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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

IMPACT Project: Integrated Modeling of Perturbations in Atmospheres for Conjunction Tracking - A New Orbital Prediction Model to Avoid Collisions in Space

We are developing a new physics-based satellite drag model to accurately predict satellite paths and to prevent collisions in space. Institutional Computing resources have been used to develop a data assimilative thermospheric density model and employ Direct Simulation Monte Carlo calculations of the satellite drag coefficient.

99 GENERAL AND MISCELLANEOUS↗

Reductions without Regret: Avoiding Wrong Turns, Roach Motels, and Box Canyons

This is the third of three papers (in addition to an introductory summary) aimed at providing a framework for evaluating future reductions or modifications of the U.S. nuclear force, first by considering previous instances in which nuclear-force capabilities were eliminated; second by looking forward into at least the foreseeable future at the features of global and regional deterrence (recognizing that new weapon systems currently projected will have expected lifetimes stretching beyond our ability to predict the future); and third by providing examples of past or possible undesirable outcomes in the shaping of the future nuclear force, as well as some closing thoughts for the future. In this paper, we provide one example each of our judgments on what constitutes a box canyon, a roach motel, and a wrong turn: Wrong Turn: The Reliable Replacement Warhead: Roach Motel: SRAM T vs the B61: and A Possible Box Canyon: A Low-Yield Version of the W76 SLBM Warhead. Recognizing that new nuclear missions or weapons are not demanded by current circumstances ₋ a development path that yields future capabilities similar to those of today, which are adequate if not always ideal, and a broader national-security strategy that supports nonproliferation and arms control by reducing the role for, and numbers, of nuclear weapons ₋ we briefly consider alternate, less desirable futures, and their possible effect on the complex problem of regional deterrence. In this regard, we discuss the issues posed by, and possible responses to, three example regional deterrence challenges: in-country defensive use of nuclear weapons by an adversary; reassurance of U.S. allies with limited strategic depth threatened by an emergent nuclear power; and extraterritorial, non-strategic offensive use of nuclear weapons by an adversary in support of limited military objectives against a U.S. ally.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Alternatives to the Maroni Process for Tritium Recovery in Fusion Reactors: Avoiding Volatile Hydrogen Fluoride and High-Temperature High-Speed Rotating Machinery

Fusion reactors now on the drawing table, including LLNL’s LIFE reactor, require liquid lithium blankets for cooling and breeding tritium fuel. The tritium fuel must be continuously removed from the blanket so that it can be returned to the reactor for burning, via target manufacturing in the case of LIFE. The baseline process for accomplishing this in the LIFE reactor is the well-known Maroni process which uses high-temperature molten mixed alkali-metal halide salts (LiCl:LiF:LiBr at 530°C) as an extraction solvent. With the generation of hydrogen isotopes, liquid and gaseous acids such as HCl, HF and HBr (and the deuterium and tritium analogs) form in the salt phase, making these solvents very corrosive, with other problems due to volatility. Following extraction of lithium tritide from the molten lithium, the tritide anion must undergo electrochemical oxidation in a high-temperature electrochemical cell to form tritium gas, which can then be separated by stripping in a stream of inert gas such as xenon or helium. The volatility of hydrogen chloride or the tritium analog (HCl or TCl), hydrogen fluoride or the tritium analog (HF or TF) and hydrogen bromide or the tritium analog (HBr or TBr) complicate this separation. An alternative electrolytic process for the conversion of lithium tritide to tritium gas and metallic lithium is based upon the use of a benign lithium hydroxide (LiOH) or lithium carbonate (Li 2 CO 3 ), which is an extremely attractive alternative to the very volatile and corrosive lithium halide electrolyte. The separation of the molten lithium and molten chloride salt phases requires numerous high-temperature (530°C) high-speed centrifugal separators, with bearings and seals exposed to the highly corrosive fluids. Currently, centrifugal contactors are proposed to contact the liquid lithium in which the tritium is bred with a molten salt extraction solvent. These high-speed centrifugal contactors must operate at high temperature for prolonged periods of time without failure. Such rotating machinery, with a highly corrosive molten salt electrolyte, and a liquid lithium phase threatening liquid metal embrittlement is a source of substantial concern. The invention disclosed here is a non-centrifugal contactor capable of operating without any moving parts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

IMPACT Project Integrated Modeling of Perturbations in Atmospheres for Conjunction Tracking: A New Orbital Prediction Model to Avoid Collisions in Space [Slides]

We are developing a new physics-based satellite drag model to accurately predict satellite paths and to prevent collisions in space. Institutional Computing resources have been used to develop a data assimilative thermospheric density model. Resources have also been employed in Direct Simulation Monte Carlo calculations of the satellite drag coefficient. First results include the Ensemble Kalman Filter method used to estimate the coupling between solar drivers. Results also include thermospheric density changes and first self-consistent drag coefficients calculations using the physics based and assimilative thermosphere model.

58 GEOSCIENCES↗

Initial Development of an Improved Creep-Fatigue Design Method that Avoids the Separate Evaluation of Creep and Fatigue Damage and Eliminates the Requirement for Stress Classification

This report describes a method for capturing the effect of strain range, temperature, hold time, and elastic follow up on the cyclic life of a material undergoing uniaxial load. Developing design correlations of this type requires methods for extrapolating experimental data as a function of hold time and follow up factor. Various extrapolation methods are developed and discussed here and recommendations are developed for the final approaches to be adopted for design use. The report also describes comparisons between the new creep-fatigue design method, described here, and current creep-fatigue design methods in the ASME Boiler and Pressure Vessel Code and associated nuclear Code Cases. These comparisons demonstrate several advantages of the new method: it is easier to execute and is less over conservative than many current approaches. This report, along with a companion on extending these results to multiaxial load and on combining load cycles, represents the accumulation of several years of work on the development of this new approach to creep-fatigue design, combining an elastic perfectly plastic analysis method with simplified model tests measuring the effect of elastic follow up on creep-fatigue cyclic life. The conclusions to this report describe a path forward to developing the required design data for high temperature advanced reactor structural materials and guiding the adoption of the new method in the ASME Boiler and Pressure Vessel Code and related standards.

36 MATERIALS SCIENCE↗

Drone Video Platform—Collision Avoidance, Situational Awareness, and Communications

Small unmanned aerial systems are ideal for delivering sensors into areas that are inaccessible or too dangerous for human entry or manned aircraft over-flights. The systems can fly low and slow for enhanced sensitivity and in tight spaces where ordinary aircraft could never fit. We have configured and flown sensor payloads for radiation, chemical, and optical detection on small fixed-wing and rotary-wing aircraft. All the sensor packages provide telemetry, GPS coordinates, LIDAR distance ranging, and absolute time of day to microsecond accuracy. Payload weights range from less than 1 kg up to 5.5 kg. Currently, communications are over 2.4 GHz and 915 MHz radios, as well as over 4G LTE cellular data links. Real-time data feeds from the sensor payloads to web browser clients anywhere in the world are possible via a virtual EC2 server on the Amazon AWS cloud. In FY 2019, the Nevada National Security Site teamed with Virginia Tech, H3D Corp., and Unmanned Systems, Inc. to accomplish the four flight missions described in this report. A large part of this year’s mission goals were to demonstrate the ability to fly beyond visual line of sight (BVLOS).

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Avoid Procuring or Storing 2-Propanol in Opaque White, Clear Containers

One of the most important responsibilities chemical owners at Los Alamos National Laboratory (LANL) have is to ensure the safety of the chemicals they own. An important consideration is how chemicals react to their environment. In the case of 2-propanol, a common solvent found in research laboratories used often in manufacturing and analytical processes, it can develop peroxides with exposure to light. 2-Propanol is classified as a Group B (class 3) peroxide-forming solvent. However, there is a dearth of literature that summarizes the risks surrounding peroxide formation in 2-propanol (IPA), leading to a lack of awareness of these hazards in the chemistry community.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Storage Effectiveness in Enabling Variable Generation and Avoiding Fossil Emissions

In this paper, we investigate the relationship between storage and variable generation (VG) and how they can be used to replace fossil-fired technologies and their associated emissions. Unlike fossil generation, VG relies on variable resources (wind, solar, etc.), and the timing of these resources does not always match system needs, creating challenges both in terms of when energy is delivered and the reliability of that delivery. These challenges are typically addressed in one of two ways: paring VG with storage to provide firmed, time-shiftable energy or by building additional VG throughout an interconnection so that adequate amounts of VG are always available. The choice of how much to build of each (storage and VG) is typically an economic one. In this work, we focus on the former case - investigating the role of storage in bringing renewables onto the grid.

13 HYDRO ENERGY↗

Exploring uranium oxidation in glue vapor to help avoid catastrophic slivers on NIF targets

Depleted uranium (DU) hohlraums are utilized for indirect drive fusion experiments at Lawrence Livermore National Laboratory. The production process for DU hohlraums is intricate, involving complex sputtering, machining, and leaching techniques. Achieving low-stress and defect-free hohlraums presents significant challenges. Recent failures have revealed that some uranium flakes, known as slivers, detach from the diagnostic windows and fall onto the capsule. These catastrophic failures were observed only after target assembly, leading to the hypothesis that oxidation of the DU by glue vapor might be the cause. A study investigating the impact of glue vapor on DU hohlraums found that spallation occurred in three out of seven sample hohlraums after three weeks. The slivers observed in these samples were consistent with those seen in assembled targets. This marks the first experimental reproduction of such catastrophic slivering failures. Consequently, future studies can now focus on sliver mitigation and the precise diagnosis of the failure mode.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Avoiding symmetry roadblocks and minimizing the measurement overhead of adaptive variational quantum eigensolvers

Quantum simulation of strongly correlated systems is potentially the most feasible useful application of near-term quantum computers. Minimizing quantum computational resources is crucial to achieving this goal. A promising class of algorithms for this purpose consists of variational quantum eigensolvers (VQEs). Among these, problem-tailored versions such as ADAPT-VQE that build variational ansätze step by step from a predefined operator pool perform particularly well in terms of circuit depths and variational parameter counts. However, this improved performance comes at the expense of an additional measurement overhead compared to standard VQEs. Here, we show that this overhead can be reduced to an amount that grows only linearly with the number n of qubits, instead of quartically as in the original ADAPT-VQE. We do this by proving that operator pools of size 2 n − 2 can represent any state in Hilbert space if chosen appropriately. We prove that this is the minimal size of such "complete" pools, discuss their algebraic properties, and present necessary and sufficient conditions for their completeness that allow us to find such pools efficiently. We further show that, if the simulated problem possesses symmetries, then complete pools can fail to yield convergent results, unless the pool is chosen to obey certain symmetry rules. We demonstrate the performance of such symmetry-adapted complete pools by using them in classical simulations of ADAPT-VQE for several strongly correlated molecules. Our findings are relevant for any VQE that uses an ansatz based on Pauli strings.

Shkolnikov, V. O.↗