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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

Adaptation to delayed auditory feedback

Delayed auditory feedback disrupts the production of speech, causing an increase in speech duration as well as many articulatory errors. To determine whether prolonged exposure to delayed auditory feedback (DAF) leads to adaptive compensations in speech production, 10 subjects were exposed in separate experimental sessions to both incremental and constant-delay exposure conditions. Significant adaptation occurred for syntactically structured stimuli in the form of increased speaking rates. After DAF was removed, aftereffects were apparent for all stimulus types in terms of increased speech rates. A carry-over effect from the first to the second experimental session was evident as long as 29 days after the first session. The use of strategies to overcome DAF and the differences between adaptation to DAF and adaptation to visual rearrangement are discussed.

Katz, D. I.↗

Evolution of photospheric magnetic field patterns during Skylab

The evolution of the photospheric magnetic-field pattern over eleven solar rotations preceding a minimum of the activity cycle is shown to be characterized by abrupt changes in the dominant geometrical patterns of the field. These changes are associated with the onset and end of a sudden increase in the calculated total energy content of the field, which is otherwise decreasing through the period. The calculated geometrical rearrangements correspond in time to observed restructurings of the corona, the interplanetary field, and the solar rotation pattern.

Levine, R. H.↗

Relating viscosity to polymer concentration

Equation developed by VanDijk and first applied to viscosity of Newtonian suspension of rigid particles by Eilers is rearranged to yield intrinsic viscosity as explicit function of polymer concentration in polymer solvent system. Experiments have shown relationship valid for polymer solutions having relative viscosities ranging from 1 to 100.

Fedors, R. F.↗

Digital data reformatter/deserializer

A method and apparatus is presented for reformatting and de-serializing a serially-received sequence of data words, each consisting of a fixed number of binary data bits. A block of nm bits is serially fed into a shift register or serially-connected group of shift registers. In lieu of the(nm-1)th shifts, the bits are rearranged within the shift register in parallel fashion, according to a prescribed scheme. Shifting then continues, until the first bit of each data word appears in the last bit position in the shift register, at which time that data word is shifted in parallel into an output buffer stage, from which it is outputted in parallel, after a fixed delay.

Engel, A.↗

Reactions of OH/+/ and H2O/+/ ions with some diatomic and simple polyatomic molecules

The rate constants and product distributions of the reactions of OH(+) and H2O(+) with some diatomic and simple polyatomic molecules were studied by ion cyclotron resonance (ICR) mass spectrometric techniques. Reaction rates with CO, NO, O2, N2, CO2, H2S, N2O, H2CO, CH4 and CD4 were measured. Charge transfer and proton transfer were generally observed in cases for which the reaction channel is exothermic, but processes involving rearrangement were not found.

Karpas, Z.↗

Calculation of residual principal stresses in CVD boron on carbon filaments

A three-dimensional finite element model of the chemical vapor deposition of boron on a carbon substrate (B/C) is developed. The model includes an expansion of the boron after deposition due to atomic rearrangement and includes creep of the boron and carbon. Curves are presented showing the variation of the principal residual stresses and the filament elongation with the parameters defining deposition strain and creep. The calculated results are compared with experimental axial residual stress and elongation measurements made on B/C filaments. For good agreement between calculated and experimental results, the deposited boron must continue to expand after deposition, and the build up of residual stresses must be limited by significant boron and carbon creep rates.

Behrendt, D. R.↗

Calculation of residual principal stresses in CVD boron on carbon filaments

A three-dimensional finite element model of the chemical vapor deposition (CVD) of boron on a carbon substrate (B/C) is developed. The model includes an expansion of the boron after deposition due to atomic rearrangement and includes creep of the boron and carbon. Curves are presented to show how the principal residual stresses and the filament elongation vary as the parameters defining deposition strain and creep are varied. The calculated results are compared with experimental axial residual stress and elongation measurements made on B/C filaments. This comparison requires that for good agreement between calculated and experimental results, the deposited boron must continue to expand after deposition, and that the build-up of residual stresses is limited by significant boron and carbon creep rates.

Behrendt, D. R.↗

An experimental study of the effects of swirl and density difference on mixing in shear flow

Experiments were carried out on the mixing of streams with and without swirl and with and without density differences in a coannular geometry. Three variations of flow visualization techniques were used: direct excitation, collisional excitation, and quenching of the tracer. The axial variation of the flow for the case with swirl in the inner annulus is investigated in some detail. From the flow visualization pictures, it is concluded that the initial Helmholtz instability of the tangential shear layer gives rise to small scale peripheral strucutres, then it is possible that the inner swirling stream drives an instability which turns these small scale peripheral structures into ones of larger scale, thereby rearranging the initial vorticity distribution of the flow field. The pictures also indicate the occurrence of interchange of fluid between the annuli. It is also concluded that the interaction of density field with the resulting radial pressure gradient may have influenced the evolution of the flow structures.

Tan, C. S.↗

Documentation for the machine-readable AGK3-BD and BD-AGK3 cross-index catalogues

The machine-readable cross identification catalogs were prepared by extracting AGK3 and BD numbers from the magnetic tape version of the AGK3 Catalog. After preparation of the AGK3-BD file, which contains all stars in the AGK3 catalog, the file was sorted according to BD number and rearranged so that the BD number occurs at the beginning of each record. During the sorting operation, all AGK3 stars having no BD numbers were omitted. The BD-AGK3 file is especially useful for finding BD stars in the AGK3 catalog, since precession has moved stars across declination boundaries and it often was necessary to examine more than one AGK3 zone to locate a BD star in the catalog. The contents of the cross index files is described so that users can read and process the tape without problems, guesswork, or consulting the parent catalog.

Warren, W. H., Jr.↗

Operations of the reconfigured Ground Communications Facility Central Communications Terminal and the Network Operations Control Center

The ground communications facility (GCF) central communications terminal and network operations control center (NOCC) hardware was rearranged, supplemented, and modified, and software programs changed to provide an improved GCF and NOCC operational environment and capability. Control center operations section activities required to make the changeover from the old to the new GCF and NOCC configuration are addressed.

Santana, J. C.↗

Rapid quenching effects in glassy polymers

Using a specially constructed microbalance for hydrostatic weighing, density changes in PVC thin film due to rapid quenching through the glass transition temperature were observed. The more severe the quench, the greater the free volume content. Isobaric volume recovery of PVC was also studied by volume dilatometry. Both show aging of relaxing molecular rearrangements taking place as a linear function of logarithmic aging time at room temperature. Distribution of retardation times and Primak's distributed activation energy spectra were applied to the volume recovery data. The concomitant changes in mechanical properties of PVC after quenching were monitored by tensile creep stress-stran to failure rates. All reflect the presence of excess free volume content due to rapid quenching.

Mcgarry, F. J.↗

Rapid quenching effects in PVC films

Using a specially constructed microbalance for hydrostatic weighing, density changes in PVC thin films (with no additives, 30-100 micrometers thick), due to rapid quenching (approximately 300 C/sec) through the glass transition temperature, have been observed. The more severe the quench, the greater is the free volume content. Isobaric volume recovery of PVC has also been studied by volume dilatometry. Both show aging of relaxing molecular rearrangements takes place as a linear function of logarithmic aging time at room temperature. Distribution of retardation times and Primak's distributed activation energy spectra have been applied to the volume recovery data. The concomitant changes in mechanical properties of PVC after quenching have been monitored by tensile creep and stress-strain to failure. All reflect the presence of excess free volume content, due to rapid quenching.

Lee, H. D.↗

Pyrolysis of Precambrian kerogens - Constraints and capabilities

Precambrian kerogens are currently considered to be the primary candidates for the search of biochemical fossils. Degradation of kerogens by relatively 'mild' pyrolysis techniques, such as under high vacuum, can liberate indicative structural moieties which were incorporated in, and perhaps shielded by, these solid and highly condensed, basically aromatic substances. It is necessary to observe analytical constraints (sample size and shape, temperature, pressure, time, etc.) in order to prevent an overabundant yield of secondary pyrolyzates (inter- and intramolecular rearrangements) which can prevent kerogen characterization. Potential biochemical fossils have been found in Precambrian kerogens. Demonstratable syngenetic biochemical fossils are expected after kerogen diagenesis and catagenesis is understood in sufficient detail, and when pyrolysis is augmented by multiple, improved analytical techniques.

Nagy, B.↗

The rotational spectra of HCNH/+/ and COH/+/ from quantum mechanical calculations

A description is provided of ab initio molecular orbital calculations designed to provide accurate predictions for the J = 1 to 0 rotational line of the candidate interstellar molecules HCNH(+) and COH(+). The former is believed to be important in the formation of both HCN and HNC in the interstellar medium. The latter, a metastable isomer of HCO(+), was first proposed as an interstellar molecule by Herbst et al. (1976). Attention is given to thermochemical arguments that this molecule can be formed in the same reactions which are proposed to form HCO(+), taking into account theoretical data which establish its stability to intramolecular rearrangement. Rotational constants are derived by applying an empirical correction to the ab initio rotational constants.

Defrees, D. J.↗

The intracellular responses of frog eggs to novel orientations to gravity

It is found that multiple short doses of ultraviolet light are as effective as a single large dose in producing neural defects. In addition, 180 deg rotation (inversion) of irradiated eggs reduces the ultraviolet effect. Since yolk platelets may be the gravity sensing mechanism, their size, density, and distribution in normal and inverted eggs are investigated. Large platelets are denser and for the most part are in a distinct zone in the vegetal hemisphere, whereas small platelets are less dense and occur in the animal hemisphere. When inverted, the large platelets flow into the animal hemisphere as a coherent mass and partially displace the small platelets. Inversion is thought to rearrange cytoplasmic components necessary for later neural development into an appropriate configuration.

Radice, G. P.↗

Formation of the thioester, N-acetyl, S-lactoylcysteine, by reaction of N-acetylcysteine with pyruvaldehyde in aqueous solution

N-acetylcysteine reacts efficiently with pyruvaldehyde (methylglyoxal) in aqueous solution (pH 7.0) in the presence of a weak base, like imidazole or phosphate, to give the thioester, N-acetyl, S-lactoylcysteine. Reactions of 100 mM N-acetylcysteine with 14 mM, 24 mM and 41 mM pyruvaldehyde yield, respectively, 86%, 76% and 59% N-acetyl, S-lactoylcysteine based on pyruvaldehyde. The decrease in the percent yield at higher pyruvaldehyde concentrations suggests that during its formation the thioester is not only consumed by hydrolysis, but also by reaction with some substance in the pyruvaldehyde preparation. Indeed, purified N-acetyl, S-lactoylcysteine disappears much more rapidly in the presence of pyruvaldehyde than in its absence. Presumably, N-acetyl, S-lactoylcysteine synthesis occurs by rearrangement of the hemithioacetal of N-acetylcysteine and pyruvaldehyde. The significance of this pathway of thioester formation to molecular evolution is discussed.

Weber, A. L.↗

A heuristic mathematical model for the dynamics of sensory conflict and motion sickness

The etiology of motion sickness is explained in terms of a qualitatively formulated sensory conflict hypothesis. By consideration of the information processing task faced by the central nervous system in estimating body spatial orientation and in controlling active body movement using an internal model referenced control strategy, a mathematical model for sensory conflict generation is developed. The model postulates a major dynamic functional role for sensory conflict signals in movement control, as well as in sensory-motor adaptation. It accounts for the role of active movement in creating motion sickness symptoms in some experimental circumstances, and in alleviating them in others. The relationship between motion sickness produced by sensory rearrangement and that resulting from external motion disturbances is explicitly defined. A nonlinear conflict averaging model is proposed which describes dynamic aspects of experimentally observed subjective discomfort sensation, and suggests resulting behaviors.

Oman, C. M.↗

A heuristic mathematical model for the dynamics of sensory conflict and motion sickness

The etiology of motion sickness is now usually explained in terms of a qualitatively formulated sensory conflict hypothesis. By consideration of the information processing task faced by the central nervous system in estimating body spatial orientation and in controlling active body movement using an internal model referenced control strategy, a mathematical model for sensory conflict generation is developed. The model postulates a major dynamic functional role for sensory conflict signals in movement control, as well as in sensory motor adaptation. It accounts for the role of active movement in creating motion sickness symptoms in some experimental circumstances, and in alleviating them in others. The relationship between motion sickness produced by sensory rearrangement and that resulting from external motion disturbances is explicitly defined. A nonlinear conflict averaging model describes dynamic aspects of experimentally observed subjective discomfort sensation, and suggests resulting behavior.

Oman, C. M.↗