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FY19 Report for Instrumentation Development for the Transient Testing Program

This report details the technical activities and accomplishment carried out under funding from the Department of Energy (DOE) Nuclear Technology Research and Development (NTRD) program for in-pile instrumentation supporting the transient testing program in FY19. These activities were performed in support of cross-cutting transient testing experiment objectives. The purpose of this report is to provide a summary of key technical work, of particular interest to nuclear irradiation test experimenters and in-pile instrumentation engineers. During FY19, development activities are focused on deployment of devices to perform online measurement of neutron flux, temperature, and mechanical behaviors in nuclear fuels experiments. Specifically, these R&D activities include in-pile investigations at the Transient Reactor Test (TREAT) facility throughout the year. Other in-pile instrumentation R&D activities are being carried out under other DOE programs, which may be recognized but not the focus of this document. A brief summary of activities and accomplishments is first provided for each major activity. More detailed summaries are presented in appendices.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Simultaneous Momentum and Position Measurement and the Instrumental Weyl-Heisenberg Group

The canonical commutation relation, [Q,P]=iℏ, stands at the foundation of quantum theory and the original Hilbert space. The interpretation of P and Q as observables has always relied on the analogies that exist between the unitary transformations of Hilbert space and the canonical (also known as contact) transformations of classical phase space. Now that the theory of quantum measurement is essentially complete (this took a while), it is possible to revisit the canonical commutation relation in a way that sets the foundation of quantum theory not on unitary transformations but on positive transformations. This paper shows how the concept of simultaneous measurement leads to a fundamental differential geometric problem whose solution shows us the following. The simultaneous P and Q measurement (SPQM) defines a universal measuring instrument, which takes the shape of a seven-dimensional manifold, a universal covering group we call the instrumental Weyl-Heisenberg (IWH) group. The group IWH connects the identity to classical phase space in unexpected ways that are significant enough that the positive-operator-valued measure (POVM) offers a complete alternative to energy quantization. Five of the dimensions define processes that can be easily recognized and understood. The other two dimensions, the normalization and phase in the center of the IWH group, are less familiar. The normalization, in particular, requires special handling in order to describe and understand the SPQM instrument.

47 OTHER INSTRUMENTATION↗

The Mars Exploration Rover Instrument Positioning System

During Mars Exploration Rover (MER) surface operations, the scientific data gathered by the in situ instrument suite has been invaluable with respect to the discovery of a significant water history at Meridiani Planum and the hint of water processes at work in Gusev Crater. Specifically, the ability to perform precision manipulation from a mobile platform (i.e., mobile manipulation) has been a critical part of the successful operation of Spirit and Opportunity rovers. As such, this paper describes the MER Instrument Positioning System that allows the in situ instruments to operate and collect their important science data using a robust, dexterous robotic arm combined with visual target selection and autonomous software functions.

in situ instruments↗

Self-Supplied Liquid Injection Field Desorption/Ionization Ion Source for an Orthogonal Time-of-Flight Instrument

A new implementation of a dedicated ion source for field ionization (FI), field desorption (FD), and liquid injection field desorption/ionization (LIFDI) for the JEOL AccuTOF GC series of orthogonal-acceleration time-of-flight instruments is presented. In contrast to existing implementations, this third-party LIFDI probe and source combination does not require the exchange of the entire ion source comprising ion source block and lens stack to switch from electron ionization (EI) to LIFDI. Rather, the methods may be swapped conveniently by only exchanging the ion source block for a mechanical probe guide and inserting the LIFDI probe in place of the standard direct insertion probe (DIP) via the vacuum lock. Further, this LIFDI setup does not require any changes of the electronics or software of the AccuTOF mass spectrometer because it is self-supplied in terms of power supply, observation optics, and computer control. The setup offers advanced FI/FD/LIFDI control features such as emission-controlled emitter heating current and emitter flash baking during elongated runs as required for gas chromatography-FI-mass spectrometry (MS). The LIFDI source and probe and its operation are reported in detail. FI spectra of the volatile analytes toluene, heptane, and pentafluoroiodobenzene are presented. LIFDI operation is demonstrated for the analysis of the saturated hydrocarbon dotriacontane and the low-mass hydrocarbon polymers polystyrene 484 and polystyrene 1050. Further, the air-sensitive 2nd-generation Hoveyda–Grubbs catalyst is analyzed by LIFDI-MS. For comparison with long-established LIFDI instrumentation, some of the spectra obtained with the new setup are also compared with those from a double-focusing magnetic sector instrument. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Hedonic Price Estimates of Lake Water Quality: Valued Attribute, Instrumental Variables, and Ecological-Economic Benefits

We estimate the effect of lake water quality on residential housing prices using cross-sectional data on water clarity from 113 lakes across the United States. An instrumental-variables approach is developed to address potential endogeneity bias in the water-clarity variable. Three lake-based physical variables serve as instrumental variables: total nitrogen concentration in lake water, total phosphorus concentration in lake water, and water temperature near the lake surface. The econometric results include three methodological findings: the instruments are valid and strong; the ordinary-least-squares estimate of the coefficient on the water-clarity variable is unbiased; and water clarity is the attribute of water quality valued in the housing market. The estimated water-clarity effect shows that a one-tenth of a meter change in water clarity leads to a one-percent change in housing price, or an elasticity of 0.20 at mean clarity. Coupling this effect with estimates of an ecological production function, a lake-specific benefit index is developed that shows the effect on housing values of bringing lakes into compliance with the US Environmental Protection Agency's regional recommendations for phosphorous concentration in lake waters.

54 ENVIRONMENTAL SCIENCES↗

The LAMP instrument at the Linac Coherent Light Source free-electron laser

The Laser Applications in Materials Processing (LAMP) instrument is a new end-station for soft X-ray imaging, high-field physics, and ultrafast X-ray science experiments that is available to users at the Linac Coherent Light Source (LCLS) free-electron laser. While the instrument resides in the Atomic, Molecular and Optical science hutch, its components can be used at any LCLS beamline. The end-station has a modular design that provides high flexibility in order to meet user-defined experimental requirements and specifications. The ultra-high-vacuum environment supports different sample delivery systems, including pulsed and continuous atomic, molecular, and cluster jets; liquid and aerosols jets; and effusive metal vapor beams. It also houses movable, large-format, high-speed pnCCD X-ray detectors for detecting scattered and fluorescent photons. Multiple charged-particle spectrometer options are compatible with the LAMP chamber, including a double-sided spectrometer for simultaneous and even coincident measurements of electrons, ions, and photons produced by the interaction of the high-intensity X-ray beam with the various samples. Here in this paper we describe the design and capabilities of the spectrometers along with some general aspects of the LAMP chamber and show some results from the initial instrument commissioning.

47 OTHER INSTRUMENTATION↗

Calibration of a neutron time-of-flight detector with a rapid instrument response function for measurements of bulk fluid motion on OMEGA

A newly developed neutron time-of-flight (nTOF) diagnostic with a fast instrument response function has been fielded on the OMEGA laser in a highly collimated line of sight. In this study, by using a small plastic scintillator volume, the detector provides a narrow instrument response of 1.7 ns full width at half maximum while maintaining a large signal-to-noise ratio for neutron yields between 10 10 and 10 14 . The OMEGA hardware timing system is used along with an optical fiducial to provide an absolute nTOF measurement to an accuracy of ~56 ps. The fast instrument response enables the accurate measurement of the primary deuterium-tritium neutron peak shape, while the optical fiducial allows for an absolute neutron energy measurement. The new detector measures the neutron mean energy with an uncertainty of ~7 keV, corresponding to a hot-spot velocity projection uncertainty of ~12 km/s. Finally, evidence of bulk fluid motion in cryogenic targets is presented with measurements of the neutron energy spectrum.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Angular scattering of protons through ultrathin graphene foils: Application for time-of-flight instrumentation

Space plasma instruments often rely on ultrathin carbon foils for incident ion detection, time-of-flight (TOF) mass spectrometry, and ionization of energetic neutral atoms. Angular scattering and energy loss of ions or neutral atoms in the foil can degrade instrument performance, including sensitivity and mass resolution; thus, there is an ongoing effort to manufacture thinner foils. Using new 3-layer graphene foils manufactured at the Los Alamos National Laboratory, we demonstrate that these are the thinnest foils reported to date and discuss future testing required for application in space instrumentation. We characterize the angular scattering distribution for 3–30 keV protons through the foils, which is used as a proxy for the foil thickness. We show that these foils are ~2.5–4.5 times thinner than the state-of-the-art carbon foils and ~1.6 times thinner than other graphene foils described in the literature. We find that the inverse relationship between angular scattering and energy no longer holds, reaffirming that this may indicate a new domain of beam–foil interactions for ultrathin (few-layer) graphene foils.

47 OTHER INSTRUMENTATION↗

First results from a multiplexed and massive instrument with sub-electron noise Skipper-CCDs

Here, we present a new instrument composed of a large number of sub-electron noise Skipper-CCDs operated with a two stage analog multiplexed readout scheme suitable for scaling to thousands of channels. New, thick, 1.35 Mpix sensors, from a new foundry, are glued into a Multi-Chip Module (MCM) printed circuit board on a ceramic substrate which has 16 sensors each. The instrument, that can hold up-to 16 MCMs, a total of 256 Skipper-CCD sensors (called a Super-Module with ≈ 130 grams of active mass and 346 Mpix), is part of the R&D effort of the OSCURA experiment which will have ≈ 94 super-modules. Experimental results with 10 MCMs and 160 Skipper-CCDs sensors are presented in this paper. This is already the largest ever built instrument with single electron sensitivity CCDs using nondestructive readout, both, in terms of active mass and number of channels.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The Macromolecular Femtosecond Crystallography Instrument at the Linac Coherent Light Source

The Macromolecular Femtosecond Crystallography (MFX) instrument at the Linac Coherent Light Source (LCLS) is the seventh and newest instrument at the world's first hard X-ray free-electron laser. It was designed with a primary focus on structural biology, employing the ultrafast pulses of X-rays from LCLS at atmospheric conditions to overcome radiation damage limitations in biological measurements. It is also capable of performing various time-resolved measurements. The MFX design consists of a versatile base system capable of supporting multiple methods, techniques and experimental endstations. The primary techniques supported are forward scattering and crystallography, with capabilities for various spectroscopic methods and time-resolved measurements. The location of the MFX instrument allows for utilization of multiplexing methods, increasing user access to LCLS by running multiple experiments simultaneously.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

IRIXS: a resonant inelastic X-ray scattering instrument dedicated to X-rays in the intermediate energy range

A new resonant inelastic X-ray scattering (RIXS) instrument has been constructed at beamline P01 of the PETRA III synchrotron. This instrument has been named IRIXS (intermediate X-ray energy RIXS) and is dedicated to X-rays in the tender-energy regime (2.5–3.5 keV). The range covers the L 2,3 absorption edges of many of the 4delements (Mo, Tc, Ru, Rh, Pd and Ag), offering a unique opportunity to study their low-energy magnetic and charge excitations. The IRIXS instrument is currently operating at the Ru L 3 -edge (2840 eV) but can be extended to the other 4d elements using the existing concept. The incoming photons are monochromated with a four-bounce Si(111) monochromator, while the energy analysis of the outgoing photons is performed by a diced spherical crystal analyzer featuring (10$\bar{2}$ lattice planes of quartz (SiO 2 ). A total resolution of 100 meV (full width at half-maximum) has been achieved at the Ru L 3 -edge, a number that is in excellent agreement with ray-tracing simulations.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

2017 Marine Hydrokinetic Instrumentation Workshop Report

The third Marine Hydrokinetic Instrumentation Workshop was held at Florida Atlantic University's Sea Tech Campus in Dania Beach, Florida, from February 28 to March 1, 2017. The workshop brought together 37 experts in marine energy measurement, testing, and technology development to present and discuss the instrumentation and data-processing needs of the marine energy industry. The workshop was comprised of a plenary session followed by two focused breakout sessions. The half-day plenary session reviewed findings from prior instrumentation workshops, presented research activities that aim to fill previously identified gaps, and had industry experts present the state of the marine energy measurement technologies. This report provides further detail on the workshop, objectives, and findings.

16 TIDAL AND WAVE POWER↗

Identifying Suspect Instrument Intervals Using Midnight Noise Time Histories

With an intense work ethic, and high levels of devotion to their craft, seismologists continue to battle the elements and wrestle with complex logistics in their efforts to field instrumentation over the entire globe. We are fortunate to see data volumes accelerating in size, and quality continuing to improve; for example, universal timing issues can now be considered rare. However, instrument response issues are still common, and can hinder research that seeks to understand amplitudes of seismic wavefields. We are interested in using the accumulations of seismic data to develop models that will predict high frequency (0.2-20 Hz, and higher) signal amplitudes for explosion monitoring purposes over broad areas, which requires large data sets and extensive quality control. To identify response and station health issues, we have collected noise time histories for global seismic data, focusing on measurements near (but not restricted to) midnight to eliminate diurnal variations, and have manually determined time intervals that appear inconsistent with background behavior. We assign descriptive labels, but do not attempt to diagnose causes. We use these intervals to discard data. To date, we have examined 39,260 channels from 11,105 stations, heavily weighted toward IRIS holdings, dates through 2017 (depending on station, roughly the date we started our manual review), bands between 1 and 8 Hz, finding 24,733 anomalous time intervals. The great majority (90%) of these intervals appear to be shifts of constant offset, often bounded by times of known instrument changes, likely the result of poor documentation of response parameters at one of many stages between the field and the plotter. We hope these results can be of use to our colleagues, and would encourage community efforts to diagnose anomalous behavior, and fix poor responses. We also hope these results will support automation efforts, including application of supervised learning techniques.

47 OTHER INSTRUMENTATION↗

Qualification and Re-Qualification of NDA Instruments

Non-Destructive Assay (NDA) instruments are a large component of nuclear material (NM) measurement at LANL. Nuclear Material Control and Accountability Group (SAFE-NMCA) personnel in the Safeguards Division are responsible for oversight of the instruments used for material accountability measurements. It is the responsibility of SAFE-NMCA to ensure that all instruments are operating as expected and can produce quality measurements to provide assurance that requirements of the DOE approved NMCA Plan are being met.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The Analysis and Support for LANL Technology Testbed: High Altitude Balloon Gondola and Orion Eagle Gamma Ray Detection Instrument

The Analysis and Support for LANL Technology Testbed: High Altitude Balloon Gondola and Orion Eagle Gamma-Ray Detection Instrument is a project where Los Alamos National Laboratory (LANL), in conjunction with the University of Michigan, are looking into gamma-ray detection in a space-like environment. The purpose of the detection is to work on instruments that can assist with planetary exploration and nuclear deterrents using a High-Altitude Balloon (HAB). For this paper, the main focus is on the mechanical aspects related to the structural analysis of the gondola. It is vital to understand the structural analysis because it helps determine if the gondola can survive the changes in the environment and the different forces or shocks that it will experience when the parachute is deployed and at landing. Additionally, NASA's Balloon Program Office (BPO) has specific requirements to meet to achieve flight certifications. Part of those certifications requires the gondola to simulate different scenarios at specific conditions with various forces applied and orientations. Therefore, it is necessary to adjust the calculations of each method and the force applied to get the right results. Once that is done, the information is inputted into the structural analysis modeling system. The system will aid the mechanical team in assessing the conditions of the gondola at each scenario and determine its margin of safety. After the gondola and instrument are certified, the payload will be able to fly. The HAB and payload are launched from NASA's Columbia Scientific Balloon Facility (CSBF) at Fort Sumner, NM. The official flight was on September 26th, 2021.

42 ENGINEERING↗

Performance Testing of Software Upgrade for SRNL CPC Instrument at the Nuclear Material Laboratory, Office of Safeguards Analytical Services, International Atomic Energy Agency

This report summarizes the performance testing for the Software upgrade for the Savannah River National Laboratory (SRNL) Controlled Potential Coulometry (CPC) instrument. This upgrade is specifically to meet the needs of the Nuclear Material Laboratory, Office of Safeguards Analytical Services, International Atomic Energy Agency at Seibersdorf, Austria. The instrument hardware was upgraded in 2010, but the software continued to operate on a Windows platform using a High Tech Basic (HT Basic) application. HT Basic usage is declining. The IAEA requested an upgrade to the existing coulometer software to Laboratory Virtual Instrument Engineering Workbench (LabVIEW), an object-oriented programming language in wide use and one the NML staff is familiar with. The software was developed by SRNL Software Engineer, with assistance from Electrical Engineer and Scientist. Once developed, the new LabVIEW software was validated, tested with Iron (surrogate for plutonium) and plutonium. Once testing was completed, the software was installed at the International Atomic Energy Agency Nuclear Material Laboratory (IAEA NML) coulometer, and SRNL provided hands on training to NML staff on using the new software.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Safety-Related Instrumentation and Control Pilot Upgrade: Conceptual - Detailed Design Phase Report and Lessons Learned

Historically, regulatory barriers have precluded nuclear plant safety-related (SR) Instrumentation and Control (I&C) system modernizations. These barriers have been largely addressed by industry and United States Nuclear Regulatory Commission (NRC) efforts, including development of the License Amendment Request (LAR) Alternate Review (AR) process for digital I&C upgrades. The U.S. Department of Energy (DOE) and the Idaho National Laboratory (INL) are supporting a SR I&C pilot upgrade at the Limerick Generating Station (LGS) to demonstrate this process and capturing associated lessons learned for the benefit of industry. In 2021, a paper summarizing lessons learned as captured in INL/EXT-20-59809, Safety Related Instrumentation & Control Pilot Upgrade Initial Scoping Phase Implementation Report and Lessons Learned was presented at the 12th NPIC & HMIT conference. It is recommended that readers of this paper review reference 1 or the associated Nuclear Journal paper for context. This paper summarizes activities performed and lessons learned for the conceptual design phase and portions of the detailed design phase as captured in INL/RPT-23-XXXX, “Safety-Related Instrumentation and Control Pilot Upgrade: Conceptual - Detailed Design Phase Report and Lessons Learned.” The portions of the effort covered by reference 2 include conceptual design phase activities from December 2020, through completion in November 2021, and detailed design activities through September 2022. These efforts and associated detailed documentation in reference 3 are intended to support similar industry upgrades as a foundation stone for a Digital Transformation that will improve plant safety, reliability, and operational performance while lowering plant total cost of ownership.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Toward the Instrumentation and Data Acquisition of a Tidal Turbine in Real Site Conditions

The National Renewable Energy Laboratory manufactured, instrumented, and deployed thermoplastic composite blades and a data acquisition system (NDAQ) on one of Verdant Power’s Gen5d 5 m diameter tidal turbines in New York’s East River. The thermoplastic blades had internal strain gages, and the NDAQ was a stand-alone system for monitoring and recording the strain and angular position of the blades. The turbine with thermoplastic blades operated and produced power successfully for 3 months, contributing energy to the New York City electric grid. The NDAQ hardware, instrumentation, and structure all survived the deployment and were still functional upon retrieval of the system, but no data were collected. Even though the data retrieval was not a success, data acquisition for deployed subsea marine renewable structures is a new undertaking, and it is critical to share lessons learned from national laboratory experiences. The successful deployment of thermoplastic composite blades marks a significant advancement toward improved materials for subsea components, as well as an advancement in recyclable composite materials. This article outlines the methodology and lessons learned for the instrumentation and data acquisition system.

16 TIDAL AND WAVE POWER↗