities like Stored Waveform Inverse Fourier Transform (SWIFT) for selected ion ejection and tandem mass spectrometry (MS/MS) are realized in LDI-MS mode, and enable the isolation and enhancement of specific mass ranges and structural analysis, respectively. We report here the technical details of these instrument components as well as system-level analytical capabilities, and we review the applications of this technology to Mars and other high-priority targets of planetary exploration.

Xiang Li↗

Preferential Heating of Oxygen 5+ Ions by Finite-Amplitude Oblique Alfven Waves

Minor ions in the fast solar wind are known to have higher temperatures and to flow faster than protons in the interplanetary space. In this study we combine previous research on parametric instability theory and 2.5D hybrid simulations to study the onset of preferential heating of Oxygen 5+ ions by large-scale finite-amplitude Alfven waves in the collisionless fast solar wind. We consider initially non-drifting isotropic multi-species plasma, consisting of isothermal massless fluid electrons, kinetic protons and kinetic Oxygen 5+ ions. The external energy source for the plasma heating and energization are oblique monochromatic Alfven-cyclotron waves. The waves have been created by rotating the direction of initial parallel pump, which is a solution of the multi-fluid plasma dispersion relation. We consider propagation angles theta less than or equal to 30 deg. The obliquely propagating Alfven pump waves lead to strong diffusion in the ion phase space, resulting in highly anisotropic heavy ion velocity distribution functions and proton beams. We discuss the application of the model to the problems of preferential heating of minor ions in the solar corona and the fast solar wind.

Maneva, Yana G.↗

Three-dimensional ion sound turbulence

A fast cold large diameter electron beam is injected into a uniform background plasma. The injected beam current is balanced by a field-aligned return current which gives rise to an ion acoustic instability. The plasma is essentially unbounded and collisionless on the time scale of the pulsed experiment. The fluctuations are analyzed by probe techniques in real time and space as well as in the frequency and wavenumber domains. Strong density fluctuations are observed in the entire ion acoustic spectrum reaching peak amplitudes at the low frequency end. The propagation of phase coherent test waves in the current carrying plasma is investigated. For the highly turbulent regime strong damping is observed while at lower drift velocities direction is observed. Oblique propagation of two strong test waves at different frequencies indicate the role of nonlinear ion Landau damping in absorption of wave energy.

Stenzel, R. L.↗

The source of midlatitude metallic ions at F-region altitudes

The results of a survey of metallic ions detected by the Bennett Ion Mass Spectrometer flown on the Atmospheric Explorer satellites are presented and discussed. The nighttime distribution of these ions observed in the F-region at middle latitudes can be accounted for by the presence of fast upward Pederson ion drifts that are produced by intense poleward-directed electric fields with magnitudes typical of those defining subauroral drift events. Such fields, which arise in the vicinity of the main electron density trough at night, result in the rapid movement of long-lived meteoric ions upwards out of their source region into the F-region. Neutral wind drag by the equatorially-directed nightside neutral wind component can lift the ions higher along the field lines until the downward drag of major ion diffusion forces them to layer under F-max.

Grebowsky, J. M.↗