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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Validation of predictive performance models for supersonic gas-jet nozzles at the Laboratory for Laser Energetics

We present results characterizing the neutral-density distributions produced by the supersonic nozzles used in experiments on the OMEGA-60 and OMEGA-EP laser systems at the University of Rochester’s Laboratory for Laser Energetics (LLE). Axisymmetric Fluent® simulations using LLE nozzle specifications capture the viscous effects, gas expansion, and shock waves that complicate flow predictions for offsets above the nozzle exit. Here, these simulations show good agreement with neutral-density measurements obtained using a four-wave shearing interferometer. An analytical form is given for the plateau length. Fits to simulation data for boundary layer thickness, mean plateau density, and density ramps are given as functions of nozzle offset and nozzle backing pressure for a number of nozzles and gases.

47 OTHER INSTRUMENTATION↗

Extreme ultraviolet spectra of highly ionized oxygen and fluorine

The foil-excitation method has been used to study the extreme ultraviolet spectra of highly ionized oxygen and fluorine. Several previously unreported lines in heliumlike fluorine are reported and other newly reported lines in heliumlike oxygen have been measured to higher accuracy. Included in the measurements are certain heliumlike oxygen transitions of significance in interpretation of solar-flare spectral observations. The wavelength determinations are usually in good agreement with calculated results which includes relativistic corrections, but discrepancies arise when nonrelativistic calculations are used. A comparison of the present results and those recently obtained by theta-pinch and laser-induced plasma sources is made for both heliumlike and lithiumlike ions; a few discrepancies occur, with results in most cases in better agreement with relativistically corrected calculations. Certain unidentified lines in the spectra may be attributable to radiative transitions between quartet states of lithiumlike ions.

Pegg, D. J.↗

Shock tube and shock wave research; Proceedings of the Eleventh International Symposium, University of Washington, Seattle, Wash., July 11-14, 1977

Papers are presented on the applications of shock-wave technology to the study of hydrodynamics, the use of the pressure-wave machine for charging diesel engines, and measurements of the heat-transfer rate in gas-turbine components. Consideration is given to shock propagation along 90-degree bends, the explosive dissemination of liquids, and rotational and vibrational relaxation behind weak shock waves in water vapor. Shock phenomena associated with expansion flows are described and stratospheric-related research using the shock tube is outlined. Attention is given to shock-wave ignition of magnesium powders, Mach reflection and boundary layers, and transition in the shock-induced unsteady boundary layer on a flat plate. Shock-tube measurements of induction and post-induction rates for low-Btu gas mixtures are presented and shock-initiated ignition in COS-N2O-Ar mixtures is described. Cluster growth rates in supersaturated lead vapor are presented and a study of laser-induced plasma motion in a solenoidal magnetic field is reviewed.

Ahlborn, B.↗

Optical efficiencies of lightning in planetary atmospheres

The first simulations of lightning in planetary atmospheres by laser-induced plasmas are reported. These simulations show that the fraction of the energy in lightning discharge channels that is radiated in the visible spectrum is similar for earth, Venus, and Titan, but quite different for Jupiter. One implication of these results is that the amount of trace gases produced by lightning in the Jovian atmosphere must be larger than previously estimated.

Borucki, W. J.↗

Systems report for payload G-652: Project origins

Experiments conducted to investigate possible hardware configurations and methodologies for a Get Away Special payload designated G-652 are discussed. Test data collected from the operation of a free electron laser wiggler using simulated ram glow phenomenon are described. Results of an experiment to synthesize organic compounds within a primordial atmosphere using a laser induced plasma are discussed. An experiment is described which utilized neutron bombardment to assess the risk of genetic alterations in embyros in space.

Bellina, J.↗

Time resolved simulation of lightning by LIP

Results of time-resolved spectra of lightning simulation in air by laser-induced plasma (LIP) are reported. The measured electron temperatures varied from 17,000 +/-1000 K at 600 ns to 12,000 +/-1000 K at 4 microsec after the ignition of the plasma. Electron densities in the plasma varied from (7.0 +/-1.4) x 10 exp 17/cu cm to (9.0 +/-1.8) x 10 exp 16/cu cm for the above times. A comparison of state variables for LIP and natural lightning is presented. Immediately following the ignition, both natural lightning and LIP are found to reach temperatures in excess of 16,000 K and relax to ambient pressure with different rates. They are expected to approach the 2000-4000-K temperature range, which is important to chemical synthesis, in an asymptotically similar fashion.

Jebens, D. S.↗

Flame Synthesis of Single- and Multi-Walled Carbon Nanotubes and Nanofibers

Metal-catalyzed carbon nanotubes are highly sought for a diverse range of applications that include nanoelectronics, battery electrode material, catalysis, hydrogen storage media and reinforcing agents in polymer composites. These latter applications will require vast quantities of nanotubes at competitive prices to be economically feasible. Moreover, reinforcing applications may not require ultrahigh purity nanotubes. Indeed, functionalization of nanotubes to facilitate interfacial bonding within composites will naturally introduce defects into the tube walls, lessening their tensile strength. Current methods of aerosol synthesis of carbon nanotubes include laser ablation of composite targets of carbon and catalyst metal within high temperature furnaces and decomposition of a organometallics in hydrocarbons mixtures within a tube furnace. Common to each approach is the generation of particles in the presence of the reactive hydrocarbon species at elevated temperatures. In the laser-ablation approach, the situation is even more dynamic in that particles and nanotubes are borne during the transient cooling phase of the laser-induced plasma for which the temperature far exceeds that of the surrounding hot gases within the furnace process tube. A shared limitation is that more efficient methods of nanoparticle synthesis are not readily incorporated into these approaches. In contrast, combustion can quite naturally create nanomaterials such as carbon black. Flame synthesis is well known for its commercial scalability and energy efficiency. However, flames do present a complex chemical environment with steep gradients in temperature and species concentrations. Moreover, reaction times are limited within buoyant driven flows to tens of milliseconds. Therein microgravity can greatly lessen temperature and spatial gradients while allowing independent control of flame residence times. In preparation for defining the microgravity experiments, the work presented here focuses on the effect of catalyst particle size and reactant gas in 1g.

VanderWal, R. L.↗

Spectral Irradiance Measurements of Simulated Lightning in Planetary Atmospheres

Optical emissions from lightning provide information to estimate the altitude, latitude and longitude of lightning storms, the energy of the discharges, and the production of important trace species such as HCN and C2H2. Knowledge of the spectra of planetary lightning is needed to deduce the total energy dissipated by lightning (and thereby, the production of trace gases) and to help design experiments to detect and track lightning storms. Measurements of the spectral irradiance from approximately 380 to 820 nm are reported for laboratory simulations of lightning in the atmospheres of Venus, Jupiter, and Titan. In our laboratory, laser-induced plasmas (LIP) are used to simulate lightning discharges. This technique avoids contamination of the spectra by elect-ode material and maintains a safe environment while allowing the use of flammable gases, such as hydrogen and methane, found in outer planet atmospheres. The observations were made at I and 5 bars pressure for Venus and Jupiter and at 1 bar for the Titan mixture. At a pressure of one bar, our results show prominent lines from H(sub alpha), H(sub beta), H(sub gamma), and H(sub delta) lines of the Balmer Series of atomic hydrogen, a single line from Helium at 588 nm and strong continuum radiation. At pressures of 5 bars, the H(sub alpha) and H(sub beta) lines are wider, the H(sub gamma), and H(sub delta) lines merge into the continuum because of pressure broadening, and the helium line at 588 nm is no longer visible. The observed spectra of simulated lightning in the venusian atmosphere at 1 and 5 bars shows that the OI multiplet at 777.7 nm dominates the spectra, but weak features due to atomic carbon and singly excited and singly ionized oxygen atoms are also visible. Although lightning has not yet been observed on Titan, it conceivable that some form of lightning discharge could be occurring. Therefore experiments on a Titan atmosphere mixture were conducted. The most prominent features seen in the simulated spectra are the H(sub alpha) at 656 nm. from the dissociation of the methane and two strong features at 740 and 820 nm from singly excited nitrogen atoms. Most of the features between 400 and 656 nm are due to ionized nitrogen atoms. A broad, highly structured feature centered near 389 nm is molecular band radiation from CN molecules formed in the cooling plasma of atomic nitrogen, carbon, and hydrogen. It is observed in the lightning simulations of both the venusian and Titan atmospheres, For Venus, Jupiter, and Titan, narrow spectral features that are ideal for detecting lightning in the presence of sunlight are present in the spectra. These features could allow lightning to be detected and tracked by Earth-based instruments.

Borucki, W. J.↗

Prebiotic Processing induced by Comet and Meteor Impact

In their study of organic synthesis from impact shocks using the laser-induced-plasma (LIP) technique, McKay and Borucki(l) found that organic synthesis preferentially occurred in a reducing gas mixture rich in methane, and not in a mixture rich in carbon dioxide. This result means chemical models based on the thermodynamical equilibrium approach do not apply to shock chemistry. In this study, we employ the technique of reacting flow, i.e., chemical kinetics in a fluid flow, to simulate the chemistry occurring in LIP and in the wake region from comet or meteor impact. Three different air compositions have been used: (1) 1/3 CO2 and 2/3 H2, (2) pure CH4, and (3) 1/4 CH4, 1/4 CO2, and 1/2 H2O. The stoichiometric ratio of gas mixtures (1) and (3) are kept the same. For (1) we obtain equal mole fractions of CO and H2O as the major products and for (2) C2H2 is the major product. In both cases our results are in agreement with Ref. (1). For (3) we find an interesting case where the nature of chemicals produced to be critically dependent on the flowfield temperature. At the higher temperature part of the wake region, CO and H2O are the dominant products, whereas in the cooler region C2H2 is the dominant product. Further studies of these reactions, as well as for the gas mixture including N2, are being pursued.

Dateo, Christopher E.↗

Effects of Two-Pulse Sequencing on Characteristics of Elementary Propellants for Ablative Laser Propulsion

This work continues on previous investigations of elementary propellants for Ablative Laser Propulsion (ALP). This paper details the experimental methods used for alignment of a non-colinear temporal pulse splitting apparatus. Spatial coincidence of the separate pulses is established, the pulses are delayed, and first data is reported on this pulse spacing effect on time-of-fight (TOF) measurements. This includes ion velocity and number density measurements, and this data is compared to results from a previous work. Also, first data on the experimental determination of the time required for the laser-induced plasma to become purely reflective to incident pulses is presented.

Thompson, M. Shane↗

Laser-induced fluorescence of filament-produced plasmas

Self-guided ultrafast laser filaments are a promising method for laser beam delivery and plasma generation for standoff and remote detection of elements and isotopes via filament-induced breakdown spectroscopy (FIBS). Yet, there are several challenges associated with the practical application of FIBS, including delivery of sufficient laser energy at the target for generating plasma with a copious amount of emission signals for obtaining a high signal-to-noise ratio. Here, in this study, we use laser-induced fluorescence (LIF) to boost the emission signal and reduce self-reversal in the spectral profiles. Ultrafast laser filaments were used to produce plasmas from an Al 6061 alloy target at various standoff distances from 1 to 10 m. For LIF emission enhancement, a narrow linewidth continuous-wave laser was used in resonance with a 394.40 nm Al I resonant transition, and the emission signal was monitored from the directly coupled transition at 396.15 nm. Emission signal features of Al I are significantly enhanced by resonant excitation. In addition, LIF of filament ablation plumes reduces the self-reversal features seen in the thermally excited spectral profiles. Time-resolved two-dimensional fluorescence spectroscopy was performed for evaluating the optical saturation effects, which are found to be non-negligible due to high Al atomic densities in the filament-produced plasmas.

47 OTHER INSTRUMENTATION↗

A study of velocity, temperature, and density in the plasma generated by laser-induced breakdowns

The paper presents velocity measurements of shock-induced flow field, leading to vortex generation and plasma deformation in air. Femtosecond-laser electronic excitation tagging (FLEET) velocimetry was performed at the times Δt = 3, 20, 50, and 100 µs post laser-induced breakdown. Emissions over Δt = 3–10 µs showed the propagations of the initially elliptic shock, transitioning into a spherical front. The shock emanated along the laser axis causes the flow outward, and then the pressure gradient generated by the rarefaction wave drives the inward flow at later moments, with the velocity magnitude approaching a steady-state value of 40 m s -1 . Temporal velocity evolution was compared with non-self-similar solutions behind the propagating shock, which are sensitive to the size of the energy deposition, and the use of the measured initial plasma diameter reproduced the experiment. There establishes a region of uniform velocity around 35 m s -1 in the air-flow running through the plasma, which triggers the roll-up of the plasma surface by a large-scale vortex, providing the detail of flow field evolution from the shock propagation to the plasma deformation. A collective Thomson scattering and hybrid fs/ps pure rotational coherent anti-Stokes Raman scattering (CARS) were also performed to gain insight into the high-temperature plasma. An effective electron–ion recombination rate of 2 x 10 -12 cm 3 s -1 was measured at Δt = 0.5–10 µs, during a dynamic plasma expansion and compression. When the shock resides close to the plasma at Δt = 0.5–1 µs, the temperature distributions were found to follow the similarity law.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Photoemission Induced Plasma Breakdown (Update)

Laser-induced photoemission of electrons offers opportunities to trigger and control plasmas and discharges. However, the underlying mechanisms are not sufficiently characterized to be fully utilized. Photoemission is highly nonlinear, achieved through multiphoton absorption, above threshold ionization, photo-assisted tunneling, etc., where the dominant process depends on the work function of the material, photon energy and associated fields, surface heating, background fields, etc. To characterize the effects of photoemission on breakdown, breakdown experiments were performed and interpreted using a 0D plasma discharge circuit model and quantum model of photoemission.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Compact, portable, laser induced fluorescence diagnostic for laboratory plasma sources

As diagnostic groups are increasingly called upon to participate in experimental campaigns at remote facilities, there is a need to develop portable versions of plasma diagnostic systems. One such diagnostic is laser induced fluorescence (LIF). Here, we describe a portable LIF apparatus that eliminates the need for an optical table, beam splitters, and an optical chopper. All of the light exiting the laser system is coupled through optical fibers to the experiment and housekeeping diagnostics. Here, the collected light is coupled through an optical fiber as well. A key feature is modulation of the tapered amplifier current instead of physical modulation of the laser output. Using this portable LIF system, measurements of ion temperature, ion flow, and relative metastable ion density are reported for two different remote experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

In-Situ Laser-Induced-Desorption-Spectroscopy Diagnostic Deployment on the Linear Plasma Device CSDX

A calibrated laser induced desorption diagnostic (LIDS) concept is developed under this award for application to fusion relevant plasma materials interactions studies. Small areal amounts of hydrogenic release from a deuterium filled PMI target are measured and quantified when irradiated by a LID flash heat event on the target surface. Good success was demonstrated by this project with the PISCES-E rf plasma device at UCSD by fully quantified measurement and removal of D from W-D co-deposit layers in experiments. However, adapting the LIDS technique to D plasma exposed W targets in the linear plasma CSDX device, now labelled PISCES-Rf, was prone to several technical challenges ranging from target line of sight access, laser focusing, and loss of optical spectroscopic signal strength in the larger PISCES-Rf vacuum system. The results are summarized in this report.

08 HYDROGEN↗

Laser-Induced Fluorescence Helps Diagnose Plasma Processes

Technique developed to provide in situ monitoring of rates of ion sputter erosion of accelerator electrodes in ion thrusters also used for ground-based applications to monitor, calibrate, and otherwise diagnose plasma processes in fabrication of electronic and optical devices. Involves use of laser-induced-fluorescence measurements, which provide information on rates of ion etching, inferred rates of sputter deposition, and concentrations of contaminants.

Beattie, J. R.↗

Laser-Plasma Spectroscopy of Hydroxyl with Applications

This article discusses laser-induced laboratory-air plasma measurements and analysis of hydroxyl (OH) ultraviolet spectra. The computations of the OH spectra utilize line strength data that were developed previously and that are now communicated for the first time. The line strengths have been utilized extensively in interpretation of recorded molecular emission spectra and have been well-tested in laser-induced fluorescence applications for the purpose of temperature inferences from recorded data. Moreover, new experiments with Q-switched laser pulses illustrate occurrence of molecular recombination spectra for time delays of the order of several dozen of microseconds after plasma initiation. The OH signals occur due to the natural humidity in laboratory air. Centrifugal stretching of the Franck-Condon factors and r-centroids are included in the process of determining the line strengths that are communicated as a Supplementary File. Laser spectroscopy applications of detailed OH computations include laser-induced plasma and combustion analyses, to name but two applications. This work also includes literature references that address various diagnosis applications.

47 OTHER INSTRUMENTATION↗

Plasma sources for advanced semiconductor applications

Semiconductors are the foundation of modern technology, used in our personal, industrial, and military-grade devices. Further, every aspect of U.S. society is closely tied to semiconductors, and our economy cannot progress at the current pace with existing chip manufacturing methods as chip features approach an atomistic scale.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗