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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Energy Harvesting RMSA Field Test

Sandia National Laboratories (SNL) is investigating photovoltaic (PV) cell configurations, integrating them with the battery-operated Remotely Monitored Sealing Array (RMSA), and testing and evaluating performance for enhanced battery life under various environmental conditions at the K-Area Material Storage (KAMS) facility at the Savannah River Site (SRS). Unattended safeguards equipment (e.g. seals) incorporates many low-power electronic circuits, which are often powered by expensive and environmentally toxic lithium batteries. These batteries must periodically be replaced, adding a radiological hazard for both safeguards inspectors and operators. An extended field test of these prototype PV energy harvesting (EH) RMSAs at an operational nuclear facility will give additional data and allow for an analysis of this technology in a variety of realistic conditions, which will be documented in a final report. RMSAs are used for this testing, but SNL envisions energy harvesting technology may be applicable to other safeguards equipment.

14 SOLAR ENERGY↗
DOE OSTI2019

Energy Harvesting Remotely Monitored Sealing Array (RMSA) (Field Test Annual Report)

Sandia National Laboratories (SNL) is investigating photovoltaic (PV) cell configurations, integrating them with the battery-operated Remotely Monitored Sealing Array (RMSA), and testing and evaluating performance for enhanced battery life under various lighting conditions at a facility at the Savannah River Site (SRS) or Savannah River National Laboratory (SRNL). Unattended safeguards equipment (e.g. seals) incorporates many low-power electronic circuits, which are often powered by expensive and environmentally toxic lithium batteries. These batteries must periodically be replaced, adding a radiological hazard for both safeguards inspectors and operators. An extended field test of these prototype PV energy harvesting (EH) RMSAs at an operational nuclear facility will give additional data and allow for an analysis of this technology in a variety of realistic conditions, which will be documented in a final report. RMSAs are used for this testing, but SNL envisions energy harvesting technology may be applicable to additional safeguards equipment.

14 SOLAR ENERGY↗
DOE OSTI2016

Profiling Photoinduced Carrier Generation in Semiconductor Microwire Arrays via Photoelectrochemical Metal Deposition

Au was photoelectrochemically deposited onto cylindrical or tapered p-Si microwires on Si substrates to profile the photoinduced charge-carrier generation in individual wires in a photoactive semiconductor wire array. Similar experiments were repeated for otherwise identical Si microwires doped to be n-type. The metal plating profile was conformal for n-type wires, but for p-type wires was a function of distance from the substrate and was dependent on the illumination wavelength. Spatially resolved charge-carrier generation profiles were computed using full-wave electromagnetic simulations, and the localization of the deposition at the p-type wire surfaces observed experimentally correlated well with the regions of enhanced calculated carrier generation in the volumes of the microwires. Finally, this technique could potentially be extended to determine the spatially resolved carrier generation profiles in a variety of mesostructured, photoactive semiconductors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Pyroelectricity of Lead Sulfide (PbS) Quantum Dot Films Induced by Janus-Ligand Shells

Asymmetry is an essential property to control. To do that in nanocrystalline systems we have developed methods to produce Janus-ligand shells on otherwise symmetric PbS quantum dots (QDs). In this work, we demonstrate that control by constructing a system that exhibits pyroelectricity built from spherical PbS QDs. We observed a pyroelectric current in two different configurations. In one configuration, the QDs are self-assembled into close-packed arrays while in the second configuration, the QDs are dispersed into an electro-inactive polymer, polydimethylsiloxane. Both exhibit a pyroelectric response. In the first configuration we estimate a lower limit of the pyroelectric coefficient to be 1.97 × 10 -7 C/m 2 K, which is likely limited by the degree of QD alignment during film formation but is already on par with common pyroelectric systems. Compared with inorganic ceramic-like and polymeric pyroelectric materials, pyroelectric films self-assembled from polar QDs are easier to prepare, responsive to light with different energies based on QD exciton energy, and the polarization of each QD could be easily tuned by constructing different Janus-ligand shells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Comparing Outdoor to Indoor Performance for Bifacial Modules Affected by Polarization-Type Potential-Induced Degradation

Bifacial photovoltaic (PV) modules have the advantage of using light reflected off of the ground to contribute to power production. Predicting the energy gain is challenging and requires complex models to do so accurately. Often, module degradation over time is neglected in models for the sake of simplicity or is underestimated. Comparing outdoor and indoor current–voltage (I–V) performance for bifacial modules is more challenging than for monofacial modules, as there are additional variables to consider such as rear albedo non-uniformity, cell mismatch, and their effects on temperature. This challenge is compounded when heterogeneous degradation modes occur, such as polarization-type potential-induced degradation (PID-p). To examine the effects of PID-p on I–V predictions using an empirical data-driven approach, 16 bifacial PERC modules are installed outdoors on racks with different albedo conditions. A subset is exposed to high-voltage biases of −1500 V or +1500 V. Outdoor data are traced at irradiance ranges of 150–250 W/m 2 , 500–600 W/m 2 , and 900–1000 W/m 2 . These curves are corrected using control module temperature, wire resistivity, and module resistance measured indoors. We examine several methods to transform indoor I–V curves to accurately, and more simply than existing methods, approximate outdoor performance for bifacial modules without and with varying levels of PID-p degradation. This way, bifacial performance modeling can be more accessible and informed by fielded, degraded modules. Distributions of percent errors between indoor and outdoor performance parameters and Mean Absolute Percent Errors (MAPEs) are used to assess method quality. Results including low-irradiance data (150–250 W/m 2 ) are discussed but are filtered for quantifying method quality as these data introduce substantial errors. The method with the most optimal tradeoff between low MAPE and analysis simplicity involves measuring the front side of a module indoors at an irradiance equal to plane-of-array irradiance plus the product of module bifaciality and albedo irradiance. This method gives MAPE values of 1–6.5% for non-degraded and 1.6–5.9% for PID-p degraded module performance.

14 SOLAR ENERGY↗
DOE OSTI2017

The detection of an extremely bright fast radio burst in a phased array feed survey

We report the detection of an ultra-bright fast radio burst (FRB) from a modest, 3.4-day pilot survey with the Australian Square Kilometre Array Pathfinder. The survey was conducted in a wide-field fly’s-eye configuration using the phased-array-feed technology deployed on the array to instantaneously observe an effective area of 160 deg{sup 2}, and achieve an exposure totaling 13200 deg{sup 2} hr . We constrain the position of FRB 170107 to a region 8{sup ′}×8{sup ′} in size (90% containment) and its fluence to be 58 ± 6 Jy ms. The spectrum of the burst shows a sharp cutoff above 1400 MHz, which could be due to either scintillation or an intrinsic feature of the burst. This confirms the existence of an ultra-bright (>20 Jy ms) population of FRBs.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Blind photovoltaic modeling intercomparison: A multidimensional data analysis and lessons learned

The Photovoltaic (PV) Performance Modeling Collaborative (PVPMC) organized a blind PV performance modeling intercomparison to allow PV modelers to blindly test their models and modeling ability against real system data. Measured weather and irradiance data were provided along with detailed descriptions of PV systems from two locations (Albuquerque, New Mexico, USA, and Roskilde, Denmark). Participants were asked to simulate the plane-of-array irradiance, module temperature, and DC power output from six systems and submit their results to Sandia for processing. The results showed overall median mean bias (i.e., the average error per participant) of 0.6% in annual irradiation and –3.3% in annual energy yield. While most PV performance modeling results seem to exhibit higher precision and accuracy as compared to an earlier blind PV modeling study in 2010, human errors, modeling skills, and derates were found to still cause significant errors in the estimates.

14 SOLAR ENERGY↗
DOE OSTI2021

Striving to translate shale physics across ten orders of magnitude: What have we learned?

Shales will play an important role in the successful transition of energy from fossil-based resources to renewables in the coming decades. Aside from being a significant source of low-carbon intensity fuels, like natural gas, they also serve as geologic seals of subsurface formations that may be used to isolate nuclear waste, sequester CO 2 , or store intermittent energy (e.g., solar hydrogen). Despite their importance, shales pose significant engineering and environmental challenges due to their nanoporous structure and extreme heterogeneity that spans at least ~10 orders of magnitude in spatial scale. Two challenges inhibit a system-level understanding: (1) the physics of fluid flow and phase behavior in shales are poorly understood due to the dominant molecular interactions between minerals and fluids under confinement, and (2) the apparent lack of scale separation that prevents a reliable (closed) description of the physics at any single scale of observation. In this review, we focus on the latter issue and discuss scale translation, which in its broadest sense is transforming data or simulations from one spatiotemporal scale to another. While effective scale translation is not exclusive to shales, but all geologic porous media, the need for it is especially acute in shales given their high degree of heterogeneity. Classical theories like homogenization, while indispensable, fail when scales are not separated. Other methods, like numerical upscaling, scale-translate in only one direction: small to large, but not the reverse, called downscaling. However, the confluence of advances in three areas are bringing challenging problems such as shales within reach: increased computational power and scalable algorithms; high-resolution imaging and multi-modal data acquisition; and machine learning to process massive amounts of data. While these advances equip geoscientists with a wide array of experimental and computational tools, no individual tool can probe the entire gamut of heterogeneity in shales. Their effective use, therefore, requires an ability to bridge between various data types obtained at different scales. The aim of this review is to present a coherent account of computational and experimental methods that may be used to achieve just that, i.e., to perform scale translation. We provide a broader definition of scale translation, one that transcends classical homogenization and upscaling methods, but is consistent with them and accommodates notions like downscaling and data translation. After a brief introduction to homogenization, we review hybrid methods, numerical upscaling and its recent extensions, multiscale computing, high-resolution imaging, and machine learning. We place particular emphasis on multiscale computing and propose an algorithmic framework to bridge between the pore (micro) and Darcy (macro) scales. Throughout the paper, we draw comparisons between the various methods and highlight their (often hidden) similarities, differences, benefits, and pitfalls. We finally conclude with two case studies on shales that exemplify some of the methods presented.

58 GEOSCIENCES↗
DOE OSTI2017

Probing the Spinning of the Massive Black Hole in the Galactic Center via Pulsar Timing: A Full Relativistic Treatment

Pulsars around the massive black hole (MBH) in the Galactic center (GC) are expected to be revealed by upcoming facilities (e.g., the Square Kilometer Array). Under a full relativistic framework with the pulsar approximated as a test particle, we investigate the constraints on the spinning of the MBH by monitoring the timing of surrounding pulsars. For GC pulsars orbiting closely around the MBH (e.g., ≲1000 au), we find that full relativistic treatment in modeling accurately their timing signals can be necessary, as the relativistic signals are orders of magnitude larger than the time-of-arrival measurement accuracies. Although usually there are near degeneracies among MBH spin parameters, the constraints on the spinning of the MBH are still very tight. By continuously monitoring a normal pulsar in orbits with a period of ∼2.6 yr and an eccentricity of 0.3–0.9 under a timing precision of 1–5 ms, within ∼8 yr the spin magnitude and the orientations of the GC MBH can be constrained with 2σ error of 10{sup −3}--10{sup −2} and 10{sup −1}--10{sup 0}, respectively. Even for pulsars in orbits similar to the detected star S2/S0-2 or S0-102, we find that the spinning of the MBH can still be constrained within 4–8 yr, with the most significant constraints provided near the pericenter passage. If the proper motion of the pulsars with astrometric accuracy of 10 μas can also be collected along with the timing measurement, then the position, velocity, mass, and distance to the solar system of the MBH can be constrained to ∼10 μas, ∼1 μas yr{sup −1}, ∼10 M{sub ⊙}, and ∼1 pc, respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Field-Array Benchmark of Commercial Bifacial PV Technologies with Publicly Available Data

We present results for a 75-kW field array deployed with rows of 5 different commercially available bifacial technologies. Four PERC (multi and mono) and 1 Silicon Heterojunction manufacturers are represented. Reference strings of equivalent monofacial PV modules are also installed in the 10-row field. High accuracy string-level DC monitoring and module-level measurements have been recorded for six months. Analysis indicates performance within expectation, with a cumulative model mean error within +/- 2% for both bifacial and monofacial models and cumulative bifacial energy gain between 6-9%. A custom-module to measure shading loss from the torque-tube was installed. One month data shows up to 6% irradiance non-uniformity. A fixed-tilt test-site with 3 years of bifacial data is also presented, with a bifacial gain of 3%.

41 EE - Solar Energy Technologies Office (EE-4S)↗
DOE OSTI2015

New measurements of the radio photosphere of Mira based on data from the JVLA and ALMA

We present new measurements of the millimeter wavelength continuum emission from the long period variable Mira (o Ceti) at frequencies of 46, 96, and 229 GHz (λ≈7, 3, and 1 mm) based on observations obtained with the Jansky Very Large Array (JVLA) and the Atacama Large Millimeter/submillimeter Array (ALMA). The measured millimeter flux densities are consistent with a radio photosphere model derived from previous observations, where flux density S{sub ν}∝ν{sup 1.86}. The stellar disk is resolved, and the measurements indicate a decrease in the size of the radio photosphere at higher frequencies, as expected if the opacity decreases at shorter wavelengths. The shape of the radio photosphere is found to be slightly elongated, with a flattening of ∼10%–20%. The data also reveal evidence for brightness non-uniformities on the surface of Mira at radio wavelengths. Mira’s hot companion, Mira B was detected at all three observed wavelengths, and we measure a radius for its radio-emitting surface of ≈2.0×10{sup 13} cm. The data presented here highlight the power of the JVLA and ALMA for the study of the atmospheres of evolved stars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Hierarchical Inorganic Assemblies for Artificial Photosynthesis

Artificial photosynthesis is an attractive approach for renewable fuel generation because it offers the prospect of a technology suitable for deployment on highly abundant, non-arable land. Recent leaps forward in the development of efficient and durable light absorbers and catalysts for oxygen evolution and the growing attention to catalysts for carbon dioxide activation brings into focus the tasks of hierarchically integrating the components into assemblies for closing of the photosynthetic cycle. A particular challenge is the efficient coupling of the multi-electron processes of CO 2 reduction and H 2 O oxidation. Among the most important requirements for a complete integrated system are catalytic rates that match the solar flux, efficient charge transport between the various components, and scalability of the photosynthetic assembly on the unprecedented scale of terawatts in order to have impact on fuel consumption. To address these challenges, we have developed in this paper a heterogeneous inorganic materials approach with molecularly precise control of light absorption and charge transport pathways. Oxo-bridged heterobinuclear units with metal-to-metal charge-transfer transitions absorbing deep in the visible act as single photon, single charge transfer pumps for driving multi-electron catalysts. A photodeposition method has been introduced for the spatially directed assembly of nanoparticle catalysts for selective coupling to the donor or acceptor metal of the light absorber. For CO 2 reduction, a Cu oxide cluster is coupled to the Zr center of a ZrOCo light absorber, while coupling of an Ir nanoparticle catalyst for water oxidation to the Co donor affords closing of the photosynthetic cycle of CO 2 conversion by H 2 O to CO and O 2 . Optical, vibrational, and X-ray spectroscopy provide detailed structural knowledge of the polynuclear assemblies. Time resolved visible and rapid-scan FT-IR studies reveal charge transfer mechanisms and transient surface intermediates under photocatalytic conditions for guiding performance improvements. Separation of the water oxidation and carbon dioxide reduction half reactions by a membrane is essential for efficient photoreduction of CO 2 by H 2 O to liquid fuel products. A concept of a macroscale artificial photosystem consisting of arrays of Co oxide–silica core–shell nanotubes is introduced in which each tube operates as a complete, independent photosynthetic unit with built-in membrane separation. The ultrathin amorphous silica shell with embedded molecular wires functions as a proton conducting, molecule impermeable membrane. Photoelectrochemical and transient optical measurements confirm tight control of charge transport through the membrane by the orbital energetics of the wire molecules. Finally, hierarchical arrangement of the components is accomplished by a combination of photodeposition, controlled anchoring, and atomic layer deposition methods.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Grain Boundary Engineering for Achieving High Thermoelectric Performance in n-Type Skutterudites

Grain or phase boundaries play a critical role in the carrier and phonon transport in bulk thermoelectric materials. Previous investigations about controlling boundaries primarily focused on the reducing grain size or forming nanoinclusions. Herein, liquid phase compaction method is first used to fabricate the Yb–filled CoSb 3 with excess Sb content, which shows the typical feature of low–angle grain boundaries with dense dislocation arrays. Seebeck coefficients show a dramatic increase via energy filtering effect through dislocation arrays with little deterioration on the carrier mobility, which significantly enhances the power factor over a broad temperature range with a high room–temperature value around 47 μW cm –2 K –1 . Simultaneously, the lattice thermal conductivity could be further suppressed via scattering phonons via dense dislocation scattering. As a result, the highest average figure of merit ZT of ≈1.08 from 300 to 850 K could be realized, comparable to the best reported result of single or triple–filled Skutterudites. Furthermore, this work clearly points out that low–angle grain boundaries fabricated by liquid phase compaction method could concurrently optimize the electrical and thermal transport properties leading to an obvious enhancement of both power factor and ZT .

36 MATERIALS SCIENCE↗
DOE OSTI2021

Masking of photovoltaic system performance problems by inverter clipping and other design and operational practices

We describe how performance problems can be “masked,” or not readily evident by several causes: by photovoltaic (PV) system configuration (such as the size of the PV array capacity relative to the size of the inverter and the resultant clipped operating mode); by instrumentation design, installation, and maintenance (such as a misaligned or dirty pyranometer); by contract clauses (when operational availability is transformed to contractual availability, which excludes many factors); and by identified management and operational practices (such as reporting on a portfolio of plants rather than individually). A simple method based on a duration curve is introduced to overcome shortcomings of Performance Ratio based on nameplate capacity and Performance Index based on hourly simulation when quantifying masking effects, and inverter clipping and pyranometer soiling are presented as two examples of the new method. With a better understanding of the non-transparency of masking issues, stakeholders can better interpret performance data and deliver improved AC and DC plant conditions through PV system operation and maintenance (O&M) for improved performance, reduced O&M costs, and a more consistently delivered, and reduced, levelized cost of energy (LCOE).

14 SOLAR ENERGY↗
DOE OSTI2022

Computational Methods to Characterize Panel Loading Conditions for Accelerated Testing

Panel cracking and degradation due to wind loading are known to have a detrimental effect on power output. Recreating these damaging conditions in a controlled experimental setting requires an understanding of the loads being generated at the panel surface as a function of both wind speed, wind direction, and panel orientation. To better understand these relationships, a computational fluid dynamics (CFD) simulation package was constructed using an open-source Python library for solving partial differential equations with the finite element method. This CFD package allows the simulated wind speed and panel orientation of a multi-panel array to be easily changed and provides the capability to measure the traction forces at discrete points along the sun-facing and ground-facing surface of an interior panel residing in the wake of one or more upstream panels. A parameter exploration was performed in which the panel angle was varied in even increments from -70 deg to 70 deg and the wind speed was varied from 2 to 30 m/s. During post processing, the measured traction along the panel surface was averaged spatially and interpreted as a time-varying signal, where further processing of this signal yielded the root mean square amplitude and a characteristic frequency associated with the loading. This study found that higher wind speeds are generally associated with increased amplitude of loading and that the panel orientation angle can significantly exacerbate or mitigate this loading. These outcomes are presented along with current work on higher-fidelity verification simulations and recommendations for performing accelerated experimental testing.

loading↗
DOE OSTI2017

Engineering the Thermoelectric Transport in Half-Heusler Materials through a Bottom-Up Nanostructure Synthesis

Half-Heusler (HH) alloys are among the best promising thermoelectric (TE) materials applicable for the middle-to-high temperature power generation. Despite of the large thermoelectric power factor and decent figure-of-merit ZT (≈1), their broad applications and enhancement on TE performance are limited by the high intrinsic lattice thermal conductivity (κ L ) due to insufficiencies of phonon scattering mechanisms, and the fewer powerful strategies associated with the microstructural engineering for HH materials. This study reports a bottom-up nanostructure synthesis approach for these HH materials based on the displacement reaction between metal chlorides/bromides and magnesium (or lithium), followed by vacuum-assisted spark plasma sintering process. The samples are featured with dense dislocation arrays at the grain boundaries, leading to a minimum κ L of ≈1 W m -1 K -1 at 900 K and one of the highest ZT (≈1) and predicted η (≈11%) for n-type Hf 0.25 Zr 0.75 NiSn 0.97 Sb 0.03 . Further manipulation on the dislocation defects at the grain boundaries of p-type Nb 0.8 Ti 0.2 FeSb leads to enhanced maximum power factor of 47 × 10 -4 W m -1 K -2 and the predicted η of ≈7.5%. Moreover, vanadium substitution in FeNb 0.56 V 0.24 Ti 0.2 Sb significantly promotes the η to ≈11%. This strategy can be extended to a broad range of advanced alloys and compounds for improved properties.

36 MATERIALS SCIENCE↗
DOE OSTI2018

A methodology to analyze photovoltaic tracker uptime

A metric is developed to analyze the daily performance of single-axis photovoltaic (PV) trackers. The metric relies on comparing correlations between the daily time series of the PV power output and an array of simulated plane-of-array irradiances for the given day. Mathematical thresholds and a logic sequence are presented, so the daily tracking metric can be applied in an automated fashion on large-scale PV systems. The results of applying the metric are visually examined against the time series of the power output data for a large number of days and for various systems. The visual inspection results suggest that overall, the algorithm is accurate in identifying stuck or functioning trackers on clear-sky days. Visual inspection also shows that there are days that are not classified by the metric where the power output data may be sufficient to identify a stuck tracker. Based on the daily tracking metric, uptime results are calculated for 83 different inverters at 34 PV sites. The mean tracker uptime is calculated at 99% based on 2 different calculation methods. The daily tracking metric clearly has limitations, but as there is no existing metrics in the literature, it provides a valuable tool for flagging stuck trackers.

14 SOLAR ENERGY↗
DOE OSTI2018

Multilayer Quantum Well–Dot InGaAs Heterostructures in GaAs-based Photovoltaic Converters

GaAs photovoltaic converters containing quantum well-dot (QWD) heterostructures are studied. The QWD properties are intermediate between those of quantum wells (QWs) and quantum dots. The QWDs are obtained by the epitaxial deposition of In{sub 0.4}Ga{sub 0.6}As with a nominal thickness of 8 single layers by metal-organic vapor phase epitaxy. QWDs are a dense array of elastically strained islands that localize carriers in three directions and are formed by a local increase in the indium concentration and/ or InGaAs-layer thickness. There are two quantum-well levels of varied nature in structures with QWDs. These levels are manifested in the spectral characteristics of GaAs photovoltaic converters. A short-wavelength peak with a maximum at around 935 nm is associated with absorption in the residual QW, and the long-wavelength peak (1015–1030 nm) is due to absorption in the QWDs. Investigation by transmission electron microscopy demonstrates that an increase in the number of InGaAs layers leads to stronger elastic stresses, which, in turn, increases the carrier confinement energy in the QWDs and lead to a corresponding long-wavelength shift of the internal quantum efficiency spectrum.

36 MATERIALS SCIENCE↗